CN108557995A - Solid phase is sustained organic carbon source biological denitrification denitrogenation module - Google Patents

Solid phase is sustained organic carbon source biological denitrification denitrogenation module Download PDF

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Publication number
CN108557995A
CN108557995A CN201810122404.6A CN201810122404A CN108557995A CN 108557995 A CN108557995 A CN 108557995A CN 201810122404 A CN201810122404 A CN 201810122404A CN 108557995 A CN108557995 A CN 108557995A
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China
Prior art keywords
carrier
carbon source
denitrification
solid phase
organic carbon
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Pending
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CN201810122404.6A
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Chinese (zh)
Inventor
王晛
李海利
黄帆
华铭
石杨洋
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Taihu Youter Water (suzhou) Co Ltd
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Taihu Youter Water (suzhou) Co Ltd
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Priority to CN201810122404.6A priority Critical patent/CN108557995A/en
Publication of CN108557995A publication Critical patent/CN108557995A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/28Anaerobic digestion processes

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  • Life Sciences & Earth Sciences (AREA)
  • Microbiology (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Biological Treatment Of Waste Water (AREA)
  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)

Abstract

The present invention provides solid phase and is sustained organic carbon source biological denitrification denitrogenation module, including denitrification denitrogenation ontology;Denitrification denitrogenation ontology includes envelope skeleton, the denitrification carrier made of PBS degradation materials, polyurethane foamed blocks;Denitrification carrier includes carrier element;Carrier element side wall is equipped with frosted line;Conducive to microorganism carry;Envelope skeletal internal envelope has several denitrification carriers and several polyurethane foamed blocks;PBS carriers while carbon source is provided, itself also can biofilm, be added polyurethane to improve activated bacterial quantity.The present invention mixes polyurethane foam block structure using denitrification carrier, increases carbon source and microorganism contact probability, on the one hand effectively avoids secondary pollution, on the other hand greatly reduce hand stock maintenance cost.Structure of the invention is reasonable, highly practical, is promoted and applied convenient for rural sewage treatment.

