CN108531034A - A kind of wear-resistant coating of cementitious composite packaging bag - Google Patents
A kind of wear-resistant coating of cementitious composite packaging bag Download PDFInfo
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- CN108531034A CN108531034A CN201810278188.4A CN201810278188A CN108531034A CN 108531034 A CN108531034 A CN 108531034A CN 201810278188 A CN201810278188 A CN 201810278188A CN 108531034 A CN108531034 A CN 108531034A
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- resistant coating
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/062—Copolymers with monomers not covered by C09D133/06
- C09D133/066—Copolymers with monomers not covered by C09D133/06 containing -OH groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
- C09D5/031—Powdery paints characterised by particle size or shape
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
- C09D5/033—Powdery paints characterised by the additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
A kind of wear-resistant coating of cementitious composite packaging bag is related to cement package bags processing technical field, it is characterised in that：Material including following parts by weight is made, 13 20 parts of resin, 49 parts of tree ash, modified 8 14 parts of silica flour, 29 parts of lignin sulfonic acid, 14 parts of nano-titanium dioxide, 15 parts of polyethylene wax micro mist, 5 10 parts of methenamine, 13 parts of polyether Glycols, 7 14 parts of 4,4 diaminodiphenyl-methane, 15 parts of tributyl phosphate, 49 parts of polyacrylamide, 7 12 parts of anti-aging agent, 9 14 parts of biological assistant, 30 35 parts of deionized water.The method of the present invention is reasonable, easy to implement, waterproof, wear-resisting, good toughness.
Description
Technical field
The present invention relates to cement package bags to process technical field, and in particular to a kind of cementitious composite packaging bag it is wear-resisting
Coating.
Background technology
Cement:Powdery hydraulicity inorganic coagulation material.At slurry after adding water to stir, can harden in air or in water
Preferably hardening, and can the materials such as sand, stone are cemented together securely.
The mixture of early stage lime and volcanic ash and modern lime pozzolanic cement are much like, are made of its cementing rubble
Concrete, not only intensity is higher after hardening, and can also resist the erosion of fresh water or brackish water.For a long time, it is as one
The important cementitious material of kind, is widely used in the engineerings such as civil construction, water conservancy, national defence.
Ball-milling technology is applied to two production links in cement industry, and a link is identical as Thermal Power Generation Industry, is applied to mill
Coal dust processed provides fire coal for production；Another link is applied to be sintered blocking clinker and grind powdering, this link
The production efficiency and product quality of cement production enterprise are played a crucial role.
And packaging bag is very important for cement, because installation, transport etc. are required for packaging bag to operate, but
Be since the performance of present many packaging bags is all not particularly good, it is all non-watertight, also not wear-resisting, packaging is transported in this way
Defeated is all very big trouble, can waste a large amount of time to re-operate, and can be caused to damage to cement.
Invention content
Technical problem to be solved by the present invention lies in overcome existing technological deficiency provide a kind of method rationally, embodiment party
Just, waterproof, a kind of wear-resisting, good toughness wear-resistant coating of cementitious composite packaging bag.
