CN108554398B - Preparation method and application of wide-temperature-window denitration catalyst - Google Patents
Preparation method and application of wide-temperature-window denitration catalyst Download PDFInfo
- Publication number
- CN108554398B CN108554398B CN201810549720.1A CN201810549720A CN108554398B CN 108554398 B CN108554398 B CN 108554398B CN 201810549720 A CN201810549720 A CN 201810549720A CN 108554398 B CN108554398 B CN 108554398B
- Authority
- CN
- China
- Prior art keywords
- catalyst
- temperature
- solution
- denitration catalyst
- denitration
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8625—Nitrogen oxides
- B01D53/8628—Processes characterised by a specific catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/20—Reductants
- B01D2251/206—Ammonium compounds
- B01D2251/2062—Ammonia
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Abstract
The invention belongs to the technical field of catalysts and provides a catalystRelates to a preparation method and catalytic application of a wide-temperature-window low-toxicity denitration catalyst. The catalyst is composed of CeO2、ZrO2And TiO2The three components are formed in the form of composite oxides; the molar ratio of Ce to Zr to Ti is 0.1-0.5: 1: 1. the cerium-zirconium-titanium catalyst synthesized by adopting a glucose hydrothermal method skillfully utilizes the polyhydroxy chelation of glucose to form coordinate bonds to be combined around cerium-zirconium-titanium particles, and then the glucose wrapped around the catalyst is carbonized and lost under the high-temperature condition, so that more oxygen vacancies and defects are generated on the surface of the catalyst; CeO synthesized by the method2‑ZrO2‑TiO2Catalyst is at 30000h‑1Has good catalytic reduction of NO at high space velocity and wide temperature range of 200-400 DEG CXThe performance and the activity are all over 80 percent, and the activity is close to 100 percent at the temperature of 280-340 ℃. The catalyst has wider temperature window and wider applicability.
Description
Technical Field
The invention belongs to the technical field of catalysts, and particularly relates to a preparation method and application of a wide-temperature-window denitration catalyst.
Background
Nitrogen oxides (NOx) are the main pollutants causing air pollution, and the most serious of the pollutants are NO and NO2And N2And O, three nitrogen oxides. Nitrogen oxides can cause acid rain, which can cause burns to ecological trees and crops, reduce yield, and corrode buildings and reduce their useful life. In addition, nitrogen oxides cause photochemical pollution, which has great influence on human health,for example, inhalation of NO can cause poisoning of the human body and, in severe cases, can cause life risks.
Selective catalytic reduction of ammonia (NH)3SCR) technology is the most effective method for treating nitrogen oxide hazards and is most widely used. The core of the SCR catalytic technology is a denitration catalyst, and the most widely applied denitration catalyst in the current market is vanadium tungsten titanium (V)2O5-WO3/TiO2) A catalyst. However, the vanadium-tungsten-titanium catalyst has the defects of narrow temperature window, poor environmental adaptability and the like, and the waste vanadium-tungsten-titanium catalyst brings great harm to the environment. Therefore, the country has made strict regulations on the purchase and use of vanadium tungsten titanium catalysts, and has actively advocated the development and use of non-vanadium titanium catalysts that are highly efficient and low in toxicity. Therefore, the catalyst with high efficiency, low toxicity and wide temperature window has wide market application prospect.
Disclosure of Invention
Aiming at the defects of the prior art, the invention aims to provide a preparation method and application of a denitration catalyst with a wide temperature window.
In order to achieve the purpose, the invention adopts the technical scheme that:
a denitration catalyst with wide temperature window is prepared from CeO2、ZrO2And TiO2The three components are formed in a composite oxide form; the molar ratio of Ce to Zr to Ti is 0.1-0.5: 1: 1.