Description

Solid phase is sustained organic carbon source biological denitrification denitrogenation module
Technical field
It is handled the present invention relates to the denitrification in water process more particularly to solid phase is sustained organic carbon source biological denitrification denitrogenation Module.
Background technology
In terms of the development course of domestic and international pollution control, sewage disposal initial interest is mainly COD resolutions, but with people Promotion to environmental quality requirement, sewage discharge require also gradually strictly getting up to the removal of nitrogen, phosphorus etc..In comparison, phosphorus Chemical precipitation method can be utilized to remove, and the degradation of nitrogen then relies primarily on biological treatment, this requires sewage treatment process Unit need to be reinforced considering Denitrogenation.
China's town sewage plant Effluent criteria is secondary discharge standard before 2002, wherein only ammonia nitrogen (NH3-N) refers to Mark requires, and does not have total nitrogen index request, and in this case, NH3-N can be oxidized to nitrate nitrogen by aeration and biological processing procedure, realizes Qualified discharge.But with people water quality is required it is increasingly strict, for cities and towns treatment plant treated foul water fraction Side (city major river valley) has required to supplement water directly as landscape, in every water quality index, especially more with nitrogen discharged index For harshness.
Currently, being typically employed in conventional two stage treatment for the domestic and international decentralized type sewage treatment facility of the removal of nitrogen in sewage Depth denitrification is carried out afterwards and proposes mark transformation, and this technology is intended to the depth of the regional decentralized type sewage processing equipment such as key breakthrough rural area Denitrification puies forward mark technology, and implementation focus engineering proposes mark transformation, completes utilization of wastewater resource degree.About denitrification denitrogenation: The denitrogenation of waste water processing procedure that nitrate nitrogen in water is reduced into ammonia nitrogen using denitrifying bacteria and is removed it in turn.Denitrification Bacterium is largely present in sewage, and reaction carries out under anoxic conditions, and oxygen in water should be less than 0.5mg/L.It is required that in sewage There are a certain number of organic substances (can supplement and add secondary precipitation sludge, methanol, acetic acid etc.).
A certain number of floating stuffings are added in traditional denitrification filter pool, when sewage is continuously across reactor, specific surface The larger filler of product gradually grows on its surface and is born because of stirring (aerobic reactor is air stirring) free movement in water Object film, different oxygen and autotrophic microbe in biomembrane carry out metabolism using the nutriment in water, and then reach and decontaminate The purpose of water pollutant, purified water;Because filler, water are all movements, therefore the mass transfer between gas and water, solid phase is preferable, on filler The activity of biomembrane is higher, strong compared with traditional biological embrane method anti impulsion load, buffer capacity.
In domestic sewage in rural areas, because the case where pesticide or rainwater has that the more carbon of nitrogen are few, in sewage treatment filtering tank Such as supplementary carbon source not in time, then total nitrogen removal effect is poor, and water outlet total nitrogen can not be up to standard;If according to traditional supplementary carbon source shape Formula causes additive amount to mismatch because of amount of inlet water fluctuation, and carbon source, which adds, to be easy to excessively ultimately cause secondary pollution, another The traditional biologic packing material of aspect such as denitrification carrier is granular or block structure, is unfavorable for microorganism attachment because surface area is small, To be unfavorable for the slow release of carbon source, especially for rural sewage treatment because measuring little and unattended situation, need Supplementary carbon source at regular time and quantity, manpower maintenance cost is high, is not easy to promotion and implementation.
Invention content
For overcome the deficiencies in the prior art, the purpose of the present invention is to provide solid phases to be sustained organic carbon source biological denitrification Denitrogenation module mixes polyurethane foam block structure using denitrification carrier, increases carbon source and microorganism contact probability, keeps carbon source slow On The Drug Release, and absorbed by denitrifying bacteria rapidly, fast degradation nitrate, on the one hand effectively avoid secondary pollution, another party Face greatly reduces hand stock maintenance cost.
The present invention provides solid phase and is sustained organic carbon source biological denitrification denitrogenation module, including denitrification denitrogenation ontology;It is described Denitrification denitrogenation ontology includes envelope skeleton, the denitrification carrier made of PBS degradation materials, polyurethane foamed blocks;It is described Envelope skeleton is the envelope ball that the hollow and surface made of plastics is equipped with several holes;The denitrification carrier includes carrier list Member;The carrier element is hollow structure;The carrier element side wall is equipped with frosted line;If the envelope skeletal internal envelope has Do the denitrification carrier and several polyurethane foamed blocks;Denitrifying bacteria biofilm is in the polyurethane foamed blocks and anti-nitre Change on carrier, the denitrification carrier slow release carbon source.
Further, the carrier element is column, and the column surface is equipped with through-hole.
Further, the denitrification carrier is made of several carrier elements, phase between several carrier elements It connects.
Further, the denitrification carrier is made of three carrier elements, and three carrier elements pass through triangle Connector is connected with each other.
Further, the quantity of the through-hole is one, and the through-hole is located at column surface centre position.
Further, the polyurethane foamed blocks are rectangular block.
Further, the polyurethane foamed blocks wrap up the denitrification carrier.
Further, a diameter of 4mm-10mm of the through-hole.
Further, the wall thickness of the column is 2mm-4mm.
Further, the thickness of the column is 5mm-10mm.
Compared with prior art, the beneficial effects of the present invention are:
The present invention provides solid phase and is sustained organic carbon source biological denitrification denitrogenation module, including denitrification denitrogenation ontology;Anti- nitre It includes envelope skeleton, the denitrification carrier made of PBS degradation materials, polyurethane foamed blocks to change denitrogenation ontology;Denitrification carries Body includes carrier element;Carrier element side wall is equipped with frosted line;Conducive to microorganism carry;Envelope skeletal internal envelope has several anti- Nitrify carrier and several polyurethane foamed blocks;PBS carriers while carbon source is provided, itself also can biofilm, be added polyurethane with Improve activated bacterial quantity.The present invention mixes polyurethane foam block structure using denitrification carrier, increases carbon source and is connect with microorganism Probability is touched, on the one hand secondary pollution is effectively avoided, on the other hand greatly reduces hand stock maintenance cost.Structure of the invention is closed Reason, it is highly practical, it is promoted and applied convenient for rural sewage treatment.
Above description is only the general introduction of technical solution of the present invention, in order to better understand the technical means of the present invention, And can be implemented in accordance with the contents of the specification, below with presently preferred embodiments of the present invention and after coordinating attached drawing to be described in detail such as. The specific implementation mode of the present invention is shown in detail by following embodiment and its attached drawing.
