CN108530704A - A kind of solid tyre compounded rubber and preparation method thereof - Google Patents

A kind of solid tyre compounded rubber and preparation method thereof Download PDF

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Publication number
CN108530704A
CN108530704A CN201810584574.6A CN201810584574A CN108530704A CN 108530704 A CN108530704 A CN 108530704A CN 201810584574 A CN201810584574 A CN 201810584574A CN 108530704 A CN108530704 A CN 108530704A
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parts
rubber
agent
carbon black
butadiene
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卞泽根
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Mingguang Snyder Solid Tire Ltd Speed
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Mingguang Snyder Solid Tire Ltd Speed
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • CCHEMISTRY; METALLURGY
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    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014Use of organic additives
    • C08J9/0023Use of organic additives containing oxygen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0061Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0066Use of inorganic compounding ingredients
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0066Use of inorganic compounding ingredients
    • C08J9/0071Nanosized fillers, i.e. having at least one dimension below 100 nanometers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0085Use of fibrous compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2307/00Characterised by the use of natural rubber
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2309/00Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2407/00Characterised by the use of natural rubber
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2409/00Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2409/00Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08J2409/06Copolymers with styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2477/00Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
    • C08J2477/10Polyamides derived from aromatically bound amino and carboxyl groups of amino carboxylic acids or of polyamines and polycarboxylic acids
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
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    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
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    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/04Carbon
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/09Carboxylic acids; Metal salts thereof; Anhydrides thereof
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/14Peroxides

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Abstract

The invention discloses a kind of solid tyre compounded rubbers and preparation method thereof, include the raw material of following parts by weight:12 18 parts of butadiene rubber, 8 12 parts of butadiene-styrene rubber, 10 20 parts of natural rubber, 23 parts of vulcanizing agent DCP, 48 parts of nano silicon dioxide, 10 16 parts of absolute ethyl alcohol, 26 parts of anti-wear agent, 12 16 parts of carbon black, aramid fiber be fine 26 parts short, 15 parts of foaming agent, 12 parts of anti-aging agent, 24 parts of anti-wear agent.The present invention solves the problems, such as conventional pneumatic by environmental restrictions failure risk and poor reliability, and invention enhances the reliabilities of tire so that tire tread is not in the phenomenon that blowing out to severe ground etc., and temperature tolerance is good, highly reliable.

