CN108549032A - A kind of evaluation method of cell health state SOH - Google Patents

A kind of evaluation method of cell health state SOH Download PDF

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Publication number
CN108549032A
CN108549032A CN201810344676.0A CN201810344676A CN108549032A CN 108549032 A CN108549032 A CN 108549032A CN 201810344676 A CN201810344676 A CN 201810344676A CN 108549032 A CN108549032 A CN 108549032A
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soh
battery
filter
new
battery core
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王静亮
张君鸿
陈浩
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Beijing Idrive Automobile Co Ltd
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Beijing Idrive Automobile Co Ltd
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Abstract

The present invention discloses a kind of evaluation method of cell health state SOH, includes the following steps:The rated capacity of battery core under current environment is obtained by temperature and charge-discharge magnification;Calculate the SOC value of current battery core;Obtain corresponding cycles left number;Obtain the currently available maximum capacity of battery core;Obtain resistance R when battery core end-of-lifeEOLInternal resistance value when dispatching from the factory with battery core;The true internal resistance of battery core is calculated according to Order RC ring model;Calculate i-th of battery cell health status of current time;I-th of battery cell health status SOH of current timeiAveraging filter, which is rolled, by one is filtered calculating;Obtain the nominal available discharge electricity amount in battery system life cycle;Calculate battery system health status SOH.The parameter that the present invention combines two levels of battery cell and battery system carries out the estimation of cell health state, and the influence factors such as temperature, cycle-index, internal resistance are considered in estimating state of health of battery, keeps estimation result more acurrate.

Description

A kind of evaluation method of cell health state SOH
Technical field
The invention belongs to technical field of new energy, and in particular to a kind of evaluation method of cell health state SOH.
Background technology
Pure electric automobile has the advantages that low stain and high performance, has become the Main way of contemporary automotive development, It has very important significance so carrying out R and D to pure electric automobile key technology.Entire car controller, motor control The three big electricity of device, battery management system as pure electric automobile electric-control system, it has also become one of electric vehicle engineering important to grind Study carefully content.Battery management system implements charge and discharge protecting, working condition detection and battery pack balancing function etc. to battery system, leads to It crosses specific algorithm and realizes software and hardware protection and balancing energy.
In the numerous monitoring parameter of battery management system, cell health state (SOH) is wherein mostly important parameter One of.The appraisal procedure precision of power battery of pure electric automobile health status is not high at present, and the factor of consideration is single, and lacks real The problem of when property.The safety of power system of electric automobile and usage time and battery SOH are closely related.According to ieee standard Regulation in 1188-1996, when battery after a period of use, capacity when battery is fully charged is less than battery rated capacity After 80%, battery should be just replaced.The performance degradation of aged battery, and be easy to cause various safety problems.If energy Accurate estimating state of health of battery reminds people more to renew battery in time, and generation can not be pre- during avoiding aged battery use The safety problem known, while can also avoid more renewing the wasting of resources caused by battery too early.
Invention content
The object of the present invention is to provide a kind of evaluation methods of cell health state SOH, to solve present battery health shape State SOH evaluation method precision is low, Consideration is single and the problem of cannot meeting real-time.
To achieve the goals above, the evaluation method of a kind of cell health state SOH provided by the invention, specifically includes step It is rapid as follows:
1) the rated capacity C of battery core under current environment is obtained by temperature and charge-discharge magnification0
2) the SOC value SOC of current battery core is calculatedEKF
3) the SOC value SOC in battery management system EEPROM is readEEPROM, obtain corresponding cycles left number;
4) current battery core temperature is obtained, by combining Current Temperatures and corresponding cycles left number, it is current to obtain battery core Maximum capacity C can be used;
5) resistance R when battery core end-of-life is obtained according to current battery core temperatureEOLInternal resistance value R when dispatching from the factory with battery coreNEW
6) the true internal resistance R of battery core is calculated according to Order RC ring model;
7) i-th of battery cell health status SOH of current time is calculatedi
8) i-th of battery cell health status SOH of current timeiAveraging filter, which is rolled, by one is filtered meter It calculates, prevents battery cell health status SOHiThe mutation of value obtains i-th of battery cell health shape after current time filtering State SOHi_new_filter
9) current total discharge electricity amount Q in battery management system EEPROM is read, and is obtained in battery system life cycle Nominal available discharge electricity amount Q0
10) battery system health status SOH is calculated.
