CN108570261A - A kind of two-component modified polyester resin thermmohardening type ink - Google Patents
A kind of two-component modified polyester resin thermmohardening type ink Download PDFInfo
- Publication number
- CN108570261A CN108570261A CN201710160000.1A CN201710160000A CN108570261A CN 108570261 A CN108570261 A CN 108570261A CN 201710160000 A CN201710160000 A CN 201710160000A CN 108570261 A CN108570261 A CN 108570261A
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- CN
- China
- Prior art keywords
- polyester resin
- concentration range
- type ink
- modified polyester
- black
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/104—Polyesters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of two-component modified polyester resin thermmohardening type ink, it is up in vain with BM 690 including BM 607 because value is black, the mixture that the BM 607 is made of polyester resin 20 50%, propylene glycol methyl ether acetate 2 10%, different boiling that ketone 25 35%, titanium dioxide 40 50%, the auxiliary agent 2 5% of concentration range (percentage) setting in vain；The BM 690 is up to because being worth the black mixture being made of polyester resin 20 50%, propylene glycol methyl ether acetate 2 10%, different boiling that ketone 25 35%, carbon black 20 30%, the auxiliary agent 2 5% of concentration range (percentage) setting, its covering power is high, printing is good, suitable for the printing of glass cover-plate, the layer of ink after solidification has the characteristics such as excellent adherence, endurance and water boiling resistance, high surface impedance, high surface tension.
Description
Technical field
The present invention relates to a kind of technical field of ink, more particularly to a kind of two-component modified polyester resin thermmohardening type oil
Ink.
Background technology
The ink of the present invention is mainly used for the printing of LED, touch panel, and silk-screen technology runs through entire glass industry, and
Very important effect is played wherein.So as one of the key areas in silk-screen industry, glass silk screen printing is in silk-screen row
The how important role of performer in industryGlass cross printing technology brief introduction glass cross prints, and is exactly to utilize screen printing forme,
Using glass glaze, decorative print is carried out on glassware.Glass glaze is also referred to as glass ink, glass print material, it be by
The paste print material that colouring matter, link stuff mix together.Colouring matter is made of inorganic pigment, high low melting point fluxing agent.Printing
Glassware afterwards will be placed in the electric baking equipment of oven class, carry out force drying, the glaze being printed onto on glass surface
It can just be fixedly arranged on glass, form polychromatic decoration pattern.If by silk-screen and other processing methods and if using, can obtain
To more preferably effect.Such as glass surface is processed before printing or after printing using the methods of polishing, engraving, corrosion
Processing, can doubly improve printing effect.
The application of the application field wire mark plate glass of glass cross printing technology and its market prospects wire mark plate glass
It is widely used in each corner of people's life：You can be in display case, space subregion, facade beautification, vapour
The place such as vehicle windshield and mosaic glass easily finds their figure.Simultaneously they be also widely used in furniture decoration
And in game tool and unnumbered decoration and artistic creation.Screen painting also becomes outside glass manufacture therewith, it also can be used
In temporary cover glass surface without areas, or in auxiliary agents such as the subregion of glass surface printing preservatives, make it not
By etching or frosted process is influenced.Relatively, acceptable directly wire mark ink special, produces etching or frosted finish effect.
Currently, the shielding of known existing product, dyne value, water droplet angle, printing is all difficult to reach client's most up-to-date techniques
It is required that (such as dyne value, an influence of the water droplet angle to the film coating process of touch panel, water droplet angle is less than 40 meetings less than 90 degree with a dyne value
Cause that the touch panel hydrophily of glue, levelability in attaching process are bad and it is excessively high to be inverted the fraction defective of product.Shielding
Because influencing to produce on will produce halation phenomenon when light in product >=5 or more measuring survey OD values with optical concentration
The beauty of product).
Invention content
Problem to be solved by this invention be to provide a kind of high whiteness, high covering power, good levelability, up to because value,
Ultralow water droplet angle, high impedance a kind of two-component modified polyester resin thermmohardening type ink.
