CN108559421A - The type ring that has no irritating odor protects protective film - Google Patents

The type ring that has no irritating odor protects protective film Download PDF

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Publication number
CN108559421A
CN108559421A CN201810373146.9A CN201810373146A CN108559421A CN 108559421 A CN108559421 A CN 108559421A CN 201810373146 A CN201810373146 A CN 201810373146A CN 108559421 A CN108559421 A CN 108559421A
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China
Prior art keywords
parts
modified eva
pressure
adhesive layer
protective film
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CN201810373146.9A
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Chinese (zh)
Inventor
金闯
梁豪
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Sidike New Materials Jiangsu Co Ltd
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Sidike New Materials Jiangsu Co Ltd
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Priority to CN201810373146.9A priority Critical patent/CN108559421A/en
Publication of CN108559421A publication Critical patent/CN108559421A/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22—Plastics; Metallised plastics
    • C09J7/24—Plastics; Metallised plastics based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/241—Polyolefin, e.g.rubber
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/04—Homopolymers or copolymers of ethene
    • C09J123/08—Copolymers of ethene
    • C09J123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C09J123/0853—Vinylacetate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/38—Pressure-sensitive adhesives [PSA]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02—Esters of monocarboxylic acids
    • C08F218/04—Vinyl esters
    • C08F218/08—Vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F261/00—Macromolecular compounds obtained by polymerising monomers on to polymers of oxygen-containing monomers as defined in group C08F16/00
    • C08F261/02—Macromolecular compounds obtained by polymerising monomers on to polymers of oxygen-containing monomers as defined in group C08F16/00 on to polymers of unsaturated alcohols
    • C08F261/04—Macromolecular compounds obtained by polymerising monomers on to polymers of oxygen-containing monomers as defined in group C08F16/00 on to polymers of unsaturated alcohols on to polymers of vinyl alcohol
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08—Macromolecular additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22—Plastics; Metallised plastics
    • C09J7/25—Plastics; Metallised plastics based on macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/255—Polyesters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/29—Laminated material
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/38—Pressure-sensitive adhesives [PSA]
    • C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/40—Adhesives in the form of films or foils characterised by release liners
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/122—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/16—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the structure of the carrier layer
    • C09J2301/162—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the structure of the carrier layer the carrier being a laminate constituted by plastic layers only
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/302—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2423/00—Presence of polyolefin
    • C09J2423/04—Presence of homo or copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2423/00—Presence of polyolefin
    • C09J2423/10—Presence of homo or copolymers of propene
    • C09J2423/106—Presence of homo or copolymers of propene in the substrate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2431/00—Presence of polyvinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2467/00—Presence of polyester
    • C09J2467/006—Presence of polyester in the substrate

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Laminated Bodies (AREA)
  • Adhesive Tapes (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The present invention discloses one kind type ring that has no irritating odor and protects protective film, including PET film, polypropylene film, pressure-sensitive modified EVA adhesive layer and separated type material layer, the pressure-sensitive modified EVA adhesive layer is between polypropylene film and separated type material layer；Modified EVA aqueous solution is further obtained by following steps：Polyvinyl alcohol, sodium iso-octoate, sulfurous acid sylvite and ferrous sulfate are dissolved in ionized water and form aqueous mixture；Aqueous mixture is put into autoclave, then is passed through ethylene and displaces air in autoclave；Material is warming up to 80 DEG C of reaction temperature by reacting kettle jacketing water and is stirred, Vinyl Acetate Monomer, acrylic acid, cumyl peroxide, tert-butyl hydroperoxide, sodium pyrosulfite are implanted sequentially.The present invention conveniently have no irritating odor type ring protect protective film be conducive to it is more preferable it is low masking liquid coating is realized in coating process, can also reuse and recycle, greatly reduce pollution.