A preparation method of a wide temperature window denitration catalyst comprises the following steps:
(1) dissolving soluble zirconium salt, soluble titanium salt and soluble cerium salt in deionized water to obtain a solution A; dissolving glucose in deionized water to obtain a solution B; stirring and mixing the solution A and the solution B uniformly to obtain a solution C
(2) Dropwise adding an ammonia water solution into the solution C while stirring until the pH is controlled to be 10 to obtain a mixed emulsion D; transferring the mixed emulsion D to a reaction kettle for hydrothermal treatment reaction, and cooling to room temperature after the reaction is finished;
(3) and (3) carrying out suction filtration on the precipitate, taking a filter cake, washing and drying the filter cake, then placing the filter cake in a muffle furnace for high-temperature calcination, cooling to room temperature after the calcination is finished, and fully grinding the obtained product to obtain the denitration catalyst with the wide temperature window.
In the above scheme, the soluble zirconium salt in step (1) is Zr (NO)3)4·5H2O, the soluble titanium salt is TiOSO4，The soluble cerium salt is Ce (NO)3)3·6H2O。
In the scheme, the concentration of the solution A in the step (1) is 0.1-0.5 mol/L.
In the scheme, the molar ratio of Ce, Zr and Ti in the step (1) is 0.1-0.5: 1: 1.
In the scheme, the molar weight of the glucose in the step (1) is 1-3 times of the total molar weight of Ce, Zr and Ti.
In the scheme, the concentration of the ammonia water solution in the step (2) is 1-2 mol/L.
In the scheme, the temperature of the hydrothermal treatment in the step (2) is 120-200 ℃, and the time is 12-36 h.
In the above scheme, the high-temperature calcination process in step (3) is as follows: firstly, the temperature is rapidly raised to 110 ℃ at the speed of 20 ℃/min, then the temperature is slowly raised to 500 ℃ at the speed of 5 ℃/min, and the mixture is roasted for 3h at 500 ℃.
The preferable molar ratio of Ce, Zr and Ti in the preparation process of the catalyst is 0.1-0.5: 1:1, when the molar ratio of Ce is less than 0.1, the activity of the catalyst is poor, and when the molar ratio of Ce is more than 0.5, the cost is increased; when the molar ratio of Zr to Ti is not 1:1, the specific surface area of the catalyst is lowered, which is disadvantageous for the catalytic process.
The optimal hydrothermal treatment temperature in the preparation process of the catalyst is 140-180 ℃, and the time is 18-24 h. If the hydrothermal temperature is lower than 140 ℃, the hydrothermal reaction of the catalyst is incomplete, and the yield of the cerium-zirconium-titanium oxide is low; if the hydrothermal temperature is higher than 180 ℃, the crystallization tendency of the catalyst is serious, and the activity of the catalyst is influenced, so that the temperature of 140-180 ℃ is more reasonable hydrothermal treatment temperature. Meanwhile, within the temperature of 140-180 ℃, the hydrothermal treatment time is less than 18h, which can cause incomplete reaction of the catalyst, while the treatment time is more than 24h, which can cause excessive consumption of energy. Therefore, the reasonable hydrothermal treatment time is 12-36 h.
The application of the wide temperature window denitration catalyst in the flue gas denitration process comprises the following steps:
(1) the flue gas analyzer is started to preheat and zero, and N is used2The air tightness test is carried out for the balance gas, and N is kept in the experimental process2The balance gas is unchanged;
(2) weighing the denitration catalyst and pressing the denitration catalyst into tablets before testing the selective catalytic reduction activity;
(3) before the SCR activity test, gradually raising the temperature to the reaction temperature of the catalyst;
(4) in the SCR activity test, introducing reaction mixed gas, respectively keeping the temperature of 80-420 ℃ for about 30min, and monitoring the numerical value on line when the gas is stable;
(5) under the action of a catalyst with wide temperature window and high activity, NO and a reducing agent NH3Reacting to produce harmless N2And H2O, and discharging into the atmosphere through a pipeline; the gas inlet and outlet of the whole system is monitored on line through a gas analyzer, and the denitration rate is obtained through calculation.