Description of the drawings
Attached drawing described herein is used to provide further understanding of the present invention, and is constituted part of this application, this hair Bright illustrative embodiments and their description are not constituted improper limitations of the present invention for explaining the present invention.In the accompanying drawings:
Fig. 1 is that the solid phase of the present invention is sustained organic carbon source biological denitrification denitrogenation modular structure schematic diagram;
Fig. 2 is that the solid phase of the present invention is sustained organic carbon source biological denitrification denitrogenation decomposition module structure schematic diagram;
Fig. 3 is a kind of carrier element structural schematic diagram of the present invention;
Fig. 4 is a kind of denitrification carrier structure schematic diagram of the present invention.
In figure:Denitrification denitrogenation ontology 1, polyurethane foamed blocks 2, envelope skeleton 3, denitrification carrier 10, carrier element 11, Triangle connection element 12.
Specific implementation mode
In the following, in conjunction with attached drawing and specific implementation mode, the present invention is described further, it should be noted that not Under the premise of conflicting, new implementation can be formed between various embodiments described below or between each technical characteristic in any combination Example.
Solid phase is sustained organic carbon source biological denitrification denitrogenation module, as shown in Figure 1 and Figure 2, including denitrification denitrogenation ontology 1; Denitrification denitrogenation ontology 1 includes envelope skeleton 3, the denitrification carrier 10 made of PBS degradation materials, polyurethane foamed blocks 2; Envelope skeleton 3 is the envelope ball that the hollow and surface made of plastics is equipped with several holes;Denitrification carrier 10 includes carrier element 11;Carrier element 11 is hollow structure;11 side wall of carrier element is equipped with frosted line;As shown in Fig. 2, 3 inside envelope of envelope skeleton There are several denitrification carriers 10 and several polyurethane foamed blocks 2;Denitrifying bacteria biofilm is carried in polyurethane foamed blocks 2 and denitrification On body 10,10 slow release carbon source of denitrification carrier.Wherein, after denitrification carrier 10 is by PBS degradable biological particle fusions Molding is made, surface frosted structure, adheres to convenient for microorganism, in domestic sewage in rural areas pipe network, because of the synthesis of rainwater and pesticide Effect, causes nitrogen source excessive, and carbon source is relatively fewer, denitrifying bacteria biofilm on polyurethane foamed blocks 2 and denitrification carrier 10, Denitrification carrier 10 is used as carbon source, denitrifying bacteria to be contacted with denitrification carrier 10 closely, 10 slow release carbon of denitrification carrier Source makes denitrification denitrogenation reaction is lasting to carry out.In one embodiment, such as Fig. 2, polyurethane foamed blocks 2 are rectangular block, polyurethane foam Foam block 2 wraps up denitrification carrier 10 so that denitrifying bacteria contacts even closer with denitrification carrier 10, and slow release effect is more preferably. Usually, envelope skeleton 3 is made of plastics, is spliced by two hemisphere of the hollow and surface equipped with several through-holes, is convenient for anti-nitre Change 1 fast assembling-disassembling of denitrogenation ontology.
As shown in figure 3, denitrification carrier 10 includes carrier element 11;Carrier element 11 is hollow structure;Carrier element 11 Side wall is equipped with frosted line;Denitrifying bacteria biofilm is reacted on 11 side wall of carrier element;The carrier being suspended in treatment sewage Unit 11 carries out anti-nitration reaction;Flow runs through the hollow structure of carrier element 11 in filter tank.While increasing specific surface area, The possibility that filler blocks is reduced, treatment effeciency is improved;On the other hand, the interior materials'use amount of unit volume is reduced, is reduced PBS material costs.
In one embodiment, as shown in figure 3, carrier element 11 is column, column surface is equipped with through-hole.
In one embodiment, denitrification carrier is made of several carrier elements 11, is mutually interconnected between several carrier elements 11 It connects.As shown in figure 4, denitrification carrier is made of three carrier elements 11, three carrier elements 11 are mutual by triangle connection element 12 Connection.Specifically, the quantity of through-hole is one, and through-hole is located at column surface centre position.In general, in denitrification carrier 10 The aperture of hollow structure is 4mm-10mm, and the too small easy formation in aperture blocks, the excessive reduction for be easy to causeing denitrification efficiency in aperture; The thickness of column is 5mm-10mm, and the wall thickness of column is 2mm-4mm.In one embodiment, a diameter of 6mm of through-hole, column The thickness of shape body is 7mm, and the wall thickness of column is 3mm, and anti-nitration reaction efficiently and slow release, ensures denitrification efficiency, Depth denitrification is realized without the case where manual maintenance or few manual maintenance.
Particularly, polyurethane foamed blocks 2 and denitrification carrier 10 are conducive to microorganism carry, to denitrification after microorganism carry Carrier 10 carries out gnawing the slow release to be formed to carbon source;Denitrification carrier 10 is designed using tricyclic, denitrification carrier side wall Equipped with frosted line, the more conducively biofilm of microorganism, so that film is formed, the time is shorter, and sustained release rate is very suitable for decentralized type sewage Denitrogenation processing demand, concentration are reduced to 5mg/L hereinafter, the highest for meeting current rural domestic sewage treatment is wanted from 30-50mg/L It asks, reaches national four class water quality standards.
The present invention provides solid phase and is sustained organic carbon source biological denitrification denitrogenation module, including denitrification denitrogenation ontology;Anti- nitre It includes envelope skeleton, the denitrification carrier made of PBS degradation materials, polyurethane foamed blocks to change denitrogenation ontology;Denitrification carries Body includes carrier element;Carrier element side wall is equipped with frosted line;Conducive to microorganism carry;Envelope skeletal internal envelope has several anti- Nitrify carrier and several polyurethane foamed blocks;PBS carriers while carbon source is provided, itself also can biofilm, be added polyurethane with Improve activated bacterial quantity.The present invention mixes polyurethane foam block structure using denitrification carrier, increases carbon source and is connect with microorganism Probability is touched, on the one hand secondary pollution is effectively avoided, on the other hand greatly reduces hand stock maintenance cost.Structure of the invention is closed Reason, it is highly practical, it is promoted and applied convenient for rural sewage treatment.
More than, only presently preferred embodiments of the present invention is not intended to limit the present invention in any form;All one's own professions The those of ordinary skill of industry can be shown in by specification attached drawing and above and swimmingly implement the present invention;But all to be familiar with sheet special The technical staff of industry without departing from the scope of the present invention, is made a little using disclosed above technology contents The equivalent variations of variation, modification and evolution are the equivalent embodiment of the present invention;Meanwhile all substantial technologicals according to the present invention To the variation, modification and evolution etc. of any equivalent variations made by above example, technical scheme of the present invention is still fallen within Within protection domain.

