CN108529638A - A kind of metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent preparation method - Google Patents
A kind of metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent preparation method Download PDFInfo
- Publication number
- CN108529638A CN108529638A CN201810216764.2A CN201810216764A CN108529638A CN 108529638 A CN108529638 A CN 108529638A CN 201810216764 A CN201810216764 A CN 201810216764A CN 108529638 A CN108529638 A CN 108529638A
- Authority
- CN
- China
- Prior art keywords
- source
- inhibiting agent
- phosphate salt
- parts
- ammonium phosphate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B35/00—Boron; Compounds thereof
- C01B35/08—Compounds containing boron and nitrogen, phosphorus, oxygen, sulfur, selenium or tellurium
- C01B35/14—Compounds containing boron and nitrogen, phosphorus, sulfur, selenium or tellurium
- C01B35/143—Phosphates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Fireproofing Substances (AREA)
Abstract
The present invention relates to anti-flaming smoke-inhibiting agent and its preparing technical fields, specifically disclose a kind of metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent preparation method, include the following steps：Step 1, raw material are prepared：Each raw material component is weighed by following weight：37 parts of boron source, 8.719 parts of source metal, 20.404 parts of source of ammonium, 10 parts of deionized water；Step 2, reacting processing：Load weighted medicament is added in the stainless steel cauldron with polytetrafluoroethyllining lining, then is added into reaction kettle and has weighed deionized water；Step 3, room temperature cooling：Reaction kettle is put into baking oven, oven temperature is set as 100 DEG C ~ 220 DEG C, and isothermal reaction cools down after 1 ~ 5 day in room temperature；Step 4, washing are filtered and are dried：It is washed with deionized water for removing unreacted excessive boric acid, is filtered, drying, you can obtain metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent repeatedly.The present invention overcomes the deficiencies in the prior art, product purity obtained is high, good dispersion, and is discharged without acid-base waste fluid in reaction process, consuming little energy.
Description
Technical field
The present invention relates to anti-flaming smoke-inhibiting agent and its preparing technical fields, particularly belong to a kind of fire-retardant suppression of metal boron ammonium phosphate salt
Fumicants preparation method.
Background technology
Wood plastic composite is a kind of lignocellulosic material in the form of fiber, powder etc.（WF）As filling or strengthening material
It is multiple to add a variety of manufacturing process such as extruded each analog assistant, hot pressing, molding or injection molding using thermoplastic as basis material for material
It closes and manufactured a kind of advanced composite material (ACM).Common thermoplastic matrix includes polyethylene（PE）, polypropylene（PP）, polyphenyl
Ethylene（PS）And polyvinyl chloride（PVC）Deng.
The wood plastic composite easy firing of fire protection flame retarding processing is not carried out, and combustion heat value is larger, while using PS and PVC
It will produce a large amount of dense smoke and poison gas when the wood plastic composite burning of plastic substrate, therefore sent out in wood plastic composite high speed
Exhibition, and when its application is gradually extended to higher to the fire safety demands field such as building doors and windows, interior decoration, furniture, carry
The flame-proof smoke-suppressing of high material has become the inevitable requirement that the material further develops.
Currently, in the research fire-retardant to wood plastic composite, researcher mostly uses ammonium polyphosphate（APP）For the swollen of representative
Swollen flame-retardant system, as the Chinese invention patent of Publication No. CN101143952A discloses a kind of flame-proof smoke-inhibiting wood-plastic composite wood
Material, the Chinese invention patent of Publication No. CN 102617915A disclose a kind of Anti-mildew halogen-free flame-retardant smoke-suppression wood and plastic composite
Material and preparation method thereof, the Chinese invention patent of Publication No. CN 1011730709A discloses a kind of wood fibre-polychlorostyrene second
Alkene composite material and preparation method is all made of APP and prepares halogen-free flame-retardant wood-plastic composite material, but APP imitates the suppression cigarette of material
Fruit is poor, while its additive amount in the material is usually larger, and the manufacturing cost for not only increasing material is more largely damaged
The mechanical performance of fire proofing is done harm to；In addition, anti-flaming smoke-inhibiting agent used in the prior art has stronger acid or alkalinity,
With certain corrosivity, there is certain adverse effect in preparation and use, especially when for being contacted with metal material
There is certain side effect to metallic material product when product is fire-retardant.