The technical problems to be solved by the invention are realized using technical solution below：
A kind of wear-resistant coating of cementitious composite packaging bag, it is characterised in that：Material including following parts by weight is made,
13-20 parts of resin, 4-9 parts of tree ash, modified 8-14 parts of silica flour, 2-9 parts of lignin sulfonic acid, nanometer titanium dioxide
1-4 parts of titanium, 1-5 parts of polyethylene wax micro mist, 5-10 parts of methenamine, 1-3 parts of polyether Glycols, 4,4- diaminodiphenyl-methanes
7-14 parts, 1-5 parts of tributyl phosphate, 4-9 parts of polyacrylamide, 7-12 parts of anti-aging agent, 9-14 parts of biological assistant, deionized water
30-35 parts；
The resin includes in E-12 epoxy resin, organic siliconresin, Hydroxylated acrylic resin, long oil alkyd
It is a kind of；
The anti-aging agent includes one kind in anti-aging agent RD, antioxidant A, antioxidant D, anti-aging agent CPPD, antioxidant A W；
The preparation method of the modified silica flour is：By quartz grinding and 300-400 mesh sieve is crossed, three fourth of methyl is then added
Ketoximinosilanes are stirred 10min at normal temperatures, then heat to 80-85 DEG C of heat preservation grinding 30min, add water stirring and be made
Solid content reaches the solution of 25-35%, and gained mixed liquor is sent into dry in spray dryer, the spheric granules of obtained 20-40 mesh,
And it is dried at 100-110 DEG C；
The mass ratio of the methyl tributanoximo silane and silica flour is 1：4.1；
The biological assistant includes that the material of following parts by weight is made,
1 part of cow-bezoar, 2 parts of uncaria, 2 parts of tussilago, 4 parts of semen allii tuberosi, 1 part of the stem of noble dendrobium, 2 parts of radix ephedrae, 3 parts of Fructus Tritici Levis, cucurbit
Bars 4 parts, 5 parts of the fruit of Chinese wolfberry, 6 parts of the fruit of glossy privet；
Preparation method is：Above-mentioned material is placed in 90-100 DEG C of drying equipment and is tiled, is then dried 2-3 small
When, it is then placed in milling apparatus and is ground into powder；
A kind of preparation method of the wear-resistant coating of cementitious composite packaging bag includes,
I by resin, tree ash, modified silica flour, lignin sulfonic acid, nano-titanium dioxide, polyethylene wax micro mist, Wu Luo
Tropine is placed in reaction kettle and is uniformly mixed, and is warming up to 220-260 DEG C, 1~2h of insulated and stirred obtains mixture stand for standby use；
II by polyether Glycols, 4,4- diaminodiphenyl-methanes, tributyl phosphate, polyacrylamide, anti-aging agent, biology
Auxiliary agent, deionized water are added in I, and cool to 100-120 DEG C, mix to form the preferable slurry of mobility；
III, by the preferable slurry indentation three-roller of above-mentioned mobility, is ground to grain size and is less than 20 μm, tinning.
Beneficial effects of the present invention are：The coating used can apply multilayer, and can be used in mixed way with others japanning etc., this
Nine enhanced convenience of sample, and pressure-resistant, the wear-resisting performance of product is very good, can prolong the service life, and due to tool
There is certain water resistance, can ensure the drying of cement, and the also very life that is good, and using of the bond properties of product
Object auxiliary agent can not only play the effect to neutralize a toxin, additionally it is possible to increase the toughness and pressure resistance, wear-resisting performance of product, product
It can be used on a variety of basic materials, coating is with a wide range of features, and few, at low cost, the nontoxic no side reaction of material consumption, processability
Good, molding is easy.
Specific implementation mode
In order to make the technical means, the creative features, the aims and the efficiencies achieved by the present invention be easy to understand, below into
One step illustrates the present invention.
Embodiment 1
A kind of wear-resistant coating of cementitious composite packaging bag, it is characterised in that：Material including following parts by weight is made,
13 parts of resin, 4 parts of tree ash, modified 8 parts of silica flour, 2 parts of lignin sulfonic acid, 1 part of nano-titanium dioxide, poly- second
1 part of alkene wax micro mist, 5 parts of methenamine, 1 part of polyether Glycols, 7 parts of 4,4- diaminodiphenyl-methanes, 1 part of tributyl phosphate,
4 parts of polyacrylamide, 7 parts of anti-aging agent, 9 parts of biological assistant, 30 parts of deionized water；
The resin includes in E-12 epoxy resin, organic siliconresin, Hydroxylated acrylic resin, long oil alkyd
It is a kind of；
The anti-aging agent includes one kind in anti-aging agent RD, antioxidant A, antioxidant D, anti-aging agent CPPD, antioxidant A W；
The preparation method of the modified silica flour is：By quartz grinding and 300-400 mesh sieve is crossed, three fourth of methyl is then added
Ketoximinosilanes are stirred 10min at normal temperatures, then heat to 80-85 DEG C of heat preservation grinding 30min, add water stirring and be made
Solid content reaches the solution of 25-35%, and gained mixed liquor is sent into dry in spray dryer, the spheric granules of obtained 20-40 mesh,
And it is dried at 100-110 DEG C；
The mass ratio of the methyl tributanoximo silane and silica flour is 1：4.1；
A kind of preparation method of the wear-resistant coating of cementitious composite packaging bag includes,
I by resin, tree ash, modified silica flour, lignin sulfonic acid, nano-titanium dioxide, polyethylene wax micro mist, Wu Luo
Tropine is placed in reaction kettle and is uniformly mixed, and is warming up to 220-260 DEG C, 1~2h of insulated and stirred obtains mixture stand for standby use；
II by polyether Glycols, 4,4- diaminodiphenyl-methanes, tributyl phosphate, polyacrylamide, anti-aging agent, biology
Auxiliary agent, deionized water are added in I, and cool to 100-120 DEG C, mix to form the preferable slurry of mobility；
III, by the preferable slurry indentation three-roller of above-mentioned mobility, is ground to grain size and is less than 20 μm, tinning.