Description

A kind of solid tyre compounded rubber and preparation method thereof
Technical field
The present invention relates to solid tyre technical field, especially a kind of solid tyre compounded rubber and preparation method thereof.
Background technology
Solid tyre is a kind of special automobile tire, does not have to cord as framework, it is not necessary to inflate, therefore be not required to the inner tube of a tyre or airtight Layer.Solid tyre is only used for the high load capacity vehicle or machinery run at a low speed or the machinery of fixed position, is primarily adapted for use in anti-riot The special cars such as vehicle, armoured van, anti-terror vehicle, engineering truck, forestry machinery.
With the enhancing of social environment consciousness and awareness of saving energy, the demand to energy-saving environmentally protective tire is stepped up. According to associated specialist, it is expected that demand of the China to energy-saving environmentally protective tire will quickly be increased with annual 8%~10% speed. With the increase of the development and green tire demand of tire industry, it is contemplated that the 2011 and 2016 energy-saving environmentally protective wheels of China The demand of tire will respectively reach 2,500,000 and 6,000,000.It can be seen that the market demand of energy-saving environmentally protective tire is very It is huge.
Invention content
It is an object of the invention to overcome the deficiencies of the prior art and provide a kind of solid tyre compounded rubber and its preparation sides Method, the present invention solve the problems, such as conventional pneumatic by environmental restrictions failure risk and poor reliability, invention enhances The reliability of tire so that tire tread is not in the phenomenon that blowing out to severe ground etc., and temperature tolerance is good, highly reliable.
The purpose of the present invention is achieved through the following technical solutions:
A kind of solid tyre compounded rubber, includes the raw material of following parts by weight:
12-18 parts of butadiene rubber, 8-12 parts of butadiene-styrene rubber, 10-20 parts of natural rubber, 2-3 parts of vulcanizing agent DCP, nanometer titanium dioxide 4-8 parts of silicon, 10-16 parts of absolute ethyl alcohol, 2-6 parts of anti-wear agent, 12-16 parts of carbon black, aramid fiber short 2-6 parts of fibre, are prevented 1-5 parts of foaming agent Old agent 1-2 parts, 2-4 parts of anti-wear agent.
Preferably, in the present invention, include the raw material of following parts by weight:
It is 12 parts of butadiene rubber, 10 parts of butadiene-styrene rubber, 16 parts of natural rubber, 2 parts of vulcanizing agent DCP, 6 parts of nano silicon dioxide, anhydrous 14 parts of ethyl alcohol, 4 parts of anti-wear agent, 14 parts of carbon black, aramid fiber be fine 4 parts short, 4 parts of foaming agent, 2 parts of anti-aging agent, 2 parts of anti-wear agent.
Preferably, in the present invention, the fibre length of the short fibre of the aramid fiber is 2-10mm.
Preferably, in the present invention, the carbon black is in carbon black N330, carbon black N234, carbon black N110 and carbon black N220 At least one.
A kind of preparation method of solid tyre compounded rubber, including following preparation process:
S1, natural rubber, butadiene-styrene rubber, butadiene rubber and carbon black are weighed according to proportioning, sequentially add in mixer and be kneaded, Then dumping obtains rubber compound at a temperature of 160-170 DEG C;
S2, rubber compound and graphene, stearic acid, silane coupling agent are added in mixer and are kneaded, in 135-145 DEG C of item Dumping obtains glue refining body under part;
S3, it will be kneaded in glue refining body and remaining raw material addition mixer, dumping obtains reality under conditions of 90-100 DEG C Heart tire material.
Preferably, in the present invention, in step s 2, further include being cooled in air often after being kneaded in mixer Temperature.
Beneficial effects of the present invention are:
The present invention solves the problems, such as conventional pneumatic by environmental restrictions failure risk and poor reliability, invention enhances The reliability of tire so that tire tread is not in the phenomenon that blowing out to severe ground etc., and temperature tolerance is good, highly reliable.
Specific implementation mode
Technical scheme of the present invention is detailed further below, but protection scope of the present invention is not limited to following institute It states.
Embodiment 1:
A kind of solid tyre compounded rubber, includes the raw material of following parts by weight:
It is 12 parts of butadiene rubber, 8 parts of butadiene-styrene rubber, 10 parts of natural rubber, 2 parts of vulcanizing agent DCP, 4 parts of nano silicon dioxide, anhydrous 10 parts of ethyl alcohol, 2 parts of anti-wear agent, 12 parts of carbon black, aramid fiber be fine 2 parts short, 1 part of foaming agent, 1 part of anti-aging agent, 2 parts of anti-wear agent.
A kind of preparation method of solid tyre compounded rubber, including following preparation process:
S1, natural rubber, butadiene-styrene rubber, butadiene rubber and carbon black are weighed according to proportioning, sequentially add in mixer and be kneaded, Then dumping obtains rubber compound at a temperature of 160 DEG C;
S2, rubber compound and graphene, stearic acid, silane coupling agent are added in mixer and are kneaded, under conditions of 135 DEG C Dumping obtains glue refining body;
S3, it will be kneaded in glue refining body and remaining raw material addition mixer, dumping obtains solid wheel under conditions of 90 DEG C Tire tire material.
Embodiment 2:
A kind of solid tyre compounded rubber, includes the raw material of following parts by weight:
It is 18 parts of butadiene rubber, 12 parts of butadiene-styrene rubber, 20 parts of natural rubber, 3 parts of vulcanizing agent DCP, 8 parts of nano silicon dioxide, anhydrous 16 parts of ethyl alcohol, 6 parts of anti-wear agent, 16 parts of carbon black, aramid fiber be fine 6 parts short, 5 parts of foaming agent, 2 parts of anti-aging agent, 4 parts of anti-wear agent.
A kind of preparation method of solid tyre compounded rubber, including following preparation process:
S1, natural rubber, butadiene-styrene rubber, butadiene rubber and carbon black are weighed according to proportioning, sequentially add in mixer and be kneaded, Then dumping obtains rubber compound at a temperature of 170 DEG C;
S2, rubber compound and graphene, stearic acid, silane coupling agent are added in mixer and are kneaded, under conditions of 145 DEG C Dumping obtains glue refining body;
S3, it will be kneaded in glue refining body and remaining raw material addition mixer, dumping obtains solid wheel under conditions of 100 DEG C Tire tire material.
Embodiment 3:
A kind of solid tyre compounded rubber, includes the raw material of following parts by weight:
It is 16 parts of butadiene rubber, 10 parts of butadiene-styrene rubber, 16 parts of natural rubber, 3 parts of vulcanizing agent DCP, 6 parts of nano silicon dioxide, anhydrous 14 parts of ethyl alcohol, 4 parts of anti-wear agent, 14 parts of carbon black, aramid fiber be fine 4 parts short, 4 parts of foaming agent, 2 parts of anti-aging agent, 4 parts of anti-wear agent.
A kind of preparation method of solid tyre compounded rubber, including following preparation process:
S1, natural rubber, butadiene-styrene rubber, butadiene rubber and carbon black are weighed according to proportioning, sequentially add in mixer and be kneaded, Then dumping obtains rubber compound at a temperature of 170 DEG C;
S2, rubber compound and graphene, stearic acid, silane coupling agent are added in mixer and are kneaded, under conditions of 140 DEG C Dumping obtains glue refining body;
S3, it will be kneaded in glue refining body and remaining raw material addition mixer, dumping obtains solid wheel under conditions of 100 DEG C Tire tire material.
Embodiment 4:
A kind of solid tyre compounded rubber, includes the raw material of following parts by weight:
It is 14 parts of butadiene rubber, 12 parts of butadiene-styrene rubber, 18 parts of natural rubber, 2 parts of vulcanizing agent DCP, 4 parts of nano silicon dioxide, anhydrous 12 parts of ethyl alcohol, 6 parts of anti-wear agent, 14 parts of carbon black, aramid fiber be fine 6 parts short, 2 parts of foaming agent, 2 parts of anti-aging agent, 4 parts of anti-wear agent.
A kind of preparation method of solid tyre compounded rubber, including following preparation process:
S1, natural rubber, butadiene-styrene rubber, butadiene rubber and carbon black are weighed according to proportioning, sequentially add in mixer and be kneaded, Then dumping obtains rubber compound at a temperature of 160 DEG C;
S2, rubber compound and graphene, stearic acid, silane coupling agent are added in mixer and are kneaded, under conditions of 145 DEG C Dumping obtains glue refining body;
S3, it will be kneaded in glue refining body and remaining raw material addition mixer, dumping obtains solid wheel under conditions of 100 DEG C Tire tire material.
Specific implementation mode of the invention above described embodiment only expresses, the description thereof is more specific and detailed, but simultaneously Cannot the limitation to the scope of the claims of the present invention therefore be interpreted as.It should be pointed out that for those of ordinary skill in the art For, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the guarantor of the present invention Protect range.