Description

The type ring that has no irritating odor protects protective film
Technical field
The present invention relates to a kind of protective film, more particularly to one kind type ring that has no irritating odor protects protective film.
Background technology
Common about 70 ~ 90% mass share of protective film product is film class base material, these film substances are difficult in nature Degradation, however, in today that environmental consciousness is constantly reinforced, the recuperability of environmentally friendly material and material is increasingly by people Attention, resource, market and environmental requirement are higher and higher.But prevailing protective film class product currently on the market, After use, it is generally used as solid-state dangerous waste, or is filled, burned or even not located effectively as industrial refuse Reason mixes in common dregs of society, this not only seriously polluted our living environment, but also also result in the pole of resource Big waste.If can be recycled, not only there is extremely important social environment benefit, will also be imitated with splendid economy Benefit.
Invention content
The present invention provide one kind have no irritating odor type ring protect protective film, this have no irritating odor type ring protect protective film realize EVA adhesive layers have viscosity and pressure-sensitive in room temperature, and pressure-sensitive modified EVA adhesive layer is water-based system environmental protection, stingless Swash property smell, is also convenient for have no irritating odor type ring guarantor's protective film recycling and recycling, greatly reduces pollution.
In order to achieve the above objectives, the technical solution adopted by the present invention is：One kind have no irritating odor type ring protect protective film, packet Include PET film, polypropylene film, pressure-sensitive modified EVA adhesive layer and separated type material layer, the pressure-sensitive modified EVA adhesive layer Between polypropylene film and separated type material layer；
The pressure-sensitive modified EVA adhesive layer is composed of the following components：
100 parts of modified EVA aqueous solution,
10 ~ 20 parts of Isooctyl acrylate monomer,
20 ~ 30 parts of deionized water,
5 ~ 8 parts of tert-butyl hydroperoxide 2- ethylhexyl carbonates,
4 ~ 6 parts of di-2-ethylhexylphosphine oxide phenylenediamine,
3 ~ 5 parts of polymethylphenylsiloxane,
2 ~ 4 parts of the peroxidating -2- ethylhexyl carbonates tert-butyl ester,
1 ~ 2 part of Triallyl isocyanurate,
1 ~ 2 part of terpene resin,
0.5 ~ 2 part of alkyl phenol polyoxyethylene ether,
0.5 ~ 1 part of dimethyl sulfoxide (DMSO)；
The modified EVA aqueous solution is further obtained by following steps：
Step 1: 32 parts of polyvinyl alcohol, 7.5 parts of sodium iso-octoates, 3.6 parts of sulfurous acid sylvite and 0.06 part of ferrous sulfate are dissolved in Aqueous mixture is formed in ionized water；
Step 2: the aqueous mixture of step 1 is put into autoclave, then it is passed through ethylene and displaces air in autoclave；
Step 3: material is warming up to 80 DEG C of reaction temperature by reacting kettle jacketing water and is stirred, it is implanted sequentially 100 parts of vinyl acetates Ester monomer, 15 parts of acrylic acid, 0.05 part of cumyl peroxide, 0.04 part of tert-butyl hydroperoxide, 0.6 part of sodium pyrosulfite；
Step 4: being cooled to 40 DEG C of modified EVA aqueous solutions formed below；
The pressure of the step 2 mesohigh kettle is 5 ~ 10MPa, and the thickness ratio of the PET film and polypropylene film is 1：2~4.
Since above-mentioned technical proposal is used, the present invention has following advantages and effect compared with prior art：
1. the present invention has no irritating odor, type ring protects protective film, uses acrylic acid and combines ferrous sulfate, polyvinyl alcohol, changes Property the ethylene-vinyl acetate copolymer formed by ethylene, vinylacetate, cooperation Isooctyl acrylate monomer, di-2-ethylhexylphosphine oxide benzene two Amine and tert-butyl hydroperoxide 2- ethylhexyl carbonates realize EVA adhesive layers has viscosity and pressure-sensitive in room temperature, and presses Quick modified EVA adhesive layer is water-based system environmental protection, is had no irritating odor, and the type ring guarantor's protective film weight that has no irritating odor is also convenient for It is multiple to utilize and recycle, greatly reduce pollution；Secondly, the peroxidating -2- ethylhexyl carbonates tert-butyl ester, three allyls are further added Base isocyanuric acid ester further improves the adhesive force of modified EVA adhesive layer and polypropylene film.
