CN108558425A - A kind of preparation method of enhancing artificial graphite material - Google Patents
A kind of preparation method of enhancing artificial graphite material Download PDFInfo
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Abstract
The invention belongs to graphite material preparing technical fields, and in particular to a kind of preparation method of enhancing artificial graphite material.The method of the present invention first pre-processes staple fiber, then will quickly be stirred in the binder pitch after the addition fusing of processed chopped carbon fiber, keeps its evenly dispersed into monofilament state;Followed by, the binder pitch for being dispersed with carbon fiber is added in kneading pot and carries out kneading stirring with by the coke granule prepared, finally, mixed thickener is added in press and suppresses raw product, and by roasting, impregnating, graphitization obtains fibre reinforced artificial graphite material at appropriate temperatures.Artificial graphite material made from the method for the present invention has the characteristics that bending strength is high, compression strength is high, resistivity is low, coefficient of thermal expansion is low.
Description
Technical field
The invention belongs to graphite material preparing technical fields, more particularly to a kind of preparation side of enhancing artificial graphite material
Method.
Background technology
Common artificial graphite material is added few using high-quality calcined petroleum coke, binder pitch as primary raw material
Measure other auxiliary materials.By crushing, dispensing, molding, roasting, dipping, the then graphite in 2500 ~ 3000 DEG C, non-oxidizing atmosphere
Change and is made.Artificial graphite material has layer structure, mechanical strength relatively low.
Carbon fiber has the excellent performances such as intensity, modulus and the corrosion resistance of superelevation, using it as the compound of reinforcing filler
Material is widely used in the fields such as Aeronautics and Astronautics, sports apparatus, therefore using carbon fiber as reinforcing filler, and being made has netted knot
The artificial graphite material of structure improves the mechanical performance of material.
When preparing carbon fibre reinforced composite, depended on since each carbon fiber wire can attract each other, it is difficult to disperse.
Carbon fiber in the base bad dispersibility the main reason for:1, carbon mono-filaments are tiny, and surface area ratio is larger, and knot is easy in collective
Group is not easy fine dispersion;2, carbon fiber surface activity group is few, and surface-active is low etc..Carbon fiber poor dispersion is just difficult to send out completely
Its netted humidification is waved, the performance of prepared material is directly affected.Evenly dispersed technology is always in the base for carbon fiber
It is a problem in use.
Carbon fiber bundle how can be just set to be uniformly dispersed into thinner carbon fiber pencil or single in matrix or solution
Carbon fiber filament, binder pitch used according to the invention are this feature of oiliness matrix, select a kind of lipophilic anion type
Surfactant Treatment of Carbon makes it have good dispersibility and adhesiveness, can be the case where not increasing carbon fiber dosage
Under make carbon fiber evenly dispersed to significantly improve the mechanical property of composite material in the base as possible.Its dispersion mechanism:1, pass through
Suction-operated is adsorbed on carbon fiber surface, and a thin layer of lubricating film is formed in carbon fiber surface, reduces the friction between fiber
Power and adhesion strength make carbon fiber slip over mutually without easy entanglement;2, the surface electricity between increased fiber, i.e., between increased fiber
Surface repulsion.
Invention content
In view of this, the purpose of the present invention is to provide a kind of preparation method with enhancing artificial graphite material, the party
Graphite material bending strength made from method is high, compression strength is high.
The technical solution adopted in the present invention is:
A kind of preparation method of enhancing artificial graphite material, includes the following steps:
1)Each raw material is taken in proportion, and coke granule is prepared by size distribution;
2)By lipophile fatty alcohol ether formulation of phosphoric acid esters and water mixing wiring solution-forming, then with the spray solution carbon fiber, then general
Carbon fiber is dried;
3)Binder is heated and is melted, by step 2)The carbon fiber of dispersion is added in binder and stirs, and carbon fiber is made to be dispersed into
Monofilament state is distributed in a binder;
4)Coke granule is put into kneading pot heating stirring, by step 3)Kneading is added in the binder obtained for being dispersed with carbon fiber
Pot continues kneading stirring, first stirring another mistake hour hands stirring clockwise, to obtain the equally distributed thickener of carbon fiber;
5)By step 4)Thickener obtained is put into extruder, and extruding obtains raw product;
6)By step 5)Raw product be put into graphite crucible and be placed in atmosphere furnace and roasted, roasting obtains a burning product;
7)By step 6)One burn product carry out impregnating by pressure, obtain a leaching product;
8)Step 7)An obtained leaching product repeat step 6)After baking is carried out, two burning product are obtained;
9)By step 8)Two obtained burning product repeat step 7)It carries out impregnating by pressure and obtains two leaching product;
10)Step 9)An obtained leaching product repeat step 6)It is roasted three times, obtains three burning product;
11)By step 10)Three obtained burning product be put into vacuum induction graphitizing furnace carry out graphitization processing obtain enhancing it is artificial
Graphite material.
The step 2)A concentration of 1.0~5.0wt% of middle solution, drying temperature are 80~90 DEG C.
The step 4)When middle heating stirring, 160~180 DEG C of kneading temperature, 30~40min of kneading time;Clockwise or
The time stirred counterclockwise is 15-30min.
The step 5)In pressure 20~30MPa precompressed 3min when extruding, then with the extrusion speed of 50~60mm/min into
Row squeezes.
The step 6)Roasting process is:It first vacuumizes, later inflated with nitrogen, adjustment nitrogen flow is 5L/min, according to 10
DEG C/heating of h heating rates, fire door and furnace roof cooling water are opened when temperature is more than 300 DEG C, are finally warming up to 900~1000 DEG C;
After heating, heating power supply is closed, stops leading to nitrogen when temperature in burner hearth is less than 400 DEG C, when fire box temperature is less than 200 DEG C
Cooling water is closed, roasting is terminated;
The step 7)Impregnating agent is the pitch of low quinoline insolubles content≤3.0%, dipping temperature 180~200 when impregnating by pressure
DEG C, 2.0~3.0MPa of impregnation pressure, 1.5~2h of dip time;
The step 11)It is first vacuumized when graphitization processing, when vacuum degree reaches 10-50Pa, beginning feeding temperature-raising graphitization, stone
2900 DEG C of inkization temperature, graphitization plot against time control is in 15h-20h.
One burns curve:
Two, which burn/tri-, burns curve:
Step 1)Middle raw material is carbon fiber, coke granule and binder, and the mass ratio of carbon fiber, coke granule and binder is
(0.01~0.10):1:(0.34~0.42);The group of coke granule as granularity be 2~0.5mm coke granule contents be 10~
25wt%, granularity be 0.5~0.1mm coke granule contents be 20~30w%, granularity is that 0.1~0mm coke granule contents are 50
~70w%.
The length of the carbon fiber is 2~3mm.
The present invention provide it is a kind of by keep carbon fiber evenly dispersed to produce preferably enhancing performance artificial graphite material
The method of material handles chopped carbon fiber and drying using lipophilic surfactant spray solution first;It then will be processed
It is quickly stirred in the binder pitch that chopped carbon fiber is added after fusing, keeps its evenly dispersed into monofilament state;Followed by, will point
Dissipating has the binder pitch of carbon fiber to be added in kneading pot carries out kneading stirring, first positive direction with by the coke granule prepared
Mix 15min, then negative direction mixing 15min;Finally, mixed thickener is added in press and suppresses raw product, and pass through roasting
It burns, dipping, graphitization obtains fibre reinforced artificial graphite material at appropriate temperatures.
When to pre-treatment of carbon fiber, selects a kind of lipophilic anion type surfactant to carry out Treatment of Carbon, made
It can make carbon fiber bundle be uniformly dispersed into thinner carbon fiber in matrix or solution in this way with good dispersibility and adhesiveness
Pencil or single carbon fiber filament are tieed up, does not have fiber agglomeration substantially, can not increase carbon fiber Wesy in this way
Make carbon fiber evenly dispersed to significantly improve the mechanical property of artificial graphite material in the base in the case of amount as possible.Its mechanism
It is that lipophilic anion type surfactant is adsorbed on carbon fiber surface by suction-operated, is formed in carbon fiber surface one layer thin
Thin lubricating film reduces frictional force and adhesion strength between fiber, Carbon fibe is made to slip over mutually without easy entanglement, while increased fiber
Between surface electricity, i.e., the surface repulsion between increased fiber.
The process conditions of each step are strictly controlled in the preparation, caused by control carbon fiber length avoids carbon fiber long
It is formed and is reunited in whipping process, while the too short caused mechanical property of carbon fiber being avoided to promote unobvious;It is kept away when graphitization processing
Exempt from that temperature is excessively high, this is because excessively high graphitization temperature can reduce enhancing performance of the carbon fiber to material;Final present invention system
Artificial graphite material have the characteristics that bending strength is high, compression strength height, resistivity is low, coefficient of thermal expansion is low, and it is common
Artificial graphite material is compared, and material bending strength and compression strength improve 40-80%.
Description of the drawings
Fig. 1 is the process flow chart of the present invention.
Specific implementation mode
Illustrate the specific implementation mode of the present invention with reference to the accompanying drawings and examples, but following embodiment is used only in detail
It describes the bright present invention in detail, does not limit the scope of the invention in any way.
Embodiment 1:
A kind of enhancing artificial graphite material, raw materials used is carbon fiber(Length 2mm), coke granule and binder, carbon fiber, coke
The mass ratio of charcoal particle and binder is 0.01:1:0.34;It is that 2~0.5mm coke granules contain that the group of coke granule, which becomes granularity,
Amount be 10wt%, granularity be 0.5~0.1mm coke granule contents be 20w%, granularity is that 0.1~0mm coke granule contents are
70w%.Preparation process is as follows:
1)Each raw material is taken in proportion, and coke granule is prepared by size distribution;
2)Lipophile fatty alcohol ether formulation of phosphoric acid esters is mixed with water and is made into a concentration of 1.0wt% solution, then with the spray solution
Carbon fiber, then will be dried at 80 DEG C of carbon fiber;
3)Binder is heated and is melted, by step 2)The carbon fiber of dispersion is added in binder and stirs, and carbon fiber is made to be dispersed into
Monofilament state is distributed in a binder;
4)Coke granule is put into kneading pot heating stirring, 160 DEG C of kneading temperature, kneading time 40min;By step 3)It is obtained
The continuation kneading stirring of kneading pot is added in the binder for being dispersed with carbon fiber, and first stirring 15min another mistake hour hands stir clockwise
15min avoids whipping process carbon fiber from reuniting, to obtain the equally distributed thickener of carbon fiber;
5)By step 4)Thickener obtained is put into extruder, in pressure 20MPa precompressed 3min when extruding, then with 50mm/min's
Extrusion speed is squeezed, and extruding obtains raw product;
6)By step 5)Raw product be put into graphite crucible and be placed in atmosphere furnace and roasted, first vacuumize, later nitrogen charging
Gas, adjustment nitrogen flow are 5L/min, are heated according to 10 DEG C/h heating rates, fire door and stove are opened when temperature is more than 300 DEG C
Cooling water is pushed up, is finally warming up to 900 DEG C;After heating, heating power supply is closed, is stopped when temperature in burner hearth is less than 400 DEG C
Logical nitrogen, fire box temperature close cooling water when being less than 200 DEG C, terminate roasting and obtain a burning product;
7)By step 6)One burn product carry out impregnating by pressure, impregnating agent be low quinoline insolubles content≤3.0% pitch, dipping
180 DEG C, impregnation pressure 2.0MPa, dip time 2h of temperature, obtains a leaching product;
8)Step 7)An obtained leaching product repeat step 6)After baking is carried out, two burning product are obtained;
9)By step 8)Two obtained burning product repeat step 7)It carries out impregnating by pressure and obtains two leaching product;
10)Step 9)An obtained leaching product repeat step 6)It is roasted three times, obtains three burning product;
11)By step 10)Three obtained burning product, which are put into vacuum induction graphitizing furnace, carries out graphitization processing, first vacuumizes, when
Vacuum degree reaches 50Pa, starts feeding temperature-raising graphitization, 2900 DEG C of graphitization temperature, and graphitization plot against time control is obtained in 15h
To enhancing artificial graphite material.
Embodiment 2:
A kind of enhancing artificial graphite material, raw materials used is carbon fiber(Length 2mm), coke granule and binder, carbon fiber, coke
The mass ratio of charcoal particle and binder is 0.05:1:0.4;It is that 2~0.5mm coke granules contain that the group of coke granule, which becomes granularity,
Amount be 25wt%, granularity be 0.5~0.1mm coke granule contents be 25w%, granularity is that 0.1~0mm coke granule contents are
50w%。
Preparation process is as follows:
1)Each raw material is taken in proportion, and coke granule is prepared by size distribution;
2)Lipophile fatty alcohol ether formulation of phosphoric acid esters is mixed with water and is made into a concentration of 3wt% solution, then with the spray solution carbon
Fiber, then will be dried at 85 DEG C of carbon fiber;
3)Binder is heated and is melted, by step 2)The carbon fiber of dispersion is added in binder and stirs, and carbon fiber is made to be dispersed into
Monofilament state is distributed in a binder;
4)Coke granule is put into kneading pot heating stirring, 170 DEG C of kneading temperature, kneading time 35min;By step 3)It is obtained
The continuation kneading stirring of kneading pot is added in the binder for being dispersed with carbon fiber, and first stirring 25min another mistake hour hands stir clockwise
25min avoids whipping process carbon fiber from reuniting, to obtain the equally distributed thickener of carbon fiber;
5)By step 4)Thickener obtained is put into extruder, in pressure 25MPa precompressed 3min when extruding, then squeezing with 55mm/min
Pressure speed is squeezed, and extruding obtains raw product;
6)By step 5)Raw product be put into graphite crucible and be placed in atmosphere furnace and roasted, first vacuumize, later nitrogen charging
Gas, adjustment nitrogen flow are 5L/min, are heated according to 10 DEG C/h heating rates, fire door and stove are opened when temperature is more than 300 DEG C
Cooling water is pushed up, is finally warming up to 950 DEG C;After heating, heating power supply is closed, is stopped when temperature in burner hearth is less than 400 DEG C
Logical nitrogen, fire box temperature close cooling water when being less than 200 DEG C, terminate roasting and obtain a burning product;
7)By step 6)One burn product carry out impregnating by pressure, impregnating agent be low quinoline insolubles content≤3.0% pitch, dipping
190 DEG C, impregnation pressure 2.5MPa, dip time 2h of temperature, obtains a leaching product;
8)Step 7)An obtained leaching product repeat step 6)After baking is carried out, two burning product are obtained;
9)By step 8)Two obtained burning product repeat step 7)It carries out impregnating by pressure and obtains two leaching product;
10)Step 9)An obtained leaching product repeat step 6)It is roasted three times, obtains three burning product;
11)By step 10)Three obtained burning product, which are put into vacuum induction graphitizing furnace, carries out graphitization processing, first vacuumizes, when
Vacuum degree reaches 30Pa, starts feeding temperature-raising graphitization, 2900 DEG C of graphitization temperature, and graphitization plot against time control is obtained in 18h
To enhancing artificial graphite material.
Embodiment 3:
A kind of enhancing artificial graphite material, raw materials used is carbon fiber(Length 2mm), coke granule and binder, carbon fiber, coke
The mass ratio of charcoal particle and binder is 0.1:1: 0.42;It is that 2~0.5mm coke granules contain that the group of coke granule, which becomes granularity,
Amount be 15wt%, granularity be 0.5~0.1mm coke granule contents be 25w%, granularity is that 0.1~0mm coke granule contents are
60w%.Preparation process is as follows:
1)Each raw material is taken in proportion, and coke granule is prepared by size distribution;
2)Lipophile fatty alcohol ether formulation of phosphoric acid esters is mixed with water and is made into a concentration of 5.0wt% solution, then with the spray solution
Carbon fiber, then will be dried at 90 DEG C of carbon fiber;
3)Binder is heated and is melted, by step 2)The carbon fiber of dispersion is added in binder and stirs, and carbon fiber is made to be dispersed into
Monofilament state is distributed in a binder;
4)Coke granule is put into kneading pot heating stirring, 180 DEG C of kneading temperature, kneading time 40min;By step 3)It is obtained
The continuation kneading stirring of kneading pot is added in the binder for being dispersed with carbon fiber, and first stirring 30min another mistake hour hands stir clockwise
30min avoids whipping process carbon fiber from reuniting, to obtain the equally distributed thickener of carbon fiber;
5)By step 4)Thickener obtained is put into extruder, in pressure 30MPa precompressed 3min when extruding, then with 60mm/min's
Extrusion speed is squeezed, and extruding obtains raw product;
6)By step 5)Raw product be put into graphite crucible and be placed in atmosphere furnace and roasted, first vacuumize, later nitrogen charging
Gas, adjustment nitrogen flow are 5L/min, are heated according to 10 DEG C/h heating rates, fire door and stove are opened when temperature is more than 300 DEG C
Cooling water is pushed up, is finally warming up to 1000 DEG C;After heating, heating power supply is closed, is stopped when temperature in burner hearth is less than 400 DEG C
Logical nitrogen, fire box temperature close cooling water when being less than 200 DEG C, terminate roasting and obtain a burning product;
7)By step 6)One burn product carry out impregnating by pressure, impregnating agent be low quinoline insolubles content≤3.0% pitch, dipping
200 DEG C, impregnation pressure 3.0MPa, dip time 1.5h of temperature, obtains a leaching product;
8)Step 7)An obtained leaching product repeat step 6)After baking is carried out, two burning product are obtained;
9)By step 8)Two obtained burning product repeat step 7)It carries out impregnating by pressure and obtains two leaching product;
10)Step 9)An obtained leaching product repeat step 6)It is roasted three times, obtains three burning product;
11)By step 10)Three obtained burning product, which are put into vacuum induction graphitizing furnace, carries out graphitization processing, first vacuumizes, when
Vacuum degree reaches 10Pa, starts feeding temperature-raising graphitization, 2900 DEG C of graphitization temperature, and graphitization plot against time control is obtained in 20h
To enhancing artificial graphite material.
Embodiment 4:
A kind of enhancing artificial graphite material, raw materials used is carbon fiber(Length 3mm), coke granule and binder, carbon fiber, coke
The mass ratio of charcoal particle and binder is 0.08:1:0.36;It is that 2~0.5mm coke granules contain that the group of coke granule, which becomes granularity,
Amount be 10wt%, granularity be 0.5~0.1mm coke granule contents be 30w%, granularity is that 0.1~0mm coke granule contents are
60w%。
With embodiment 2 when preparation.
Embodiment 5:
A kind of enhancing artificial graphite material, raw materials used is carbon fiber(Length 3mm), coke granule and binder, carbon fiber, coke
The mass ratio of charcoal particle and binder is 0.06:1:0.38;It is that 2~0.5mm coke granules contain that the group of coke granule, which becomes granularity,
Amount be 25wt%, granularity be 0.5~0.1mm coke granule contents be 20w%, granularity is that 0.1~0mm coke granule contents are
55w%。
With embodiment 1 when preparation.
Embodiment 6:
A kind of enhancing artificial graphite material, raw materials used is carbon fiber(Length 3mm), coke granule and binder, carbon fiber,
The mass ratio of coke granule and binder is 0.07:1:0.35;It is 2~0.5mm coke granules that the group of coke granule, which becomes granularity,
Content is 10wt%, granularity be 0.5~0.1mm coke granule contents be 30w%, granularity is that 0.1~0mm coke granule contents are
60w%。
With embodiment 3 when preparation.
Flexural strength, compression strength and the resistivity and heat that enhancing artificial graphite material is made are corresponded to each embodiment
The coefficient of expansion is detected, and testing result see the table below:
Found out by data above, is obtained using enhancing artificial graphite material flexural strength, compression strength made from the method for the present invention
It significantly improves, is fully able to meet the needs of properties of product.
Finally illustrate, the above examples are only used to illustrate the technical scheme of the present invention and are not limiting, this field is common
Other modifications or equivalent replacement that technical staff makes technical scheme of the present invention, without departing from technical solution of the present invention
Spirit and scope, be intended to be within the scope of the claims of the invention.
Claims (9)
1. a kind of preparation method of enhancing artificial graphite material, which is characterized in that include the following steps:
1)Each raw material is taken in proportion, and coke granule is prepared by size distribution;
2)By lipophile fatty alcohol ether formulation of phosphoric acid esters and water mixing wiring solution-forming, then with the spray solution carbon fiber, then general
Carbon fiber is dried;
3)Binder is heated and is melted, by step 2)The carbon fiber of dispersion is added in binder and stirs, and carbon fiber is made to be dispersed into
Monofilament state is distributed in a binder;
4)Coke granule is put into kneading pot heating stirring, by step 3)Kneading is added in the binder obtained for being dispersed with carbon fiber
Pot continues kneading stirring, first stirring another mistake hour hands stirring clockwise, to obtain the equally distributed thickener of carbon fiber;
5)By step 4)Thickener obtained is put into extruder, and extruding obtains raw product;
6)By step 5)Raw product be put into graphite crucible and be placed in atmosphere furnace and roasted, roasting obtains a burning product;
7)By step 6)One burn product carry out impregnating by pressure, obtain a leaching product;
8)Step 7)An obtained leaching product repeat step 6)After baking is carried out, two burning product are obtained;
9)By step 8)Two obtained burning product repeat step 7)It carries out impregnating by pressure and obtains two leaching product;
10)Step 9)An obtained leaching product repeat step 6)It is roasted three times, obtains three burning product;
11)By step 10)Three obtained burning product be put into vacuum induction graphitizing furnace carry out graphitization processing obtain enhancing it is artificial
Graphite material.
2. the preparation method of enhancing artificial graphite material according to claim 3, it is characterised in that:The step 2)In it is molten
A concentration of 1.0~5.0wt% of liquid, drying temperature are 80~90 DEG C.
3. the preparation method of enhancing artificial graphite material according to claim 3, it is characterised in that:The step 4)In plus
When thermal agitation, 160~180 DEG C of kneading temperature, 30~40min of kneading time;The time stirred clockwise or counterclockwise is 15-
30min。
4. the preparation method of enhancing artificial graphite material according to claim 3, it is characterised in that:The step 5)It squeezes
When squeezed in pressure 20~30MPa precompressed 3min, then with the extrusion speed of 50~60mm/min.
5. the preparation method of enhancing artificial graphite material according to claim 3, it is characterised in that:The step 6)Roasting
Process is:It first vacuumizes, later inflated with nitrogen, adjustment nitrogen flow is 5L/min, is heated according to 10 DEG C/h heating rates, works as temperature
Fire door and furnace roof cooling water are opened when more than 300 DEG C, are finally warming up to 900~1000 DEG C;After heating, heating electricity is closed
Source stops leading to nitrogen when temperature in burner hearth is less than 400 DEG C, and fire box temperature closes cooling water when being less than 200 DEG C, terminate roasting.
6. the preparation method of enhancing artificial graphite material according to claim 3, it is characterised in that:The step 7)Pressurization
When dipping impregnating agent be low quinoline insolubles content≤3.0% pitch, 180~200 DEG C of dipping temperature, impregnation pressure 2.0~
3.0MPa, 1.5~2h of dip time.
7. the preparation method of enhancing artificial graphite material according to claim 3, it is characterised in that:The step 11)Stone
It is first vacuumized when inkization processing, when vacuum degree reaches 10-50Pa, beginning feeding temperature-raising graphitization, 2900 DEG C of graphitization temperature, stone
Inkization plot against time is controlled in 15h-20h.
8. the preparation method of enhancing artificial graphite material according to claim 1, it is characterised in that:Step 1)Middle raw material is
The mass ratio of carbon fiber, coke granule and binder, carbon fiber, coke granule and binder is(0.01~0.10):1:(0.34
~0.42);The group of coke granule as granularity be 2~0.5mm coke granule contents be 10~25wt%, granularity be 0.5~
0.1mm coke granule contents are 20~30w%, granularity is that 0.1~0mm coke granule contents are 50~70w%.
9. the preparation method of enhancing artificial graphite material according to claim 8, it is characterised in that:The length of the carbon fiber
Degree is 2~3mm.
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CN114538946A (en) * | 2022-03-09 | 2022-05-27 | 湖南大学 | High-strength and high-toughness graphite and preparation method thereof |
CN115141004A (en) * | 2022-08-11 | 2022-10-04 | 佛山欧神诺陶瓷有限公司 | Preparation method and application of high-strength ceramic rock plate |
CN116178018A (en) * | 2023-03-15 | 2023-05-30 | 黑龙江省墨砾新型材料有限责任公司 | Fine-particle high-tap-density spherical graphite |
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CN111348929A (en) * | 2020-03-13 | 2020-06-30 | 河南开炭新材料设计研究院有限公司 | Carbon fiber reinforced porous heat-insulating carbon block and preparation method thereof |
CN114538946A (en) * | 2022-03-09 | 2022-05-27 | 湖南大学 | High-strength and high-toughness graphite and preparation method thereof |
CN115141004A (en) * | 2022-08-11 | 2022-10-04 | 佛山欧神诺陶瓷有限公司 | Preparation method and application of high-strength ceramic rock plate |
CN116178018A (en) * | 2023-03-15 | 2023-05-30 | 黑龙江省墨砾新型材料有限责任公司 | Fine-particle high-tap-density spherical graphite |
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Address after: Dong Jiao Bian Cun, Shunhe District, Kaifeng City, Henan Province Applicant after: Kaifeng Pingmei new carbon material technology Co., Ltd Address before: 475000 east suburb village of Shun He District, Kaifeng City, Henan Applicant before: Kaifeng Carbon Co., Ltd., China Pingmei Shenma Group |
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Application publication date: 20180921 |