CN108542046A - A kind of degradable shoe tree and its manufacture craft with starch making - Google Patents

A kind of degradable shoe tree and its manufacture craft with starch making Download PDF

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Publication number
CN108542046A
CN108542046A CN201810452115.2A CN201810452115A CN108542046A CN 108542046 A CN108542046 A CN 108542046A CN 201810452115 A CN201810452115 A CN 201810452115A CN 108542046 A CN108542046 A CN 108542046A
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CN
China
Prior art keywords
shoe tree
high speed
starch
degradable
raw material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810452115.2A
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Chinese (zh)
Inventor
魏宝坤
刘德深
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yongjia Yuheng Biotechnology Research Institute Co Ltd
Original Assignee
Yongjia Yuheng Biotechnology Research Institute Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yongjia Yuheng Biotechnology Research Institute Co Ltd filed Critical Yongjia Yuheng Biotechnology Research Institute Co Ltd
Priority to CN201810452115.2A priority Critical patent/CN108542046A/en
Publication of CN108542046A publication Critical patent/CN108542046A/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43DMACHINES, TOOLS, EQUIPMENT OR METHODS FOR MANUFACTURING OR REPAIRING FOOTWEAR
    • A43D3/00Lasts
    • A43D3/14Stretching or spreading lasts; Boot-trees; Fillers; Devices for maintaining the shape of the shoe
    • A43D3/1433Shoe-trees
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21JFIBREBOARD; MANUFACTURE OF ARTICLES FROM CELLULOSIC FIBROUS SUSPENSIONS OR FROM PAPIER-MACHE
    • D21J3/00Manufacture of articles by pressing wet fibre pulp, or papier-mâché, between moulds

Abstract

The present invention relates to a kind of shoe tree manufacture craft, more particularly to a kind of degradable shoe tree made of starch and its manufacture craft;Its raw material includes by mass fraction:Modified starch:22-26, stalk fibre:18-22, paperboard fibres:4-5.5, bentonite:8-14, talcum powder:3-4, above-mentioned raw materials are pressed into process ratio and feeding sequence, it is sequentially placed into high speed mixing smelting machine, high speed rotation 20 minutes, so that material is uniformly mixed and to play the role of curing-crosslinked, then after the raw material being kneaded is claimed through quantitative point, input moulding mould special, finished product shoe tree is obtained through compression molding, the object of the present invention is to provide a kind of fully biodegradable, the degradable shoe tree free from environmental pollution made of starch and its manufacture crafts.