2. the present invention has no irritating odor, type ring protects protective film, and alkyl phenol polyoxyethylene ether, dimethyl is added in system Sulfoxide can make the substance that solid material is more easy to be soaked in water.By reducing its surface tension or interfacial tension, allow the water to be deployed in On solid material surface, or its surface is penetrated, and solid material is soaked；Secondly, addition polymethylphenylsiloxane improves The compatibility and surface tension of system are conducive to the more preferable low realization masking liquid coating in coating process.
Description of the drawings
Attached drawing 1 be the present invention have no irritating odor type ring protect protection membrane structure diagram.
In the figures above：1, polypropylene film；2, pressure-sensitive modified EVA adhesive layer；3, separated type material layer；4, PET film.
Specific implementation mode
The invention will be further described with reference to the accompanying drawings and embodiments：
Embodiment：One kind type ring that has no irritating odor protects protective film, including PET film 4, polypropylene film 1, pressure-sensitive modified EVA Adhesive layer 2 and separated type material layer 3, the pressure-sensitive modified EVA adhesive layer 2 be located at polypropylene film 1 and separated type material layer 3 it Between；
The pressure-sensitive modified EVA adhesive layer 2 is composed of the following components：100 parts of modified EVA aqueous solution, Isooctyl acrylate monomer 14 Part, 24 parts of deionized water, 6 parts of tert-butyl hydroperoxide 2- ethylhexyl carbonates, 4 parts of di-2-ethylhexylphosphine oxide phenylenediamine, polymethyl-benzene base 4.5 parts of siloxanes, 3 parts of the peroxidating -2- ethylhexyl carbonates tert-butyl ester, 1.2 parts of Triallyl isocyanurate, terpene resin 1.8 parts, 1.4 parts of alkyl phenol polyoxyethylene ether, 0.9 part of dimethyl sulfoxide (DMSO)；
The modified EVA aqueous solution is further obtained by following steps：
Step 1: 32 parts of polyvinyl alcohol, 7.5 parts of sodium iso-octoates, 3.6 parts of sulfurous acid sylvite and 0.06 part of ferrous sulfate are dissolved in Aqueous mixture is formed in ionized water；
Step 2: the aqueous mixture of step 1 is put into autoclave, then it is passed through ethylene and displaces air in autoclave；
Step 3: material is warming up to 80 DEG C of reaction temperature by reacting kettle jacketing water and is stirred, it is implanted sequentially 100 parts of vinyl acetates Ester monomer, 15 parts of acrylic acid, 0.05 part of cumyl peroxide, 0.04 part of tert-butyl hydroperoxide, 0.6 part of sodium pyrosulfite；
Step 4: being cooled to 40 DEG C of modified EVA aqueous solutions formed below.
The pressure of two mesohigh kettle of above-mentioned steps is 5 ~ 10MPa.
The PET film 4 of embodiment is 1 with the thickness ratio of polypropylene film 1：3.2.
Table 1
When protecting protective film using the above-mentioned type ring that has no irritating odor, uses acrylic acid and combine ferrous sulfate, polyvinyl alcohol, change Property the ethylene-vinyl acetate copolymer formed by ethylene, vinylacetate, cooperation Isooctyl acrylate monomer, di-2-ethylhexylphosphine oxide benzene two Amine and tert-butyl hydroperoxide 2- ethylhexyl carbonates realize EVA adhesive layers has viscosity and pressure-sensitive in room temperature, and presses Quick modified EVA adhesive layer is water-based system environmental protection, is had no irritating odor, and the type ring guarantor's protective film weight that has no irritating odor is also convenient for It is multiple to utilize and recycle, greatly reduce pollution；Secondly, the peroxidating -2- ethylhexyl carbonates tert-butyl ester, three allyls are further added Base isocyanuric acid ester further improves the adhesive force of modified EVA adhesive layer and polypropylene film；Again, it is added in system Alkyl phenol polyoxyethylene ether, dimethyl sulfoxide (DMSO) can make the substance that solid material is more easy to be soaked in water.By reducing its surface tension Or interfacial tension, it allows the water to be deployed on solid material surface, or penetrate its surface, and solid material is soaked；Secondly, add Addition polymerization methyl phenyl siloxane improves the compatibility and surface tension of system, is conducive to more preferable low realize masking liquid in coating process Coating.
The above embodiments merely illustrate the technical concept and features of the present invention, and its object is to allow person skilled in the art Scholar cans understand the content of the present invention and implement it accordingly, and it is not intended to limit the scope of the present invention.It is all according to the present invention Equivalent change or modification made by Spirit Essence, should be covered by the protection scope of the present invention.

