CN108546354A - A kind of corrosion-resistant antiultraviolet composite material and preparation method - Google Patents
A kind of corrosion-resistant antiultraviolet composite material and preparation method Download PDFInfo
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- CN108546354A CN108546354A CN201810346883.XA CN201810346883A CN108546354A CN 108546354 A CN108546354 A CN 108546354A CN 201810346883 A CN201810346883 A CN 201810346883A CN 108546354 A CN108546354 A CN 108546354A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The invention discloses a kind of corrosion-resistant antiultraviolet composite materials, and according to the mass fraction, composition of raw materials is as follows：1000~1500 parts of isoprene rubber, 1000~1300 parts of medium density polyethylene resin, 1000~1500 parts of butyl acetate, 800~1200 parts of metallocene linear-low density polyethylene, 1200~1800 parts of nano-sized carbon, 35~50 parts of ultraviolet-resistant absorbent, 10~20 parts of polyvinyl chloride resin, 50~80 parts of polysiloxane, 60~90 parts of dipentaerythritol, 30~60 parts of polyurethane.The present invention prepares corrosion-resistant antiultraviolet composite material using isoprene rubber, polyvinyl chloride resin, ultraviolet-resistant absorbent and polysiloxane, with no coupling product, strong operability, and the advantages that effectively controlling production cost, the present invention can both dissolve auxiliary resin very well, isoprene rubber in formula can improve floor antiseptic property, while ultraviolet-resistant absorbent can also further weaken destruction of the ultraviolet light to color.
Description
Technical field
The present invention relates to a kind of corrosion-resistant antiultraviolet composite material and preparation methods.
Background technology
With the rapid development of economic construction, the continuous improvement of people's standard of living, all kinds of infrastructure in town and country it is quick
Development, it is increasing to all kinds of floor demands, therefore the quality that floor is continuously improved seems particularly significant, and it is continuously improved ground
The performance of plate improves the performances such as anti-corrosion, wear-resisting, anti-aging, it can be ensured that the protecting effect on floor.
Invention content
The technical problem to be solved by the present invention is to overcome the existing defects, provides a kind of corrosion-resistant antiultraviolet composite wood
Material, according to the mass fraction, composition of raw materials is as follows：
1000~1500 parts of isoprene rubber, 1000~1300 parts of medium density polyethylene resin, butyl acetate 1000~1500
Part, 800~1200 parts of metallocene linear-low density polyethylene, 1200~1800 parts of nano-sized carbon, ultraviolet-resistant absorbent 35~50
Part, 10~20 parts of polyvinyl chloride resin, 50~80 parts of polysiloxane, 60~90 parts of dipentaerythritol, 30~60 parts of polyurethane.
Further, according to the mass fraction, composition of raw materials is as follows for the corrosion-resistant antiultraviolet composite material：
1200 parts of isoprene rubber, 1000 parts of medium density polyethylene resin, butyl acetate 1200, metallocene linear low density are poly-
Ethylene 1000,1500 parts of nano-sized carbon, 40~45 parts of ultraviolet-resistant absorbent, 15 parts of polyvinyl chloride resin, polysiloxane 60~70
Part, 70~85 parts of dipentaerythritol, 40~50 parts of polyurethane.
Preferably, according to the mass fraction, composition of raw materials is as follows for the corrosion-resistant antiultraviolet composite material：
1000 parts of isoprene rubber, 1000 parts of medium density polyethylene resin, 1000 parts of butyl acetate, metallocene linear low density
800 parts of polyethylene, 1200 parts of nano-sized carbon, 35 parts of ultraviolet-resistant absorbent, 10 parts of polyvinyl chloride resin, 50 parts of polysiloxane, double seasons
Penta 60 parts of tetrol, 30 parts of polyurethane.
Preferably, according to the mass fraction, composition of raw materials is as follows for the corrosion-resistant antiultraviolet composite material：
1500 parts of isoprene rubber, 1300 parts of medium density polyethylene resin, 1500 parts of butyl acetate, metallocene linear low density
1200 parts of polyethylene, 1800 parts of nano-sized carbon, 50 parts of ultraviolet-resistant absorbent, 20 parts of polyvinyl chloride resin are 80 parts of polysiloxane, double
90 parts of pentaerythrite, 60 parts of polyurethane.