Description

A kind of degradable shoe tree and its manufacture craft with starch making
Technical field
The present invention relates to a kind of shoe tree manufacture craft, more particularly to a kind of degradable shoe tree made of starch and its making Technique.
Background technology
Shoes manufacturing enterprise of the country is numerous at present, in the leather shoes technological process of production, needs a kind of to cry the production of shoe tree mating system Product protect leather shoes shape to ensure the accurate shape of leather shoes and the resistance to compression in transport-storage process and impact.
The shoe tree used now is entirely to be made of polyphenyl expanded material or polyurethane foam material.Due to polyphenyl materials and Polyurethane material is plastic products, be a kind of light, non-degradable, volume it is big, without recycling the waste plastic of value " in vain Color pollution sources ".Since footwear product is a kind of staple commodities of whole people's consumption, enormous amount, therefore plastic foamed shoe tree product Caused by " white pollution " can not be ignored.
The shoe tree made through special process by biological material starch that this patent is invented, have it is solid, beautiful, can be complete Complete biodegradable, feature free from environmental pollution are a kind of novel substituted for plastic shoe tree upgraded products, have good ring Border friendly and practicability.
Invention content
In order to overcome the shortcomings of background technology, the object of the present invention is to provide a kind of fully biodegradables, not dirty Contaminate the degradable shoe tree made of starch and its manufacture craft of environment.
The technical solution adopted in the present invention is:A kind of degradable shoe tree made of starch, raw material press mass fraction Including:
Modified starch:22—26
Stalk fibre:18—22
Paperboard fibres:4—5.5
Bentonite:8—14
Talcum powder:3—4
The above-mentioned degradable shoe tree manufacture craft made of starch, using following steps:
1)Biological material in claim 1 is pressed into process ratio and feeding sequence, is sequentially placed into high speed in high speed mixing smelting machine Rotation is kneaded, and high speed mixing smelting machine rotating speed is adjusted to 60 revs/min, batch mixing 5 minutes;
2)Rotating speed after five minutes, is adjusted to 400-800 revs/min by high speed mixing smelting machine batch mixing in step 1, temperature be adjusted to 120 DEG C- 160 DEG C, the cellulose solution that concentration 5% is tuned into paste, high speed rotation 15-20 minutes is added;
3)By in step 2 in kneading machine material and the abundant melting mixing of cellulose solution at homogeneous bulk raw material, and Material can discharge when being in curing state;
4)Material in step 3 is cooled down by cooler;
5)Bulk raw material after cooling in step 4 is weighed up into the material block of constant weight by product size, puts into molding die, warp Compression molding;
6) deburring deburring is carried out to the shoe tree of compression molding in step 5, obtains finished product shoe tree.
Preferably, the feeding sequence in step 1 is starch → bentonite → talcum powder → paperboard fibres → stalk fibre.
Preferably, the rotating speed of step 2 high speed kneading machine is 500 revs/min.
Preferably, in step 2 in temperature be 120 DEG C.
Preferably, the step 2 high speed kneading machine high speed rotation time is 15 minutes.
The beneficial effects of the invention are as follows:1, biomass(Starch)Material has Natural Degradation advantage, through Special moulding process skill Degradable shoe tree made of art is the upgraded product of plastic foamed product, has natural environment-friendly advantage and raw material advantage; 2, stablize, application technology maturation;3, solid, performance is excellent, and degradation is reliable, of low cost.
Specific implementation mode
The present invention provides a kind of degradable shoe tree made of starch, and raw material includes by mass fraction:
Modified starch:22—26
Stalk fibre:18—22
Paperboard fibres:4—5.5
Bentonite:8—14
Talcum powder:3—4
The above-mentioned degradable shoe tree manufacture craft made of starch, using following steps:
1)Biological material in claim 1 is pressed into process ratio and feeding sequence, is sequentially placed into high speed in high speed mixing smelting machine Rotation is kneaded, and high speed mixing smelting machine rotating speed is adjusted to 60 revs/min, batch mixing 5 minutes;
2)Rotating speed after five minutes, is adjusted to 400-800 revs/min by high speed mixing smelting machine batch mixing in step 1, temperature be adjusted to 120 DEG C- 160 DEG C, the cellulose solution that concentration 5% is tuned into paste, high speed rotation 15-20 minutes is added;
3)By in step 2 in kneading machine material and the abundant melting mixing of cellulose solution at homogeneous bulk raw material, and Material can discharge when being in curing state;
4)Material in step 3 is cooled down by cooler;
5)Bulk raw material after cooling in step 4 is weighed up into the material block of constant weight by product size, puts into molding die, warp Compression molding;
6) deburring deburring is carried out to the shoe tree of compression molding in step 5, obtains finished product shoe tree.
Wherein, the feeding sequence in step 1 is starch → bentonite → talcum powder → paperboard fibres → stalk fibre.
The rotating speed of step 2 high speed kneading machine is 500 revs/min.
Temperature in step 2 is 120 DEG C.
The step 2 high speed kneading machine high speed rotation time is 15 minutes.
In said program, it is kneaded by high speed using modified starch, stalk fibre, paperboard fibres, bentonite and talcum powder It is made shoe tree after machine mixing, for more traditional shoe tree, material is changed, main to be sent out instead of traditional plastics with starch Brewage has preferable degradation effect, environmental protection, and simple process and low cost is honest and clean, is suitble to widely popularize.
With reference to five groups of embodiments, the invention will be further described:
Embodiment 1:
A kind of degradable shoe tree made of starch, raw material include by mass fraction:
Modified starch:22, stalk fibre:18, paperboard fibres:4, bentonite:8, talcum powder:3
