CN108569849A - A kind of enamel suspending agent and the enamelled pressed steel with it - Google Patents
A kind of enamel suspending agent and the enamelled pressed steel with it Download PDFInfo
- Publication number
- CN108569849A CN108569849A CN201810671964.7A CN201810671964A CN108569849A CN 108569849 A CN108569849 A CN 108569849A CN 201810671964 A CN201810671964 A CN 201810671964A CN 108569849 A CN108569849 A CN 108569849A
- Authority
- CN
- China
- Prior art keywords
- enamel
- suspending agent
- pressed steel
- enamelled pressed
- glaze
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/16—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions with vehicle or suspending agents, e.g. slip
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23D—ENAMELLING OF, OR APPLYING A VITREOUS LAYER TO, METALS
- C23D11/00—Continuous processes; Apparatus therefor
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23D—ENAMELLING OF, OR APPLYING A VITREOUS LAYER TO, METALS
- C23D5/00—Coating with enamels or vitreous layers
- C23D5/02—Coating with enamels or vitreous layers by wet methods
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2207/00—Compositions specially applicable for the manufacture of vitreous enamels
- C03C2207/04—Compositions specially applicable for the manufacture of vitreous enamels for steel
Abstract
The invention discloses a kind of enamel suspending agent and with its enamelled pressed steel, enamel suspending agent includes the component of following parts by weight：7.5 8.5 parts of base-material, 0.2 0.5 parts of electrolyte, 40 50 parts of solvent.The enamel suspending agent of the present invention has good dispersion, suspensibility high, diffusion is good in water, particle is small, surface-active is big, penetration is strong, preparation process without dust, it is at low cost the features such as；Using water as decentralized medium, the problem of no organic solvent is also easy to produce poisonous and harmful substance, it is diluted with water that rear suspension is good, the physical stability of glaze slip can be made to reach best.Enamel suspending agent and the pure titanium glaze of the present invention grinds the glaze slip produced and be sprayed on to fire on enamel plate after mixing can obtain enamelled pressed steel, and prepared enamelled pressed steel properties all meet standard requirement, and workability is good.
Description
Technical field
The present invention relates to a kind of suspending agent and its applications, and in particular to a kind of enamel suspending agent and the glassed steel with it
Plate.
Background technology
The mechanism of action of suspending agent reduces the interface between liquid-liquid or solid-liquid by being adsorbed in the surface of solid particle
Power.The solid particles surface of cohesion is set to be easy to moisten.Adsorption layer is formed on the surface of solid particle simultaneously, makes solid particles surface
Charge increase, improve and form the intergranular reaction force of steric hindrance.To make solid particle surfaces form bilayer
Structure, outer layer dispersant polar end has with water increases the degree that solids are spontaneously wet out by water compared with strong affinity.Solid particle it
Between it is separate because of electrostatic repulsion.Finally keep system uniform, suspendability increases, and does not precipitate, keeps whole system physico-chemical property the same.
With the rapid development of Enamel Industry, also there are various new requirements in the various aspects of performance of enamel, traditional
In the preparation of wet method glaze slip, it is an indispensable ring to be added using clay as suspending agent, but on the market each at present
Kind bentonite and green hill soil can all generate the glaze pulp color of pure base glaze faint influence, and this influence causes part enamel colored
Realization encounter difficulties, the pure titanium glaze in part be ground with normal clay prepare glaze slip firing after color it is partially yellow,
The allotment that cannot further realize cool tone, is difficult to ensure the operable of glaze slip the case where can realize cool tone color
Property, and cost problem can not be taken into account.
Invention content
In view of this, the present invention provides a kind of enamel suspending agent and its applications, it is intended to ensure the case where cost does not increase
Under, realize the vivid effect of enamel color.
To achieve the goals above, the present invention provides a kind of enamel suspending agent, include the component of following parts by weight：Base
7.5-8.5 parts of material, 0.2-0.5 parts of electrolyte, preferably 0.2 part, 40-50 parts of solvent, preferably 45 parts.
The enamel suspending agent of the present invention has good dispersion, and suspensibility is high, and diffusion is good in water, particle is small, surface is lived
Property is big, penetration is strong, preparation process without dust, it is at low cost the features such as；Using water as decentralized medium, no organic solvent has been also easy to produce
It the problem of malicious harmful substance, is diluted with water that rear suspension is good, the physical stability of glaze slip can be made to reach best.
Further, base-material is methylcellulose mixture UC-D1；Electrolyte is any of borax, potassium chloride or barium chloride
Kind, preferably potassium chloride；Solvent is the ethyl alcohol of any concentration or any, preferably water of water.
It is using above-mentioned further advantageous effect：Suspending agent methylcellulose mixture UC-D1 can not only make glaze
Slurry has suspendability, can also increase the adhesion strength of glaze slip and substrate, while the firing amplitude of enamel can be made maximum, chlorination
Potassium can effectively prevent the generation of rust staining, and to reduce focal spot, using water as decentralized medium, no organic solvent is also easy to produce venomous injurant
The problem of matter, the hydrophily for also assigning enamel suspending agent methylcellulose mixture UC-D1 has certain condition, to make glaze
Slurry has suspension.
The present invention also provides a kind of enamelled pressed steels, and system is ground after mixing with above-mentioned enamel suspending agent and pure titanium glaze
The glaze slip made is sprayed on enamel plate obtained by firing.
All meet standard requirement, and application property with the enamelled pressed steel properties prepared by enamel suspending agent of the present invention
It can be good.
Further, the mass ratio that enamel suspending agent is mixed with pure titanium glaze is 4.5-5.5:10.
It is using above-mentioned further advantageous effect：Enamel suspending agent and the ratio of pure titanium glaze mixing directly affect glaze slip
Fluidity, determine glaze slip can be evenly applied on green body, have preferably with the prepared glaze slip of aforementioned proportion of the present invention
Fluidity, the uniform coating thickness sprayed, being not likely to produce that ground-coat enamel was burnt, prepared enamelled pressed steel physicochemical property is low etc. asks
Topic.
Further, the operation of grinding is to be ground to 140 mesh；The time of grinding is 10-15min, preferably 12min；Spraying
Porcelain thickness be 80-100 μm.
It is using above-mentioned further advantageous effect：All kinds of glaze slips since the difference of purposes and the requirement of the application of slip are different,
The thickness of fineness and spraying to grinding has different requirements, the above-mentioned grinding fineness degree of the present invention to can guarantee the glaze slip of the present invention
Suspension is preferable, and coating thickness, which ensure that under the premise of cost is minimum, higher physical property, and in preparation process not
It is also easy to produce focal spot.
Further, the temperature of firing be 800-900 DEG C, preferably 800 DEG C, firing time 3-5min, preferably 4min.
It is using above-mentioned further advantageous effect：So that glaze slip is adequately fired on enamelled pressed steel, it will not
It generates and fires insufficient, be charred, burst porcelain, the problems such as prepared enamelled pressed steel is coarse, gloss difference.
Specific implementation mode
The following is a clear and complete description of the technical scheme in the embodiments of the invention, it is clear that described embodiment
Only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field
The every other embodiment that art personnel are obtained without making creative work belongs to the model that the present invention protects
It encloses.
Embodiment 1
Each raw material is weighed according to following ratio：Pure titanium glaze TMW 170:100g, Foshan Pu Ji board suspending agent methylcellulose
Mixture UC-D1：8g, potassium chloride：0.2g, water：45g after mixing grinds on Quick ball grinder and to produce for 12 minutes
Glaze slip is sprayed on normal enamel plate, and for porcelain thickness at 80 μm, firing process is 800 DEG C, 4min, and enamelled pressed steel is made,
Gained steel plate specific performance parameter such as table 1.
1 enamel inspection result of table
As shown in Table 1, all meet standard requirement, and workability using the UC-D1 enamelled pressed steel properties made
Well, it can be applied in enamel production.
Embodiment 2
Each raw material is weighed according to following ratio：Pure titanium glaze TMW 170:100g, suspending agent：7.5g, potassium chloride：0.2g, water：
45g, wherein suspending agent is respectively：1, EZ957V clays, 2, the kaolin of white imperial board, 3, the 18# clays of more agate morals, 4, Pu Ji
UC-D1, grind 12 minutes glaze slips produced on Quick ball grinder after mixing and be sprayed on normal enamel plate,
For porcelain thickness at 90 μm, firing process is 800 DEG C, 4min, and enamelled pressed steel, four groups of enamelled pressed steel performance parameter such as tables of gained are made
2。
2 four groups of enamelled pressed steel service check results of table
As shown in Table 2, by comparing in the same direction, enamelled pressed steel color is most shallow made from enamel suspending agent UC-D1, and effect is more normal
The EZ957V clays of rule are not bad, can be used as the substitute for selecting clay.
Embodiment 3
Each raw material is weighed according to following ratio：Pure titanium glaze TMW 170:100g, suspending agent：8g, potassium chloride：0.2g, water：
45g, wherein suspending agent is respectively：1, EZ957V clays 4g, UC-D14g, 2, kaolin 4g, UC-D14g, 3,18# clay 4g,
UC-D14g grinds 12 minutes glaze slips produced after mixing on Quick ball grinder and is sprayed on normal enamel plate,
For porcelain thickness at 100 μm, firing process is 800 DEG C, 4min, enamelled pressed steel is made, three groups of enamelled pressed steel performance parameters of gained are such as
Table 3.
The glaze slip performance comparison that 3 different schemes same time of table is prepared
Contrast table 2 and 3 data cannot reach color it is found that the enamel color produced after the mixing of different suspending agent is still partially yellow
Requirement of the coloured silk 3 or so, it is seen then that its effect is better than the effect after different suspending agent compoundings using UC-D1 as suspending agent.
Embodiment 4
Each raw material is weighed according to following ratio：Pure titanium glaze TMW 170:100g, suspending agent：6.5-8.5g, potassium chloride：
0.2g, water：45g, wherein suspending agent is respectively：1, EZ957V clays, 2, the kaolin of white imperial board, 3, the 18# of more agate morals it is viscous
Soil, each suspending agent prepare the glaze slip of tetra- kinds of concentration of suspending agent-containing 6.5-7g, 7-7.5g, 7.5-8g, 8-8.5g respectively, and mixing is equal
12 minutes glaze slips produced are ground after even on Quick ball grinder to be sprayed on normal enamel plate, porcelain thickness is in 90 μ
M, firing process are 800 DEG C, 4min, and enamelled pressed steel, four groups of enamelled pressed steel performance parameters of gained such as table 4-6 is made.
The glaze slip performance that the external clay EZ957V clay different proportion same times of table 4 are prepared
The glaze slip performance that 5 kaolin different proportion same time of table is prepared
The glaze slip performance that 6 18# clay different proportion same times of table are prepared
The data of contrast table 4-6 can produce satisfaction production it is found that pure different suspending agents match when suitable
It is required that glaze slip, but the enamel color produced is generally partially yellow, yellow mutually all close to 4, cannot be used for replacing former suspending agent, also can not
It can achieve the effect that when reaching with UC-D1 as suspending agent.
Embodiment 5
Each raw material is weighed according to following ratio：Pure titanium glaze TMW 170:100g, suspending agent UC-D1：7-8.5g, potassium chloride：
0.2g, water：45g, wherein suspending agent UC-D1 dosages distinguish value：7g, 7.5g, 8g, 8.5g, after mixing in quick ball milling
It grinds 12 minutes glaze slips produced on machine to be sprayed on normal enamel plate, porcelain thickness is at 90 μm, firing process 800
DEG C, enamelled pressed steel, four groups of enamelled pressed steel performance parameters of gained such as table 7 is made in 4min.
The glaze slip performance that 7 enamel suspending agent different proportion same time of table is prepared
As shown in Table 7, suspending agent UC-D1 substitutes clay, is ground with addition 7g, obtained glaze slip effect is not
Good, addition, which is 7.5g, can substantially meet requirement, work well to 8.5g but can also reduce in cost, through Experimental comparison 8g
Dosage can meet production requirement.
Each embodiment is described by the way of progressive in this specification, the highlights of each of the examples are with other
The difference of embodiment, just to refer each other for identical similar portion between each embodiment.For device disclosed in embodiment
For, since it is corresponded to the methods disclosed in the examples, so description is fairly simple, related place is said referring to method part
It is bright.
The foregoing description of the disclosed embodiments enables those skilled in the art to implement or use the present invention.
Various modifications to these embodiments will be apparent to those skilled in the art, as defined herein
General Principle can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore, of the invention
It is not intended to be limited to the embodiments shown herein, and is to fit to and the principles and novel features disclosed herein phase one
The widest range caused.
Claims (10)
1. a kind of enamel suspending agent, which is characterized in that the suspending agent includes the component of following parts by weight：Base-material 7.5-8.5
Part, 0.2-0.5 parts of electrolyte, 40-50 parts of solvent.
2. a kind of enamel suspending agent according to claim 1, which is characterized in that the base-material mixes for carboxymethyl cellulose
Object.
3. a kind of enamel suspending agent according to claim 1, which is characterized in that the electrolyte be borax, potassium chloride or
Barium chloride it is any.
4. a kind of enamel suspending agent according to any one of claims 1 to 3, which is characterized in that the solvent be ethyl alcohol or
Water it is any.
5. a kind of enamelled pressed steel, which is characterized in that the enamelled pressed steel is to be suspended with claim 1-4 any one of them enamel
Agent and pure titanium glaze grind the glaze slip produced and be sprayed on enamel plate after mixing fires obtained enamelled pressed steel.
6. a kind of enamelled pressed steel according to claim 5, which is characterized in that the enamel suspending agent is mixed with pure titanium glaze
Mass ratio is 4.5-5.5:10.
7. a kind of enamelled pressed steel according to claim 5, which is characterized in that the operation of the grinding is to be ground to 140 mesh.