Another aspect of the present invention discloses a kind of production method of corrosion-resistant antiultraviolet composite material comprising with
Lower step：
1), isoprene rubber is crushed, is then proportionally added into nano-sized carbon, medium density polyethylene resin, butyl acetate, anti-purple
Ultraviolet absorbers, metallocene linear-low density polyethylene, polyvinyl chloride resin, dipentaerythritol, obtain mixture；
2) other residual components are added, is sent into high-speed kneading machine, 6-15min is mediated at 110-150 DEG C, wait mediating material
After cooling, it is sent into double screw extruder and is granulated to get corrosion-resistant antiultraviolet composite material.
The advantageous effect that is reached of the present invention is：The present invention using isoprene rubber, polyvinyl chloride resin, ultraviolet-resistant absorbent and
Polysiloxane prepares corrosion-resistant antiultraviolet composite material, has no coupling product, strong operability, and effectively control is produced into
This advantages that, the present invention can both dissolve auxiliary resin very well, and the isoprene rubber in formula can improve floor antiseptic property, together
When ultraviolet-resistant absorbent can also further weaken destruction of the ultraviolet light to color.
Specific implementation mode
Hereinafter, preferred embodiments of the present invention will be described, it should be understood that preferred embodiment described herein is only used
In the description and interpretation present invention, it is not intended to limit the present invention.
Embodiment 1
A kind of corrosion-resistant antiultraviolet composite material, according to the mass fraction, composition of raw materials is as follows：
1000 parts of isoprene rubber, 1300 parts of medium density polyethylene resin, 1000 parts of butyl acetate, metallocene linear low density
1200 parts of polyethylene, 1200 parts of nano-sized carbon, 50 parts of ultraviolet-resistant absorbent, 10 parts of polyvinyl chloride resin, 80 parts of polysiloxane.
The corrosion-resistant antiultraviolet composite material of the present invention, is prepared using following methods：
1), isoprene rubber is crushed, is then proportionally added into nano-sized carbon, medium density polyethylene resin, butyl acetate, anti-purple
Ultraviolet absorbers, metallocene linear-low density polyethylene, polyvinyl chloride resin, dipentaerythritol, obtain mixture；
2) other residual components are added, is sent into high-speed kneading machine, 6-15min is mediated at 110-150 DEG C, wait mediating material
After cooling, it is sent into double screw extruder and is granulated to get corrosion-resistant antiultraviolet composite material.
Embodiment 2
A kind of corrosion-resistant antiultraviolet composite material, according to the mass fraction, composition of raw materials is as follows：
1500 parts of isoprene rubber, 1000 parts of medium density polyethylene resin, 1500 parts of butyl acetate, metallocene linear low density
800 parts of polyethylene, 1800 parts of nano-sized carbon, 35 parts, 20 parts polyvinyl chloride resins of ultraviolet-resistant absorbent, 50 parts of polysiloxane.
The corrosion-resistant antiultraviolet composite material of the present invention, is prepared using following methods：
1), isoprene rubber is crushed, is then proportionally added into nano-sized carbon, medium density polyethylene resin, butyl acetate, anti-purple
Ultraviolet absorbers, metallocene linear-low density polyethylene, polyvinyl chloride resin, dipentaerythritol, obtain mixture；
2) other residual components are added, is sent into high-speed kneading machine, 6-15min is mediated at 110-150 DEG C, wait mediating material
After cooling, it is sent into double screw extruder and is granulated to get corrosion-resistant antiultraviolet composite material.
Embodiment 3
A kind of corrosion-resistant antiultraviolet composite material, according to the mass fraction, composition of raw materials is as follows：
1200 parts of isoprene rubber, 1000 parts of medium density polyethylene resin, 1200 parts of butyl acetate, metallocene linear low density
1000 parts of polyethylene, 1500 parts of nano-sized carbon, 45 parts of ultraviolet-resistant absorbent, 15 parts of polyvinyl chloride resins, 60 parts of polysiloxane.