According to the above ratio and feeding sequence by raw material, it is sequentially placed into high speed rotation in high speed mixing smelting machine to be kneaded, high speed mixing smelting machine turns Velocity modulation is to 60 revs/min, batch mixing 5 minutes;Feeding sequence is:Starch → bentonite → talcum powder → paperboard fibres → stalk fibre, Batch mixing is adjusted to 500 revs/min after five minutes, by rotating speed, and temperature is adjusted to 120 DEG C, and the cellulose solution that concentration 5% is tuned into paste is added, High speed rotation 15 minutes;Quality forms uniform bulk raw material after raw material in high speed mixing smelting machine fully melts, and material is in ripe When change state, the taking-up of bulk raw material is cooled down, after complete cooling, raw material is pressed into product size, weighs up constant weight Expect block, put into molding die, forms shoe tree through compression molding, deburring deburring then is carried out to the shoe tree of compression molding, is obtained To finished product shoe tree.
Embodiment 2:
A kind of degradable shoe tree made of starch, raw material include by mass fraction:
Modified starch:26, stalk fibre:22, paperboard fibres:5.5, bentonite:14, talcum powder:4
According to the above ratio and feeding sequence by raw material, it is sequentially placed into high speed rotation in high speed mixing smelting machine to be kneaded, high speed mixing smelting machine turns Velocity modulation is to 60 revs/min, batch mixing 5 minutes;Feeding sequence is:Starch → bentonite → talcum powder → paperboard fibres → stalk fibre, Batch mixing is adjusted to 500 revs/min after five minutes, by rotating speed, and temperature is adjusted to 120 DEG C, and the cellulose solution that concentration 5% is tuned into paste is added, High speed rotation 15 minutes;Quality forms uniform bulk raw material after raw material in high speed mixing smelting machine fully melts, and material is in ripe When change state, the taking-up of bulk raw material is cooled down, after complete cooling, raw material is pressed into product size, weighs up constant weight Expect block, put into molding die, forms shoe tree through compression molding, deburring deburring then is carried out to the shoe tree of compression molding, is obtained To finished product shoe tree.
Embodiment 3:
A kind of degradable shoe tree made of starch, raw material include by mass fraction:
Modified starch:22, stalk fibre:18, paperboard fibres:5.5, bentonite:9, talcum powder:4
According to the above ratio and feeding sequence by raw material, it is sequentially placed into high speed rotation in high speed mixing smelting machine to be kneaded, high speed mixing smelting machine turns Velocity modulation is to 60 revs/min, batch mixing 5 minutes;Feeding sequence is:Starch → bentonite → talcum powder → paperboard fibres → stalk fibre, Batch mixing is adjusted to 500 revs/min after five minutes, by rotating speed, and temperature is adjusted to 120 DEG C, and the cellulose solution that concentration 5% is tuned into paste is added, High speed rotation 15 minutes;Quality forms uniform bulk raw material after raw material in high speed mixing smelting machine fully melts, and material is in ripe When change state, the taking-up of bulk raw material is cooled down, after complete cooling, raw material is pressed into product size, weighs up constant weight Expect block, put into molding die, forms shoe tree through compression molding, deburring deburring then is carried out to the shoe tree of compression molding, is obtained To finished product shoe tree.
Embodiment 4:
A kind of degradable shoe tree made of starch, raw material include by mass fraction:
Modified starch:24, stalk fibre:20, paperboard fibres:4.5, bentonite:12, talcum powder:3.5
According to the above ratio and feeding sequence by raw material, it is sequentially placed into high speed rotation in high speed mixing smelting machine to be kneaded, high speed mixing smelting machine turns Velocity modulation is to 60 revs/min, batch mixing 5 minutes;Feeding sequence is:Starch → bentonite → talcum powder → paperboard fibres → stalk fibre, Batch mixing is adjusted to 500 revs/min after five minutes, by rotating speed, and temperature is adjusted to 120 DEG C, and the cellulose solution that concentration 5% is tuned into paste is added, High speed rotation 15 minutes;Quality forms uniform bulk raw material after raw material in high speed mixing smelting machine fully melts, and material is in ripe When change state, the taking-up of bulk raw material is cooled down, after complete cooling, raw material is pressed into product size, weighs up constant weight Expect block, put into molding die, forms shoe tree through compression molding, deburring deburring then is carried out to the shoe tree of compression molding, is obtained To finished product shoe tree.
Embodiment 5:
A kind of degradable shoe tree made of starch, raw material include by mass fraction:
Modified starch:25, stalk fibre:19, paperboard fibres:5, bentonite:10, talcum powder:3
According to the above ratio and feeding sequence by raw material, it is sequentially placed into high speed rotation in high speed mixing smelting machine to be kneaded, high speed mixing smelting machine turns Velocity modulation is to 60 revs/min, batch mixing 5 minutes;Feeding sequence is:Starch → bentonite → talcum powder → paperboard fibres → stalk fibre, Batch mixing is adjusted to 500 revs/min after five minutes, by rotating speed, and temperature is adjusted to 120 DEG C, and the cellulose solution that concentration 5% is tuned into paste is added, High speed rotation 15 minutes;Quality forms uniform bulk raw material after raw material in high speed mixing smelting machine fully melts, and material is in ripe When change state, the taking-up of bulk raw material is cooled down, after complete cooling, raw material is pressed into product size, weighs up constant weight Expect block, put into molding die, forms shoe tree through compression molding, deburring deburring then is carried out to the shoe tree of compression molding, is obtained To finished product shoe tree.
Embodiment 1~5 is formulated and material property is shown in Table 1:
Composition Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5
Modified starch 22 26 22 24 25
Stalk fibre 18 22 18 20 19
Paperboard fibres 4 5.5 5.5 4.5 5
Bentonite 8 14 9 12 10
Talcum powder 3 4 4 3.5 3
Tensile strength/MPa 0.40 0.50 0.41 0.43 0.48
Tensile modulus of elasticity/MPa 285.5 288.8 287.8 232.6 302.8
Yield load/N 1080 1043 1025 1050 1086
Poisson's ratio 0.0024 0.0026 0.0025 0.0022 0.0023

