CN108570554B - Adhesive, preparation method and application thereof - Google Patents

Adhesive, preparation method and application thereof Download PDF

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Publication number
CN108570554B
CN108570554B CN201810618119.3A CN201810618119A CN108570554B CN 108570554 B CN108570554 B CN 108570554B CN 201810618119 A CN201810618119 A CN 201810618119A CN 108570554 B CN108570554 B CN 108570554B
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binder
adhesive
powder
electric furnace
titanium slag
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CN108570554A (en
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秦洁
刘功国
齐建玲
李占军
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Pangang Group Panzhihua Iron and Steel Research Institute Co Ltd
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Pangang Group Panzhihua Iron and Steel Research Institute Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00Preliminary treatment of ores or scrap
    • C22B1/14Agglomerating; Briquetting; Binding; Granulating
    • C22B1/24Binding; Briquetting ; Granulating
    • C22B1/242Binding; Briquetting ; Granulating with binders

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
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  • General Life Sciences & Earth Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention provides a binder which is prepared from the following raw materials: 20-70 wt% of dust removed from a titanium slag electric furnace; 20-70 wt% of plant adhesive; 1 to 10 weight percent of polyacrylamide. The invention also provides a method for agglomerating the powder resources, which comprises the following steps: a) dry-mixing the powder resource and the binder, and adding water for wet mixing to obtain a mixture; the adhesive is the adhesive in the technical scheme or the adhesive prepared by the preparation method in the technical scheme; b) granulating and forming the mixture obtained in the step a) to obtain a formed briquette. Compared with the prior art, the binder provided by the invention takes the titanium slag electric furnace dust removal ash as a main raw material, is matched with other components with specific contents, and has higher resource utilization rate and lower cost; meanwhile, the binder is suitable for granulating and molding of powder resources, and has good molding rate and strength, so that the powder resources are fully utilized.