In the above scheme, the reaction conditions of step (5) are as follows: [ NO ]]＝720ppm,[NH3]＝800ppm,[O2]＝3vol％，N2As balance gas, the space velocity is 30,000h-1。
The invention has the following beneficial effects: the cerium-zirconium-titanium (Ce, Zr and Ti) composite catalyst synthesized by adopting a glucose hydrothermal method skillfully utilizes the polyhydroxy chelation of glucose to form coordinate bonds to be combined around cerium-zirconium-titanium particles, so that the uniformity and the dispersibility of the catalyst particles are improved; then under the condition of high temperature, the glucose wrapped around the catalyst is carbonized and lost, so that more oxygen vacancies and defects are generated on the surface of the catalyst; the catalyst prepared by the method has higher specific surface area and more surface acid sites, is beneficial to the adsorption and reaction of reaction gas molecules, has high efficiency and low toxicity, and does not contain V2O5And the like harmful to the environment; said catalyst is notThe denitration catalyst exists in a single oxide form, but exists in a solid solution form, and the solid solution has a better denitration rate compared with a single oxide; the denitration rate is more than 80% in a wide temperature window range of 200-400 ℃, and the activity of 280-340 ℃ is close to 100%, which shows that the denitration catalyst has a wider temperature window and wider applicability.
Drawings
FIG. 1 shows CeO prepared by the present invention2-ZrO2-TiO2The catalytic activity of the catalyst is compared with that of other catalysts.
FIG. 2 shows 0.3CeO prepared in example 3 of the present invention2-ZrO2-TiO2SEM image of catalyst.
FIG. 3 shows CeO prepared in examples 1 and 3 of the present invention2-ZrO2-TiO2XPS spectra of the catalyst.
Detailed Description
In order to better understand the present invention, the following examples are further provided to illustrate the present invention, but the present invention is not limited to the following examples.
The following examples are not specifically described, and the purity of the reagent used is 99.9% chemical reagent.
In the practice of the present invention, the reaction conditions for the SCR activity test are as follows: [ NO ]]＝720ppm,[NH3]＝800ppm,[O2]＝3vol％，N2As balance gas, the space velocity is 30,000h-1. In addition, the temperature points between 200 ℃ and 400 ℃ are respectively kept for about 30min, and the numerical value is monitored on line when the gas is stable. The influent and effluent gases were both detected by a gas analyzer (Gasboard-3800P), NOXIs determined by the formula ([ NO ]]in－[NO]out)/[NO]inAnd calculating to characterize the activity of the catalyst.
Example 1
A denitration catalyst with a wide temperature window is prepared by mixing three components of Ce, Zr and Ti according to a molar ratio of 0.1:1:1, and is prepared by the following method: 1) firstly, 4.2932g of zirconium nitrate pentahydrate, 1.9595g of titanyl sulfate and 0.4312g of cerous nitrate hexahydrate are weighed, mixed and dissolved in 250mL of deionized water, and stirred by a magnetic stirrer for 2-3 hours until the solution becomes clear from turbidity, so as to obtain a mixed solution A; 2) the dosage of the glucose is 2.5 times of the total molar ratio of Ce, Zr and Ti, 10.4039g of glucose is weighed and dissolved in 100mL of deionized water to obtain liquid B; mixing the solution B with a clear solution mixed solution A containing cerium, zirconium and titanium to obtain a mixed solution C, and continuously stirring for 30 min; 3) preparing 1mol/L ammonia water solution, dropwise adding the 1mol/L ammonia water solution into the mixed solution C, controlling the pH value to be 10 to obtain emulsion D, transferring the emulsion into a 150mL reaction kettle, and carrying out hydrothermal treatment at 160 ℃ for 24 hours; 4) cooling to room temperature, carrying out suction filtration on the precipitate through a circulating water type vacuum pump, carrying out ultrasonic dispersion on the obtained filter cake through an ultrasonic disperser, and then continuing suction filtration, repeating the steps, and carrying out suction filtration for 2-3 times; dispersing with absolute ethyl alcohol, and performing suction filtration for 1-2 times; the obtained precipitate is dried for 12h at 110 ℃, and the dried substance is calcined in a muffle furnace at high temperature: firstly, rapidly heating to 110 ℃ at a speed of 20 ℃/min, then slowly heating to 500 ℃ at a speed of 5 ℃/min, and roasting for 3h at 500 ℃; 5) grinding the product obtained by calcination to finally obtain the cerium-zirconium-titanium catalyst with high efficiency, low toxicity and wide temperature window.
