CN108549617B - Frozen soil phase change latent heat calculation method considering non-linear change of unfrozen water content - Google Patents

Frozen soil phase change latent heat calculation method considering non-linear change of unfrozen water content Download PDF

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CN108549617B
CN108549617B CN201810349127.2A CN201810349127A CN108549617B CN 108549617 B CN108549617 B CN 108549617B CN 201810349127 A CN201810349127 A CN 201810349127A CN 108549617 B CN108549617 B CN 108549617B
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latent heat
frozen soil
phase change
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unfrozen water
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陈之祥
李顺群
张勋程
潘林娜
冯彦芳
夏锦红
姚士霞
赵磊
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Tianjin Chengjian University
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Abstract

The invention provides a frozen soil phase change latent heat calculation method considering non-linear change of the content of unfrozen water in frozen soil. The method has the advantages that the fact that the latent heat is constantly changed along with the change of the content of the unfrozen water is considered, and the change relation between the latent heat and different negative temperatures can be drawn through the provided method. Multiple times of actual measurement and calculation show that the prediction accuracy of the calculation method is improved by 72.4% compared with that of the traditional method. The improvement of the precision can realize the calculation of the non-linear phase change latent heat of the frozen soil to the maximum extent, and the calculation of the temperature field in the frozen soil engineering is facilitated.

Description

Frozen soil phase change latent heat calculation method considering non-linear change of unfrozen water content
Technical Field
The invention belongs to the field of latent heat calculation in the field of frozen soil engineering, and particularly relates to a method for calculating frozen soil phase change latent heat by considering non-linear change of unfrozen water content, which can be used for equation description of frozen soil phase change latent heat and calculation of latent heat total under the condition of known frozen soil unfrozen water content.
Background
Latent heat of phase change refers to the heat absorbed or released by a substance changing from one phase to another under isothermal and isobaric conditions, such as freezing and evaporation of water, and melting of ice. The research on the influence of latent heat on the frozen soil temperature field has important significance and engineering value on the research on the frozen soil temperature field in cold regions and in the process of artificial freezing method.
Under the influence of various factors such as mineral composition in soil, external load, salt content, soil particle surface tension and the like, when a soil body is frozen, part of liquid water in the soil is kept in an unfrozen state, and the part of liquid water is called unfrozen water. The existing research shows that the unfrozen water content of the frozen soil is nonlinearly changed with different negative temperatures. It can be seen that the latent heat of phase change resulting from the non-linear change in the unfrozen water of the frozen earth is also non-linear.
The existing latent heat of phase change is calculated according to the variation of unfrozen water at two temperature points before and after phase change, and because a certain distance exists between the two temperature points all the time, a nonlinear equation cannot be formed by a method for calculating latent heat according to the difference of the content of the unfrozen water at the two temperature points, namely the latent heat obtained by calculation by a conventional method is a constant, and the variation trend of the latent heat between the two temperature points cannot be considered. Meanwhile, the problem of different values of the temperature range also leads to the fact that the obtained latent heat change trend cannot reflect the nonlinear phase change latent heat of the frozen soil. The analytical solution problem requires a specific equation that can characterize the trend of change, and therefore, the conventional latent heat calculation method cannot be used for solving the analytical solution equation.
The method is limited to the large difference of the properties of soil bodies with different regionalities and different causes, provides a general method capable of calculating and expressing the phase change latent heat of frozen soil, and is an important choice for solving the construction problem of the manual freezing method. With the wide application of the artificial freezing method in underground and mining engineering, a frozen soil phase change latent heat calculation method capable of reflecting the nonlinear change of frozen soil is urgently needed, and the method has important significance for the research of the analysis solution problem of the frozen soil temperature field and the improvement of the temperature field prediction precision.
Disclosure of Invention
The invention aims to provide a frozen soil phase change latent heat calculation method considering non-linear change of the content of unfrozen water, so as to be beneficial to calculation of the non-linear phase change latent heat of the frozen soil.
In order to achieve the purpose, the invention provides a method for calculating the phase change latent heat of frozen soil considering the non-linear change of the content of unfrozen water, which comprises the following steps:
1) the relation of the variation of the unfrozen water content of the frozen soil along with the negative temperature is expressed as a form of an equation (1), wherein the equation (1) is as follows:
Wu(T)=AeBT+CT3+DT2+ET+F (1)
in the formula, Wu(T) is the unfrozen water content of the frozen soil at the time of temperature T,%; A. b, C, D, E, F is a fitting constant; t is temperature, DEG C; e is the override number.
2) The derivative of T in equation (1) is:
Wu(T)'=ABeBT+3CT2+2DT+E (2)
3) the latent heat change dQ in an infinitely small negative temperature range can be expressed as
Figure BDA0001632659590000021
In the formula, dQ is the latent heat variable quantity in an infinitesimal negative temperature interval, and the unit is kJ/kg; l is the heat released by water condensation and ice formation, and the unit is kJ/kg; rhodIs the dry density of the soil sample in kg/m3(ii) a Rho is the density of the soil sample and has the unit of kg/m3(ii) a dT is infinitesimal negative temperature range, and the unit is ℃.
4) Certain negative temperature interval [ T ]n~Tj](Tn<Tj) The frozen soil in the section has latent heat of phase change of
Figure BDA0001632659590000031
In the formula (I), the compound is shown in the specification,
Figure BDA0001632659590000032
is a negative temperature interval [ Tn~Tj](Tn<Tj) The phase change latent heat of the frozen soil in the section is kJ/kg. According to the method, the non-linear change of the content of unfrozen water can be considered to represent and calculate the phase change latent heat of the frozen soil, and a foundation is laid for calculating the temperature field of the frozen soil.
The method has the advantages that the fact that the latent heat is constantly changed along with the change of the content of the unfrozen water is considered, and the change relation between the latent heat and different negative temperatures can be drawn through the provided method. Multiple times of actual measurement and calculation show that the prediction accuracy of the calculation method is improved by 72.4% compared with that of the traditional method. The improvement of the precision can realize the calculation of the nonlinear phase change latent heat of the frozen soil to the maximum extent, and the calculation of the temperature field in the frozen soil engineering is facilitated.
Detailed Description
The method for calculating the phase change latent heat of the frozen soil considering the non-linear change of the content of the unfrozen water is explained.
The invention discloses a method and a principle for calculating the phase change latent heat of frozen soil by considering the non-linear change of the content of unfrozen water, which comprises the following steps: the gradient of the change of the content of unfrozen water is obtained, the latent heat change quantity of the frozen soil in an infinite negative temperature interval is obtained by a differential means, and on the basis, the phase change latent heat of the frozen soil with nonlinear change is calculated by an integral method.
The invention provides a method for calculating phase change latent heat of frozen soil considering non-linear change of unfrozen water content, which comprises the following steps of:
1) the relation of the variation of the unfrozen water content of the frozen soil along with the negative temperature is expressed as a form of an equation (1), wherein the equation (1) is as follows:
Wu(T)=AeBT+CT3+DT2+ET+F (1)
in the formula, Wu(T) is the unfrozen water content of the frozen soil at the time of temperature T,%; A. b, C, D, E, F is a fitting constant; t is temperature, DEG C; e is the override number.
2) The derivative of T in equation (1) is:
Wu(T)'=ABeBT+3CT2+2DT+E (2)
3) the latent heat change dQ in an infinitely small negative temperature range can be expressed as
Figure BDA0001632659590000041
In the formula, dQ is the latent heat variable quantity in an infinitesimal negative temperature interval, and the unit is kJ/kg; l is the heat released by water condensation and ice formation, and 333.51kJ/kg is taken; rhodIs the dry density of the soil sample, kg/m3(ii) a Rho is the density of the soil sample, kg/m3(ii) a dT is infinitesimal negative temperature range, DEG C.
4) Certain negative temperature interval [ T ]n~Tj](Tn<Tj) The frozen soil in the section has latent heat of phase change of
Figure BDA0001632659590000042
In the formula (I), the compound is shown in the specification,
Figure BDA0001632659590000043
is a negative temperature interval [ Tn~Tj](Tn<Tj) The frozen soil in the section has latent heat of phase change, kJ/kg. According to the method, the non-linear change of the content of unfrozen water can be considered to represent and calculate the phase change latent heat of the frozen soil, and a foundation is laid for calculating the temperature field of the frozen soil.
The dry density was determined by testing to be 1.8g/cm3,dsThe powder clay sample with the temperature of 2.72 has the unfrozen water content of-1 ℃, 2 ℃ and 3 ℃, and the phase change latent heat at the temperature of-2 ℃ is calculated and obtained by utilizing the proposed method for calculating the phase change latent heat of the frozen soil considering the nonlinear change of the unfrozen water content. And calculating the phase change latent heat Q of the frozen soil according to the unfrozen water content difference between-1 ℃ and-3 ℃ by adopting a conventional method(-1~-3)Will be
Figure BDA0001632659590000044
Obtained at-2 ℃ determined by conventional methodsLatent heat of phase change of frozen earth. Compared with the conventional method and the calculation method of the frozen soil phase change latent heat considering the non-linear change of the content of the unfrozen water, the calculation method provided by the invention has the advantage that the prediction precision is improved by 72.4% compared with the traditional method.
The above description is only for the purpose of illustration in conjunction with the present calculation process, and it will be apparent to those skilled in the art that various changes and modifications may be made in the present invention. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (1)