The corrosion-resistant antiultraviolet composite material of the present invention, is prepared using following methods：
1), isoprene rubber is crushed, is then proportionally added into nano-sized carbon, medium density polyethylene resin, butyl acetate, anti-purple
Ultraviolet absorbers, metallocene linear-low density polyethylene, polyvinyl chloride resin, dipentaerythritol, obtain mixture；
2) other residual components are added, is sent into high-speed kneading machine, 6-15min is mediated at 110-150 DEG C, wait mediating material
After cooling, it is sent into double screw extruder and is granulated to get corrosion-resistant antiultraviolet composite material.
Embodiment 4
A kind of corrosion-resistant antiultraviolet composite material, according to the mass fraction, composition of raw materials is as follows：
1200 parts of isoprene rubber, 1100 parts of medium density polyethylene resin, 1200 parts of butyl acetate, metallocene linear low density
1000 parts of polyethylene, 1500 parts of nano-sized carbon, 40 parts of ultraviolet-resistant absorbent, 15 parts of polyvinyl chloride resins, 70 parts of polysiloxane.
The corrosion-resistant antiultraviolet composite material of the present invention, is prepared using following methods：
1), isoprene rubber is crushed, is then proportionally added into nano-sized carbon, medium density polyethylene resin, butyl acetate, anti-purple
Ultraviolet absorbers, metallocene linear-low density polyethylene, polyvinyl chloride resin, dipentaerythritol, obtain mixture；
2) other residual components are added, is sent into high-speed kneading machine, 6-15min is mediated at 110-150 DEG C, wait mediating material
After cooling, it is sent into double screw extruder and is granulated to get corrosion-resistant antiultraviolet composite material.
Finally it should be noted that：The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention,
Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still may be used
With technical scheme described in the above embodiments is modified or equivalent replacement of some of the technical features.
All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in the present invention's
Within protection domain.
Claims (7)
1. a kind of corrosion-resistant antiultraviolet composite material, which is characterized in that according to the mass fraction, composition of raw materials is as follows：
1000~1500 parts of isoprene rubber, 1000~1300 parts of medium density polyethylene resin, 1000~1500 parts of butyl acetate, cyclopentadienyl
800~1200 parts of metal linear low density polyethylene (LDPE), 1200~1800 parts of nano-sized carbon, 35~50 parts of ultraviolet-resistant absorbent, PVC
10~20 parts of resin, 50~80 parts of polysiloxane, 60~90 parts of dipentaerythritol, 30~60 parts of polyurethane.
2. a kind of corrosion-resistant antiultraviolet composite material as described in claim 1, which is characterized in that according to the mass fraction,
Composition of raw materials is as follows：
1200 parts of isoprene rubber, 1000 parts of medium density polyethylene resin, 1200 parts of butyl acetate, the poly- second of metallocene linear low density
1000 parts of alkene, 1500 parts of nano-sized carbon, 40~45 parts of ultraviolet-resistant absorbent, 15 parts of polyvinyl chloride resin, polysiloxane 60~70
Part, 70~85 parts of dipentaerythritol, 40~50 parts of polyurethane.
3. a kind of corrosion-resistant antiultraviolet composite material as described in claim 1, which is characterized in that according to the mass fraction,
Composition of raw materials is as follows：
1000 parts of isoprene rubber, 1000 parts of medium density polyethylene resin, 1000 parts of butyl acetate, the poly- second of metallocene linear low density
800 parts of alkene, 1200 parts of nano-sized carbon, 35 parts of ultraviolet-resistant absorbent, 10 parts of polyvinyl chloride resin, 50 parts of polysiloxane, double Ji Wusi
60 parts of alcohol, 30 parts of polyurethane.
4. a kind of corrosion-resistant antiultraviolet composite material as described in claim 1, which is characterized in that according to the mass fraction,
Composition of raw materials is as follows：
1500 parts of isoprene rubber, 1300 parts of medium density polyethylene resin, 1500 parts of butyl acetate, the poly- second of metallocene linear low density
1200 parts of alkene, 1800 parts of nano-sized carbon, 50 parts of ultraviolet-resistant absorbent, 20 parts of polyvinyl chloride resin, 80 parts of polysiloxane, double seasons penta
90 parts of tetrol, 60 parts of polyurethane.