Claims (10)

1. solid phase is sustained organic carbon source biological denitrification denitrogenation module, it is characterised in that:Including denitrification denitrogenation ontology;It is described anti- It includes envelope skeleton, the denitrification carrier made of PBS degradation materials, polyurethane foamed blocks to nitrify denitrogenation ontology;The packet Network skeleton is the envelope ball that the hollow and surface made of plastics is equipped with several holes;The denitrification carrier includes carrier element; The carrier element is hollow structure;The carrier element side wall is equipped with frosted line;The envelope skeletal internal envelope has several The denitrification carrier and several polyurethane foamed blocks;Denitrifying bacteria biofilm is in the polyurethane foamed blocks and denitrification On carrier, the denitrification carrier slow release carbon source.
2. solid phase as described in claim 1 is sustained organic carbon source biological denitrification denitrogenation module, it is characterised in that:The carrier Unit is column, and the column surface is equipped with through-hole.
3. solid phase as claimed in claim 2 is sustained organic carbon source biological denitrification denitrogenation module, it is characterised in that:The anti-nitre Change carrier to be made of several carrier elements, be connected with each other between several carrier elements.
4. solid phase as claimed in claim 3 is sustained organic carbon source biological denitrification denitrogenation module, it is characterised in that:The anti-nitre Change carrier to be made of three carrier elements, three carrier elements are connected with each other by triangle connection element.
5. as claim 2-4 any one of them solid phases are sustained organic carbon source biological denitrification denitrogenation module, it is characterised in that: The quantity of the through-hole is one, and the through-hole is located at column surface centre position.
6. solid phase as claimed in claim 5 is sustained organic carbon source biological denitrification denitrogenation module, it is characterised in that:The poly- ammonia Ester foam block is rectangular block.
7. solid phase as claimed in claim 6 is sustained organic carbon source biological denitrification denitrogenation module, it is characterised in that:The poly- ammonia Ester foam block wraps up the denitrification carrier.
8. solid phase as claimed in claim 7 is sustained organic carbon source biological denitrification denitrogenation module, it is characterised in that:The through-hole A diameter of 10mm-20mm.
9. solid phase as claimed in claim 7 is sustained organic carbon source biological denitrification denitrogenation module, it is characterised in that:The column The wall thickness of body is 2mm-10mm.
10. solid phase as claimed in claim 7 is sustained organic carbon source biological denitrification denitrogenation module, it is characterised in that:The column The thickness of shape body is 5mm-10mm.
CN201810122404.6A 2018-02-07 2018-02-07 Solid phase is sustained organic carbon source biological denitrification denitrogenation module Pending CN108557995A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111233145A (en) * 2020-01-16 2020-06-05 桂林理工大学 Novel inorganic-organic material synergistic rapid-separation biochemical ball and preparation method thereof

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Application publication date: 20180921