CN108530154A - Improve the conditioning agent of plant anti-oxidation ability - Google Patents

Improve the conditioning agent of plant anti-oxidation ability Download PDF

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Publication number
CN108530154A
CN108530154A CN201810138443.5A CN201810138443A CN108530154A CN 108530154 A CN108530154 A CN 108530154A CN 201810138443 A CN201810138443 A CN 201810138443A CN 108530154 A CN108530154 A CN 108530154A
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China
Prior art keywords
parts
conditioning agent
oxidation ability
plant anti
cepha
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CN201810138443.5A
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Chinese (zh)
Inventor
汪珂
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Jinhua Jing He Technology Co Ltd
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Jinhua Jing He Technology Co Ltd
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Priority to CN201810138443.5A priority Critical patent/CN108530154A/en
Publication of CN108530154A publication Critical patent/CN108530154A/en
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05CNITROGENOUS FERTILISERS
    • C05C11/00Other nitrogenous fertilisers
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/60Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants

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  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses the conditioning agents for improving plant anti-oxidation ability, and ingredient and its parts by weight are:60 80 parts of ethyl alcohol, 35 parts of ethephon (CEPHA),2-(chloroethyl) phosphonic acids, 14 parts of mashed garlic juice, 12 parts of aloes, 0.2 0.3 parts of amino acid, 8 10 parts of water soluble chitosans.It has the beneficial effect that:The conditioning agent that the present invention is announced can effectively improve plant anti-oxidation ability, while have good Germination effect;Preparation method is simple, and raw material is easy to get, of low cost;The simple synthetic method of ethephon (CEPHA),2-(chloroethyl) phosphonic acid, at low cost, production moderate pressure and product content are up to 94%, are suitable for China's industrialized production process, while solving pollution problem present in old technique.