5. the production method of corrosion-resistant antiultraviolet composite material described in a kind of claim 1, which is characterized in that including following step
Suddenly：
1), isoprene rubber is crushed, is then proportionally added into nano-sized carbon, medium density polyethylene resin, butyl acetate, uvioresistant
Absorbent, metallocene linear-low density polyethylene, polyvinyl chloride resin, dipentaerythritol, obtain mixture；
2) other residual components are added, is sent into high-speed kneading machine and mediates, after mediating material cooling, is sent into double screw extruder and makes
Grain is to get corrosion-resistant antiultraviolet composite material.
6. the production method of corrosion-resistant antiultraviolet composite material according to claim 5, which is characterized in that the ratio of each material
Example be according to the mass fraction：
1000~1500 parts of isoprene rubber, 1000~1300 parts of medium density polyethylene resin, 1000~1500 parts of butyl acetate, cyclopentadienyl
800~1200 parts of metal linear low density polyethylene (LDPE), 1200~1800 parts of nano-sized carbon, 35~50 parts of ultraviolet-resistant absorbent, PVC
10~20 parts of resin, 50~80 parts of polysiloxane, 60~90 parts of dipentaerythritol, 30~60 parts of polyurethane.
7. the production method of corrosion-resistant antiultraviolet composite material according to claim 5, which is characterized in that in step 2),
Each raw material is sent into high-speed kneading machine, 6-15min is mediated at 110-150 DEG C.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810346883.XA CN108546354A (en) | 2018-04-18 | 2018-04-18 | A kind of corrosion-resistant antiultraviolet composite material and preparation method |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810346883.XA CN108546354A (en) | 2018-04-18 | 2018-04-18 | A kind of corrosion-resistant antiultraviolet composite material and preparation method |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117247701A (en) * | 2023-04-04 | 2023-12-19 | 广州思奇高分子材料技术有限公司 | UV-resistant silica gel paste and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104927178A (en) * | 2015-06-15 | 2015-09-23 | 安徽顺驰电缆有限公司 | Anti-abrasion ultraviolet-resistant polyethylene cable material |
| CN107043480A (en) * | 2016-11-18 | 2017-08-15 | 安徽伊法拉电气有限公司 | Capacitor insulation shield material and preparation method thereof |
| CN107739466A (en) * | 2017-10-30 | 2018-02-27 | 安徽嘉中金属材料有限公司 | It is a kind of to be modified compound low temperature resistant building cable jacket material and preparation method thereof |
-
2018
- 2018-04-18 CN CN201810346883.XA patent/CN108546354A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104927178A (en) * | 2015-06-15 | 2015-09-23 | 安徽顺驰电缆有限公司 | Anti-abrasion ultraviolet-resistant polyethylene cable material |
| CN107043480A (en) * | 2016-11-18 | 2017-08-15 | 安徽伊法拉电气有限公司 | Capacitor insulation shield material and preparation method thereof |
| CN107739466A (en) * | 2017-10-30 | 2018-02-27 | 安徽嘉中金属材料有限公司 | It is a kind of to be modified compound low temperature resistant building cable jacket material and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117247701A (en) * | 2023-04-04 | 2023-12-19 | 广州思奇高分子材料技术有限公司 | UV-resistant silica gel paste and preparation method thereof |
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| TA01 | Transfer of patent application right |
Effective date of registration: 20200826 Address after: 225500 Jiangsu Province, Taizhou City Industrial Zone Jiangyan Zhang Dian Zhen concentrated area Applicant after: Taizhou Huali New Material Co.,Ltd. Address before: 225500 Jiangsu Province, Taizhou City Industrial Zone Jiangyan Zhang Dian Zhen concentrated area Applicant before: JIANGSU HUAJUN NEW MATERIAL Co.,Ltd. |
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Application publication date: 20180918 |
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