Embodiment 2
A kind of wear-resistant coating of cementitious composite packaging bag, it is characterised in that：Material including following parts by weight is made,
20 parts of resin, modified 14 parts of silica flour, 9 parts of lignin sulfonic acid, 4 parts of nano-titanium dioxide, gathers at 9 parts of tree ash
5 parts of ethylene waxes micro mist, 10 parts of methenamine, 3 parts of polyether Glycols, 14 parts of 4,4- diaminodiphenyl-methanes, tributyl phosphate 5
Part, 9 parts of polyacrylamide, 12 parts of anti-aging agent, 14 parts of biological assistant, 35 parts of deionized water；
The resin includes in E-12 epoxy resin, organic siliconresin, Hydroxylated acrylic resin, long oil alkyd
It is a kind of；
The anti-aging agent includes one kind in anti-aging agent RD, antioxidant A, antioxidant D, anti-aging agent CPPD, antioxidant A W；
The preparation method of the modified silica flour is：By quartz grinding and 300-400 mesh sieve is crossed, three fourth of methyl is then added
Ketoximinosilanes are stirred 10min at normal temperatures, then heat to 80-85 DEG C of heat preservation grinding 30min, add water stirring and be made
Solid content reaches the solution of 25-35%, and gained mixed liquor is sent into dry in spray dryer, the spheric granules of obtained 20-40 mesh,
And it is dried at 100-110 DEG C；
The mass ratio of the methyl tributanoximo silane and silica flour is 1：4.1；
A kind of preparation method of the wear-resistant coating of cementitious composite packaging bag includes,
I by resin, tree ash, modified silica flour, lignin sulfonic acid, nano-titanium dioxide, polyethylene wax micro mist, Wu Luo
Tropine is placed in reaction kettle and is uniformly mixed, and is warming up to 220-260 DEG C, 1~2h of insulated and stirred obtains mixture stand for standby use；
II by polyether Glycols, 4,4- diaminodiphenyl-methanes, tributyl phosphate, polyacrylamide, anti-aging agent, biology
Auxiliary agent, deionized water are added in I, and cool to 100-120 DEG C, mix to form the preferable slurry of mobility；
III, by the preferable slurry indentation three-roller of above-mentioned mobility, is ground to grain size and is less than 20 μm, tinning.
Embodiment 3
A kind of wear-resistant coating of cementitious composite packaging bag, it is characterised in that：Material including following parts by weight is made,
17 parts of resin, 8 parts of tree ash, modified 11 parts of silica flour, 7 parts of lignin sulfonic acid, nano-titanium dioxide 3, poly- second
2 parts of alkene wax micro mist, 8 parts of methenamine, 2 parts of polyether Glycols, 12 parts of 4,4- diaminodiphenyl-methanes, 3 parts of tributyl phosphate,
6 parts of polyacrylamide, 9 parts of anti-aging agent, 12 parts of biological assistant, 33 parts of deionized water；
The resin includes in E-12 epoxy resin, organic siliconresin, Hydroxylated acrylic resin, long oil alkyd
It is a kind of；
The anti-aging agent includes one kind in anti-aging agent RD, antioxidant A, antioxidant D, anti-aging agent CPPD, antioxidant A W；
The preparation method of the modified silica flour is：By quartz grinding and 300-400 mesh sieve is crossed, three fourth of methyl is then added
Ketoximinosilanes are stirred 10min at normal temperatures, then heat to 80-85 DEG C of heat preservation grinding 30min, add water stirring and be made
Solid content reaches the solution of 25-35%, and gained mixed liquor is sent into dry in spray dryer, the spheric granules of obtained 20-40 mesh,
And it is dried at 100-110 DEG C；
The mass ratio of the methyl tributanoximo silane and silica flour is 1：4.1；
A kind of preparation method of the wear-resistant coating of cementitious composite packaging bag includes,
I by resin, tree ash, modified silica flour, lignin sulfonic acid, nano-titanium dioxide, polyethylene wax micro mist, Wu Luo
Tropine is placed in reaction kettle and is uniformly mixed, and is warming up to 220-260 DEG C, 1~2h of insulated and stirred obtains mixture stand for standby use；
II by polyether Glycols, 4,4- diaminodiphenyl-methanes, tributyl phosphate, polyacrylamide, anti-aging agent, biology
Auxiliary agent, deionized water are added in I, and cool to 100-120 DEG C, mix to form the preferable slurry of mobility；
III, by the preferable slurry indentation three-roller of above-mentioned mobility, is ground to grain size and is less than 20 μm, tinning.