Description

Adhesive, preparation method and application thereof
Technical Field
The invention relates to the technical field of granulation molding, in particular to a binder and a preparation method and application thereof.
Background
The method for producing high titanium slag by smelting titanium concentrate in an electric furnace is a main method for treating titanium raw materials, and is characterized in that the existing titanium slag electric furnace of a titanium smelting plant of a steel share company is 3, 25 ten thousand tons of titanium concentrate are treated annually, and 14 ten thousand tons of high titanium slag are produced annually.
In actual production, because the titanium concentrate has an excessively fine particle size (the proportion of particles below 200 meshes is more than 75%), fine particles are easily sucked into a flue by an air suction system and enter a dust removal system in the smelting process in a furnace to form dust removal ash, 1.5 million tons of dust removal ash are generated in a titanium smelting plant every year, the raw material loss is large, a certain amount of expenditure is required for processing the dust removal ash, the economic loss is caused, and the production cost is increased.
On the other hand, the titanium concentrate powder is directly smelted in the electric furnace, so that fine powder enters a flue along with furnace gas, the flue and a furnace gas treatment system are frequently blocked, and production stop and cleaning are required, so that the smooth operation of production is influenced, and the production efficiency is reduced; in addition, fine powders are very prone to dust emission during transportation, resulting in deterioration of production environment.
In order to reduce the loss of the titanium concentrate powder and promote the smooth smelting of the electric furnace, the titanium concentrate is granulated and then enters the furnace, so that the blockage of a dust removal pipeline can be relieved to a certain extent and the generation amount of dust removal ash can be reduced.
Similarly, a large amount of by-products such as dust, etc., such as enriched sludge, converter fly ash, etc., are generated inside the steel plant. The dust is rich in iron, so the dust is also a precious secondary resource, and the utilization of the resource is an important way for improving the utilization efficiency of the resource, reducing the cost and improving the efficiency. At present, secondary resources such as enriched sludge rich in iron, converter fly ash and the like are mostly used as vanadium extraction cooling agents and converter slagging agents after agglomeration,
in summary, since the secondary resources are mostly powder materials, the amount of dust generated directly is large, and the air permeability is affected, the prior art needs to use the powder materials after agglomeration; however, the cost of the caking agent for agglomeration is high, and the large-scale utilization of secondary resources is restricted to a certain extent.
Disclosure of Invention
In view of the above, the invention aims to provide a binder, a preparation method and an application thereof, and the binder provided by the invention takes titanium slag electric furnace dust removal ash as a main raw material, has higher resource utilization rate and lower cost, and is suitable for granulation molding of powder resources.
The invention provides a binder which is prepared from the following raw materials:
20-70 wt% of dust removed from a titanium slag electric furnace;
20-70 wt% of plant adhesive;
1 to 10 weight percent of polyacrylamide.
Preferably, the chemical composition of the titanium slag electric furnace dust removal ash comprises: fe2O3TiO content not less than 20 percent2The content is more than or equal to 20 percent, and SiO is2The content is more than or equal to 10 percent.
Preferably, the plant adhesive comprises one or more of starch glue, bean glue, rosin glue, carboxymethyl cellulose glue and lignin glue.
The invention also provides a preparation method of the adhesive, which comprises the following steps:
mixing the titanium slag electric furnace dust removal ash, the plant adhesive and the polyacrylamide to obtain the binder.
The invention also provides a method for agglomerating the powder resources, which comprises the following steps:
a) dry-mixing the powder resource and the binder, and adding water for wet mixing to obtain a mixture; the adhesive is the adhesive in the technical scheme or the adhesive prepared by the preparation method in the technical scheme;
b) granulating and forming the mixture obtained in the step a) to obtain a formed briquette.
Preferably, the powder resources in step a) are selected from titanium concentrate, enriched sludge or converter fly ash.
Preferably, the mass ratio of the powder resources to the binder in the step a) is 100: (2-6).
Preferably, the adding amount of the water in the step a) is 6-12% of the total mass of the powder resources and the binder.
Preferably, the granulation molding mode in the step b) is rolling molding or compression molding.
Preferably, the pressure for press molding is 10 to 20 MPa.
The invention provides a binder which is prepared from the following raw materials: 20-70 wt% of dust removed from a titanium slag electric furnace; 20-70 wt% of plant adhesive; 1 to 10 weight percent of polyacrylamide. The invention also provides a method for agglomerating the powder resources, which comprises the following steps: a) dry-mixing the powder resource and the binder, and adding water for wet mixing to obtain a mixture; the adhesive is the adhesive in the technical scheme or the adhesive prepared by the preparation method in the technical scheme; b) granulating and forming the mixture obtained in the step a) to obtain a formed briquette. Compared with the prior art, the binder provided by the invention takes the titanium slag electric furnace dust removal ash as a main raw material, is matched with other components with specific contents, and has higher resource utilization rate and lower cost; meanwhile, the binder is suitable for granulating and molding of powder resources, and has good molding rate and strength, so that the powder resources are fully utilized.
In addition, the binder solves the problems of production cost increase caused by powder material stacking and adverse influence on the environment, has obvious comprehensive benefit and has wide application prospect.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The invention provides a binder which is prepared from the following raw materials:
20-70 wt% of dust removed from a titanium slag electric furnace;
20-70 wt% of plant adhesive;
1 to 10 weight percent of polyacrylamide.
In the invention, the titanium slag electric furnace dedusting ash is formed by pumping titanium concentrate fine particles into a flue by an air draft system and entering a dedusting system in the smelting process of the titanium slag electric furnace; the present invention is not particularly limited in its origin. In the invention, the chemical composition of the titanium slag electric furnace dust removal ash preferably comprises: fe2O3TiO content not less than 20 percent2The content is more than or equal to 20 percent, and SiO is2The content is more than or equal to 10 percent; more preferably: fe2O3TiO content not less than 20 percent2The content is more than or equal to 20 percent, and SiO is2The content is more than or equal to 20 percent.