The cerium-zirconium-titanium catalyst prepared in the embodiment is subjected to a simulated flue gas denitration test in a reactor, and the result shows that: when the NO concentration is 720ppm, NH3/NO＝1.1、O2The content is 3 percent and 30000h-1When the air velocity ratio is high, the denitration rate is more than 80% in a wide temperature window range of 240-380 ℃, and the activity is more than 90% at 280-320 ℃.
Example 2
A denitration catalyst with a wide temperature window is prepared by mixing three components of Ce, Zr and Ti according to a molar ratio of 0.2:1:1, and is prepared by the following method: 1) firstly, 4.2932g of zirconium nitrate pentahydrate, 1.9595g of titanyl sulfate and 0.8682g of cerous nitrate hexahydrate are weighed, mixed and dissolved in 250mL of deionized water, and stirred by a magnetic stirrer for 2-3 hours until the solution becomes clear from turbidity, so as to obtain a mixed solution A; 2) the dosage of the glucose is 2.5 times of the total molar ratio of Ce, Zr and Ti, 10.4039g of glucose is weighed and dissolved in 100mL of deionized water to obtain liquid B; mixing the solution B with a clear solution mixed solution A containing cerium, zirconium and titanium to obtain a mixed solution C, and continuously stirring for 30 min; 3) preparing 1mol/L ammonia water solution, dropwise adding the 1mol/L ammonia water solution into the mixed solution C, controlling the pH value to be 10 to obtain emulsion D, transferring the emulsion into a 150mL reaction kettle, and carrying out hydrothermal treatment at 160 ℃ for 24 hours; 4) cooling to room temperature, carrying out suction filtration on the precipitate through a circulating water type vacuum pump, carrying out ultrasonic dispersion on the obtained filter cake through an ultrasonic disperser, and then continuing suction filtration, repeating the steps, and carrying out suction filtration for 2-3 times; dispersing with absolute ethyl alcohol, and performing suction filtration for 1-2 times; the obtained precipitate is dried for 12h at 110 ℃, and the dried substance is calcined in a muffle furnace at high temperature: firstly, rapidly heating to 110 ℃ at a speed of 20 ℃/min, then slowly heating to 500 ℃ at a speed of 5 ℃/min, and roasting for 3h at 500 ℃; 5) grinding the product obtained by calcination to finally obtain the cerium-zirconium-titanium catalyst with high efficiency, low toxicity and wide temperature window.
The catalyst prepared in the embodiment is subjected to a simulated flue gas denitration test in a reactor, and the result shows that: when the NO concentration is 720ppm, NH3/NO＝1.1、O2The content is 3 percent and 30000h-1When the air velocity ratio is high, the denitration rate is more than 80% within a wide temperature window range of 220-380 ℃, and the activity is more than 90% at 280-340 ℃.
Example 3
A denitration catalyst with a wide temperature window is prepared by mixing three components of Ce, Zr and Ti according to a molar ratio of 0.3:1:1, and is prepared by the following method: 1) firstly, 4.2932g of zirconium nitrate pentahydrate, 1.9595g of titanyl sulfate and 1.3024g of cerous nitrate hexahydrate are weighed, mixed and dissolved in 250mL of deionized water, and stirred by a magnetic stirrer for 2-3 hours until the solution becomes clear from turbidity, so as to obtain a mixed solution A; 2) the dosage of the glucose is 2.5 times of the total molar ratio of Ce, Zr and Ti, 11.3948g of glucose is weighed and dissolved in 100mL of deionized water to obtain liquid B; mixing the solution B with a clear solution mixed solution A containing cerium, zirconium and titanium to obtain a mixed solution C, and continuously stirring for 30 min; 3) preparing 1mol/L ammonia water solution, dropwise adding the 1mol/L ammonia water solution into the mixed solution C, controlling the pH value to be 10 to obtain emulsion D, transferring the emulsion into a 150mL reaction kettle, and carrying out hydrothermal treatment at 160 ℃ for 24 hours; 4) cooling to room temperature, carrying out suction filtration on the precipitate through a circulating water type vacuum pump, carrying out ultrasonic dispersion on the obtained filter cake through an ultrasonic disperser, and then continuing suction filtration, repeating the steps, and carrying out suction filtration for 2-3 times; dispersing with absolute ethyl alcohol, and performing suction filtration for 1-2 times; the obtained precipitate is dried for 12h at 110 ℃, and the dried substance is calcined in a muffle furnace at high temperature: firstly, rapidly heating to 110 ℃ at a speed of 20 ℃/min, then slowly heating to 500 ℃ at a speed of 5 ℃/min, and roasting for 3h at 500 ℃; 5) grinding the product obtained by calcination to finally obtain the cerium-zirconium-titanium catalyst with high efficiency, low toxicity and wide temperature window.
