CN108559367A - A kind of pearl point coating - Google Patents

A kind of pearl point coating Download PDF

Info

Publication number
CN108559367A
CN108559367A CN201611246331.9A CN201611246331A CN108559367A CN 108559367 A CN108559367 A CN 108559367A CN 201611246331 A CN201611246331 A CN 201611246331A CN 108559367 A CN108559367 A CN 108559367A
Authority
CN
China
Prior art keywords
pearl point
pearl
coating
point coating
ink material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201611246331.9A
Other languages
Chinese (zh)
Other versions
CN108559367B (en
Inventor
岳志近
师照敏
岳斌
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yue Zhijin
Original Assignee
Dongguan Heng Yue Printing Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dongguan Heng Yue Printing Technology Co Ltd filed Critical Dongguan Heng Yue Printing Technology Co Ltd
Priority to CN201611246331.9A priority Critical patent/CN108559367B/en
Publication of CN108559367A publication Critical patent/CN108559367A/en
Application granted granted Critical
Publication of CN108559367B publication Critical patent/CN108559367B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • C09D11/104Polyesters
    • C09D11/105Alkyd resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Paints Or Removers (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The present invention provides a kind of pearl point coating, the pearl point coating includes construction, cured gloss oil material and ink material successively, wherein, according to mass percentage, the gloss oil material includes macromolecule polyester resin 45%~78%, higher boiling environmentally friendly solvent 16%~49%, isocyanates 0.6%~2.3% and pearl point initiator A 2%~7%;The ink material includes high concentration alkyd resin 80%~90%, low boiling point solvent 5%~22% and pearl point initiator B 0.3%~4.3%.The suitable offset printing of the pearl point coating or roller coating, easy for construction, loss is low, can increase substantially production efficiency;Can be presented pearl point decorative pattern after solidification, appearance is beautiful, it is decorative it is strong, the shallower mechanical scar in coated article body surface face and rough whole surface defect can be covered up.