Claims (6)

1. a kind of degradable shoe tree made of starch, which is characterized in that its raw material includes by mass fraction:
1. modified starch:22—26
2. stalk fibre:18—22
3. paperboard fibres:4—5.5
4. bentonite:8—14
5. talcum powder:3—4.
2. a kind of degradable shoe tree manufacture craft according to claim 1 made of starch, it is characterised in that:Use with Lower step:
1) biological material in claim 1 is pressed into process ratio and feeding sequence, is sequentially placed into high speed in high speed mixing smelting machine Rotation is kneaded, and high speed mixing smelting machine rotating speed is adjusted to 60 revs/min, batch mixing 5 minutes;
2) rotating speed after five minutes, is adjusted to 400-800 revs/min, temperature is adjusted to 120 DEG C -160 by high speed mixing smelting machine batch mixing in step 1 DEG C, the cellulose solution that concentration 5% is tuned into paste, high speed rotation 15-20 minutes is added;
3) by step 2 in kneading machine material and the abundant melting mixing of cellulose solution at homogeneous bulk raw material, and Material can discharge when being in curing state;
4) material in step 3 is cooled down by cooler;
5) bulk raw material after cooling in step 4 is weighed up into the material block of constant weight by product size, puts into molding die, warp Compression molding;
6) deburring deburring is carried out to the shoe tree of compression molding in step 5, obtains finished product shoe tree.
3. a kind of degradable shoe tree manufacture craft made of starch according to claim 2, it is characterised in that:Step 1 In feeding sequence be starch → bentonite → talcum powder → paperboard fibres → stalk fibre.
4. a kind of degradable shoe tree manufacture craft made of starch according to claim 2, it is characterised in that:Step 2 The rotating speed of high speed kneading machine is 500 revs/min.
5. a kind of degradable shoe tree manufacture craft made of starch according to claim 2, it is characterised in that:Step 2 In in temperature be 120 DEG C.
6. a kind of degradable shoe tree manufacture craft made of starch according to claim 2, it is characterised in that:Step 2 The high speed kneading machine high speed rotation time is 15 minutes.
CN201810452115.2A 2018-05-12 2018-05-12 A kind of degradable shoe tree and its manufacture craft with starch making Pending CN108542046A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810452115.2A CN108542046A (en) 2018-05-12 2018-05-12 A kind of degradable shoe tree and its manufacture craft with starch making

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810452115.2A CN108542046A (en) 2018-05-12 2018-05-12 A kind of degradable shoe tree and its manufacture craft with starch making

Publications (1)

Publication Number Publication Date
CN108542046A true CN108542046A (en) 2018-09-18

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113331538A (en) * 2021-06-04 2021-09-03 广州市宏晓包装制品有限公司 Environment-friendly paper shoe stretcher and preparation method of material thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1263906A (en) * 2000-03-07 2000-08-23 苏笑海 Process for preparing full-degradable internal packing pad of plant starch for household electric appliances
CN2471157Y (en) * 2001-04-24 2002-01-16 福州开发区泛顺贸易有限公司 Environment protecting internal linings of shoes
CN1357564A (en) * 2001-12-30 2002-07-10 北京中宣绿环科技发展有限公司 Superfine stuffing for plastic and its application
CN103819919A (en) * 2012-11-16 2014-05-28 无锡市黄盛包装制品有限公司 Preparation method of degradable foam packing material
KR101968686B1 (en) * 2016-07-08 2019-04-12 건국대학교 산학협력단 Manufacturing methods of antibiotic shoes insole using bioplastic and antibiotic shoes manufactured by them

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1263906A (en) * 2000-03-07 2000-08-23 苏笑海 Process for preparing full-degradable internal packing pad of plant starch for household electric appliances
CN2471157Y (en) * 2001-04-24 2002-01-16 福州开发区泛顺贸易有限公司 Environment protecting internal linings of shoes
CN1357564A (en) * 2001-12-30 2002-07-10 北京中宣绿环科技发展有限公司 Superfine stuffing for plastic and its application
CN103819919A (en) * 2012-11-16 2014-05-28 无锡市黄盛包装制品有限公司 Preparation method of degradable foam packing material
KR101968686B1 (en) * 2016-07-08 2019-04-12 건국대학교 산학협력단 Manufacturing methods of antibiotic shoes insole using bioplastic and antibiotic shoes manufactured by them

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113331538A (en) * 2021-06-04 2021-09-03 广州市宏晓包装制品有限公司 Environment-friendly paper shoe stretcher and preparation method of material thereof
CN113331538B (en) * 2021-06-04 2022-08-09 广州市宏晓包装制品有限公司 Environment-friendly paper shoe stretcher

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Application publication date: 20180918