The catalyst prepared in the embodiment is subjected to a simulated flue gas denitration test in a reactor, and the result shows that: when the NO concentration is 720ppm, NH3/NO＝1.1、O2The content is 3 percent and 30000h-1When the air velocity ratio is high, the denitration rate is more than 80% within a wide temperature window range of 200-400 ℃, and the activity is more than 95% at 240-360 ℃. As can be seen, the catalyst prepared by the embodiment has a wide reaction temperature window and an excellent NOx removal rate in a low temperature range.
Example 4
A denitration catalyst with a wide temperature window is prepared by mixing three components of Ce, Zr and Ti according to a molar ratio of 0.4:1:1, and is prepared by the following method: 1) firstly, 4.2932g of zirconium nitrate pentahydrate, 1.9595g of titanyl sulfate and 1.7365g of cerous nitrate hexahydrate are weighed, mixed and dissolved in 250mL of deionized water, and stirred by a magnetic stirrer for 2-3 hours until the solution becomes clear from turbidity, so as to obtain a mixed solution A; 2) the dosage of the glucose is 2.5 times of the total molar ratio of Ce, Zr and Ti, 11.3948g of glucose is weighed and dissolved in 100mL of deionized water to obtain liquid B; mixing the solution B with a clear solution mixed solution A containing cerium, zirconium and titanium to obtain a mixed solution C, and continuously stirring for 30 min; 3) preparing 1mol/L ammonia water solution, dropwise adding the 1mol/L ammonia water solution into the mixed solution C, controlling the pH value to be 10 to obtain emulsion D, transferring the emulsion into a 150mL reaction kettle, and carrying out hydrothermal treatment at 160 ℃ for 24 hours; 4) cooling to room temperature, carrying out suction filtration on the precipitate through a circulating water type vacuum pump, carrying out ultrasonic dispersion on the obtained filter cake through an ultrasonic disperser, and then continuing suction filtration, repeating the steps, and carrying out suction filtration for 2-3 times; dispersing with absolute ethyl alcohol, and performing suction filtration for 1-2 times; the obtained precipitate is dried for 12h at 110 ℃, and the dried substance is calcined in a muffle furnace at high temperature: firstly, rapidly heating to 110 ℃ at a speed of 20 ℃/min, then slowly heating to 500 ℃ at a speed of 5 ℃/min, and roasting for 3h at 500 ℃; 5) grinding the product obtained by calcination to finally obtain the cerium-zirconium-titanium catalyst with high efficiency, low toxicity and wide temperature window.
The catalyst prepared in the embodiment is subjected to a simulated flue gas denitration test in a reactor, and the result shows that: when the NO concentration is 720ppm, NH3/NO＝1.1、O2The content is 3 percent and 30000h-1When the air velocity ratio is high, the denitration rate is more than 80% within a wide temperature window range of 220-380 ℃, and the activity is more than 90% at 280-340 ℃.