Description

A kind of pearl point coating
Technical field
The present invention relates to artistic coating field more particularly to a kind of pearl point coating.
Background technology
Artistic coating is called novelty finish, fine arts paint;Artistic coating is that have special efficiency by what sapecial coating was constituted Coating variety is a kind of industrial finish, and as other coating, this coating, which is coated in body surface, can play to various objects Protective effect, unlike after its coating film forming, coating surface self-assembling formation and naturally various beautiful patterns can occur, such as Mallear stria, wrinkle, tangerine line, stone pattern, speckle, crystallized, crackle, wood grain etc.;Appearance is beautiful, decorative strong, can cover up coated article body surface The shallower mechanical scar in face and rough whole surface defect.In the prior art, the decorative pattern of pearl dot shape is mainly by spraying skill It being formed, when coating decoration, will generally spray repeatedly, first uniformly construct according to conventional spraying process, after it is completely dried, choosing The paint solution of stiff is sprayed into sparse raindrop shape varnish stain and is sprinkled upon workpiece surface under lower air pressure with the nozzle being relatively large in diameter On, paint solution point has little time levelling, and solvent has volatilized, to formed it is uniform in size, ask away from almost the same droplet shape.
However, this construction technology is to the more demanding of construction personnel and nozzle, not stable in performance, repeatability is not high, Therefore, it is necessary to provide a kind of pearl point coating, by way of offset printing or roller coating also can natural shape beading point decorative pattern, it is right Construction technology does not require, with overcome the deficiencies in the prior art.
Invention content
The purpose of the present invention is to provide a kind of pearl point coating, are suitble to offset printing or roller coating, easy for construction, presentation naturally Pearl point decorative pattern, appearance be beautiful, it is decorative it is strong, the shallower mechanical scar in coated article body surface face can be covered up and rough whole surface lacks It falls into.
To realize that the purpose, the present invention provide a kind of pearl point coating, which is characterized in that the pearl point coating includes applying successively Work, cured gloss oil material and ink material, wherein according to mass percentage, the gloss oil material includes macromolecule polyester Resin 45%~78%, higher boiling environmentally friendly solvent 16%~49%, isocyanates 0.6%~2.3% and pearl point initiator A 2%~7%;The ink material includes high concentration alkyd resin 80%~90%, low boiling point solvent 5%~22% and pearl point Initiator B 0.3%~4.3%.
The pearl point coating of the present invention is suitable on roller coating or printing to metal base, such as iron-based material or aluminium base, first It by the roller coating of gloss oil material or is printed on metal base, baking removal higher boiling environmentally friendly solvent, macromolecule at 150 DEG C~170 DEG C Polyester resin is crosslinked with isocyanates reacts film forming.Then roller coating or printing ink material on the gloss oil material after film forming Expect, high-temperature baking cures at 150 DEG C~160 DEG C, and pearl point decorative pattern is formed on ink material surface after solidification.Specifically, pearl point is spent The formation basic theory of line is:Ink material is constructed when the film surface that gloss oil material is formed, and surface tension makes ink material as possible Film is shrunk to the shape of surface area minimum, having the surface levelling of wrinkle, groove mark, streak or ridge into even curface, still, When film surface is there are when pearl point initiator B, pearl point initiator B has lower surface tension, and surface tension can be caused uneven, Generating shrinkage cavity so that the surface of ink material forms protuberance and low ebb, and bump pad is faster than the low boiling point solvent volatilization at low ebb place, this Meaning that the cooling velocity of bump pad is fast, viscosity is high, has larger surface tension, and ink material film is pulled up from low ebb is past, Low ebb is correspondingly set to become deeper, to form shrinkage cavity.In addition, being added in gloss oil material has pearl point initiator A, pearl point initiator A reduces the surface tension of gloss oil material, and the film forming for being not only conducive to gloss oil material is smooth, smooth and uniform, and gloss oil after film forming There is non-infiltration phenomenon between material and the ink material of liquid, keep the shrinkage cavity of above-mentioned formation until ink material is solidified into Shape, to form pearl point decorative pattern.
Wherein, high concentration alkyd resin is from thermosetting resin, and very fast to the release of solvent, drying property is good, and low boiling point is molten Agent is quickly volatilized under 150 DEG C~160 DEG C high temperature.
In the present invention, it can dissolve macromolecule polyester resin and boiling point can be used as this hair in 150 DEG C~170 DEG C of solvent Bright higher boiling environmentally friendly solvent, can dissolve high concentration alkyd resin and solvent of the boiling point less than 150 DEG C can be used as the present invention's Low boiling point solvent.
Preferably, the high concentration alkyd resin is polymerized by polyalcohol, vegetable oil and binary acid, the high concentration The oil content of alkyd resin is 45%~55%.
Preferably, the polyalcohol be glycerine, trimethylolpropane, trimethylolethane, pentaerythrite, ethylene glycol, At least one of 1,2-PD and 1,3-PD, the vegetable oil are linseed oil or dehydrated castor oil, the binary acid For phthalic anhydride or M-phthalic acid.
Preferably, according to mass percentage, the gloss oil material further includes levelling agent 0.1%~3%, drawing oil 0.2%~2% and wax liquor 2%~6%.
Preferably, according to mass percentage, the ink material further includes drier 0.04%~2.1%.
Preferably, according to mass percentage, the drier includes manganese dry oily 0.03%~2% or/and the dry oil of cobalt 0.01~0.1%.
Preferably, the ink material further includes having pigment.
Preferably, the pearl point initiator A is anticrater agent, including isophorone, diacetone alcohol or butyl cellulose.
Preferably, the pearl point initiator B is spheric granules object.
Preferably, the pearl point initiator B in nano silicon dioxide, carbon black, nano-magnetic powder, nano mica at least It is a kind of.
The prior art is compared, and the present invention has the advantages that:
Suitable offset printing or roller coating, easy for construction, loss is low, can increase substantially production efficiency;Can be in after solidification Existing pearl point decorative pattern, appearance is beautiful, it is decorative it is strong, the shallower mechanical scar in coated article body surface face and rough whole surface can be covered up Defect.
Figure of description
Fig. 1 is the design sketch after pearl point coating of the present invention cures on metal base, has pearl point decorative pattern.
Fig. 2 be pearl point coating of the present invention cure on metal base after another design sketch, with yellow uitramarine pattern with Pearl point decorative pattern.
Specific implementation mode
The technical solution further illustrated the present invention below by specific implementation mode.
Embodiment 1
A kind of pearl point coating is provided, including is constructed successively, cured gloss oil material and ink material, according to mass percent Meter, the gloss oil material include:
The ink material includes:
Embodiment 2
A kind of pearl point coating is provided, including is constructed successively, cured gloss oil material and ink material, according to mass percent Meter, the gloss oil material include:
The ink material includes:
Embodiment 3
A kind of pearl point coating is provided, including is constructed successively, cured gloss oil material and ink material, according to mass percent Meter, the gloss oil material include:
The ink material includes:
Embodiment 4
A kind of pearl point coating is provided, including is constructed successively, cured gloss oil material and ink material, according to mass percent Meter, the gloss oil material include:
The ink material includes:
Comparative example 1
A kind of coating is provided, including is constructed successively, cured gloss oil material and ink material, according to mass percentage, The gloss oil material includes:
The ink material includes:
The pearly coating of above-described embodiment 1~4 and the coating of comparative example 1 are constructed using identical method in metal base On, it is specific as follows:
By the gloss oil material roller coating of each embodiment and comparative example on iron substrate, toasted 10 minutes at 170 DEG C, gloss oil material Expect that film-forming, the roller coating ink material on the gloss oil material of film forming toast 10 minutes at 155 DEG C, ink material is solid Change.
The results show that comparative example 1 can only form plane pattern, no pearl point is formed.
As shown in Figure 1, being formed with pearl point decorative pattern on the ink material of each embodiment, it is notable that in ink material Pigment be distributed evenly on gloss oil material, shrinkage cavity phenomenon does not occur with the other components of ink material, Fig. 2 illustrates ink Material is printed in spider reticulation on gloss oil material, and after baking, pigment is distributed evenly on gloss oil material, shape on ink material Cheng Youzhu point decorative patterns so that pearl point coating of the invention has the effect of that characteristic, pigment can be random color.
The prior art is compared, and the present invention has the advantages that:
Suitable offset printing or roller coating, easy for construction, loss is low, can increase substantially production efficiency;Can be in after solidification Existing pearl point decorative pattern, appearance is beautiful, it is decorative it is strong, the shallower mechanical scar in coated article body surface face and rough whole surface can be covered up Defect.
More than, only presently preferred embodiments of the present invention for those of ordinary skill in the art can be according to this hair Bright technical solution and technical concept makes other various corresponding change and deformations, and all these change and distortions should all belong to In the range of the claims in the present invention.
The present invention illustrates the method detailed of the present invention by above-described embodiment, but the invention is not limited in above-mentioned detailed Method does not mean that the present invention has to rely on above-mentioned method detailed and could implement.Person of ordinary skill in the field should It is illustrated, any improvement in the present invention, addition, the concrete mode of equivalence replacement and auxiliary element to each raw material of product of the present invention Selection etc., all fall within protection scope of the present invention and the open scope.