The SOC value SOC of current battery core is calculated in the step 2) by expanded Kalman filtration algorithm EKFEKF
The SOC value SOC in battery management system EEPROM is read in the step 3)EEPROM, obtain corresponding cycles left The method of number is, if │ SOCEKF-SOCEEPROM│ >=90% is then judged as a deep discharge, corresponding cycles left number 1 is reduced, otherwise, corresponding cycles left number reduces k, k=90%/│ SOCEKF-SOCEEPROM│, k are judgement factor.
The computational methods for calculating the true internal resistance R of battery core in the step 6) according to Order RC ring model are R=Re+Rl+ Rs, wherein ReIt is the ohmic internal resistance of battery, real-time value, R is calculated by expanded Kalman filtration algorithm EKFlIndicate length Effect polarization resistance, RsIt indicates short-acting and answers polarization resistance, Rl+RsIndicate the polarization resistance of battery.
The method that i-th of battery cell health status of current time is calculated in the step 7) is as follows:
SOHi=wC/C0+(1-W)(REOL-R)/(REOL-RNEW)
Wherein, w is weighting coefficient, REOLIndicate battery core end-of-life internal resistance, RNEWIndicate internal resistance when battery core manufacture.
I-th of battery cell health status SOH after current time filtering is obtained in the step 8)i_new_filter's Method is as follows:
SOHi_new_filter=[tsample/(tsample+tc)]×(SOHi_new-SOHi_old_filter)+SOHi_old_filter
Wherein, tsampleFor sampling time, tcTo roll the time constant filter of filter.SOHi_old_filterIt is adopted for upper one I-th of battery cell health status after the filtering of sample moment, SOHi_newThere is no filtered i-th of battery for current time Monomer health status, SOHi_new_filterBe it is current it is filtered after i-th of battery cell health status.
The method that battery system health status SOH is calculated in the step 10) is as follows:
SOH=a × min [SOH1_new_filter, SOH2_new_filter... ..., SOHn_new_filter]+(1-a)(Q0-Q)/Q0
Wherein, a is weighting coefficient, and n is battery core quantity, min [SOH1_new_filter, SOH2_new_filter... ..., SOHn_new_filter] represent the minimum value for taking health status in all monomers, SOH1_new_filter, SOH2_new_filter... ..., SOHn_new_filterIndicate the 1st, 2 ... ..., n battery cell health status.
It is provided by the invention, it has the advantages that.
1. the present invention combines the estimation of the parameter progress cell health state of two levels of battery cell and battery system.
2. the present invention considered in estimating state of health of battery temperature, cycle-index, internal resistance, capacity, charge-discharge magnification, The influence factors such as depth of discharge make the factor considered when estimation more fully, and the result of estimation is more accurate.
3 life cycle data invention introduces battery cell under various circumstances.
Description of the drawings
Fig. 1 is the flow diagram of the evaluation method of cell health state SOH provided by the invention.
Specific implementation mode
The present invention provides a kind of evaluation method of cell health state SOH, considers the factors for influencing battery life, than Such as:Temperature, internal resistance, capacity, charge-discharge magnification, depth of discharge etc. introduce lifetime data of the battery core in whole life cycle With internal resistance data, the advantages of in combination with internal resistance Commutation Law and capacity definition method and EKF Extended Kalman filter calculates SOC With the real time characteristic of ohmic internal resistance, and by carrying out dual assessment in battery core level and system level, realize to battery SOH In high precision, the assessment of real-time.
The present invention provides a kind of evaluation method of cell health state SOH, as shown in Figure 1, specifically including, steps are as follows:
1) the temperature value T and current parameters I that battery core is obtained by PACK inner sensors, using the temperature value T of battery core as defeated Enter temperature;The current flow parameter I of battery core is converted into corresponding charge-discharge magnification.It is tabled look-up by temperature and charge-discharge magnification (table is the rated capacity table under different temperatures, charge-discharge magnification, it is known that generally being provided by battery core producer) obtains working as front ring The rated capacity C of battery core under border0
2) " SOC value of current battery core " is calculated by expanded Kalman filtration algorithm EKF:SOCEKF
3) battery management system " SOC value in EEPROM " is read:SOCEEPROMIf │ SOCEKF-SOCEEPROM│ >=90%, Then it is judged as that a deep discharge, corresponding cycles left number reduce 1, otherwise, corresponding cycles left number reduces k (k < 1), k=90%/│ SOCEKF-SOCEEPROM│, k are judgement factor.
