CN108558243A - A kind of clay hardening agent and preparation method thereof - Google Patents
A kind of clay hardening agent and preparation method thereof Download PDFInfo
- Publication number
- CN108558243A CN108558243A CN201711446871.6A CN201711446871A CN108558243A CN 108558243 A CN108558243 A CN 108558243A CN 201711446871 A CN201711446871 A CN 201711446871A CN 108558243 A CN108558243 A CN 108558243A
- Authority
- CN
- China
- Prior art keywords
- clay
- red mud
- hardening agent
- metakaolin
- gypsum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/24—Cements from oil shales, residues or waste other than slag
- C04B7/243—Mixtures thereof with activators or composition-correcting additives, e.g. mixtures of fly ash and alkali activators
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
The present invention relates to a kind of clay hardening agent and preparation method thereof, including：Red mud, metakaolin, carbide slag and gypsum, wherein the mass ratio of clay hardening agent each component is：Red mud is 50 70 parts, 10 20 parts of metakaolin, 5 15 parts of battery slag, 5 10 parts of gypsum.The clay hardening agent and preparation method thereof uses solid waste for primary raw material, the solidification that clay is realized using solid waste chemical property itself and mutual activity excitation has the characteristics that non-secondary pollution, of low cost, preparation is convenient and resource utilization is high.
Description
Technical field
The present invention relates to field of environment engineering technology, more particularly to a kind of clay hardening agent and preparation method thereof.
Background technology
With the iterative method of China's industrialization and urbanization, domestic waste problem is concerned by people further.
Garbage-surrounded city phenomenon is very prominent, Domestic Waste Minimization, innoxious extremely urgent with recycling treatment.Currently, garbage loading embeading
It is the main disposal options of China's house refuse.Due to China's house refuse complicated component,
Rubbish after landfill is in H2O and O2Under the action of be decomposed to form a large amount of percolates, research shows that main in landfill leachate
63 kinds of organic pollution and various heavy metal contaminants are wanted, ecological environment security around landfill yard and resident's health are caused
Great threat.Clay compaction impervious barrier is one of common percolate impervious barrier, to improve the impermeability and durability of argillic horizon,
Inorganic coagulation material (cement, lime, flyash) etc. is common to do clay lenses additive.
Inorganic coagulation material treated clay has that of high cost, infiltration coefficient is big, intensity is low and durable in the prior art
Property it is poor the shortcomings of, in addition, the productions such as inorganic coagulation materials such as cement have the drawbacks such as high energy consumption, high pollution.
Invention content
The present invention provides a kind of clay hardening agent and preparation method thereof, solve or part solve in the prior art without
Machine cementitious material treated clay has technical problem of high cost, infiltration coefficient is big, intensity is low and durability is poor.
A kind of clay hardening agent provided by the invention, including：Red mud, metakaolin, carbide slag and gypsum, wherein described
The mass ratio of clay hardening agent each component is：The red mud be 50-70 parts, described metakaolin 10-20 parts, the battery slag 5-
15 parts, described gypsum 5-10 parts.
Based on same inventive concept, present invention also provides a kind of preparation methods of clay hardening agent, are used to prepare institute
Clay hardening agent is stated, is included the following steps：
After washing by the red mud, it is dried under the conditions of 60 DEG C, ball milling simultaneously sieves with 100 mesh sieve；Wherein, in the red mud
CaO content is higher than 30%, Al2O3Content is higher than 10%；
The metakaolin is dried under the conditions of 60 DEG C, through ball milling and is sieved with 100 mesh sieve；
The carbide slag is dried under the conditions of 60 DEG C, through ball milling and is sieved with 100 mesh sieve, the content of CaO in the carbide slag
More than 65%；
The gypsum is dried under the conditions of 60 DEG C, through ball milling and is sieved with 100 mesh sieve；
At normal temperatures, the red mud, the metakaolin, the carbide slag and the gypsum are uniformly mixed described in being formed
Clay hardening agent.
One or more technical solutions provided herein, have at least the following technical effects or advantages：
Red mud avoids shadow of the soluble-salt to follow-up hydration reaction by washing, effectively removing soluble-salt therein
It rings, improves gelling reaction intensity, carbide slag can guarantee the activating oxide in red mud, metakaolin and gypsum, the silicon of generation
Calcium aluminate gel can realize the solidification of clay, and clay particle is made to reunite, and enhance the cohesive force between clay particle, reduce clay
Pore volume, make the clay after disposition have higher-strength, lower permeability and good long-time stability.The curing agent
It uses industrial residue for primary raw material, clay is realized using industrial residue chemical property itself and mutual activity excitation
Solidification has the characteristics that of low cost, resource utilization is high and disposition effect is good.In this way, efficiently solve in the prior art without
Machine cementitious material treated clay has technical problem of high cost, infiltration coefficient is big, intensity is low and durability is poor, realizes
Intensity is high, infiltration coefficient is low and long-time stability are good, and prepare convenient, of low cost and low stain, low energy consumption technique effect.
Description of the drawings
Fig. 1 is the flow diagram of the preparation method of clay hardening agent provided by the invention.
Specific implementation mode
Clay hardening agent provided by the embodiments of the present application and preparation method thereof, solves or part solves in the prior art
Inorganic coagulation material treated clay has technical problem of high cost, infiltration coefficient is big, intensity is low and durability is poor.
A kind of clay hardening agent provided by the invention, including：Red mud, metakaolin, carbide slag and gypsum, wherein clay
The mass ratio of curing agent each component is：Red mud is 50-70 parts, 10-20 parts of metakaolin, 5-15 parts of battery slag, 5-10 parts of gypsum.
Based on same inventive concept, referring to attached drawing 1, present invention also provides a kind of preparation method of clay hardening agent,
It is used to prepare clay hardening agent, is included the following steps：
S1：After washing by red mud, it is dried under the conditions of 60 DEG C, ball milling simultaneously sieves with 100 mesh sieve；Wherein, CaO content in red mud
Higher than 30%, Al2O3Content is higher than 10%.
S2：Metakaolin is dried under the conditions of 60 DEG C, through ball milling and is sieved with 100 mesh sieve.
S3：Carbide slag is dried under the conditions of 60 DEG C, through ball milling and is sieved with 100 mesh sieve, the content of CaO is more than in carbide slag
65%.
S4：Gypsum is dried under the conditions of 60 DEG C, through ball milling and is sieved with 100 mesh sieve.
S5：At normal temperatures, red mud, metakaolin, carbide slag and gypsum are uniformly mixed and form clay hardening agent.
Clay hardening agent provided by the present application and preparation method thereof is discussed in detail below by specific embodiment：
Case study on implementation 1
The red mud that CaO content is 32% is chosen, red mud is cleaned with tap water, then is dried under the conditions of 60 DEG C, using ball
Grinding machine sieves with 100 mesh sieve rock phosphate in powder ball milling.The carbide slag that CaO content is 68% is dried under the conditions of 60 DEG C, simultaneously through ball milling
It sieves with 100 mesh sieve.Gypsum and metakaolin are dried under the conditions of 60 DEG C, through ball milling and sieved with 100 mesh sieve.
Weigh that treated respectively red mud 60kg, metakaolin 15kg, carbide slag 15kg, gypsum 10kg, is uniformly mixed shape
Resulting mixture forms curing agent.The curing agent additive amount is the 10%-30% of clay quality.
Case study on implementation 2
The red mud that CaO content is 35% is chosen, red mud is cleaned with tap water, then is dried under the conditions of 60 DEG C, using ball
Grinding machine sieves with 100 mesh sieve rock phosphate in powder ball milling.The carbide slag that CaO content is 72% is dried under the conditions of 60 DEG C, simultaneously through ball milling
It sieves with 100 mesh sieve.Gypsum and metakaolin are dried under the conditions of 60 DEG C, through ball milling and sieved with 100 mesh sieve.
Weigh that treated respectively red mud 70kg, metakaolin 15kg, carbide slag 10kg, gypsum 5kg, is uniformly mixed and is formed
Mixture forms curing agent.The curing agent additive amount is the 10%-30% of clay quality.
Case study on implementation 3
The red mud that CaO content is 38% is chosen, red mud is cleaned with tap water, then is dried under the conditions of 60 DEG C, using ball
Grinding machine sieves with 100 mesh sieve rock phosphate in powder ball milling.The carbide slag that CaO content is 76% is dried under the conditions of 60 DEG C, simultaneously through ball milling
It sieves with 100 mesh sieve.Gypsum and metakaolin are dried under the conditions of 60 DEG C, through ball milling and sieved with 100 mesh sieve.
Weigh that treated respectively red mud 55kg, metakaolin 20kg, carbide slag 15kg, gypsum 10kg, is uniformly mixed shape
Resulting mixture forms curing agent.The curing agent additive amount is the 10%-30% of clay quality.
One or more technical solutions provided herein, have at least the following technical effects or advantages：
Red mud avoids shadow of the soluble-salt to follow-up hydration reaction by washing, effectively removing soluble-salt therein
It rings, improves gelling reaction intensity, carbide slag can guarantee the activating oxide in red mud, metakaolin and gypsum, the silicon of generation
Calcium aluminate gel can realize the solidification of clay, and clay particle is made to reunite, and enhance the cohesive force between clay particle, reduce clay
Pore volume, make the clay after disposition have higher-strength, lower permeability and good long-time stability.The curing agent
It uses industrial residue for primary raw material, clay is realized using industrial residue chemical property itself and mutual activity excitation
Solidification has the characteristics that of low cost, resource utilization is high and disposition effect is good.In this way, efficiently solve in the prior art without
Machine cementitious material treated clay has technical problem of high cost, infiltration coefficient is big, intensity is low and durability is poor, realizes
Intensity is high, infiltration coefficient is low and long-time stability are good, and prepare convenient, of low cost and low stain, low energy consumption technique effect.
Above-described specific implementation mode has carried out further the purpose of the present invention, technical solution and advantageous effect
It is described in detail, it should be understood that the foregoing is merely the specific implementation mode of the present invention, is not limited to this hair
Bright, all within the spirits and principles of the present invention, any modification, equivalent substitution, improvement and etc. done should be included in the present invention
Protection domain within.
Claims (2)
1. a kind of clay hardening agent, which is characterized in that including：Red mud, metakaolin, carbide slag and gypsum, wherein the clay
The mass ratio of curing agent each component is：The red mud be 50-70 parts, described metakaolin 10-20 parts, the battery slag 5-15
Part, described gypsum 5-10 parts.
2. a kind of preparation method of clay hardening agent, which is characterized in that it is used to prepare clay hardening agent described in claim 1,
Include the following steps：
After washing by the red mud, it is dried under the conditions of 60 DEG C, ball milling simultaneously sieves with 100 mesh sieve；Wherein, CaO contains in the red mud
Amount is higher than 30%, Al2O3Content is higher than 10%；
The metakaolin is dried under the conditions of 60 DEG C, through ball milling and is sieved with 100 mesh sieve；
The carbide slag is dried under the conditions of 60 DEG C, through ball milling and is sieved with 100 mesh sieve, the content of CaO is more than in the carbide slag
65%；
The gypsum is dried under the conditions of 60 DEG C, through ball milling and is sieved with 100 mesh sieve；
At normal temperatures, the red mud, the metakaolin, the carbide slag and the gypsum are uniformly mixed and form the clay
Curing agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711446871.6A CN108558243A (en) | 2017-12-27 | 2017-12-27 | A kind of clay hardening agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711446871.6A CN108558243A (en) | 2017-12-27 | 2017-12-27 | A kind of clay hardening agent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108558243A true CN108558243A (en) | 2018-09-21 |
Family
ID=63529446
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711446871.6A Pending CN108558243A (en) | 2017-12-27 | 2017-12-27 | A kind of clay hardening agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108558243A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113185980A (en) * | 2021-04-09 | 2021-07-30 | 太原理工大学 | Lead-polluted soil curing agent combining red mud, carbide slag and phosphogypsum and preparation method thereof |
| CN115340321A (en) * | 2022-09-20 | 2022-11-15 | 河南省交通规划设计研究院股份有限公司 | Composite soil curing agent and preparation method thereof |
| CN116477915A (en) * | 2023-04-10 | 2023-07-25 | 中国科学院武汉岩土力学研究所 | Micro powder curing agent for reinforcing and regenerating sea sludge and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104098281A (en) * | 2013-04-03 | 2014-10-15 | 神华集团有限责任公司 | Geopolymer composition, geopolymer material and preparation method thereof |
-
2017
- 2017-12-27 CN CN201711446871.6A patent/CN108558243A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104098281A (en) * | 2013-04-03 | 2014-10-15 | 神华集团有限责任公司 | Geopolymer composition, geopolymer material and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 王维波: "低渗-特低渗裂缝性油藏地质聚合物封窜堵漏技术", 《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113185980A (en) * | 2021-04-09 | 2021-07-30 | 太原理工大学 | Lead-polluted soil curing agent combining red mud, carbide slag and phosphogypsum and preparation method thereof |
| CN115340321A (en) * | 2022-09-20 | 2022-11-15 | 河南省交通规划设计研究院股份有限公司 | Composite soil curing agent and preparation method thereof |
| CN116477915A (en) * | 2023-04-10 | 2023-07-25 | 中国科学院武汉岩土力学研究所 | Micro powder curing agent for reinforcing and regenerating sea sludge and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Liu et al. | The impact of cold-bonded artificial lightweight aggregates produced by municipal solid waste incineration bottom ash (MSWIBA) replace natural aggregates on the mechanical, microscopic and environmental properties, durability of sustainable concrete | |
| Wu et al. | Expansive soil modified by waste steel slag and its application in subbase layer of highways | |
| CN105152609B (en) | Building brick prepared with the flying dust after consumer waste incineration or slag and preparation method thereof | |
| Liu et al. | Effect of SiO2 and Al2O3 on characteristics of lightweight aggregate made from sewage sludge and river sediment | |
| Shi et al. | Characteristics of municipal solid wastes incineration (MSWI) fly ash–cement matrices and effect of mineral admixtures on composite system | |
| CN101994283B (en) | Steamed ecological water permeable environmentally friendly brick produced by waste ceramic residues and manufacturing method thereof | |
| CN103172347B (en) | Sintered porous light-weight insulating brick produced from ceramic waste mud and manufacturing method thereof | |
| CN102503274B (en) | Curing agent for heavy-metal polluted bottom sludge | |
| CN112028582B (en) | Vertical anti-seepage isolation ecological barrier material for polluted site and preparation method thereof | |
| CN104310884B (en) | Curing agent for attapulgite reinforced printing and dyeing sludge treatment and curing method thereof | |
| CN101397198A (en) | Composite blending material for concrete and preparation method thereof | |
| CN104479685A (en) | Compound heavy metal solidifying agent for governing contaminated soil and preparation method thereof | |
| Chin et al. | Characterization of sewage sludge ASH (SSA) in cement mortar | |
| CN109761515B (en) | Preparation method for producing mineral powder cementing material by using activated fly ash solidified by industrial waste residues | |
| CN108558243A (en) | A kind of clay hardening agent and preparation method thereof | |
| Tabak et al. | Ceramic tile waste as a waste management solution for concrete | |
| CN106431351A (en) | Ecological self-cleaning clog-proof water permeable brick based on construction waste and preparing method thereof | |
| CN106278350A (en) | A kind of alkaline residue building waste water-permeable brick and preparation method thereof | |
| CN109250955A (en) | Non-light tight concrete and preparation method thereof | |
| Liu et al. | Alkali-activated binders based on incinerator bottom ash combined with limestone-calcined clay or fly ash | |
| CN111762998A (en) | High-temperature activated composite sludge powder solidified dewatered sludge/silt and solidification method thereof | |
| Zhao et al. | Preparation and environmental toxicity of non-sintered ceramsite using coal gasification coarse slag | |
| CN109553345A (en) | A kind of preparation method with the modified concrete processed of domestic garbage incineration flyash | |
| Fan et al. | New applications of municipal solid waste incineration bottom ash (MSWIBA) and calcined clay in construction: Preparation and use of an eco-friendly artificial aggregate | |
| CN114195468A (en) | Method for producing roadbed material by using dredged sludge and construction waste |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180921 |