In the invention, the binder comprises 20-70 wt% of titanium slag electric furnace dust removal ash, and preferably 30-70 wt%. In a preferred embodiment of the invention, the binder comprises 70 wt% of titanium slag electric furnace dust; in another preferred embodiment of the invention, the binder comprises 30 wt% of titanium slag electric furnace dust; in another preferred embodiment of the invention, the binder comprises 45 wt% of titanium slag electric furnace dust.
In the present invention, the plant adhesive preferably includes one or more of starch gum, bean gum, rosin gum, carboxymethyl cellulose gum and lignin gum, and more preferably starch gum and/or carboxymethyl cellulose gum. The source of the plant adhesive is not particularly limited in the present invention, and commercially available products of the above starch gum, bean gum, rosin gum, carboxymethyl cellulose gum and lignin gum, which are well known to those skilled in the art, may be used.
In the invention, the binder comprises 20 wt% -70 wt% of plant adhesive, preferably 29 wt% -65 wt%. In a preferred embodiment of the invention, the binder comprises 29 wt% of a vegetable adhesive; in another preferred embodiment of the present invention, the binder comprises 65 wt% of a vegetable adhesive; in another preferred embodiment of the present invention, the binder comprises 50 wt% of the plant adhesive.
The source of the polyacrylamide is not particularly limited in the present invention, and commercially available products known to those skilled in the art may be used. In the present invention, the binder comprises 1 wt% to 10 wt% of polyacrylamide, preferably 1 wt% to 5 wt%. In a preferred embodiment of the invention, the binder comprises 1 wt% polyacrylamide; in another preferred embodiment of the invention, the binder comprises 5 wt% polyacrylamide.
The invention also provides a preparation method of the adhesive, which comprises the following steps:
mixing the titanium slag electric furnace dust removal ash, the plant adhesive and the polyacrylamide to obtain the binder. The mixing mode is not particularly limited, and the technical scheme of mechanical stirring or manual stirring which is well known by the technical personnel in the field can be adopted; aims to uniformly mix the titanium slag electric furnace dust removal ash, the plant adhesive and the polyacrylamide.
The binder provided by the invention takes the titanium slag electric furnace dust as a main raw material and is matched with other components with specific contents, so that on one hand, the titanium slag electric furnace dust is recycled, the resource utilization rate is higher, on the other hand, the cost of the binder for forming can be reduced, the large-scale utilization rate of powder resources is improved, the economic benefit is obvious, and the application prospect is wide.
The invention also provides a method for agglomerating the powder resources, which comprises the following steps:
a) dry-mixing the powder resource and the binder, and adding water for wet mixing to obtain a mixture; the adhesive is the adhesive in the technical scheme or the adhesive prepared by the preparation method in the technical scheme;
b) granulating and forming the mixture obtained in the step a) to obtain a formed briquette.
The invention firstly dry-mixes the powder material resource and the binder, and then adds water to wet-mix to obtain the mixture. In the invention, the powder resource is preferably selected from titanium concentrate, enriched sludge or converter fly ash.
In a preferred embodiment of the invention, the powder resource is titanium concentrate; the titanium concentrate is a superfine-particle-grade titanium concentrate, the particle size of the titanium concentrate is fine, and the proportion of particles below 200 meshes reaches more than 75%.
In another preferred embodiment of the invention, the powder resource is enriched sludge; the enriched sludge is enriched sludge of an iron and steel plant, is a secondary resource of the iron and steel plant, and comprises enriched sludge of a new material area and enriched sludge of an old material area, wherein the mass ratio of the enriched sludge of the new material area to the enriched sludge of the old material area is preferably 1: 1.
in another preferred embodiment of the invention, the powder resource is converter fly ash; the converter fly ash is a secondary resource of an iron and steel plant.
In the present invention, the mass ratio of the powder resource to the binder is preferably 100: (2-6), more preferably 100: (3-5).
The dry blending method is not particularly limited in the present invention, and a stirring technical scheme well known to those skilled in the art can be adopted. In the present invention, the dry mixing time is preferably 1min to 5min, more preferably 2min to 3 min.
In the invention, the adding amount of the water is preferably 6-12%, more preferably 7-11% of the total mass of the powder resources and the binder.
The wet mixing method is not particularly limited, and the stirring technical scheme well known to those skilled in the art can be adopted. In the invention, the rotation speed of the wet mixing is 30 r/min-120 r/min; the time for the wet mixing is preferably 2min to 5min, more preferably 3 min.
After the mixture is obtained, the obtained mixture is granulated and formed to obtain a formed briquette. In the present invention, the granulation molding is preferably roll molding or press molding.
In a preferred embodiment of the invention, the powder resource is titanium concentrate, and the granulation molding mode is rolling molding to obtain titanium concentrate agglomerates. The apparatus for roll forming is not particularly limited in the present invention, and a rotary drum well known to those skilled in the art is used. The obtained titanium concentrate agglomeration is dried and then is smelted in a titanium slag electric furnace, so that the further application of the agglomeration is realized.
In another preferred embodiment of the invention, the powder resource is enriched sludge, and the granulating and forming mode is compression forming to obtain enriched sludge agglomerates, so that further application of secondary resources in iron and steel plants is realized. The equipment for the press forming is not particularly limited, and a ball press known to those skilled in the art is used. In the present invention, the pressure for the press molding is preferably 10 to 20MPa, more preferably 10 to 15 MPa.
In another preferred embodiment of the invention, the powder resource is converter fly ash, and the granulation molding mode is compression molding to obtain converter fly ash agglomerates, thereby realizing further application of secondary resources in iron and steel plants. The equipment for the press forming is not particularly limited, and a ball press known to those skilled in the art is used. In the present invention, the pressure for the press molding is preferably 10 to 20MPa, more preferably 10 to 15 MPa.
The binder used in the agglomeration method of powder resources provided by the invention is the binder described in the technical scheme or the binder prepared by the preparation method described in the technical scheme, and the binder is suitable for granulation and molding of the powder resources and has better molding rate and strength, thereby realizing full utilization of the powder resources.