In order to achieve the above objectives, technical solution is used by the present invention solves above-mentioned technical problem：A kind of two-component changes
Property polyester resin thermmohardening type ink, including BM 607 in vain and BM 690 up to because value it is black,
The BM 607 is in vain by the polyester resin 20-50% of concentration range (percentage) setting, propylene glycol methyl ether acetate
The mixture of 2-10%, different boiling that ketone 25-35%, titanium dioxide 40-50%, auxiliary agent 2-5% compositions；
The BM 690 is up to because being worth the black polyester resin 20-50% being arranged by concentration range (percentage), propylene glycol first
The mixture of ether acetate 2-10%, different boiling that ketone 25-35%, carbon black 20-30%, auxiliary agent 2-5% compositions.
Further, your ketone of the different boiling is diethylene glycol monoethyl ether acetate.
Further, the auxiliary agent is composed of thixotropic agent, dispersant, levelling agent and defrother.
Further, the concentration range ＜ 3% of the thixotropic agent, the concentration range 5~10% of dispersant, the concentration of levelling agent
The concentration range ＜ 3% of range L T.LT.LT 3% and defrother.
Compared with prior art, technical scheme of the present invention has the following advantages that：Its covering power is high, printing is good, is applicable in
In the printing of glass cover-plate, the layer of ink after solidification has excellent adherence, endurance and water boiling resistance, high surface impedance, high table
The characteristics such as face tension；The constituent white wherein described BM 607 has the spies such as high whiteness, high covering power, good levelability
Property, the BM 690 up to has high covering power, up to because of characteristics such as value, ultralow water droplet angle, high impedances because value is black.
Specific implementation mode
Following example is described in further detail the specific implementation mode of the present invention.Following embodiment is for illustrating
The present invention, but it is not limited to the scope of the present invention.
A kind of two-component modified polyester resin thermmohardening type ink that the present embodiment is provided, including BM 607 is white and BM
690 is up to black because being worth, and the BM 607 is in vain by the polyester resin 20-50% of concentration range (percentage) setting, propylene glycol monomethyl ether
The mixture of acetate 2-10%, different boiling that ketone 25-35%, titanium dioxide 40-50%, auxiliary agent 2-5% compositions；The BM 690 is high
Dyne value it is black by concentration range (percentage) setting polyester resin 20-50%, propylene glycol methyl ether acetate 2-10%, different boiling you
The mixture of ketone 25-35%, carbon black 20-30%, auxiliary agent 2-5% compositions, your ketone of the different boiling is diethylene glycol monoethyl ether vinegar
Acid esters, the auxiliary agent are composed of thixotropic agent, dispersant, levelling agent and defrother, the concentration range ＜ of the thixotropic agent
3%, the concentration range 5~10% of dispersant, the concentration range ＜ 3% of levelling agent and defrother concentration range ＜ 3%.
When ink is used for the printing of glass product, first by BM 607 it is white in by percentage BM-H2 hardening is added
Agent: AD0016 reinforcing agents: solvent=100 S-880: 10: 3: 2；BM 690 up to because be worth it is black in by percentage be added BM-H
Curing agent: AD0016 reinforcing agents: solvent=100 S-880: 10: 3: 2；Then mixed proportion is dried on glassware,
Its temperature dried is generally 150 DEG C, and the dry time is generally 30 minutes.(solvent S-880 ratios among the above can be by printing
Need be properly added its accounting section be 2-5.)
When need test b M 607 it is white/BM 690 up to because of the black characteristic effect of value, the printing oil proportion used：BM
607 is white: BM-H2 curing agents: AD0016 reinforcing agents: solvent=100 S-880: 10: 3: 4；BM 690 is up to black because being worth: BM-H is hard
Agent: AD0016 reinforcing agents: solvent=100 S-860: 10: 3: 5；Then cured on 150 DEG C of white or green glass, Gu
The temperature of change is generally 150 DEG C, and the cured time is generally 30 minutes, to obtain corresponding test result, as a result such as
Shown in following table one.