Claims (10)

1. a kind of pearl point coating, which is characterized in that the pearl point coating includes construction, cured gloss oil material and ink material successively Material,
Wherein, according to mass percentage, the gloss oil material includes:
The ink material includes:
High concentration alkyd resin 80%~90%;
Low boiling point solvent 5%~22%;And
Pearl point initiator B 0.3%~4.3%.
2. epoxy resin as described in claim 1, which is characterized in that the high concentration alkyd resin is by polyalcohol, plant Oil and binary acid are polymerized, and the oil content of the high concentration alkyd resin is 45%~55%.
3. pearl point coating as claimed in claim 2, which is characterized in that the polyalcohol is glycerine, trimethylolpropane, three At least one of hydroxymethyl ethane, pentaerythrite, ethylene glycol, 1,2-PD and 1,3-PD, the vegetable oil are Asia Sesame oil or dehydrated castor oil, the binary acid are phthalic anhydride or M-phthalic acid.
4. pearl point coating as described in claim 1, which is characterized in that according to mass percentage, the gloss oil material also wraps It includes:
Levelling agent 0.1%~3%;
Drawing oil 0.2%~2%;And
Wax liquor 2%~6%.
5. pearl point coating as described in claim 1, which is characterized in that according to mass percentage, the ink material also wraps Include drier 0.04%~2.1%.
6. pearl point coating as claimed in claim 5, which is characterized in that according to mass percentage, the drier includes manganese Dry oily 0.03%~2% or/and cobalt dry oily 0.01~0.1%.
7. pearl point coating as described in claim 1, which is characterized in that the ink material further includes having pigment.
8. pearl point coating as described in claim 1, which is characterized in that the pearl point initiator A is anticrater agent, including different Buddhist That ketone, diacetone alcohol or butyl cellulose.
9. pearl point coating as described in claim 1, which is characterized in that the pearl point initiator B is spheric granules object.
10. pearl point coating as claimed in claim 9, which is characterized in that the pearl point initiator B be selected from nano silicon dioxide, At least one of carbon black, nano-magnetic powder, nano mica.
CN201611246331.9A 2016-12-29 2016-12-29 Bead coating Active CN108559367B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611246331.9A CN108559367B (en) 2016-12-29 2016-12-29 Bead coating

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611246331.9A CN108559367B (en) 2016-12-29 2016-12-29 Bead coating

Publications (2)

Publication Number Publication Date
CN108559367A true CN108559367A (en) 2018-09-21
CN108559367B CN108559367B (en) 2020-06-02

Family

ID=63529146

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611246331.9A Active CN108559367B (en) 2016-12-29 2016-12-29 Bead coating

Country Status (1)