The invention provides a binder which is prepared from the following raw materials: 20-70 wt% of dust removed from a titanium slag electric furnace; 20-70 wt% of plant adhesive; 1 to 10 weight percent of polyacrylamide. The invention also provides a method for agglomerating the powder resources, which comprises the following steps: a) dry-mixing the powder resource and the binder, and adding water for wet mixing to obtain a mixture; the adhesive is the adhesive in the technical scheme or the adhesive prepared by the preparation method in the technical scheme; b) granulating and forming the mixture obtained in the step a) to obtain a formed briquette. Compared with the prior art, the binder provided by the invention takes the titanium slag electric furnace dust removal ash as a main raw material, is matched with other components with specific contents, and has higher resource utilization rate and lower cost; meanwhile, the binder is suitable for granulating and molding of powder resources, and has good molding rate and strength, so that the powder resources are fully utilized.
In addition, the binder solves the problems of production cost increase caused by powder material stacking and adverse influence on the environment, has obvious comprehensive benefit and has wide application prospect.
In order to further illustrate the present invention, the following detailed description of the technical solutions provided by the present invention is provided with reference to examples. The main components and contents of the titanium slag electric furnace dust removal ash used in the following examples of the invention are shown in table 1; other raw materials are all commercial products.
TABLE 1 main components and contents (mass%/%) of dust removed from titanium slag electric furnace used in examples of the present invention
Fe2O3 FeO TiO2 SiO2 CaO MgO Al2O3
28.85 3.41 24.75 22.90 1.12 12.57 2.09
Example 1
(1) Preparing a binder:
the materials are prepared according to the following mass percentages: dust removal of a titanium slag electric furnace: starch glue: polyacrylamide 70%: 29%: 1 percent; and uniformly mixing the titanium slag electric furnace dust removal ash, the starch glue and the polyacrylamide under the stirring condition to obtain the binder.
(2) Agglomeration of fine-particle-fraction titanium concentrate:
the main particle size distribution of the fine fraction titanium concentrate used in example 1 is shown in table 2;
table 2 main particle size distribution of fine fraction titanium concentrate used in example 1
Size fraction 200 mesh at minus 325 mesh
Ratio/%) 79.24 46.32
Mixing the superfine fraction titanium concentrate and the binder obtained in the step (1) according to a mass ratio of 100: 5, mixing materials, and dry-mixing for 3min to obtain a mixed material; then adding water accounting for 11% of the total mass of the mixture into the obtained mixture, and mixing for 3min under strong stirring at the rotating speed of 90r/min to obtain a mixture; finally, granulating and forming the obtained mixture by adopting a rotary drum device with the inner diameter of 2.0m, the length of 6m and the inclination of 0.04 (the mixture is added from the end head, rolls on the inner wall of the drum along with the rotary motion of the drum body and gradually grows into particles), so as to obtain formed agglomerates; the particle diameter of the shaped agglomerate is about 5 mm.
And drying the obtained formed blocks, and smelting in a titanium slag electric furnace.
Through detection, the forming rate of the binder provided by the embodiment 1 of the invention on the titanium concentrate with the superfine fraction is 90%, and the falling strength of the obtained formed agglomeration is 2 times/m.
Example 2
(1) Preparing a binder:
the materials are prepared according to the following mass percentages: dust removal of a titanium slag electric furnace: carboxymethyl cellulose gum: polyacrylamide 30%: 65%: 5 percent; and uniformly mixing the titanium slag electric furnace dust removal ash, the carboxymethyl cellulose gum and the polyacrylamide under the stirring condition to obtain the binder.
(2) Steel plant enrichment sludge agglomeration:
the main components and contents of the steel plant enriched sludge used in example 2 are shown in table 3, and the particle size composition thereof is shown in table 4;
TABLE 3 main components and contents (mass%/%) of the steel works enriched sludge used in example 2
Source of raw materials MFe FeO CaO SiO2
New material area 39.44 24.04 8.30 10.49
Old material area 54.56 25.97 4.21 4.57
TABLE 4 composition of particle size of enriched sludge from iron and steel works used in example 2
Source of raw materials Is more than 60 meshes 100 to 60 mesh 120~100Eyes of a user 250 to 120 mesh < 250 mesh Total up to
New material area 30.08 37.73 7.46 22.22 2.51 100.00
Old material area 26.18 26.55 5.35 39.01 2.91 100.00
And (2) mixing the new material area enriched sludge and the old material area enriched sludge with the binder obtained in the step (1) according to the mass ratio of 50: 50: 3, mixing the materials, and performing dry mixing for 2min to obtain a mixed material; then adding water accounting for 7% of the total mass of the mixture into the obtained mixture, and carrying out wet mixing for 3min under strong stirring at the rotating speed of 90r/min to obtain a mixture; and finally, granulating and forming the obtained mixture by a ball press with the pressure of 10MPa to obtain a formed briquette.
Through detection, the forming rate of the binder provided by the embodiment 2 of the invention to the enriched sludge of the steel plant is more than or equal to 85%, and the falling strength of the obtained formed agglomerate is 4 times/m.
Example 3
(1) Preparing a binder:
the materials are prepared according to the following mass percentages: dust removal of a titanium slag electric furnace: carboxymethyl cellulose gum: polyacrylamide 45%: 50%: 5 percent; and uniformly mixing the titanium slag electric furnace dust removal ash, the carboxymethyl cellulose gum and the polyacrylamide under the stirring condition to obtain the binder.
(2) Converter fly ash agglomeration:
the main components and contents of the converter fly ash used in example 3 are shown in table 5;
TABLE 5 main components and contents (mass%/%) of converter fly ash used in example 3
Fe2O3 FeO SiO2 CaO MnO
46.35 10.55 5.37 14.13 1.95
Mixing the converter fly ash and the binder obtained in the step (1) according to a mass ratio of 100: 5, mixing materials, and dry-mixing for 2min to obtain a mixed material; then adding water accounting for 8% of the total mass of the mixture into the obtained mixture, and carrying out wet mixing for 3min under strong stirring at the rotating speed of 90r/min to obtain a mixture; and finally, granulating and forming the obtained mixture by adopting a ball press, wherein the pressure is 15MPa, and obtaining a formed briquette.
Through detection, the forming rate of the binder provided by the embodiment 3 of the invention on converter fly ash is more than or equal to 85%, and the falling strength of the obtained formed agglomerate is 4 times/m.
The previous description of the disclosed embodiments is provided to enable any person skilled in the art to make or use the present invention. Various modifications to these embodiments will be readily apparent to those skilled in the art, and the generic principles defined herein may be applied to other embodiments without departing from the spirit or scope of the invention. Thus, the present invention is not intended to be limited to the embodiments shown herein but is to be accorded the widest scope consistent with the principles and novel features disclosed herein.