The CeO prepared by the invention2-ZrO2-TiO2The catalytic activity of the catalyst was compared with that of the other catalysts, and the results are shown in FIG. 1, which shows that: pure CeO2The catalytic activity is poor, the maximum catalytic activity is only 40 percent, and the binary CeO2-ZrO2And ZrO2-TiO2The catalyst activity was also poor, although CeO2-TiO2The catalyst has certain activity, but the temperature window is narrow, and the highest activity is only 80 percent. The CeO prepared by the invention2-ZrO2-TiO2The catalyst has a denitration rate of more than 80% in a wide temperature window range of 220-380 ℃, and the activity of more than 90% in a temperature range of 280-340 ℃, which shows that the catalyst has better catalytic activity and a wide temperature window.
The BET characterization of the denitration catalyst prepared in example 3 of the present invention was carried out, and the results are shown in Table 1, wherein Table 1 shows that the catalyst prepared in example 3 of the present invention has a specific surface area of 205m2(ii)/g, higher specific surface area than other catalysts; the scanning electron microscope picture of the method is shown in figure 2, and figure 2 shows that the dispersing effect of the active ingredients of the catalyst is better. FIG. 3 shows the preparation of CeO according to examples 1 and 32-ZrO2-TiO2XPS spectrum of the catalyst, XPS analysis showing the lattice oxygen O of the catalystβIs high in ratio of Oβ/(Oα+Oβ) 0.29, indicating that the catalyst has stronger oxygen storage capacity and more surface active oxygen OαThe catalyst is shown to have more oxygen vacancies and defects, which all contribute to catalyst productionHigh catalytic activity.
TABLE 1 denitration catalyst BET characterization results
| Sample (I) | Specific surface area (m)2/g) |
| ZrO2-TiO2 | 156 |
| CeO2 | 71 |
| CeO2-TiO2 | 122 |
| CeO2-ZrO2 | 78 |
| 0.3Ce-Zr-Ti | 205 |
It is apparent that the above embodiments are only examples for clearly illustrating and do not limit the embodiments. Other variations and modifications will be apparent to persons skilled in the art in light of the above description. And are neither required nor exhaustive of all embodiments. And obvious variations or modifications are therefore intended to be included within the scope of the invention as claimed.
Claims (8)
1. A preparation method of a denitration catalyst with a wide temperature window is characterized by comprising the following steps:
(1) dissolving soluble zirconium salt, soluble titanium salt and soluble cerium salt in deionized water to obtain a solution A; dissolving glucose in deionized water to obtain a solution B; uniformly stirring and mixing the solution A and the solution B to obtain a solution C; the soluble zirconium salt is Zr (NO)3)4·5H2O, the soluble titanium salt is TiOSO4The soluble cerium salt is Ce (NO)3)3·6H2O; the denitration catalyst with wide temperature window is composed of CeO2、ZrO2And TiO2The three components are formed in the form of solid solution; the molar ratio of Ce to Zr to Ti is 0.1-0.5: 1:1, and the molar amount of glucose is 1-3 times of the total molar amount of Ce, Zr and Ti;
(2) dropwise adding an ammonia water solution into the solution C while stirring until the pH value of the solution is controlled to be 10 to obtain a mixed emulsion D; transferring the mixed emulsion D to a reaction kettle for hydrothermal treatment reaction, and cooling to room temperature after the reaction is finished;
(3) and (3) carrying out suction filtration on the precipitate, taking a filter cake, washing and drying the filter cake, then placing the filter cake in a muffle furnace for high-temperature calcination, cooling to room temperature after the calcination is finished, and fully grinding the obtained calcined product to obtain the denitration catalyst with the wide temperature window.
2. The method according to claim 1, wherein the concentration of the solution A in the step (1) is 0.1 to 0.5 mol/L.
3. The method according to claim 1, wherein the concentration of the aqueous ammonia solution in the step (2) is 1 to 2 mol/L.
4. The preparation method of claim 1, wherein the temperature of the hydrothermal treatment in the step (2) is 120-200 ℃ and the time is 12-36 hours.
5. The preparation method according to claim 1, wherein the high-temperature calcination in step (3) is carried out by the following steps: firstly, the temperature is rapidly raised to 110 ℃ at the speed of 20 ℃/min, then the temperature is slowly raised to 500 ℃ at the speed of 5 ℃/min, and the mixture is roasted for 3h at 500 ℃.
