CN108570219A - For dark textile fabric or the color masterbatch constituent and its product of engineering plastics - Google Patents
For dark textile fabric or the color masterbatch constituent and its product of engineering plastics Download PDFInfo
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- CN108570219A CN108570219A CN201710131426.4A CN201710131426A CN108570219A CN 108570219 A CN108570219 A CN 108570219A CN 201710131426 A CN201710131426 A CN 201710131426A CN 108570219 A CN108570219 A CN 108570219A
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- constituent
- color masterbatch
- engineering plastics
- textile fabric
- colorant component
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0041—Optical brightening agents, organic pigments
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/04—Pigments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/06—Dyes
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2310/00—Masterbatches
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A kind of color masterbatch constituent being used for dark textile fabric or engineering plastics, including thermoplastic polyester, yellow colorant component, red colorant component and blue colorant component.The yellow colorant component is selected from pigment yellow 147, pigment yellow 181, pigment yellow 183, dyestuff palm fibre 53 or combinations thereof.The red colorant component is selected from pigment red 122, paratonere 144, paratonere 202, pigment red 21 4 or combinations thereof.The blue colorant component is selected from pigment blue 60, dyestuff indigo plant 67 or combinations thereof.The present invention separately provide it is a kind of for dark textile fabric or the micelle of engineering plastics, be by color masterbatch constituent as described above in the base material based on polyethylene terephthalate (PET) color development and obtain.Product obtained by the present invention has the effect of slowing down and reducing heat absorption, and can still maintain its original color in process.
Description
Technical field
The present invention relates to a kind of color masterbatch constituent (color masterbatch composition), more particularly to one
Kind is for dark textile fabric or the color masterbatch constituent and its product of engineering plastics (engineering plastics).
Background technology
Dark textile fabric is commonly used to clothing, curtain and sofa etc., and dark engineering plastics are widely used in electric appliance and automobile zero
Component etc. has the function of good light-proofness and avoids dirty.Before the spinning of general dark color textile fabric or engineering plastics coloring be
It is added in raw material and is easy to obtain and is provided as the carbon black (carbon black) of pigment and is made, but also therefore generated and be easy to absorb
Infrared ray and the problem of cause its product to be rapidly heated.
TaiWan, China TW I509038 disclose a kind of low heating pigment constituent of infrared ray, pass through and select several specific face
Material is combined, and can reduce temperature rise effect caused by due to absorbing infrared ray.However, its disclosed most of pigment constituent with
Thermoplastic polyester (thermoplastic polyesters) is formed by film, in necessity by textile fabric or engineering plastics
Process (such as：Heated in 285-300 DEG C) after, it is unable to maintain that its original color of pigment constituent, it is necessary to formed
Dark textile fabric (spinning after stain) or engineering plastics could be made by carrying out dyeing after product again, therefore increase the complexity of processing
And the problem of contaminated wastewater.
Invention content
The first object of the present invention be to provide it is a kind of for dark textile fabric or the color masterbatch constituent of engineering plastics, can be with
The shortcomings that overcoming above-mentioned background technology.
The color masterbatch constituent for dark textile fabric or engineering plastics of the present invention includes thermoplastic polyester, yellow colorant group
Point, red colorant component and blue colorant component.The yellow colorant component is to be selected from pigment yellow 147 (pigment yellow
147), pigment yellow 181, pigment yellow 183, dyestuff palm fibre 53 (solvent brown 53) or combinations thereof.The red colorant component is
Selected from pigment red 122 (pigment red 122), paratonere 144, paratonere 202, pigment red 21 4 or combinations thereof.The blue
Colorant component is selected from pigment blue 60 (pigment blue 60), dyestuff indigo plant 67 (solvent blue 67) or combinations thereof.
Above-mentioned colorant is indicated according to color index (color index) adopted name.
The second object of the present invention is to provide a kind of micelle being used for dark textile fabric or engineering plastics, is by institute as above
The color masterbatch constituent stated in the base material based on polyethylene terephthalate (PET) color development and obtain.
The third object of the present invention is to provide a kind of fiber for dark textile fabric, is that micelle as described above exists
It reels off raw silk from cocoons and obtains in 285-300 DEG C.
The fourth object of the present invention is to provide a kind of material for engineering plastics, is that micelle as described above exists
It projected in 285-300 DEG C, squeeze out or mould and obtain.
The beneficial effects of the present invention are：Color masterbatch constituent institute using the present invention for dark textile fabric or engineering plastics
Product obtained, without other addition or it is modified have the effect of slowing down and reducing heat absorption, and in necessary process
In can still maintain its original color.
It will be described in detail below with regard to the content of present invention：
Preferably, in the present invention is for the color masterbatch constituent of dark textile fabric or engineering plastics, the color masterbatch constituent is also
Including titanium dioxide, the gross weight with the color masterbatch constituent is 100wt%, the content range of the titanium dioxide be more than 0 to
5wt%.
Preferably, which is selected from polyethylene terephthalate (PET), polybutylene terephthalate
(PBT), (the functionalized derivatives of of the polyethylene terephthalate derivative through functional groupization
) and its copolymer (copolymers) or its blend (blends) PET.
Preferably, it is 100wt% with the gross weight of the color masterbatch constituent, the content range of the yellow colorant component is 7-
The content range of 15wt%, the red colorant component are 8-15wt%, and the content range of the blue colorant component is 5-15wt%.
It is highly preferred that being 100wt% with the gross weight of the color masterbatch constituent, which is that content range is 7-
The dyestuff palm fibre 53 of 10wt%.
It is highly preferred that being 100wt% with the gross weight of the color masterbatch constituent, which is that content range is 5-10wt%
Dyestuff indigo plant 67.
Preferably, which also includes existing additive, such as ultra-violet absorber, antioxidant, fire-retardant
Agent or combinations thereof.
Preferably, in the present invention is for the micelle of dark textile fabric or engineering plastics, it is with the gross weight of the micelle
The content range of 100wt%, the color masterbatch constituent are 1-10wt%.
Preferably, the present invention is film or plastic film for the material of engineering plastics.
Specific implementation mode
The present invention will be described further with regard to following embodiment, however, it should be noted that the embodiment is only to illustrate to say
Bright use, and it is not necessarily to be construed as the limitation that the present invention is implemented.
＜ embodiments ＞
[embodiment A1-A32] color masterbatch constituent
Content ratio according to the following table 1 will mix in the thermoplastic polyester grain after colorant addition crushing, then at 240-280 DEG C
In extruding mixing carried out with twin (double) screw extruder, the color masterbatch constituent of embodiment A1-A32 is made.
Table 1
[embodiment B1-B32] color masterbatch constituent
Colorant is added in the thermoplastic polyester grain after crushing content ratio according to the following table 2 mixes (total 95wt%), and
5wt% titanium dioxide is added, extruding mixing is carried out with twin (double) screw extruder in 240-280 DEG C, embodiment B1- is made
The color masterbatch constituent of B32.
Table 2
[embodiment C1-C32, D1-D32] color masterbatch constituent
The step of embodiment C1-C32 and D1-D32, is similar to embodiment A1-A32 and B1-B32 respectively, difference be in
PBT replaces PET, the color masterbatch constituent of embodiment C1-C32 and D1-D32 to be made respectively.
＜ comparative examples ＞
[comparative example Z1-Z4] color masterbatch constituent
Content ratio according to the following table 3 will mix in the thermoplastic polyester grain after colorant addition crushing, then at 240-280 DEG C
In extruding mixing carried out with twin (double) screw extruder, the color masterbatch constituent of comparative example Z1-Z4 is made.
Table 3
＜ application examples ＞
[application examples 1] PET micelles
After the color masterbatch constituent pelletizing of above-described embodiment A1-A32, B1-B32, C1-C32 and D1-D32, it is added in PET
Color development (color masterbatch constituent accounts for the 6wt% of gross weight), the PET micelles PET of application examples 1 is madeA1-A32、PETB1-B32、PETC1-C32And
PETD1-D32。
[application examples 2] is used for the fiber of dark textile fabric
By the PET micelles PET of the above application examples 1A1-A32、PETB1-B32、PETC1-C32And PETD1-D32It is taken out in 285-300 DEG C
Silk, the fiber F for dark textile fabric of application examples 2 is madeA1-A32、FB1-B32、FC1-C32And FD1-D32(fibre fineness is
3DPF).Wherein, fiber FA1-A32And FB1-B32For black, fiber FC1-C32And FD1-D32For Dark grey, it is applicable to dark weaving
Object.
[application examples 3] is used for the material of engineering plastics
By the PET micelles PET of the above application examples 1A1-A32、PETB1-B32、PETC1-C32And PETD1-D32It is penetrated in 285-300 DEG C
Go out, the film S for engineering plastics of application examples 3 is madeA1-A32、SB1-B32、SC1-C32And SD1-D32.Wherein, film SA1-A32And
SB1-B32For black, film SC1-C32And SD1-D32For Dark grey, it is applicable to dark engineering plastics.
＜ compares application examples ＞
[comparing application examples 1] PET micelles
Mixing in the thermoplastic polyester grain (70wt%) after crushing is added in carbon black (30wt%), in 240-280 DEG C
Extruding mixing is carried out with twin (double) screw extruder, carbon black color masterbatch constituent is made.And color development (carbon black in PET is added after pelletizing
Color masterbatch constituent accounts for the 5.5wt% of gross weight), obtain the carbon black PET micelles PET for comparing application examples 1CB。
[comparing application examples 2] PET micelles
Compare application examples 2 to be in the color masterbatch constituent substitution embodiment with above-mentioned comparative example Z1-Z4 with 1 difference of application examples
The color masterbatch constituent of A1-A32, B1-B32, C1-C32 and D1-D32, and obtain comparing application examples 2 in being added in PET after color development
Black PET micelles PETZ1-Z4。
[comparing application examples 3] fiber
By the carbon black PET micelles PET of above-mentioned relatively application examples 1CBAnd compare the black PET micelles PET of application examples 2Z1-Z4
It reels off raw silk from cocoons in 285-300 DEG C, the fiber F of relatively application examples 3 to be made respectivelyCBAnd FZ1-Z4.Wherein, fiber FZ1-Z4It all fades and shoals
In inclined brown.
＜ test cases ＞
Infrared ray heating test
At 23 DEG C, with infrared lamp (Philips PAR38IR Red 150W 125-130V, wave-length coverage 600-
It 1400nm) is irradiated 55 minutes with 17 centimetres of PET micelles distance, and above-mentioned ratio was measured every 5 minutes with infra-red thermometer respectively
Compared with the PET micelle temperature of application examples 1 and application examples 1, result is as shown in table 4 below.Wherein, PET micelles PETB1-B32、PETC1-C32
And PETD1-D32Heating test result all respectively with PET micelles PETA1-A32Heating test result it is similar.
【Table 4】
Table 4 and above-mentioned infrared ray heating test result are shown, use the PET micelles obtained by color masterbatch constituent of the present invention
PETA1-A32、PETB1-B32、PETC1-C32And PETD1-D32, the temperature of infrared ray after ten minutes is absorbed all at 67 DEG C hereinafter, it is inhaled
It receives temperature of the infrared ray after 55 minutes and all maintains 74 DEG C or less；And use the carbon black PET micelles PET obtained by carbon blackCB, inhale
It receives the temperature of infrared ray after ten minutes and has been higher than 100 DEG C, illustrate that its heating rate is very fast and increasing extent of temperature is larger, indicate the present invention
Color masterbatch constituent for dark textile fabric or engineering plastics can slow down and reduce temperature rise effect caused by due to absorbing infrared ray.
In conclusion the present invention is used for the color masterbatch constituent of dark textile fabric or engineering plastics without other addition or changes
Property can slow down and reduce temperature rise effect caused by due to absorbing infrared ray, and suitable for dark textile fabric or engineering plastics plus
Work process, so the purpose of the present invention can be reached really.
The above, only the embodiment of the present invention, when cannot be limited the scope of implementation of the present invention with this, i.e., it is all according to
Simple equivalent changes and modifications, all still belong to the scope of the present invention made by claims of the present invention and description.
Claims (10)
1. a kind of color masterbatch constituent being used for dark textile fabric or engineering plastics, it is characterised in that it includes：
Thermoplastic polyester；
Yellow colorant component, selected from pigment yellow 147, pigment yellow 181, pigment yellow 183, dyestuff palm fibre 53 or combinations thereof；
Red colorant component, selected from pigment red 122, paratonere 144, paratonere 202, pigment red 21 4 or combinations thereof；And
Blue colorant component, selected from pigment blue 60, dyestuff indigo plant 67 or combinations thereof, above-mentioned colorant is according to color index common name
Claim to indicate.
2. the color masterbatch constituent according to claim 1 for being used for dark textile fabric or engineering plastics, it is characterised in that the color
Female constituent includes also titanium dioxide, and the gross weight with the color masterbatch constituent is 100wt%, and the content range of the titanium dioxide is big
In 0 to 5wt%.
3. the color masterbatch constituent according to claim 1 for being used for dark textile fabric or engineering plastics, it is characterised in that：The heat
Plasticity polyester is selected from polyethylene terephthalate, polybutylene terephthalate, the poly- terephthaldehyde through functional groupization
Sour second diester deriv and its copolymer or its blend.
4. the color masterbatch constituent according to claim 1 for being used for dark textile fabric or engineering plastics, it is characterised in that：With this
The gross weight of color masterbatch constituent is 100wt%, and the content range of the yellow colorant component is 7-15wt%, the red colorant component
Content range is 8-15wt%, and the content range of the blue colorant component is 5-15wt%.
5. the color masterbatch constituent according to claim 4 for being used for dark textile fabric or engineering plastics, it is characterised in that：With this
The gross weight of color masterbatch constituent is 100wt%, and the content range of the yellow colorant component is 7-10wt%, which is
Dyestuff palm fibre 53.
6. the color masterbatch constituent according to claim 4 for being used for dark textile fabric or engineering plastics, it is characterised in that：With this
The gross weight of color masterbatch constituent is 100wt%, and the content range of the blue colorant component is 5-10wt%, which is
Dyestuff indigo plant 67.
7. a kind of micelle being used for dark textile fabric or engineering plastics, it is characterised in that it is will be according to claim 1
Color masterbatch constituent in the base material based on polyethylene terephthalate color development and obtain.
8. the micelle according to claim 7 for being used for dark textile fabric or engineering plastics, it is characterised in that：With the micelle
Gross weight is 100wt%, and the content range of the color masterbatch constituent is 1-10wt%.
9. a kind of fiber for dark textile fabric, it is characterised in that it is by micelle according to claim 7 in 285-
It reels off raw silk from cocoons and obtains in 300 DEG C.
10. a kind of material for engineering plastics, it is characterised in that it is by micelle according to claim 7 in 285-
It projected in 300 DEG C, squeeze out or mould and obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710131426.4A CN108570219B (en) | 2017-03-07 | 2017-03-07 | Color master batch composition for dark color textile or engineering plastic and product thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710131426.4A CN108570219B (en) | 2017-03-07 | 2017-03-07 | Color master batch composition for dark color textile or engineering plastic and product thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108570219A true CN108570219A (en) | 2018-09-25 |
| CN108570219B CN108570219B (en) | 2020-09-11 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710131426.4A Active CN108570219B (en) | 2017-03-07 | 2017-03-07 | Color master batch composition for dark color textile or engineering plastic and product thereof |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1359982A (en) * | 2000-12-21 | 2002-07-24 | 大日精化工业株式会社 | Near infrared reflection composite pigment |
| CN1903937A (en) * | 2005-07-25 | 2007-01-31 | 章浩龙 | PET coloured mother material, its manufacturing method and use |
| CN103160125A (en) * | 2011-12-19 | 2013-06-19 | 合肥杰事杰新材料股份有限公司 | High temperature resisting orange material and preparation method thereof |
| CN103825694A (en) * | 2009-03-09 | 2014-05-28 | Lg电子株式会社 | Method for transmitting and receiving signals |
| CN105273349A (en) * | 2015-11-10 | 2016-01-27 | 宁波色母粒有限公司 | Polymethyl-methacrylate black master batch and preparing method thereof |
-
2017
- 2017-03-07 CN CN201710131426.4A patent/CN108570219B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1359982A (en) * | 2000-12-21 | 2002-07-24 | 大日精化工业株式会社 | Near infrared reflection composite pigment |
| CN1903937A (en) * | 2005-07-25 | 2007-01-31 | 章浩龙 | PET coloured mother material, its manufacturing method and use |
| CN103825694A (en) * | 2009-03-09 | 2014-05-28 | Lg电子株式会社 | Method for transmitting and receiving signals |
| CN103160125A (en) * | 2011-12-19 | 2013-06-19 | 合肥杰事杰新材料股份有限公司 | High temperature resisting orange material and preparation method thereof |
| CN105273349A (en) * | 2015-11-10 | 2016-01-27 | 宁波色母粒有限公司 | Polymethyl-methacrylate black master batch and preparing method thereof |
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| Publication number | Publication date |
|---|---|
| CN108570219B (en) | 2020-09-11 |
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