Claims (9)

1. The adhesive is prepared from the following raw materials:
30-70 wt% of dust removed from a titanium slag electric furnace;
29-65 wt% of plant adhesive;
1-5 wt% of polyacrylamide;
the chemical components of the titanium slag electric furnace dust removal ash comprise: fe2O3TiO content not less than 20 percent2The content is more than or equal to 20 percent, and SiO is2The content is more than or equal to 20 percent.
2. The binder of claim 1 wherein the vegetable adhesive comprises one or more of a starch gum, a bean gum, a rosin gum, a carboxymethyl cellulose gum, and a lignin gum.
3. A method for preparing the binder of any one of claims 1 to 2, comprising the steps of:
mixing the titanium slag electric furnace dust removal ash, the plant adhesive and the polyacrylamide to obtain the binder.
4. A method for agglomerating powder resources comprises the following steps:
a) dry-mixing the powder resource and the binder, and adding water for wet mixing to obtain a mixture; the adhesive is prepared by the adhesive of any one of claims 1-2 or the preparation method of claim 3;
b) granulating and forming the mixture obtained in the step a) to obtain a formed briquette.
5. The agglomeration method according to claim 4, wherein the powder resource in step a) is selected from titanium concentrate, enriched sludge or converter fly ash.
6. The agglomeration method according to claim 4, wherein the mass ratio of the powder resource to the binder in step a) is 100: (2-6).
7. The agglomeration method according to claim 4, wherein the amount of the water added in step a) is 6% to 12% of the total mass of the powder resources and the binder.
8. The agglomeration method according to claim 4, wherein the granulation molding in step b) is roll molding or press molding.
9. The agglomeration method according to claim 8, wherein the pressure of the press molding is 10 to 20 MPa.
CN201810618119.3A 2018-06-15 2018-06-15 Adhesive, preparation method and application thereof Active CN108570554B (en)