6. The denitration catalyst with a wide temperature window prepared by the preparation method of any one of claims 1 to 5 is characterized in that: the denitration catalyst is prepared from CeO2、ZrO2And TiO2The three components are formed in the form of solid solution; the molar ratio of Ce to Zr to Ti is 0.1-0.5: 1: 1.
7. The application of the wide temperature window denitration catalyst obtained by the preparation method of the wide temperature window denitration catalyst in the flue gas denitration process in claim 1.
8. The application according to claim 7, characterized in that it comprises in particular the steps of:
(1) the flue gas analyzer is started to preheat and zero, and N is used2The air tightness test is carried out for the balance gas, and N is kept in the experimental process2The balance gas is unchanged;
(2) weighing the denitration catalyst and pressing the denitration catalyst into tablets before testing the selective catalytic reduction activity;
(3) before the SCR activity test, gradually raising the temperature to the reaction temperature of the catalyst;
(4) in the SCR activity test, introducing reaction mixed gas, respectively keeping the temperature of 80-420 ℃ for 30min, and monitoring the numerical value on line when the gas is stable;
(5) under the action of a catalyst with wide temperature window and high activity, NO and a reducing agent NH3Reacting to produce harmless N2And H2O, and discharging into the atmosphere through a pipeline; the gas inlet and outlet of the whole system is monitored on line through a gas analyzer, and the denitration rate is obtained through calculation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810549720.1A CN108554398B (en) | 2018-05-31 | 2018-05-31 | Preparation method and application of wide-temperature-window denitration catalyst |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810549720.1A CN108554398B (en) | 2018-05-31 | 2018-05-31 | Preparation method and application of wide-temperature-window denitration catalyst |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108554398A CN108554398A (en) | 2018-09-21 |
| CN108554398B true CN108554398B (en) | 2021-04-20 |
Family
ID=63552583
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810549720.1A Active CN108554398B (en) | 2018-05-31 | 2018-05-31 | Preparation method and application of wide-temperature-window denitration catalyst |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108554398B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11560819B2 (en) * | 2019-03-07 | 2023-01-24 | The Chugoku Electric Power Co., Inc. | Combustion system |
| EP3936766B1 (en) * | 2019-03-07 | 2024-01-17 | The Chugoku Electric Power Co., Inc. | Combustion system having a vanadium oxide denitration catalyst |
| CN112547115A (en) * | 2019-09-26 | 2021-03-26 | 中国石油化工股份有限公司 | Multi-effect catalyst for waste gas purification and waste gas purification method |
| CN113856667A (en) * | 2021-10-26 | 2021-12-31 | 烟台大学 | Method for preparing denitration catalyst by utilizing titanium-containing blast furnace slag |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4402724B2 (en) * | 2005-11-30 | 2010-01-20 | 財団法人大阪産業振興機構 | Catalyst encapsulated in hollow layer porous capsule and method for producing the same |
| CN101028594A (en) * | 2006-03-01 | 2007-09-05 | 中国科学院生态环境研究中心 | Composite oxide catalyst for cryogenic selective catalystic reductic oxide nitrogen |
| CN100369669C (en) * | 2006-03-09 | 2008-02-20 | 浙江大学 | Selective catalytic reducing NOx catalyst based on MnOx/TiO2 system at low-temperature and production thereof |
| CN101829573B (en) * | 2010-04-16 | 2012-10-03 | 环境保护部华南环境科学研究所 | Composite oxidant SCR (Selective Catalytic Reduction) denitrating catalyst, preparation method and applications thereof |
| CN102019182B (en) * | 2010-12-16 | 2012-08-29 | 沈阳化工大学 | Preparation method of Cu/ZnO catalyst for preparing methanol from synthesis gas |
| CN103127956B (en) * | 2013-02-05 | 2015-01-14 | 浙江工商大学 | Low-temperature selective catalytic reduction NOx catalyst based on nanometer activated carbon microspheres and preparation method thereof |
| CN103752323B (en) * | 2014-01-02 | 2016-04-27 | 上海大学 | There is the preparation method of the denitrating catalyst of nanometer many squashes shape spinel structure |
