CN108546481A - A kind of aluminium frame anticorrosive paint and preparation method thereof - Google Patents
A kind of aluminium frame anticorrosive paint and preparation method thereof Download PDFInfo
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- CN108546481A CN108546481A CN201810447857.6A CN201810447857A CN108546481A CN 108546481 A CN108546481 A CN 108546481A CN 201810447857 A CN201810447857 A CN 201810447857A CN 108546481 A CN108546481 A CN 108546481A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/10—Block or graft copolymers containing polysiloxane sequences
- C09D183/12—Block or graft copolymers containing polysiloxane sequences containing polyether sequences
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
A kind of aluminium frame anticorrosive paint of present invention offer and preparation method thereof, is prepared by following component：Organic resin lotion, slurry, kaolin, nano silicon dioxide, mineral oil, ethylene glycol, thickener, dispersant and deionized water.Coating covering power prepared by the present invention is good, has excellent Corrosion Protection, and the paint film property of coating is excellent, and weatherability is strong, and scrubbing resistance, ageing-resistant, scratch resistance, use scope is wide, and preparation method is simple, and production process three wastes generate, Environmental Safety.
Description
Technical field
The invention belongs to technology for producing coating fields, and in particular to a kind of aluminium frame anticorrosive paint and preparation method thereof.
Background technology
With the high speed development of scientific and technological progress and national economy, the environmental consciousness of people enhances, increasingly to healthy pursuit
Also higher and higher, environmental protection and energy saving have become the main problem that coating industry faces.Currently, metallic paint because its coverage effect is good,
Bright in color, the class that can improve building fully show elegant makings and are known and like.Currently, market
On high-test metal coating need to can be only achieved good coverage effect using excellent material, this kind of good metallic paint is logical
Normal powder containing quantity is relatively high and cost price is high；And on the market some common metal coating paint film property is poor, make moist after metope it is de-
Powder, is easy moldy metamorphism at peeling cracking, and users is made to receive puzzlement.
In summary, it is therefore desirable to a kind of better coating, to change the deficiencies in the prior art.
Invention content
The object of the present invention is to provide a kind of aluminium frame anticorrosive paint and preparation method thereof, coating covering power prepared by the present invention
It is good, there is excellent Corrosion Protection, the paint film property of coating is excellent, and weatherability is strong, scrubbing resistance, ageing-resistant, scratch resistance, uses
Range is wide, and preparation method is simple, and production process three wastes generate, Environmental Safety.
The present invention provides the following technical solutions：
A kind of aluminium frame anticorrosive paint, includes the raw material of following parts by weight：22-29 parts of organic resin lotion, 13-18 parts of slurry, height
Soil 10-17 parts of ridge, 14-18 parts of nano silicon dioxide, 8-13 parts of mineral oil, 5-9 parts of ethylene glycol, 7-11 parts of thickener, dispersant
7-15 parts and 12-19 parts of deionized water.
Preferably, the coating includes the raw material of following parts by weight：22-26 parts of organic resin lotion, 13-17 parts of slurry,
13-17 parts of kaolin, 14-17 parts of nano silicon dioxide, 11-13 parts of mineral oil, 6-9 parts of ethylene glycol, 8-11 parts of thickener, dispersion
12-17 parts of 7-14 parts of agent and deionized water.
Preferably, the coating includes the raw material of following parts by weight：25 parts of organic resin lotion, 16 parts of slurry, kaolin
17 parts, 14 parts of nano silicon dioxide, 13 parts of mineral oil, 6 parts of ethylene glycol, 11 parts of thickener, 7 parts of dispersant and deionized water 15
Part.
A kind of preparation method of aluminium frame anticorrosive paint, including following preparation process：
A, it by organic resin lotion, slurry and mineral oil, imports in blender, heats and be stirred to react at 55-65 DEG C
30-50min obtains mixture one；
B, kaolin is placed in sintering furnace, 1-2h is calcined at 600-800 DEG C, then import in ball mill, was milled to 300-
500 mesh sieve, uniform with nano silicon dioxide, ethylene glycol and dispersant, import in Scattered Kettle, in turning for 300-400r/min
Speed is lower to stir 20-30min, adds mixture one, is warming up to 60-70 DEG C, is stirred to react under the rotating speed of 500-600r/min
40-50min obtains mixture two；
C, thickener and deionized water are added into mixture two, 20-30min is stirred under the rotating speed of 400-500r/min, then
It imports in reaction kettle, is dehydrated to water content 30% at 60-80 DEG C hereinafter, can be obtained finished product.
Preferably, the organic resin lotion of the step a is mixed by organosilicon-acrylic resin emulsion and organosilicon modified polyether
It closes.
Preferably, the slurry of the step a is the mixture of Titanium dioxide slurry and carbon black.
Preferably, the preparation method of the Titanium dioxide slurry is：By titanium dioxide, antifoaming agent, fungicide, wetting agent and water according to
In secondary input stirred tank, under the rotating speed of 200-300r/min, it is stirred to react 20-30min, then be warming up to 50-65 DEG C,
It is stirred to react in 30-40min, then sand mill under the rotating speed of 600-800r/min and grinds 20-30min, you can obtain finished product.
Preferably, the thickener of the step c is the mixture of polyurethane thickener and cellulose ether.
The beneficial effects of the invention are as follows：
Coating covering power prepared by the present invention is good, has excellent Corrosion Protection, the paint film property of coating is excellent, weatherability
By force, scrubbing resistance, ageing-resistant, scratch resistance, use scope is wide, and preparation method is simple, and production process three wastes generate, environmental protection
Safety.
The main component that organic resin lotion in the present invention uses is organosilicon-acrylic resin emulsion, with excellent resistance to
Hou Xing coordinates the use of organosilicon modified polyether, during being stirred to react, can reduce gas such as acid and alkali-resistance, wear-resisting, ageing-resistant
The generation of bubble so that the coating of preparation does not have bubble, convenient for coating and molding.
Slurry in the present invention, is made of Titanium dioxide slurry and carbon black, the wear-resisting property and shock resistance that ingredient has
The weatherability of finished product can be improved in performance, and titanium dioxide can also increase smoothness and texture after coating drying.
Specific implementation mode
Embodiment 1
A kind of aluminium frame anticorrosive paint, includes the raw material of following parts by weight：22 parts of organic resin lotion, 18 parts of slurry, kaolin 17
Part, 14 parts of nano silicon dioxide, 13 parts of mineral oil, 5 parts of ethylene glycol, 11 parts of thickener, 7 parts of dispersant and 19 parts of deionized water.
A kind of preparation method of aluminium frame anticorrosive paint, including following preparation process：
A, it by organic resin lotion, slurry and mineral oil, imports in blender, heats and be stirred to react at 55 DEG C
50min obtains mixture one；
B, kaolin is placed in sintering furnace, 2h is calcined at 600 DEG C, then import in ball mill, be milled to 500 mesh sieve, with
Nano silicon dioxide, ethylene glycol and dispersant are uniform, import in Scattered Kettle, 30min is stirred under the rotating speed of 300r/min,
Mixture one is added, is warming up to 60 DEG C, 40min is stirred to react under the rotating speed of 600r/min, obtains mixture two；
C, thickener and deionized water are added into mixture two, 30min is stirred under the rotating speed of 400r/min, then import reaction
In kettle, it is dehydrated to water content 30% at 80 DEG C hereinafter, can be obtained finished product.
The organic resin lotion of step a is mixed by organosilicon-acrylic resin emulsion and organosilicon modified polyether.
The slurry of step a is the mixture of Titanium dioxide slurry and carbon black.
The preparation method of Titanium dioxide slurry is：Titanium dioxide, antifoaming agent, fungicide, wetting agent and water are put into stirring successively
In kettle, under the rotating speed of 200r/min, it is stirred to react 20min, then be warming up to 55 DEG C, is stirred under the rotating speed of 800r/min anti-
It answers and grinds 30min in 40min, then sand mill, you can obtain finished product.
The thickener of step c is the mixture of polyurethane thickener and cellulose ether.
Embodiment 2
A kind of aluminium frame anticorrosive paint, includes the raw material of following parts by weight：22 parts of organic resin lotion, 17 parts of slurry, kaolin 13
Part, 14 parts of nano silicon dioxide, 11 parts of mineral oil, 6 parts of ethylene glycol, 8 parts of thickener, 7 parts of dispersant and 12 parts of deionized water.
A kind of preparation method of aluminium frame anticorrosive paint, including following preparation process：
A, it by organic resin lotion, slurry and mineral oil, imports in blender, heats and be stirred to react at 55 DEG C
30min obtains mixture one；
B, kaolin is placed in sintering furnace, 1h is calcined at 600 DEG C, then import in ball mill, be milled to 300 mesh sieve, with
Nano silicon dioxide, ethylene glycol and dispersant are uniform, import in Scattered Kettle, 20min is stirred under the rotating speed of 300r/min,
Mixture one is added, is warming up to 60 DEG C, 40min is stirred to react under the rotating speed of 500r/min, obtains mixture two；
C, thickener and deionized water are added into mixture two, 20min is stirred under the rotating speed of 400r/min, then import reaction
In kettle, it is dehydrated to water content 30% at 60 DEG C hereinafter, can be obtained finished product.
The organic resin lotion of step a is mixed by organosilicon-acrylic resin emulsion and organosilicon modified polyether.
The slurry of step a is the mixture of Titanium dioxide slurry and carbon black.
The preparation method of Titanium dioxide slurry is：Titanium dioxide, antifoaming agent, fungicide, wetting agent and water are put into stirring successively
In kettle, under the rotating speed of 200r/min, it is stirred to react 20min, then be warming up to 50 DEG C, is stirred under the rotating speed of 600r/min anti-
It answers and grinds 20min in 30min, then sand mill, you can obtain finished product.
The thickener of step c is the mixture of polyurethane thickener and cellulose ether.
Embodiment 3
A kind of aluminium frame anticorrosive paint, includes the raw material of following parts by weight：25 parts of organic resin lotion, 16 parts of slurry, kaolin 17
Part, 14 parts of nano silicon dioxide, 13 parts of mineral oil, 6 parts of ethylene glycol, 11 parts of thickener, 7 parts of dispersant and 15 parts of deionized water.
A kind of preparation method of aluminium frame anticorrosive paint, including following preparation process：
A, it by organic resin lotion, slurry and mineral oil, imports in blender, heats and be stirred to react at 65 DEG C
50min obtains mixture one；
B, kaolin is placed in sintering furnace, 2h is calcined at 800 DEG C, then import in ball mill, be milled to 500 mesh sieve, with
Nano silicon dioxide, ethylene glycol and dispersant are uniform, import in Scattered Kettle, 30min is stirred under the rotating speed of 400r/min,
Mixture one is added, is warming up to 70 DEG C, 50min is stirred to react under the rotating speed of 600r/min, obtains mixture two；
C, thickener and deionized water are added into mixture two, 30min is stirred under the rotating speed of 4500r/min, then imports anti-
It answers in kettle, is dehydrated to water content 30% at 80 DEG C hereinafter, can be obtained finished product.
The organic resin lotion of step a is mixed by organosilicon-acrylic resin emulsion and organosilicon modified polyether.
The slurry of step a is the mixture of Titanium dioxide slurry and carbon black.
The preparation method of Titanium dioxide slurry is：Titanium dioxide, antifoaming agent, fungicide, wetting agent and water are put into stirring successively
In kettle, under the rotating speed of 300r/min, it is stirred to react 30min, then be warming up to 55 DEG C, is stirred under the rotating speed of 800r/min anti-
It answers and grinds 30min in 40min, then sand mill, you can obtain finished product.
The thickener of step c is the mixture of polyurethane thickener and cellulose ether.
Finished product prepared by above example is detected, following detection data is obtained：
Table one：
| Project | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Adhesive force（Grade） | 1 | 1 | 1 |
| Impact strength（cm） | 50 | 50 | 50 |
| Acid resistance（5% sulfuric acid） | Phenomena such as without peeling, blistering, crackle | Phenomena such as without peeling, blistering, crackle | Phenomena such as without peeling, blistering, crackle |
| Alkali resistance（5% sodium hydroxide） | Phenomena such as without peeling, blistering, crackle | Phenomena such as without peeling, blistering, crackle | Phenomena such as without peeling, blistering, crackle |
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although with reference to the foregoing embodiments
Invention is explained in detail, for those skilled in the art, still can be to foregoing embodiments institute
The technical solution of record is modified or equivalent replacement of some of the technical features.It is all the present invention spirit and
Within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention.
Claims (8)
1. a kind of aluminium frame anticorrosive paint, which is characterized in that include the raw material of following parts by weight：22-29 parts of organic resin lotion, slurry
13-18 parts of material, 10-17 parts of kaolin, 14-18 parts of nano silicon dioxide, 8-13 parts of mineral oil, 5-9 parts of ethylene glycol, thickener 7-
12-19 parts of 11 parts, 7-15 parts of dispersant and deionized water.
2. a kind of aluminium frame anticorrosive paint according to claim 1, which is characterized in that the coating includes following parts by weight
Raw material：22-26 parts of organic resin lotion, 13-17 parts of slurry, 13-17 parts of kaolin, 14-17 parts of nano silicon dioxide, mineral oil
12-17 parts of 11-13 parts, 6-9 parts of ethylene glycol, 8-11 parts of thickener, 7-14 parts of dispersant and deionized water.
3. a kind of aluminium frame anticorrosive paint according to claim 1, which is characterized in that the coating includes following parts by weight
Raw material：25 parts of organic resin lotion, 16 parts of slurry, 17 parts of kaolin, 14 parts of nano silicon dioxide, 13 parts of mineral oil, ethylene glycol 6
Part, 11 parts of thickener, 7 parts of dispersant and 15 parts of deionized water.
4. a kind of preparation method of aluminium frame anticorrosive paint of claim 1-3 any one of them, which is characterized in that including following system
Standby step：
A, it by organic resin lotion, slurry and mineral oil, imports in blender, heats and be stirred to react at 55-65 DEG C
30-50min obtains mixture one；
B, kaolin is placed in sintering furnace, 1-2h is calcined at 600-800 DEG C, then import in ball mill, was milled to 300-
500 mesh sieve, uniform with nano silicon dioxide, ethylene glycol and dispersant, import in Scattered Kettle, in turning for 300-400r/min
Speed is lower to stir 20-30min, adds mixture one, is warming up to 60-70 DEG C, is stirred to react under the rotating speed of 500-600r/min
40-50min obtains mixture two；
C, thickener and deionized water are added into mixture two, 20-30min is stirred under the rotating speed of 400-500r/min, then
It imports in reaction kettle, is dehydrated to water content 30% at 60-80 DEG C hereinafter, can be obtained finished product.
5. a kind of preparation method of aluminium frame anticorrosive paint according to claim 4, which is characterized in that the step a's has
Machine resin emulsion is mixed by organosilicon-acrylic resin emulsion and organosilicon modified polyether.
6. a kind of preparation method of aluminium frame anticorrosive paint according to claim 4, which is characterized in that the slurry of the step a
Material is the mixture of Titanium dioxide slurry and carbon black.
7. a kind of preparation method of aluminium frame anticorrosive paint according to claim 5, which is characterized in that the Titanium dioxide slurry
Preparation method be：Titanium dioxide, antifoaming agent, fungicide, wetting agent and water are put into stirred tank successively, in 200-300r/
Under the rotating speed of min, it is stirred to react 20-30min, then be warming up to 50-65 DEG C, is stirred to react under the rotating speed of 600-800r/min
20-30min is ground in 30-40min, then sand mill, you can obtain finished product.
8. a kind of preparation method of aluminium frame anticorrosive paint according to claim 4, which is characterized in that the increasing of the step c
The thick dose of mixture for polyurethane thickener and cellulose ether.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810447857.6A CN108546481A (en) | 2018-05-11 | 2018-05-11 | A kind of aluminium frame anticorrosive paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810447857.6A CN108546481A (en) | 2018-05-11 | 2018-05-11 | A kind of aluminium frame anticorrosive paint and preparation method thereof |
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| Publication Number | Publication Date |
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| CN108546481A true CN108546481A (en) | 2018-09-18 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201810447857.6A Withdrawn CN108546481A (en) | 2018-05-11 | 2018-05-11 | A kind of aluminium frame anticorrosive paint and preparation method thereof |
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| CN (1) | CN108546481A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115232524A (en) * | 2021-06-18 | 2022-10-25 | 佛山市顺德区博宜防腐涂料科技有限公司 | Preparation method and use method of low-cost water-based ultrahigh-temperature-resistant paint capable of being cured into film in self-crosslinking and sintering crosslinking modes |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104559601A (en) * | 2015-01-15 | 2015-04-29 | 淄博沃特曼普环保技术有限公司 | Metallic water-based paint |
-
2018
- 2018-05-11 CN CN201810447857.6A patent/CN108546481A/en not_active Withdrawn
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104559601A (en) * | 2015-01-15 | 2015-04-29 | 淄博沃特曼普环保技术有限公司 | Metallic water-based paint |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115232524A (en) * | 2021-06-18 | 2022-10-25 | 佛山市顺德区博宜防腐涂料科技有限公司 | Preparation method and use method of low-cost water-based ultrahigh-temperature-resistant paint capable of being cured into film in self-crosslinking and sintering crosslinking modes |
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Application publication date: 20180918 |