Table one：
BM 607 is in vain/690 up to because being worth black close beta result：
A kind of two-component modified polyester resin thermmohardening type ink that the present embodiment is provided, covering power height, printing
It is good, it is suitable for the printing of glass cover-plate, there is the layer of ink after solidification excellent adherence, endurance and water boiling resistance, high surface to hinder
The characteristics such as anti-, high surface tension；The constituent white wherein described BM 607 has high whiteness, high covering power, good levelling
Property etc. characteristics, the BM 690 up to because be worth it is black have high covering power, up to because of characteristics such as value, ultralow water droplet angle, high impedances.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, without departing from the technical principles of the invention, several improvements and modifications can also be made, these improvements and modifications
Also it should be regarded as protection scope of the present invention.
Claims (4)
1. a kind of two-component modified polyester resin thermmohardening type ink, which is characterized in that be up in vain with BM 690 including BM 607
It is black because being worth,
Polyester resin 20-50%, the propylene glycol methyl ether acetate 2- that the BM 607 is arranged by concentration range (percentage) in vain
10%, the mixture of different boiling that ketone 25-35%, titanium dioxide 40-50%, auxiliary agent 2-5% compositions；
The BM 690 is up to because being worth black polyester resin 20-50%, propylene glycol monomethyl ether vinegar by concentration range (percentage) setting
The mixture of acid esters 2-10%, different boiling that ketone 25-35%, carbon black 20-30%, auxiliary agent 2-5% compositions.
2. a kind of two-component modified polyester resin thermmohardening type ink according to claim 1, which is characterized in that described different
Your ketone of boiling is diethylene glycol monoethyl ether acetate.
3. a kind of two-component modified polyester resin thermmohardening type ink according to claim 1, which is characterized in that described to help
Agent is composed of thixotropic agent, dispersant, levelling agent and defrother.
4. a kind of two-component modified polyester resin thermmohardening type ink according to claim 3, which is characterized in that described to touch
Become the dense of the concentration range ＜ 3% of agent, the concentration range 5~10% of dispersant, the concentration range ＜ 3% of levelling agent and defrother
Spend range L T.LT.LT 3%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710160000.1A CN108570261A (en) | 2017-03-13 | 2017-03-13 | A kind of two-component modified polyester resin thermmohardening type ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710160000.1A CN108570261A (en) | 2017-03-13 | 2017-03-13 | A kind of two-component modified polyester resin thermmohardening type ink |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108570261A true CN108570261A (en) | 2018-09-25 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710160000.1A Pending CN108570261A (en) | 2017-03-13 | 2017-03-13 | A kind of two-component modified polyester resin thermmohardening type ink |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116135932A (en) * | 2021-11-17 | 2023-05-19 | 广州亦盛环保科技有限公司 | Glass printing ink and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103408995A (en) * | 2013-09-02 | 2013-11-27 | 苏州市金鸿包装材料有限公司 | Screen printing ink |
| CN103773108A (en) * | 2014-01-29 | 2014-05-07 | 苏州昭奇凯虹精细化工有限公司 | White ink for glass cover plates |
| CN106118230A (en) * | 2016-07-18 | 2016-11-16 | 佛山市高明绿色德化工有限公司 | A kind of ink being applied on ultrawhite safety glass and preparation method thereof |
-
2017
- 2017-03-13 CN CN201710160000.1A patent/CN108570261A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103408995A (en) * | 2013-09-02 | 2013-11-27 | 苏州市金鸿包装材料有限公司 | Screen printing ink |
| CN103773108A (en) * | 2014-01-29 | 2014-05-07 | 苏州昭奇凯虹精细化工有限公司 | White ink for glass cover plates |
| CN106118230A (en) * | 2016-07-18 | 2016-11-16 | 佛山市高明绿色德化工有限公司 | A kind of ink being applied on ultrawhite safety glass and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116135932A (en) * | 2021-11-17 | 2023-05-19 | 广州亦盛环保科技有限公司 | Glass printing ink and preparation method thereof |
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Application publication date: 20180925 |