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Publication number Priority date Publication date Assignee Title
CN109112297B (en) * 2018-10-19 2020-08-28 攀钢集团攀枝花钢铁研究院有限公司 Binder for forming converter enriched sludge and converter enriched sludge forming method
CN109680144A (en) * 2018-12-18 2019-04-26 攀钢集团攀枝花钢铁研究院有限公司 A kind of ferriferous oxide pelletizing and its preparation method and application
CN110156019A (en) * 2019-06-21 2019-08-23 攀钢集团攀枝花钢铁研究院有限公司 It is used to prepare the electric arc furnaces and titanium carbide slag preparation method of titanium carbide slag

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JP2002256350A (en) * 2001-03-01 2002-09-11 Aica Kogyo Co Ltd Binder utilizing industrial waste product and method for materializing shapeless raw material using the binder
CN103898319A (en) * 2012-12-31 2014-07-02 攀钢集团钛业有限责任公司 Method for preparing titanium concentrate pellet
CN107699687A (en) * 2017-10-16 2018-02-16 攀钢集团攀枝花钢铁研究院有限公司 The method of granulating of ilmenite concentrate and ilmenite concentrate binding agent

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Publication number Priority date Publication date Assignee Title
JPH0635623B2 (en) * 1989-04-12 1994-05-11 日本磁力選鉱株式会社 How to make carbon powder
JP2002256350A (en) * 2001-03-01 2002-09-11 Aica Kogyo Co Ltd Binder utilizing industrial waste product and method for materializing shapeless raw material using the binder
CN103898319A (en) * 2012-12-31 2014-07-02 攀钢集团钛业有限责任公司 Method for preparing titanium concentrate pellet
CN107699687A (en) * 2017-10-16 2018-02-16 攀钢集团攀枝花钢铁研究院有限公司 The method of granulating of ilmenite concentrate and ilmenite concentrate binding agent

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