Description

Improve the conditioning agent of plant anti-oxidation ability
Technical field
The present invention relates to agriculture fields, more particularly, to the conditioning agent for improving plant anti-oxidation ability.
Background technology
Plant can be coerced in growth course by various environmental factors, including temperature, illumination, moisture are Pathogen etc..These external environmental factors stress can usually influence the growth and development of plant, and the modern farming underproduction Main cause.When plant is forced, its in vivo generate living radical when plant be forced after initial reaction it One.Wherein, some reactive oxygen compounds, such as H2O2, it is found to be a kind of signaling molecule, downstream stress-related genes can be adjusted Expression, make plant obtain resistance, and in addition also have some active oxygen radicals there is presently no find its serve as signaling molecule The effect of aspect, such as O2-Deng.Although some active oxygen radicals can induce the expression of downstream stress-related genes, if For intensity height, the stress of period length makes the active oxygen radical in plant in high level, plant will be made thin for a long time The structure for the substance of the membrane structure of intracellular, albumen and nucleic acid being easily reduced is destroyed, and cell death is caused.Therefore, it carries The oxidation resistance of high plant has very important significance.
Invention content
The object of the present invention is to provide the conditioning agent for improving plant anti-oxidation ability, which can effectively improve plant Oxidation resistance, while there is good Germination effect.
Technical solution provided by the invention in order to achieve the above object is:The conditioning agent of plant anti-oxidation ability is improved, Ingredient and its parts by weight are:60-80 parts of ethyl alcohol, 3-5 parts of ethephon (CEPHA),2-(chloroethyl) phosphonic acids, 1-4 parts of mashed garlic juice, 1-2 parts of aloes, 0.2-0.3 parts of ammonia Base acid, 8-10 parts of water soluble chitosans.The conditioning agent can effectively improve plant anti-oxidation ability, while have good vernalization Effect.
Preferably, the preparation method of conditioning agent is:Make in the presence of 60-80 parts of ethyl alcohol 3-5 parts of ethephon (CEPHA),2-(chloroethyl) phosphonic acids, 1-4 parts Mashed garlic juice, 1-2 part aloe, 0.2-0.3 parts of amino acid and 8-10 parts of water soluble chitosan mixing, form conditioning agent.The party Method is simple, and raw material is easy to get, of low cost, and the water soluble chitosan being added has good fungistatic effect, can give plant Desinsection, it is disease-resistant, play the role of fertilizer, and minor metallic element can be decomposed, to be converted into the nutrient of plant, enhances plant Immunity.
Preferably, the synthetic method of ethephon (CEPHA),2-(chloroethyl) phosphonic acid is:Bis- (2- chloroethyls)-(2- chloroethyls) phosphonic acids is added into reaction kettle Ester is passed through hydrogen chloride gas precursor reactant with synthesizing ethylene profit in the case of stirring.The simple synthetic method of ethephon (CEPHA),2-(chloroethyl) phosphonic acid, it is at low cost, It produces moderate pressure and product content is up to 94%, be suitable for China's industrialized production process, while solving and being deposited in old technique Pollution problem.
Preferably, the synthesis reaction temperature of ethephon (CEPHA),2-(chloroethyl) phosphonic acid is 152-158 DEG C.Under this condition, reaction speed is fast, but violent journey Spend small, the impurity generated in the process is few, and the content for reacting ethephon (CEPHA),2-(chloroethyl) phosphonic acid in the product of gained is big.
Preferably, the synthesising reacting time of ethephon (CEPHA),2-(chloroethyl) phosphonic acid is 13-14h.Under this condition, the content of ethephon (CEPHA),2-(chloroethyl) phosphonic acid is high in product, Yield is big, and the raw material being added is fully used, and has good economic and environment-friendly benefit.
Preferably, the synthetic reaction pressure of ethephon (CEPHA),2-(chloroethyl) phosphonic acid is 0.51-0.56MPa.Under this condition, reaction is not easy to make equipment At damage, and the reaction time is few, so as to shorten the period of reaction, improves the competitiveness of final products conditioning agent.
Preferably, the synthesis mixing speed of ethephon (CEPHA),2-(chloroethyl) phosphonic acid is 630-640r/min.(2- chloroethyls)-bis- in reaction raw materials (2- chloroethyls) phosphonate ester viscosity is larger, if rotating speed is too low, is unfavorable for the mixing of reactant, if rotating speed is excessively high, is unfavorable for two-phase Reaction.
Preferably, amino acid is asparatate or glycine or proline.Amino acid is necessary to plant growth Nutriment there is facilitation, amino acid can increase chlorophyll content of plant the photosynthesis of crop, improve plant The activity of enzyme, promotes the infiltration of carbon dioxide, keeps photosynthesis more vigorous, can greatly improve the product of plant in tissue Matter.
Compared with prior art, beneficial effects of the present invention are:The conditioning agent that the present invention is announced can effectively improve plant Object oxidation resistance, while there is good Germination effect;Preparation method is simple, and raw material is easy to get, of low cost;The conjunction of ethephon (CEPHA),2-(chloroethyl) phosphonic acid It is easy, at low cost at method, production moderate pressure and product content be up to 94%, be suitable for China's industrialized production process, together When solve pollution problem present in old technique.
Specific implementation mode
It is described in further detail by the following examples:
Embodiment 1:The conditioning agent for improving plant anti-oxidation ability, includes the following steps:
1) synthesis of ethephon (CEPHA),2-(chloroethyl) phosphonic acid:Bis- (2- chloroethyls)-(2- chloroethyls) phosphonate ester is added into reaction kettle, in the case of stirring Hydrogen chloride gas precursor reactant is passed through with synthesizing ethylene profit, wherein reaction temperature is 152 DEG C, reaction time 13h, and reaction pressure is 0.51MPa, mixing speed 630r/min, the simple synthetic method of ethephon (CEPHA),2-(chloroethyl) phosphonic acid, at low cost, production moderate pressure and product content Up to 94%, it is suitable for China's industrialized production process, while solving pollution problem present in old technique;
2) preparation of conditioning agent:Make 3 parts of ethephon (CEPHA),2-(chloroethyl) phosphonic acids, 1 part of mashed garlic juice, 1 part of aloe, 0.2 part of day in the presence of 60 parts of ethyl alcohol L-aminobutanedioic acid and 8 parts of water soluble chitosan mixing, form conditioning agent, preparation method is simple, and raw material is easy to get, of low cost, institute The conditioning agent of preparation can effectively improve plant anti-oxidation ability, while have good Germination effect.
Embodiment 2:The conditioning agent for improving plant anti-oxidation ability, includes the following steps:
1) synthesis of ethephon (CEPHA),2-(chloroethyl) phosphonic acid:Bis- (2- chloroethyls)-(2- chloroethyls) phosphonate ester is added into reaction kettle, in the case of stirring Hydrogen chloride gas precursor reactant is passed through with synthesizing ethylene profit, wherein reaction temperature is 158 DEG C, reaction time 14h, and reaction pressure is 0.56MPa, mixing speed 640r/min, the simple synthetic method of ethephon (CEPHA),2-(chloroethyl) phosphonic acid, at low cost, production moderate pressure and product content Up to 94%, it is suitable for China's industrialized production process, while solving pollution problem present in old technique;
2) preparation of conditioning agent:Make in the presence of 80 parts of ethyl alcohol 5 parts of ethephon (CEPHA),2-(chloroethyl) phosphonic acids, 4 parts of mashed garlic juice, 2 parts of aloes, 0.3 part it is sweet Propylhomoserin and 10 parts of water soluble chitosan mixing, form conditioning agent, preparation method is simple, and raw material is easy to get, of low cost, prepared Conditioning agent can effectively improve plant anti-oxidation ability, while there is good Germination effect.
Embodiment 3:The conditioning agent for improving plant anti-oxidation ability, includes the following steps:
1) synthesis of ethephon (CEPHA),2-(chloroethyl) phosphonic acid:Bis- (2- chloroethyls)-(2- chloroethyls) phosphonate ester is added into reaction kettle, in the case of stirring Hydrogen chloride gas precursor reactant is passed through with synthesizing ethylene profit, wherein reaction temperature is 153 DEG C, reaction time 13h, and reaction pressure is 0.52MPa, mixing speed 632r/min, the simple synthetic method of ethephon (CEPHA),2-(chloroethyl) phosphonic acid, at low cost, production moderate pressure and product content Up to 94%, it is suitable for China's industrialized production process, while solving pollution problem present in old technique;
2) preparation of conditioning agent:Make 4 parts of ethephon (CEPHA),2-(chloroethyl) phosphonic acids, 2 parts of mashed garlic juice, 2 parts of aloes, 0.25 portion of dried meat in the presence of 63 parts of ethyl alcohol Propylhomoserin and 9 parts of water soluble chitosan mixing, form conditioning agent, preparation method is simple, and raw material is easy to get, of low cost, prepared Conditioning agent can effectively improve plant anti-oxidation ability, while there is good Germination effect.
Embodiment 4:The conditioning agent for improving plant anti-oxidation ability, includes the following steps:
1) synthesis of ethephon (CEPHA),2-(chloroethyl) phosphonic acid:Bis- (2- chloroethyls)-(2- chloroethyls) phosphonate ester is added into reaction kettle, in the case of stirring Hydrogen chloride gas precursor reactant is passed through with synthesizing ethylene profit, wherein reaction temperature is 157 DEG C, reaction time 14h, and reaction pressure is 0.55MPa, mixing speed 638r/min, the simple synthetic method of ethephon (CEPHA),2-(chloroethyl) phosphonic acid, at low cost, production moderate pressure and product content Up to 94%, it is suitable for China's industrialized production process, while solving pollution problem present in old technique;
2) preparation of conditioning agent:Make 5 parts of ethephon (CEPHA),2-(chloroethyl) phosphonic acids, 4 parts of mashed garlic juice, 2 parts of aloes, 0.3 portion of dried meat in the presence of 78 parts of ethyl alcohol Propylhomoserin and 10 parts of water soluble chitosan mixing, add 0.02 part of trimethyl orthoacetate and 0.013 part of trioctylamine, stir For 20min to form conditioning agent, preparation method is simple, and raw material is easy to get, of low cost, and prepared conditioning agent has good vernalization Effect;The trimethyl orthoacetate and trioctylamine being added have synergistic effect, anion that can be significantly in activated plant body, make Plant electronics inversely incudes with high energy electron, and tree body photosynthate is hindered to convey downwards, promotes endogenous ethylene to generate, intensifies bud Differentiation, healthy and strong flowering gene and floral organ ovary breed a large amount of high-quality buds.
Embodiment of above is merely to illustrate the present invention, and not limitation of the present invention, the ordinary skill people of this field Member can also make a variety of changes and modification without departing from the spirit and scope of the present invention.Therefore, all equivalent Technical solution also belong to scope of the invention, scope of patent protection of the invention should be defined by the claims.