| CN104001497B (en) * | 2014-06-20 | 2017-01-04 | 上海电力学院 | A kind of wide temperature window denitrating catalyst and its preparation method and application |
| CN105214652A (en) * | 2015-11-13 | 2016-01-06 | 中国科学院重庆绿色智能技术研究院 | Efficient Ce 1-xmn xo 2-δthe preparation method of solid solution low-temperature denitration catalyst and application |
| CN105582962B (en) * | 2015-12-22 | 2018-06-12 | 武汉理工大学 | A kind of MnOx/TiO2The regeneration method of based low-temperature denitration catalyst |
| CN106179327B (en) * | 2016-07-07 | 2018-08-14 | 国电环境保护研究院 | Activated coke support type manganese cerium titanium zirconium mixed oxide low-temperature SCR catalyst and preparation method thereof |
| CN107983354B (en) * | 2017-11-24 | 2020-04-21 | 武汉理工大学 | Preparation method of alkali poisoning resistant copper-based spinel low-temperature denitration catalyst |
-
2018
- 2018-05-31 CN CN201810549720.1A patent/CN108554398B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN108554398A (en) | 2018-09-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108554398B (en) | Preparation method and application of wide-temperature-window denitration catalyst | |
| CN111229212B (en) | CO-SCR denitration catalyst, preparation method and application | |
| WO2021208596A1 (en) | Catalyst for ozone decomposition, preparation method therefor and use thereof | |
| CN104998680B (en) | A kind of anti-SO2And H2The low-temperature denitration catalyst and preparation method thereof of O poisonings | |
| WO2019179225A1 (en) | Cerium manganese catalyst, preparation method therefor and use thereof | |
| CN107308944B (en) | A kind of TiO 2-based catalyst and its preparation method and application | |
| CN110354846A (en) | A kind of preparation method of manganese cerium dopping graphene low temperature SCR denitration catalyst | |
| CN101274281A (en) | Room temperature catalyst for removing formaldehyde in air and method of preparing the same | |
| CN112742413B (en) | Low-temperature SCR denitration catalyst and preparation method and application thereof | |
| CN110773153B (en) | Supported manganese-based medium-low temperature denitration catalyst, preparation method and application thereof | |
| CN108187661A (en) | A kind of high temperature SCR denitration with anti-high concentration K poisoning performances and preparation method thereof | |
| CN110339832A (en) | A kind of sheet Detitanium-ore-type TiO2For the manganese cerium compound of carrier and preparation and application | |
| CN104209115A (en) | Vanadium-series loading type high-temperature SCR catalyst and preparation method thereof | |
| CN103894194A (en) | Loading type catalyst for removing formaldehyde under room temperature | |
| CN112058276A (en) | Iron ion modified photocatalyst composite material and preparation method thereof | |
| CN110026182A (en) | Low-temperature denitration catalyst and its preparation and application in high sulfur resistive | |
| CN108404930A (en) | A kind of low-temperature denitration catalyst and preparation method thereof with nucleocapsid | |
| CN112844404A (en) | Low-temperature denitration catalyst with TiO2 nanotube as carrier and preparation and application thereof | |
| CN113398920B (en) | Ultra-long cerium dioxide nanorod-loaded manganese oxide low-temperature denitration catalyst and preparation method thereof | |
| CN107185555B (en) | Preparation method of copper-doped cerium sulfide-based nanocrystalline denitration catalyst | |
| CN107552042B (en) | Sheet manganese titanate coats attapulgite loaded CeO2Low temperature Photo-SCR denitrating catalyst and preparation method | |
| CN110075837A (en) | Metal-metatitanic acid composite oxides preparation method and application | |
| CN105879869A (en) | Catalyst used for hydrogen selective reduction of nitric oxide as well as preparation method and application thereof | |
| CN113262780A (en) | High-activity and high-stability manganese-based carbon smoke catalyst and preparation method and application thereof | |
| CN105727965A (en) | Copper, zirconium, cerium and titanium composite oxide catalyst for flue gas denitrification and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |