CN108534222A - A kind of molten salt energy-storage heating system with fused salt static mixer - Google Patents

A kind of molten salt energy-storage heating system with fused salt static mixer Download PDF

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Publication number
CN108534222A
CN108534222A CN201810566791.2A CN201810566791A CN108534222A CN 108534222 A CN108534222 A CN 108534222A CN 201810566791 A CN201810566791 A CN 201810566791A CN 108534222 A CN108534222 A CN 108534222A
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salt
temperature
molten salt
low
pump
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CN108534222B (en
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刘斌
薛凌云
王志伟
赵峥峥
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Barry (tianjin) New Energy Co Ltd
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Barry (tianjin) New Energy Co Ltd
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24DDOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
    • F24D15/00Other domestic- or space-heating systems
    • F24D15/02Other domestic- or space-heating systems consisting of self-contained heating units, e.g. storage heaters
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24DDOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
    • F24D19/00Details
    • F24D19/10Arrangement or mounting of control or safety devices

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Other Air-Conditioning Systems (AREA)

Abstract

The present invention is a kind of molten salt energy-storage heating system with fused salt static mixer, which includes low-temperature molten salt tank, low-temperature molten salt pump, fused salt electric heater, high temperature melting salt cellar, high-temperature melting salt pump, mixed salt pump for liquid salts, static mixer, feed pump, oxygen-eliminating device, water circulating pump, preheater, evaporator and heat user;The high temperature melting salt cellar is connected by an entrance of high-temperature melting salt pump and corresponding fused salt pipeline and static mixer, low-temperature molten salt tank is connected by mixed salt pump for liquid salts and another entrance of corresponding fused salt pipeline and static mixer, and the one outlet of the low-temperature molten salt tank is pumped by low-temperature molten salt to be entered after the heating of fused salt electric heater in high-temperature molten salt tank;The fused salt entrance of the outlet connection evaporator of the static mixer.The heating system can make heat exchanger temperature difference between the two ends reduce by 100 DEG C or so by adding a set of fused salt static mixer, significantly reduce heat exchanger difficulty and manufacturing cost, make that it is suitable for the big temperature difference heat transfer process in power generation molten salt energy storage system.

Description

A kind of molten salt energy-storage heating system with fused salt static mixer
Technical field
The present invention relates to molten salt energy-storage heat supply process field, especially a kind of molten salt energy-storage with fused salt static mixer Heating system.
Background technology
With the development of social economy, the demand to heat supply constantly rises, and coal-fired consumption is also increasing, draws in face of fire coal The a series of environmental problems of hair, for energy storage technology increasingly by each very big concern with hot industry, " coal changes electricity " energy storage technology is suitable Policy requirements are answered to come into being.Energy-accumulating mediums of the Molten Binary Salts Solar Salt as photo-thermal power generation, it is ripe to be applied to state In outer photo-thermal power station energy-storage system.Fused salt has the temperature difference big, and thermal capacitance is high, it is environmental-friendly pollution-free the features such as, be fabulous middle height Intermediate temperature regenerator material.
Since the higher fusing point such as Molten Binary Salts Solar Salt of the fusing point of fused salt is 220 DEG C, to maximally utilise The operating temperature of the energy storage warm area of fused salt, general high-temperature molten salt is all higher (400 DEG C of >), and in molten salt energy-storage heating system, The temperature parameter that heat user requires is often 180-200 DEG C of high-temperature-hot-water or steam, leads to fused salt/water (steam) heat exchanger Temperature difference between the two ends are excessive, about 200 DEG C or so of maximum temperature difference, but in Practical Project, heat exchanger media of both sides excessive temperature differentials, heat exchanger The temperature stress born is bigger, and heat exchanger is also just more difficult to manufacture, and cost is higher, is unfavorable for the popularization of energy storage heating system and makes With.
Invention content
In view of the above problems, the fused salt storage with fused salt static mixer that it is an object of the present invention to provide a kind of Energy heating system, the heating system is big for heat exchanger heat transfer temperature difference in high-temperature molten salt energy storage heating system, heat exchange is difficult, exchanges heat The big problem of device manufacture difficulty is improved existing system, can make heat exchanger both ends by adding a set of fused salt static mixer The temperature difference reduces by 100 DEG C or so, significantly reduces heat exchanger difficulty and manufacturing cost, makes that it is suitable in power generation molten salt energy storage system Big temperature difference heat transfer process.
The technical scheme is that:A kind of molten salt energy-storage heating system with fused salt static mixer, feature exist In the system include low-temperature molten salt tank, low-temperature molten salt pump, fused salt electric heater, high temperature melting salt cellar, high-temperature melting salt pump, mixed salt fused salt Pump, static mixer, feed pump, oxygen-eliminating device, water circulating pump, preheater, evaporator and heat user;
The high temperature melting salt cellar is connected by an entrance of high-temperature melting salt pump and corresponding fused salt pipeline and static mixer It connects, low-temperature molten salt tank is connected by mixed salt pump for liquid salts and another entrance of corresponding fused salt pipeline and static mixer, described low The one outlet of temperature molten salt tank is pumped by low-temperature molten salt to be entered after the heating of fused salt electric heater in high-temperature molten salt tank;The static state The fused salt entrance of the outlet connection evaporator of mixer, the fused salt outlet connection low-temperature molten salt tank of evaporator, the thermal technology of evaporator Three branches are drawn in matter outlet, and first branch be directly connected to heat user, are judged whether there is with hot mode according to heat user cold Condensate recycles, and if any condensing hot air furnace, then condensed water is pumped by feed pump in oxygen-eliminating device;
Article 2 branch connects a side-entrance of preheater, and a side outlet of preheater connects oxygen-eliminating device, and oxygen-eliminating device goes out Mouth connects another side-entrance of preheater by water circulating pump;
Article 3 branch is directly connected to oxygen-eliminating device;
Another side outlet of the preheater connects the hot working fluid import of the evaporator.
The beneficial effects of the invention are as follows:
The present invention carries the molten salt energy-storage heating system of static mixer, and static mixer is applied in energy supply heat accumulation field To reduce heat storage medium temperature, temperature is obtained less than height after the advanced row of height temperature molten salt being mixed by the effect of static mixer The middle temperature molten salt of temperature molten salt, then exchange heat with evaporator, and then substantially reduce the heat transfer temperature difference at evaporator both ends.Whole system It is simple in structure, easy to operate, control it is simple, at low cost, be very suitable for commercial introduction application, have huge economic benefit.
Description of the drawings
Fig. 1 is the structural schematic diagram of molten salt energy-storage heating system of the present invention with fused salt static mixer;
In figure, 1 low-temperature molten salt tank, 2 low-temperature molten salts pump, 3 fused salt electric heaters, 4 high temperature melting salt cellars, 5 high-temperature melting salt pumps, 6 Mixed salt pump for liquid salts, 7 static mixers, 8 feed pumps, 9 oxygen-eliminating devices, 10 water circulating pumps, 11 preheaters, 12 evaporators, 13 heat are used Family.
Specific implementation mode
The present invention is explained further with reference to embodiment and attached drawing, but not in this, as to the application protection domain It limits.
The present invention a kind of molten salt energy-storage heating system (abbreviation system or heating system, ginseng with fused salt static mixer See Fig. 1) include low-temperature molten salt tank 1, low-temperature molten salt pump 2, fused salt electric heater 3, high temperature melting salt cellar 4, high-temperature melting salt pump 5, mixed salt Pump for liquid salts 6, static mixer 7, feed pump 8, oxygen-eliminating device 9, water circulating pump 10, preheater 11, evaporator 12 and heat user 13;
The high temperature melting salt cellar 4 passes through high-temperature melting salt pump 5 and an entrance of corresponding fused salt pipeline and static mixer 7 Connection, low-temperature molten salt tank 1 are connected by mixed salt pump for liquid salts 6 and another entrance of corresponding fused salt pipeline and static mixer, institute The one outlet for stating low-temperature molten salt tank is entered after the heating of fused salt electric heater 3 in high-temperature molten salt tank 4 by low-temperature molten salt pump 2; The fused salt entrance of the outlet connection evaporator 12 of the static mixer 7, the fused salt outlet connection low-temperature molten salt tank of evaporator 12 1, three branches are drawn in the hot working fluid outlet of evaporator, and first branch is directly connected to heat user 13, according to heat user heat Mode judges whether there is condensing hot air furnace, and if any condensing hot air furnace, then condensed water is pumped by feed pump 8 in oxygen-eliminating device 9, is carried out down One cycle;
Article 2 branch connects a side-entrance of preheater 11, and a side outlet of preheater 11 connects oxygen-eliminating device 9, deoxygenation The outlet of device 9 connects another side-entrance of preheater 11 by water circulating pump 10;Hot working fluid in evaporator out is as heat source The condensed water from oxygen-eliminating device 9 is heated to 180 DEG C, oxygen-eliminating device 9 is then returned to after steam cooling;
Article 3 branch is directly connected to oxygen-eliminating device 9, and the hot working fluid come out in evaporator removes water supply as heat source and is pumped into Water supply (condensed water) in oxygen, and the water supply (condensed water) in oxygen-eliminating device 9 is heated to 104 DEG C;
Another side outlet of the preheater connects the hot working fluid import of the evaporator.
Heretofore described heat user is not limited only to industrial steam user, can also be the heat source of secondary heating net, And its temperature can be adjusted according to user demand.
The course of work of molten salt energy-storage heating system of the present invention with fused salt static mixer be:
The night dip electricity period, (operating temperature of low-temperature molten salt is set as the low-temperature molten salt being placed in low-temperature molten salt tank 1 190 DEG C) heating is pumped into fused salt electric heater 3 by low-temperature molten salt pump 2 becomes high-temperature molten salt (operating temperature of high-temperature molten salt is set It is set to 405 DEG C), and be stored in high temperature melting salt cellar 4, complete fused salt heat-accumulating process;
When end heat user 13 needs heat, high-temperature melting salt pump 5, mixed salt pump for liquid salts 6 are respectively by high-temperature molten salt and low temperature Fused salt is pumped into static mixer 7 mixes simultaneously, work temperature of the mixed temperature of molten salt between high-temperature molten salt and low-temperature molten salt (for 300 DEG C) between degree, after evaporator 12, temperature of molten salt returns after being reduced to 190 DEG C in low-temperature molten salt tank 1.
The present embodiment heat user is only by taking 185 DEG C of saturated vapor as an example.It is flowed through through feed pump 8 with the system water supply of hot side Enter evaporator 12 after oxygen-eliminating device 9, water circulating pump 10, preheater 11, is changed with 300 DEG C of fused salt mixts from static mixer 7 Heat, (185 DEG C of saturated vapor is come out from evaporator 12 to the saturated vapor of 185 DEG C of generation after heat exchange, and whole flow process is:104 DEG C water supply through water circulating pump 10 enter preheater 11,180 DEG C are heated at preheater 11, later 180 DEG C of saturated water Into evaporator 12, become 185 DEG C of saturated vapor through the heating of evaporator 12.), it is detached through evaporator 12, hot steam point three Branch flows out, and first branch steam is routed directly to heat user, which can be industrial steam user, according to heat user Judge whether there is condensing hot air furnace with hot mode, if any condensing hot air furnace, then condensed water is pumped into system by feed pump 8, carries out down One cycle;Article 2 branch steam enters preheater 11, heats the condensed water from oxygen-eliminating device 9 to 180 DEG C as heat source, steam Oxygen-eliminating device 9 is then returned to after cooling;Article 3 branch steam is directly entered oxygen-eliminating device 9, is removed in water supply (condensed water) as heat source Oxygen, and the water supply (condensed water) in oxygen-eliminating device 9 is heated to 104 DEG C.The purpose for adding oxygen-eliminating device be in order to system to The steam condensate (SC) deoxygenation and heating of water, preheater 11, because easily generating corrosion to equipment if oxygen is more in water;By oxygen-eliminating device Operating pressure limits, and oxygen-eliminating device outlet temperature is generally 104 DEG C, to prevent from causing to melt into the feed temperature of evaporator 12 is too low Salt frozen block need to be pumped into preheater 11 through water circulating pump 10 in evaporator, from the system water supply of oxygen-eliminating device out and be again heated to 180 DEG C, into evaporator heat exchange, the purpose for adding preheater here is mainly heating system water supply, promotes feed temperature, because Fused salt has solidification point, and if feed temperature is too low, fused salt is just easy to be set in evaporator, causes system frozen block, institute To have to promote feed temperature, feed temperature is made to be on fused salt solidification point, ensure that fused salt does not solidify, ensures system safety Operation.
Molten salt energy-storage heating system of the present invention with fused salt static mixer can effectively improve the temperature in use of fused salt, On the basis of identical amount of stored heat Q, such as in the energy storage heating system of not static mixer, the temperature of energy storage high-temperature molten salt is 300 DEG C, the low-temperature molten salt temperature after heat exchange is 190 DEG C, and the energy storage temperature difference is 110 DEG C, according to heat balance formula
Q=cm Δs t
Under conditions of not considering fused salt allowance and heat exchange efficiency, calculating energy storage molten salt dosage is Q/ (c*110).It adds quiet After state mixer, the temperature in use of energy storage high-temperature molten salt is up to 405 DEG C, and the low-temperature molten salt temperature after heat exchange is 190 DEG C, energy storage temperature Difference is 215 DEG C, and can be calculated energy storage molten salt dosage according to heat balance formula is Q/ (c*215), and dosage is not added only quiet The 51.2% of state mixer fused salt dosage.It can be seen that the molten salt energy-storage heating system for adding static mixer significantly reduces The usage amount of fused salt reduces energy storage device volume, saves system footprint area, and the flow of pump for liquid salts accordingly reduces, and significantly reduces Pump power consumption.
The energy storage molten salt used in the above process is low melting point fused salt, and fusing point is 115 DEG C, to ensure it in heat transfer process In do not solidify, the low-temperature molten salt temperature after evaporator heat exchange is set as 190 DEG C, the upper limit temperature in use of this low melting point energy storage molten salt Take higher than 405 DEG C, but to reduce storage tank manufacture material, it is 405 DEG C that the temperature of heat accumulation high-temperature molten salt is taken in this system.
The temperature in use of energy storage high-temperature molten salt can also further increase in the present invention, can be to high temperature when temperature improves again The material of fused salt tank requires stringenter, high temperature melting salt cellar made of the application selection carbon steel, the use of storage high-temperature molten salt Temperature upper limit is 405 DEG C, if laying particular emphasis on the dosage for reducing high-temperature molten salt or increasing its energy storage capacity, can select other resistance to height High temperature melting salt cellar made of warm material, fused salt dosage is less, equipment volume smaller.
Molten salt energy-storage heating system of the present invention with fused salt static mixer only need to add in system structure one it is mixed The process that high temperature energy-storage can be realized in salt pump and corresponding fused salt pipeline, valve, low temperature mixed salt exchanges heat, whole system structure letter It is single, easy to operate, control it is simple, at low cost, be very suitable for commercial introduction application.
The present invention does not address place and is suitable for the prior art.

Claims (3)

1. a kind of molten salt energy-storage heating system with fused salt static mixer, it is characterised in that the system includes low-temperature molten salt Tank, low-temperature molten salt pump, fused salt electric heater, high temperature melting salt cellar, high-temperature melting salt pump, mixed salt pump for liquid salts, static mixer, water supply Pump, oxygen-eliminating device, water circulating pump, preheater, evaporator and heat user;
The high temperature melting salt cellar is connected by an entrance of high-temperature melting salt pump and corresponding fused salt pipeline and static mixer, low Temperature molten salt tank is connected by mixed salt pump for liquid salts and another entrance of corresponding fused salt pipeline and static mixer, the low-temperature molten salt The one outlet of tank is pumped by low-temperature molten salt to be entered after the heating of fused salt electric heater in high-temperature molten salt tank;The static mixer Outlet connection evaporator fused salt entrance, evaporator fused salt outlet connection low-temperature molten salt tank, evaporator hot working fluid outlet Three branches are drawn, first branch is directly connected to heat user, and judging whether there is condensed water with hot mode according to heat user returns It receives, if any condensing hot air furnace, then condensed water is pumped by feed pump in oxygen-eliminating device;
Article 2 branch connects a side-entrance of preheater, and a side outlet of preheater connects oxygen-eliminating device, and the outlet of oxygen-eliminating device is logical Cross another side-entrance of water circulating pump connection preheater;
Article 3 branch is directly connected to oxygen-eliminating device;
Another side outlet of the preheater connects the hot working fluid import of the evaporator.
2. the molten salt energy-storage heating system according to claim 1 with fused salt static mixer, it is characterised in that described Heat user be industrial steam user or it is secondary heating net heat source.
3. the molten salt energy-storage heating system according to claim 1 with fused salt static mixer, it is characterised in that the confession The course of work of hot systems is:
It the night dip electricity period, is placed in the low-temperature molten salt in low-temperature molten salt tank and is pumped into fused salt electric heater by low-temperature molten salt Heating becomes high-temperature molten salt, and is stored in high temperature melting salt cellar, completes fused salt heat-accumulating process;
When end, heat user needs heat, high-temperature melting salt pump, mixed salt pump for liquid salts respectively by high-temperature molten salt and low-temperature molten salt simultaneously It is pumped into static mixer and mixes, mixed temperature of molten salt is between high-temperature molten salt and the operating temperature of low-temperature molten salt, warp After pervaporation device, temperature of molten salt returns after being reduced to the initial temperature of low-temperature molten salt in low-temperature molten salt tank.
CN201810566791.2A 2018-06-05 2018-06-05 Molten salt energy storage and heat supply system with molten salt static mixer Active CN108534222B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109539215A (en) * 2018-11-16 2019-03-29 深圳市爱能森储能技术创新有限公司 A kind of energy storage device and peak regulating method for peak regulation of power plant
CN114484903A (en) * 2021-12-28 2022-05-13 青海中控太阳能发电有限公司 Photovoltaic photo-thermal sharing energy storage device and use method thereof
WO2024187555A1 (en) * 2023-03-13 2024-09-19 西安热工研究院有限公司 Resistance-type molten salt heater capable of avoiding overtemperature risk, and use method therefor

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CN204042829U (en) * 2014-08-12 2014-12-24 淮南中科储能科技有限公司 High-temperature molten salt steam generation and pre-heating system
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CN107013892A (en) * 2017-05-17 2017-08-04 杭州锅炉集团股份有限公司 A kind of combustion engine waste heat boiler device with fused salt heat accumulation
KR20170092811A (en) * 2016-02-04 2017-08-14 한국기계연구원 Heat exchanger of molten salt
CN206929835U (en) * 2017-06-26 2018-01-26 北京华业阳光新能源有限公司 Adjustable fused salt heat reservoir
CN208382321U (en) * 2018-06-05 2019-01-15 百吉瑞(天津)新能源有限公司 A kind of molten salt energy-storage heating system with fused salt static mixer

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN204042829U (en) * 2014-08-12 2014-12-24 淮南中科储能科技有限公司 High-temperature molten salt steam generation and pre-heating system
CN204187709U (en) * 2014-11-04 2015-03-04 哈尔滨汽轮机厂有限责任公司 A kind of thermal storage heating system
KR20170092811A (en) * 2016-02-04 2017-08-14 한국기계연구원 Heat exchanger of molten salt
CN107013892A (en) * 2017-05-17 2017-08-04 杭州锅炉集团股份有限公司 A kind of combustion engine waste heat boiler device with fused salt heat accumulation
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CN208382321U (en) * 2018-06-05 2019-01-15 百吉瑞(天津)新能源有限公司 A kind of molten salt energy-storage heating system with fused salt static mixer

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109539215A (en) * 2018-11-16 2019-03-29 深圳市爱能森储能技术创新有限公司 A kind of energy storage device and peak regulating method for peak regulation of power plant
CN114484903A (en) * 2021-12-28 2022-05-13 青海中控太阳能发电有限公司 Photovoltaic photo-thermal sharing energy storage device and use method thereof
WO2024187555A1 (en) * 2023-03-13 2024-09-19 西安热工研究院有限公司 Resistance-type molten salt heater capable of avoiding overtemperature risk, and use method therefor

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