4) current battery core temperature is obtained, by combining Current Temperatures and corresponding cycles left number, tables look-up and obtains battery core Currently available maximum capacity C.
5) according to current battery core temperature, table look-up (table be different temperatures under battery core end-of-life when internal resistance table, Know, generally provided by battery core producer) obtain battery core end-of-life when resistance REOLInternal resistance value R when dispatching from the factory with battery coreNEW
6) according to Order RC ring model, the true internal resistance R of battery core is calculated:
R=Re+Rl+Rs
Wherein, ReIt is the ohmic internal resistance of battery, real-time value can be calculated by expanded Kalman filtration algorithm EKF.Rl With RsAnd polarization resistance for battery, R is found out by parameter identificationl+RsValue.RlIndicate long effect polarization resistance (Order RC Model parameter);RsIt indicates short-acting and answers polarization resistance (Order RC model parameter).
7) i-th of battery cell health status SOH of current time is calculated according to following formulai
SOHi=wC/C0+(1-W)(REOL-R)/(REOL-RNEW)
Wherein, REOLIndicate battery core end-of-life internal resistance, RNEWIndicate internal resistance when battery core manufacture, w is weighting coefficient, should be added Weight coefficient can be obtained by experiment, or be provided by battery core producer, and knot is calculated for " capacity method SOH " and " internal resistance method SOH " The accounting of fruit, initial stage can be with values for 0.5.
8) i-th of battery cell health status SOH of current timeiAveraging filter, which is rolled, by one is filtered meter It calculates, prevents battery cell health status SOHiThe mutation of value obtains i-th of battery cell health shape after current time filtering State SOHi_new_filter:
SOHi_new_filter=[tsample/(tsample+tc)]×(SOHi_new-SOHi_old_filter)+SOHi_old_filter
In above formula, tsampleFor sampling time, tcTo roll the time constant filter of filter.SOHi_old_filterIt is upper one I-th of battery cell health status (voltage value) after sampling instant filtering, SOHi_newIt is not filtered for current time I-th of battery cell health status (voltage value), SOHi_new_filterBe it is current it is filtered after i-th of battery cell Health status (voltage value).
9) current total discharge electricity amount Q in battery management system EEPROM is read, and is obtained in battery system life cycle Nominal available discharge electricity amount Q0(it is known that generally being provided by battery core producer).
10) battery system health status SOH is calculated as follows, and wherein n is battery core quantity:
SOH=a × min [SOH1_new_filter, SOH2_new_filter... ..., SOHn_new_filter]+(1-a)(Q0-Q)/Q0On In formula, a is weighting coefficient, can be obtained by experiment, is " monomer SOH " and " calculating gained SOH according to PACK discharge capacities " meter Result accounting is calculated, initial stage can be with value for 0.5.
min[SOH1_new_filter, SOH2_new_filter... ..., SOHn_new_filter] represent take health status in all monomers Minimum value.
SOH1_new_filter, SOH2_new_filter... ..., SOHn_new_filterIndicate the 1st, 2 ... ..., n battery cell is strong Health state.
Specific case used herein elaborates inventive concept, the explanation of above example is only intended to Help understands core of the invention thought.It should be pointed out that for those skilled in the art, not departing from this Under the premise of inventive concept, any obvious modification, equivalent replacement or the other improvements made should be included in the present invention Protection domain within.

Claims (7)

1. a kind of evaluation method of cell health state SOH, which is characterized in that specifically include that steps are as follows:
1) the rated capacity C of battery core under current environment is obtained by temperature and charge-discharge magnification0
2) the SOC value SOC of current battery core is calculatedEKF
3) the SOC value SOC in battery management system EEPROM is readEEPROM, obtain corresponding cycles left number;
4) current battery core temperature is obtained, by combining Current Temperatures and corresponding cycles left number, it is currently available to obtain battery core Maximum capacity C;
5) resistance R when battery core end-of-life is obtained according to current battery core temperatureEOLInternal resistance value R when dispatching from the factory with battery coreNEW
6) the true internal resistance R of battery core is calculated according to Order RC ring model;
7) i-th of battery cell health status SOH of current time is calculatedi
8) i-th of battery cell health status SOH of current timeiAveraging filter is rolled by one and is filtered calculating, is obtained I-th of battery cell health status SOH after being filtered to current timei_new_filter
9) current total discharge electricity amount Q in battery management system EEPROM is read, and obtains the mark in battery system life cycle Title can use discharge electricity amount Q0
10) battery system health status SOH is calculated.
2. the evaluation method of cell health state SOH according to claim 1, which is characterized in that lead in the step 2) Cross the SOC value SOC that expanded Kalman filtration algorithm EKF calculates current battery coreEKF
3. the evaluation method of cell health state SOH according to claim 1, which is characterized in that read in the step 3) Take the SOC value SOC in battery management system EEPROMEEPROM, the method for obtaining corresponding cycles left number is, if │ SOCEKF- SOCEEPROM│ >=90% is then judged as that a deep discharge, corresponding cycles left number reduce 1, and otherwise, corresponding residue is followed Ring number reduces k, k=90%/│ SOCEKF-SOCEEPROM│, k are judgement factor.
4. the evaluation method of cell health state SOH according to claim 1, which is characterized in that root in the step 6) The computational methods that the true internal resistance R of battery core is calculated according to Order RC ring model are R=Re+Rl+Rs, wherein ReIt is in ohm of battery Resistance, real-time value, R are calculated by expanded Kalman filtration algorithm EKFlIndicate long effect polarization resistance, RsIt indicates short-acting to answer Polarization resistance, Rl+RsIndicate the polarization resistance of battery.
5. the evaluation method of cell health state SOH according to claim 1, which is characterized in that the step 7) is fallen into a trap The method for calculating i-th of battery cell health status of current time is as follows:
SOHi=wC/C0+(1-W)(REOL-R)/(REOL-RNEW)
Wherein, w is weighting coefficient, REOLIndicate battery core end-of-life internal resistance, RNEWIndicate internal resistance when battery core manufacture.
6. the evaluation method of cell health state SOH according to claim 1, which is characterized in that in the step 8) I-th of battery cell health status SOH after being filtered to current timei_new_filterMethod it is as follows:
SOHi_new_filter=[tsample/(tsample+tc)]×(SOHi_new-SOHi_old_filter)+SOHi_old_filter
Wherein, tsampleFor sampling time, tcTo roll the time constant filter of filter.SOHi_old_filterWhen being sampled for upper one Carve i-th of battery cell health status after filtering, SOHi_newThere is no filtered i-th of battery cell for current time Health status, SOHi_new_filterBe it is current it is filtered after i-th of battery cell health status.
7. the evaluation method of cell health state SOH as claimed in any of claims 1 to 6, which is characterized in that institute The method for stating calculating battery system health status SOH in step 10) is as follows:
SOH=a × min [SOH1_new_filter, SOH2_new_filter... ..., SOHn_new_filter]+(1-a)(Q0-Q)/Q0
Wherein, a is weighting coefficient, and n is battery core quantity, min [SOH1_new_filter, SOH2_new_filter... ..., SOHn_new_filter] represent the minimum value for taking health status in all monomers, SOH1_new_filter, SOH2_new_filter... ..., SOHn_new_filterIndicate the 1st, 2 ... ..., n battery cell health status.
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CN109633473A (en) * 2019-01-23 2019-04-16 刘平 A kind of distributed battery group state-of-charge algorithm for estimating
CN109655750A (en) * 2019-01-31 2019-04-19 北汽福田汽车股份有限公司 Prediction technique, the prediction meanss of battery life
CN110161423A (en) * 2019-06-26 2019-08-23 重庆大学 A kind of dynamic lithium battery state joint estimation method based on various dimensions coupling model
CN110568375A (en) * 2019-09-03 2019-12-13 昆山宝创新能源科技有限公司 SOH (state of health) determination method and device for power battery
CN110568373A (en) * 2019-07-29 2019-12-13 深圳市科陆电子科技股份有限公司 Lithium battery health state evaluation method, system, terminal and storage medium
CN111366865A (en) * 2020-03-25 2020-07-03 松下电器机电(中国)有限公司 Method for calculating health degree of battery
CN111781502A (en) * 2019-04-04 2020-10-16 宁德时代新能源科技股份有限公司 Battery detection method and device for electric automobile and detection equipment
CN112014751A (en) * 2020-09-04 2020-12-01 福建飞毛腿动力科技有限公司 SOC estimation method based on estimation of actual dischargeable capacity of lithium ion battery
CN112363077A (en) * 2020-11-11 2021-02-12 上海电享信息科技有限公司 Battery health degree capacity estimation method
CN112485691A (en) * 2020-10-30 2021-03-12 傲普(上海)新能源有限公司 SOH estimation method of lithium ion battery
CN113281656A (en) * 2021-05-20 2021-08-20 北京现代汽车有限公司 Method and device for determining health degree of battery
CN113567862A (en) * 2021-07-13 2021-10-29 珠海朗尔电气有限公司 SOH estimation method and device for lithium battery standby system
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CN114091975A (en) * 2021-12-08 2022-02-25 绍兴建元电力集团有限公司 Method for evaluating operation life of energy storage power station
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CN116299005A (en) * 2023-02-07 2023-06-23 江南大学 Power battery health state prediction method based on AAF and deep learning
CN116930773A (en) * 2023-09-15 2023-10-24 杭州鹏成新能源科技有限公司 Lithium battery SOH estimation method and system
CN117406125A (en) * 2023-12-15 2024-01-16 山东派蒙机电技术有限公司 Battery health state confirmation method, device, equipment and storage medium
CN117541334A (en) * 2024-01-04 2024-02-09 深圳海辰储能科技有限公司 Value evaluation method and related device of energy storage equipment

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CN109541473A (en) * 2018-10-18 2019-03-29 东北电力大学 Lead carbon battery health status evaluation method based on discharge capacity weighted accumulation
CN109633473A (en) * 2019-01-23 2019-04-16 刘平 A kind of distributed battery group state-of-charge algorithm for estimating
CN109655750A (en) * 2019-01-31 2019-04-19 北汽福田汽车股份有限公司 Prediction technique, the prediction meanss of battery life
CN111781502A (en) * 2019-04-04 2020-10-16 宁德时代新能源科技股份有限公司 Battery detection method and device for electric automobile and detection equipment
CN110161423A (en) * 2019-06-26 2019-08-23 重庆大学 A kind of dynamic lithium battery state joint estimation method based on various dimensions coupling model
CN110568373A (en) * 2019-07-29 2019-12-13 深圳市科陆电子科技股份有限公司 Lithium battery health state evaluation method, system, terminal and storage medium
CN110568375A (en) * 2019-09-03 2019-12-13 昆山宝创新能源科技有限公司 SOH (state of health) determination method and device for power battery
US11575271B2 (en) 2019-12-24 2023-02-07 Calb Co., Ltd. SOC and SOH estimation methods of battery pack
CN111366865A (en) * 2020-03-25 2020-07-03 松下电器机电(中国)有限公司 Method for calculating health degree of battery
US11402434B2 (en) 2020-07-02 2022-08-02 Contemporary Amperex Technology Co., Limited Battery state estimation method, apparatus, device, battery system and storage medium
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WO2022000415A1 (en) * 2020-07-02 2022-01-06 宁德时代新能源科技股份有限公司 Battery state estimation method and apparatus, and device, battery system and storage medium
CN112014751B (en) * 2020-09-04 2023-04-07 福建飞毛腿动力科技有限公司 SOC estimation method based on estimation of actual dischargeable capacity of lithium ion battery
CN112014751A (en) * 2020-09-04 2020-12-01 福建飞毛腿动力科技有限公司 SOC estimation method based on estimation of actual dischargeable capacity of lithium ion battery
CN112485691B (en) * 2020-10-30 2022-10-21 傲普(上海)新能源有限公司 SOH estimation method of lithium ion battery
CN112485691A (en) * 2020-10-30 2021-03-12 傲普(上海)新能源有限公司 SOH estimation method of lithium ion battery
CN112363077A (en) * 2020-11-11 2021-02-12 上海电享信息科技有限公司 Battery health degree capacity estimation method
CN113281656A (en) * 2021-05-20 2021-08-20 北京现代汽车有限公司 Method and device for determining health degree of battery
CN113567862A (en) * 2021-07-13 2021-10-29 珠海朗尔电气有限公司 SOH estimation method and device for lithium battery standby system
CN114091975A (en) * 2021-12-08 2022-02-25 绍兴建元电力集团有限公司 Method for evaluating operation life of energy storage power station
CN116299005A (en) * 2023-02-07 2023-06-23 江南大学 Power battery health state prediction method based on AAF and deep learning
CN116299005B (en) * 2023-02-07 2023-09-05 江南大学 Power battery health state prediction method based on AAF and deep learning
CN116930773A (en) * 2023-09-15 2023-10-24 杭州鹏成新能源科技有限公司 Lithium battery SOH estimation method and system
CN117406125A (en) * 2023-12-15 2024-01-16 山东派蒙机电技术有限公司 Battery health state confirmation method, device, equipment and storage medium
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Application publication date: 20180918