Claims (7)

1. improving the conditioning agent of plant anti-oxidation ability, it is characterised in that:The ingredient and its parts by weight of the conditioning agent be:60- 80 parts of ethyl alcohol, 3-5 parts of ethephon (CEPHA),2-(chloroethyl) phosphonic acids, 1-4 parts of mashed garlic juice, 1-2 parts of aloes, 0.2-0.3 parts of amino acid, 8-10 parts of water soluble shells are poly- Sugar.
2. the conditioning agent according to claim 1 for improving plant anti-oxidation ability, it is characterised in that:The system of the conditioning agent Preparation Method is:Make in the presence of 60-80 parts of ethyl alcohol 3-5 parts of ethephon (CEPHA),2-(chloroethyl) phosphonic acids, 1-4 parts of mashed garlic juice, 1-2 parts of aloes, 0.2-0.3 parts Amino acid and 8-10 parts of water soluble chitosan mixing, form conditioning agent.
3. the conditioning agent according to claim 2 for improving plant anti-oxidation ability, it is characterised in that:The conjunction of the ethephon (CEPHA),2-(chloroethyl) phosphonic acid It is at method:Bis- (2- chloroethyls)-(2- chloroethyls) phosphonate ester is added into reaction kettle, is passed through hydrogen chloride in the case of stirring Gas reaction is with synthesizing ethylene profit.
4. the conditioning agent according to claim 3 for improving plant anti-oxidation ability, it is characterised in that:The reaction temperature is 152-158℃。
5. the conditioning agent according to claim 3 for improving plant anti-oxidation ability, it is characterised in that:The reaction time is 13-14h。
6. the conditioning agent according to claim 3 for improving plant anti-oxidation ability, it is characterised in that:The reaction pressure is 0.51-0.56MPa。
7. the conditioning agent according to claim 3 for improving plant anti-oxidation ability, it is characterised in that:The mixing speed is 630-640r/min。
CN201810138443.5A 2018-02-10 2018-02-10 Improve the conditioning agent of plant anti-oxidation ability Pending CN108530154A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112120046A (en) * 2019-09-25 2020-12-25 黄淮学院 Landscape plant growth regulator and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101120679A (en) * 2007-09-04 2008-02-13 常熟市农药厂有限公司 Method for preparing 2-chloro-thyl phosphoric acid powder
CN102037830A (en) * 2009-10-20 2011-05-04 四川国光农化股份有限公司 Plant growth regulator composition
CN104982115A (en) * 2015-06-14 2015-10-21 安徽徽大农业有限公司 Asparagus lettuce seed germination accelerating method
CN105658068A (en) * 2013-08-23 2016-06-08 精细农用化学品有限公司 Growth regulator concentrate and use thereof
CN107624787A (en) * 2017-09-30 2018-01-26 无为腾龙生态林业开发有限公司 A kind of golden fruit-bearing forest plantation growth promotion conditioning agent

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101120679A (en) * 2007-09-04 2008-02-13 常熟市农药厂有限公司 Method for preparing 2-chloro-thyl phosphoric acid powder
CN102037830A (en) * 2009-10-20 2011-05-04 四川国光农化股份有限公司 Plant growth regulator composition
CN105658068A (en) * 2013-08-23 2016-06-08 精细农用化学品有限公司 Growth regulator concentrate and use thereof
CN104982115A (en) * 2015-06-14 2015-10-21 安徽徽大农业有限公司 Asparagus lettuce seed germination accelerating method
CN107624787A (en) * 2017-09-30 2018-01-26 无为腾龙生态林业开发有限公司 A kind of golden fruit-bearing forest plantation growth promotion conditioning agent

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
孙德群等: "乙烯利加压法合成工艺改进", 《现代农药》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112120046A (en) * 2019-09-25 2020-12-25 黄淮学院 Landscape plant growth regulator and preparation method thereof

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