Country Link
CN (1) CN108559367B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109605930A (en) * 2019-01-08 2019-04-12 厦门吉宏包装科技股份有限公司 A kind of printing technology and its printed matter forming crack effect in printed matter surface

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002212498A (en) * 2001-01-23 2002-07-31 Kansai Paint Co Ltd Paint composition to form yuzu skin-like coating film
CN101210126A (en) * 2007-12-20 2008-07-02 青岛嘉泽包装有限公司 Pearl ink and preparation method thereof
CN104231846A (en) * 2013-06-24 2014-12-24 江苏长松科技发展有限公司 Raindrop pit type art powder coating
CN104497831A (en) * 2014-12-31 2015-04-08 东莞市新威环保涂料有限公司 Crystallized coating
CN104527249A (en) * 2014-11-21 2015-04-22 杭州中粮包装有限公司 Partial pearly luster mixing metal printing method
CN104530930A (en) * 2014-12-31 2015-04-22 东莞市新威环保涂料有限公司 Orange-peel coating
CN104830210A (en) * 2015-05-15 2015-08-12 展辰涂料集团股份有限公司 Water-based dotting paint

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002212498A (en) * 2001-01-23 2002-07-31 Kansai Paint Co Ltd Paint composition to form yuzu skin-like coating film
CN101210126A (en) * 2007-12-20 2008-07-02 青岛嘉泽包装有限公司 Pearl ink and preparation method thereof
CN104231846A (en) * 2013-06-24 2014-12-24 江苏长松科技发展有限公司 Raindrop pit type art powder coating
CN104527249A (en) * 2014-11-21 2015-04-22 杭州中粮包装有限公司 Partial pearly luster mixing metal printing method
CN104497831A (en) * 2014-12-31 2015-04-08 东莞市新威环保涂料有限公司 Crystallized coating
CN104530930A (en) * 2014-12-31 2015-04-22 东莞市新威环保涂料有限公司 Orange-peel coating
CN104830210A (en) * 2015-05-15 2015-08-12 展辰涂料集团股份有限公司 Water-based dotting paint

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109605930A (en) * 2019-01-08 2019-04-12 厦门吉宏包装科技股份有限公司 A kind of printing technology and its printed matter forming crack effect in printed matter surface

Also Published As

Publication number Publication date
CN108559367B (en) 2020-06-02

Similar Documents

Publication Publication Date Title
US7351469B2 (en) Method of producing surface coatings on articles, and article having a surface coating
CN104987828B (en) Coloured UV coating with curing plastic and preparation method thereof
CN105907177A (en) Tempered glass ink for ink-jet printing and preparation method thereof
CN112852209A (en) Color-changing crack paint film and preparation method thereof
CN106634465B (en) A kind of aqueous hammer paint and its coating process
CN103144483A (en) Water transfer printing manufacturing technique applied to sanitary products
CN108219175A (en) A kind of preparation process of the silica gel product with color dot
CN104591786A (en) Manufacturing method of ceramic sheet with infiltration layer
CN111976248A (en) Stain-resistant scratch-resistant PVC decorative film and preparation method thereof
CN108559367A (en) A kind of pearl point coating
CN103756485B (en) Water-based is coated with tin graphed sheet whitewash and preparation method thereof outward
CN216473010U (en) Color-changing crackle paint film
JP6294315B2 (en) Thermally stable particulate ink for inkjet applications
CN104591804A (en) Preparation method of ceramic brick with stereoscopic decorative effects
CN102774227A (en) Method for manufacturing decorative plate painting
US6780512B2 (en) Methods for preparing decorative coatings
CN104085243A (en) Making method of vitrolite painting
CN103551294A (en) Furniture screen printing internal engraving 3D (three-dimensional) paint process
CN106366901A (en) Doubly solidified coloring UV nanometer paint
CN105331188B (en) Art printing ink for crystallized metal printing
CN101623974A (en) Emblema method of decorative board
CN103317931A (en) Surface processing technology of plastic base material panel
CN108822617A (en) A kind of clothes printing ink and preparation method thereof
CN101342841A (en) Method for preparing ceramics handicraft article
CN105017885B (en) A kind of automatic throwing type lacquer painting renovation agent

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
TR01 Transfer of patent right

Effective date of registration: 20201125

Address after: Room 901, building 8, feicuiwan, country garden, Qingxi Town, Dongguan City, Guangdong Province 523000

Patentee after: Yue Zhijin

Address before: 523000, Dongguan, Guangdong province Qing Qing town, Wang Qing village, new round of commercial residential building 8 berth

Patentee before: DONGGUAN HENGYUE PRINTING TECHNOLOGY Co.,Ltd.

TR01 Transfer of patent right