8. a kind of enamelled pressed steel according to claim 5, which is characterized in that the time of the grinding is 10-15min.
9. a kind of enamelled pressed steel according to claim 5, which is characterized in that the porcelain thickness of the spraying is 80-100 μ
m。
10. a kind of enamelled pressed steel according to claim 5, which is characterized in that the temperature of the firing is 800-900 DEG C,
Firing time is 3-5min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810671964.7A CN108569849A (en) | 2018-06-26 | 2018-06-26 | A kind of enamel suspending agent and the enamelled pressed steel with it |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810671964.7A CN108569849A (en) | 2018-06-26 | 2018-06-26 | A kind of enamel suspending agent and the enamelled pressed steel with it |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108569849A true CN108569849A (en) | 2018-09-25 |
Family
ID=63573761
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810671964.7A Pending CN108569849A (en) | 2018-06-26 | 2018-06-26 | A kind of enamel suspending agent and the enamelled pressed steel with it |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108569849A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102086091A (en) * | 2010-07-08 | 2011-06-08 | 石家庄正中科技有限公司 | Surface glaze, white enamel and preparation method thereof |
| US20130217560A1 (en) * | 2010-09-16 | 2013-08-22 | Daunia Solar Cell S.R.L. | Sealing agent with low softening temperature useful in the preparation of electronic devices |
| CN104163570A (en) * | 2014-08-26 | 2014-11-26 | 陈建英 | Bronze enameled glaze and preparation method thereof |
-
2018
- 2018-06-26 CN CN201810671964.7A patent/CN108569849A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102086091A (en) * | 2010-07-08 | 2011-06-08 | 石家庄正中科技有限公司 | Surface glaze, white enamel and preparation method thereof |
| US20130217560A1 (en) * | 2010-09-16 | 2013-08-22 | Daunia Solar Cell S.R.L. | Sealing agent with low softening temperature useful in the preparation of electronic devices |
| CN104163570A (en) * | 2014-08-26 | 2014-11-26 | 陈建英 | Bronze enameled glaze and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103289455B (en) | Formaldehyde-free VOC-free (volatile organic compounds-free) inorganic functional coating and preparation method thereof | |
| CN103289454B (en) | Inorganic functional coating for degrading formaldehyde by negative ions and preparation method of coating | |
| CN107011792A (en) | A kind of antibacterial wearable ceramic coat of non-stick pan and preparation method thereof | |
| WO2018059451A1 (en) | Hydrophobic anti-settling far-infrared absorber material and manufacturing method thereof, and kitchen appliance product and manufacturing method thereof | |
| CN111423759B (en) | Exterior wall waterproof putty and preparation method thereof | |
| CN106280749A (en) | Insulation aqueous fluorocarbon coating and preparation method thereof | |
| CN107903718A (en) | A kind of aqueous color paste and preparation method thereof | |
| CN110143804B (en) | Transfer printing pattern inorganic artificial stone plate and preparation method thereof | |
| CN109401370A (en) | The smoke-free and tasteless of resistance to greasy dirt aqueous inorganic nano ceramics kitchen tools coating and preparation method thereof | |
| CN104119708A (en) | Inorganic zinc-rich anticorrosive paint | |
| CN108569849A (en) | A kind of enamel suspending agent and the enamelled pressed steel with it | |
| CN110078537A (en) | A kind of preparation process of high-strength anti-fouling type domestic ceramics | |
| KR101687379B1 (en) | Method for preparing vegetable glue composition | |
| CN108526388A (en) | A kind of cast paint and preparation method thereof for flow coat | |
| CN110330821A (en) | Inorganic environment-friendly fire prevention mineral coating and its preparation process | |
| CN109020476B (en) | Modified composite clay and preparation method thereof | |
| KR20150035612A (en) | Coating sol composition for ceramic wallpaper, ceramic wallpaper and method for preparing ceramic wallpaper | |
| CN106167652A (en) | A kind of anti-static ceramic ink with leather pattern effect and preparation method thereof | |
| CN106752163A (en) | Novel fireproof woodwork coating and its preparation and application | |
| CN109796824A (en) | A kind of emulation mineral varnish color grain, emulation mineral varnish and its preparation method and application | |
| CN106065126B (en) | A kind of high melanism microcapsule coated red phosphorus combustion inhibitor master batch of high concentration and preparation method thereof | |
| CN108517716A (en) | It is a kind of colored to bake paper and its manufacture craft | |
| CN107523208A (en) | Water-borne wood coating and its preparation method and application | |
| CN108624121A (en) | Halogen synergistic flame retardant, the ink and preparation method thereof using the fire retardant | |
| CN106867349A (en) | A kind of aqueous colorful paint preparation method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180925 |
|
| RJ01 | Rejection of invention patent application after publication |