Claims (6)

1. a kind of solid tyre compounded rubber, which is characterized in that include the raw material of following parts by weight:
12-18 parts of butadiene rubber, 8-12 parts of butadiene-styrene rubber, 10-20 parts of natural rubber, 2-3 parts of vulcanizing agent DCP, nanometer titanium dioxide 4-8 parts of silicon, 10-16 parts of absolute ethyl alcohol, 2-6 parts of anti-wear agent, 12-16 parts of carbon black, aramid fiber short 2-6 parts of fibre, are prevented 1-5 parts of foaming agent Old agent 1-2 parts, 2-4 parts of anti-wear agent.
2. a kind of solid tyre compounded rubber according to claim 1, which is characterized in that include the raw material of following parts by weight:
It is 12 parts of butadiene rubber, 10 parts of butadiene-styrene rubber, 16 parts of natural rubber, 2 parts of vulcanizing agent DCP, 6 parts of nano silicon dioxide, anhydrous 14 parts of ethyl alcohol, 4 parts of anti-wear agent, 14 parts of carbon black, aramid fiber be fine 4 parts short, 4 parts of foaming agent, 2 parts of anti-aging agent, 2 parts of anti-wear agent.
3. a kind of solid tyre compounded rubber according to claim 1, which is characterized in that the fibre length of the short fibre of aramid fiber For 2-10mm.
4. a kind of solid tyre compounded rubber according to claim 1, which is characterized in that the carbon black is carbon black N330, charcoal At least one of black N234, carbon black N110 and carbon black N220.
5. a kind of preparation method of solid tyre compounded rubber, which is characterized in that including following preparation process:
S1, natural rubber, butadiene-styrene rubber, butadiene rubber and carbon black are weighed according to proportioning, sequentially add in mixer and be kneaded, Then dumping obtains rubber compound at a temperature of 160-170 DEG C;
S2, rubber compound and graphene, stearic acid, silane coupling agent are added in mixer and are kneaded, in 135-145 DEG C of item Dumping obtains glue refining body under part;
S3, it will be kneaded in glue refining body and remaining raw material addition mixer, dumping obtains reality under conditions of 90-100 DEG C Heart tire material.
6. a kind of preparation method of solid tyre compounded rubber according to claim 5, which is characterized in that in step s 2, Further include being cooled to room temperature in air after being kneaded in mixer.
CN201810584574.6A 2018-06-08 2018-06-08 A kind of solid tyre compounded rubber and preparation method thereof Pending CN108530704A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109467755A (en) * 2018-11-12 2019-03-15 永橡胶有限公司 A kind of low-heat-generation solid tyre and preparation method thereof
CN112898649A (en) * 2021-01-27 2021-06-04 郑英翻 High-performance composite material based on nano material modification and preparation process thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002069239A (en) * 2000-08-28 2002-03-08 Bridgestone Corp Rubber composition for tire tread and tire using the same
CN104140569A (en) * 2014-05-07 2014-11-12 浙江东南橡胶机带有限公司 High-abrasion-resistance anti-tear aramid fiber compound type solid tire tube and tire skin, and manufacturing method of solid tire
CN105131376A (en) * 2015-06-25 2015-12-09 浙江东南橡胶股份有限公司 Aramid fiber composite material, composite material for preparing solid tyre and manufacturing methods of two
CN107266729A (en) * 2017-08-07 2017-10-20 四川远星橡胶有限责任公司 Tyre for rock sizing material containing nylon short fibre
CN107312218A (en) * 2017-06-22 2017-11-03 青岛科技大学 A kind of rubber composite of low rolling resistance high abrasion-resistant tread rubber and preparation method thereof
CN107987324A (en) * 2017-11-30 2018-05-04 江苏托普车轮有限公司 With anti-fire and anlistatig solid tyre and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002069239A (en) * 2000-08-28 2002-03-08 Bridgestone Corp Rubber composition for tire tread and tire using the same
CN104140569A (en) * 2014-05-07 2014-11-12 浙江东南橡胶机带有限公司 High-abrasion-resistance anti-tear aramid fiber compound type solid tire tube and tire skin, and manufacturing method of solid tire
CN105131376A (en) * 2015-06-25 2015-12-09 浙江东南橡胶股份有限公司 Aramid fiber composite material, composite material for preparing solid tyre and manufacturing methods of two
CN107312218A (en) * 2017-06-22 2017-11-03 青岛科技大学 A kind of rubber composite of low rolling resistance high abrasion-resistant tread rubber and preparation method thereof
CN107266729A (en) * 2017-08-07 2017-10-20 四川远星橡胶有限责任公司 Tyre for rock sizing material containing nylon short fibre
CN107987324A (en) * 2017-11-30 2018-05-04 江苏托普车轮有限公司 With anti-fire and anlistatig solid tyre and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109467755A (en) * 2018-11-12 2019-03-15 永橡胶有限公司 A kind of low-heat-generation solid tyre and preparation method thereof
CN112898649A (en) * 2021-01-27 2021-06-04 郑英翻 High-performance composite material based on nano material modification and preparation process thereof

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