Claims (1)

1. one kind has no irritating odor, type ring protects protective film, it is characterised in that：Including PET film（4）, polypropylene film（1）, pressure Quick modified EVA adhesive layer（2）With separated type material layer（3）, the pressure-sensitive modified EVA adhesive layer（2）Positioned at polypropylene film （1）With separated type material layer（3）Between；
The pressure-sensitive modified EVA adhesive layer（2）It is composed of the following components：
100 parts of modified EVA aqueous solution,
10 ~ 20 parts of Isooctyl acrylate monomer,
20 ~ 30 parts of deionized water,
5 ~ 8 parts of tert-butyl hydroperoxide 2- ethylhexyl carbonates,
4 ~ 6 parts of di-2-ethylhexylphosphine oxide phenylenediamine,
3 ~ 5 parts of polymethylphenylsiloxane,
2 ~ 4 parts of the peroxidating -2- ethylhexyl carbonates tert-butyl ester,
1 ~ 2 part of Triallyl isocyanurate,
1 ~ 2 part of terpene resin,
0.5 ~ 2 part of alkyl phenol polyoxyethylene ether,
0.5 ~ 1 part of dimethyl sulfoxide (DMSO)；
The modified EVA aqueous solution is further obtained by following steps：
Step 1: 32 parts of polyvinyl alcohol, 7.5 parts of sodium iso-octoates, 3.6 parts of sulfurous acid sylvite and 0.06 part of ferrous sulfate are dissolved in Aqueous mixture is formed in ionized water；
Step 2: the aqueous mixture of step 1 is put into autoclave, then it is passed through ethylene and displaces air in autoclave；
Step 3: material is warming up to 80 DEG C of reaction temperature by reacting kettle jacketing water and is stirred, it is implanted sequentially 100 parts of vinyl acetates Ester monomer, 15 parts of acrylic acid, 0.05 part of cumyl peroxide, 0.04 part of tert-butyl hydroperoxide, 0.6 part of sodium pyrosulfite；
Step 4: being cooled to 40 DEG C of modified EVA aqueous solutions formed below；
The pressure of the step 2 mesohigh kettle is 5 ~ 10MPa, the PET film（4）With polypropylene film（1）Thickness ratio be 1：2~4.
CN201810373146.9A 2016-07-12 2016-07-12 The type ring that has no irritating odor protects protective film Pending CN108559421A (en)

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CN201810342345.3A Pending CN108611014A (en) 2016-07-12 2016-07-12 Aqueous environment protection protective film
CN201810367336.XA Pending CN108559420A (en) 2016-07-12 2016-07-12 The recyclable pad pasting of water-based system
CN201710052683.9A Pending CN107629715A (en) 2016-07-12 2016-07-12 The environmentally friendly pressure sensitive adhesive tape of surface protection
CN201710052682.4A Pending CN107629718A (en) 2016-07-12 2016-07-12 The recyclable diaphragm of water-based system
CN201810342313.3A Pending CN108587511A (en) 2016-07-12 2016-07-12 Recyclable pressure sensitive adhesive tape for surface protection
CN201710052831.7A Pending CN107629716A (en) 2016-07-12 2016-07-12 Green non-pollution protects pad pasting
CN201810346282.9A Pending CN108753190A (en) 2016-07-12 2016-07-12 Reclaiming type is facilitated to protect pad pasting
CN201810373146.9A Pending CN108559421A (en) 2016-07-12 2016-07-12 The type ring that has no irritating odor protects protective film
CN201810366185.6A Pending CN108559419A (en) 2016-07-12 2016-07-12 Energy saving and environment friendly recyclable pad pasting
CN201610545418.XA Pending CN106189898A (en) 2016-07-12 2016-07-12 Recyclable protecting film
CN201810346280.XA Pending CN108707433A (en) 2016-07-12 2016-07-12 The protection pad pasting that can be recycled

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CN201810342345.3A Pending CN108611014A (en) 2016-07-12 2016-07-12 Aqueous environment protection protective film
CN201810367336.XA Pending CN108559420A (en) 2016-07-12 2016-07-12 The recyclable pad pasting of water-based system
CN201710052683.9A Pending CN107629715A (en) 2016-07-12 2016-07-12 The environmentally friendly pressure sensitive adhesive tape of surface protection
CN201710052682.4A Pending CN107629718A (en) 2016-07-12 2016-07-12 The recyclable diaphragm of water-based system
CN201810342313.3A Pending CN108587511A (en) 2016-07-12 2016-07-12 Recyclable pressure sensitive adhesive tape for surface protection
CN201710052831.7A Pending CN107629716A (en) 2016-07-12 2016-07-12 Green non-pollution protects pad pasting
CN201810346282.9A Pending CN108753190A (en) 2016-07-12 2016-07-12 Reclaiming type is facilitated to protect pad pasting

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CN201810366185.6A Pending CN108559419A (en) 2016-07-12 2016-07-12 Energy saving and environment friendly recyclable pad pasting
CN201610545418.XA Pending CN106189898A (en) 2016-07-12 2016-07-12 Recyclable protecting film
CN201810346280.XA Pending CN108707433A (en) 2016-07-12 2016-07-12 The protection pad pasting that can be recycled

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CN108587511A (en) 2018-09-28
CN108559419A (en) 2018-09-21
CN107629715A (en) 2018-01-26
CN108753190A (en) 2018-11-06
CN108611014A (en) 2018-10-02
CN108707433A (en) 2018-10-26
CN107629716A (en) 2018-01-26
CN107629718A (en) 2018-01-26
CN106189898A (en) 2016-12-07

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