1. A method for calculating the phase change latent heat of frozen soil considering the non-linear change of the content of unfrozen water comprises the following steps:
1) the relation of the variation of the unfrozen water content of the frozen soil along with the negative temperature is expressed as a form of an equation (1), wherein the equation (1) is as follows:
Wu(T)=AeBT+CT3+DT2+ET+F (1)
in the formula, Wu(T) is the percentage of the unfrozen water content of the frozen soil at the time of temperature T; A. b, C, D, E, F is a fitting constant; t is the temperature; e is the overrun number;
2) the derivative of T in equation (1) is:
Wu(T)'=ABeBT+3CT2+2DT+E (2)
3) the latent heat change dQ in an infinitely small negative temperature range can be expressed as
Figure FDA0001632659580000011
In the formula, dQ is the latent heat variable quantity in an infinitesimal negative temperature interval, and the unit is kJ/kg; l is the heat released by water condensation and ice formation, and the unit is kJ/kg; rhodIs the dry density of the soil sample in kg/m3(ii) a Rho is the density of the soil sample and has the unit of kg/m3(ii) a dT is an infinite small negative temperature interval, and the unit is;
4) certain negative temperature interval [ T ]n~Tj](Tn<Tj) The frozen soil in the section has latent heat of phase change of
Figure FDA0001632659580000012
In the formula (I), the compound is shown in the specification,
Figure FDA0001632659580000013
is a negative temperature interval [ Tn~Tj](Tn<Tj) The phase change latent heat of the frozen soil in the section is kJ/kg.
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