Comparative example：
A kind of water-repellent paint of packaging bag, including：18 parts of polyvinyl resin, 10 parts of mica powder, phenyl glycidyl ether 5
Part, 5 parts of dimethylamine propylamine, 8 parts of casein sodium, 5 parts of oxalic acid, 33 parts of water；
Preparation method：Above-mentioned material is put into reaction kettle, 40-50 points are stirred in 110-120 DEG C of temperature
Clock is then pressed into three-roller, is ground into powder.
By experiment, the performance and effect of 1-3 of the embodiment of the present invention and comparative example, such as following table are measured：
The above shows and describes the basic principles and main features of the present invention and the advantages of the present invention.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this
The principle of invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent thereof.
Claims (2)
1. a kind of wear-resistant coating of cementitious composite packaging bag, it is characterised in that：Material including following parts by weight is made,
13-20 parts of resin, 4-9 parts of tree ash, modified 8-14 parts of silica flour, 2-9 parts of lignin sulfonic acid, nano-titanium dioxide 1-
4 parts, 1-5 parts of polyethylene wax micro mist, 5-10 parts of methenamine, 1-3 parts of polyether Glycols, 4,4- diaminodiphenyl-methanes 7-14
Part, 1-5 parts of tributyl phosphate, 4-9 parts of polyacrylamide, 7-12 parts of anti-aging agent, 9-14 parts of biological assistant, deionized water 30-35
Part.
2. a kind of wear-resistant coating of cementitious composite packaging bag according to claim 1, it is characterised in that：A kind of cement
The preparation method of the wear-resistant coating of combined package bag includes,
I by resin, tree ash, modified silica flour, lignin sulfonic acid, nano-titanium dioxide, polyethylene wax micro mist, methenamine
It is placed in reaction kettle and is uniformly mixed, be warming up to 220-260 DEG C, 1~2h of insulated and stirred obtains mixture stand for standby use；
II helps polyether Glycols, 4,4- diaminodiphenyl-methanes, tributyl phosphate, polyacrylamide, anti-aging agent, biology
Agent, deionized water are added in I, and cool to 100-120 DEG C, mix to form the preferable slurry of mobility；
III, by the preferable slurry indentation three-roller of above-mentioned mobility, is ground to grain size and is less than 20 μm, tinning.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810278188.4A CN108531034A (en) | 2018-03-31 | 2018-03-31 | A kind of wear-resistant coating of cementitious composite packaging bag |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810278188.4A CN108531034A (en) | 2018-03-31 | 2018-03-31 | A kind of wear-resistant coating of cementitious composite packaging bag |
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| CN108531034A true CN108531034A (en) | 2018-09-14 |
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107760081A (en) * | 2017-09-27 | 2018-03-06 | 阜南县邰氏宇崴运动器材有限公司 | A kind of barrier coat of the outer vamp of roller skate |
-
2018
- 2018-03-31 CN CN201810278188.4A patent/CN108531034A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107760081A (en) * | 2017-09-27 | 2018-03-06 | 阜南县邰氏宇崴运动器材有限公司 | A kind of barrier coat of the outer vamp of roller skate |
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