Invention content
The object of the present invention is to provide a kind of metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent preparation methods, overcome existing skill
The deficiency of art, it is big based on the fire retardant additive amount described in existing flame-retardant wood-plastic composite material technology, seriously affect Wood-plastic material
Mechanical performance, the disadvantages such as flame-retardant smoke inhibition efficiency is low, and provide a kind of dedicated anti-flaming smoke-inhibiting agent of Wood-plastic material --- metal boron
Ammonium phosphate salt anti-flaming smoke-inhibiting agent and a kind of preparation method of metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent, based on classical hydro-thermal
Synthetic method, and in conjunction with emerging boric acid fusion method be easy to introduce boron atom the characteristics of, respectively in excessive boron source（Boric acid）, source metal
（Metal oxide, metal halide, metal oxyacid salts class, including metal sulfate, metal acetate salt, metal halate）,
Source of ammonium（(NH4)2HPO4）And a certain amount of deionized water generates under certain temperature and reaction time.
To solve the above problems, the technical solution used in the present invention is as follows：
A kind of metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent preparation method, includes the following steps：
Step 1, raw material are prepared：Accurately each raw material component is weighed by following weight：3-7 parts of boron source, 8.719 parts of source metal, ammonium
20.404 parts of source, 10 parts of deionized water；
Step 2, reacting processing：Load weighted medicament is added in the stainless steel cauldron with polytetrafluoroethyllining lining, then
It is added into reaction kettle and has weighed deionized water；
Step 3, room temperature cooling：Reaction kettle is put into baking oven, oven temperature is set as 100 DEG C ~ 220 DEG C, isothermal reaction 1 ~ 5
It is cooled down in room temperature after it；
Step 4, washing are filtered and are dried：It is washed repeatedly with deionized water for removing unreacted excessive boric acid, filters, dry
It is dry, you can to obtain metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent.
Further, the ZnCl that the source metal is 4.089 parts2, the source of ammonium is 8.716 parts of (NH4)2HPO4, described
The H that boron source is 20.404 parts3BO3, the raw material proportioning is 1 according to the molar ratio of Zn and P:The molar ratio of 2.2, B and P is 5:1,
H2O is 8 with P molar ratios:1；The oven temperature is set as 200 °C, and the metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent is (NH4)
[ZnBP2O8]。
Further, the Zn (OAC) that the source metal is 6.585 parts2·2H2The O, (NH that the source of ammonium is 8.716 parts4)2HPO4, the boron source is 20.404 parts of H3BO3, the raw material proportioning is 1 according to the molar ratio of Zn and P:2.2, B and P's rubs
You are than being 5:1, H2O is 8 with P molar ratios:1, the oven temperature is set as 180 °C, the fire-retardant suppression of metal boron ammonium phosphate salt
Fumicants is (NH4)16[Zn16B8P24O96]。
Further, the FeCl that the source metal is 3.802 parts2·4H2The O, (NH that the source of ammonium is 8.716 parts4)2HPO4,
The H that the boron source is 20.404 parts3BO3, raw material proportioning is 1 according to the molar ratio of Zn and P:The molar ratio of 2.2, B and P is 5:1,
H2O is 8 with P molar ratios:1, the oven temperature is set as 200 °C, and the metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent is NH4·
FeⅢ [BP2O8(OH)]。
Further, the MgCl that the source metal is 6.099 parts2·6H2The O, (NH that the source of ammonium is 8.716 parts4)2HPO4,
The H that the boron source is 20.404 parts3BO3, raw material proportioning is 1 according to the molar ratio of Zn and P:The molar ratio of 2.2, B and P is 5:1,
H2O is 8 with P molar ratios:1, the oven temperature is set as 200 °C, and the metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent is NH4·
Mg (H2O)2[BP2O8]·H2O。
Further, the boron source is boric acid, and the source of ammonium is (NH4)2HPO4；The source metal is metal oxide, metal
Halide and its one or more of salt or metal salt.
Further, the molar ratio of metallic element and P elements is more than or equal to 1 in the step 1:4 and be less than or equal to 1:1,
The molar ratio of boron element and P elements is more than or equal to 3:1 and be less than or equal to 8:1, the molar ratios of deionized water and P elements is more than etc.
In 5:1 and be less than or equal to 10:1.
Further, the molar ratio of metallic element and P elements is 1 in the step 1:2.2, boron element and P elements rub
You are than being 5:1, the molar ratio of deionized water and P elements is 8:1.
Further, the metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent is (NH4)[ZnBP2O8], (NH4)16
[Zn16B8P24O96], NH4·M [BP2O8(OH)] （Wherein M=Fe, Al, Sc, In, Ga）And NH4·(X) (H2O)2
[BP2O8]·H2O（Wherein X=Zn, Cu, Fe, Ni, Mg, Mn, Co, Ca, Cd）One or more of combination.
Compared with prior art, implementation result of the invention is as follows by the present invention：
A kind of metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent preparation method of the present invention, metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent pair
Wood fibre filler and plastic substrate have good flame-proof smoke-suppressing in wood plastic composite, can be catalyzed to form fine and close carbon-coating
It is heat-insulated it is oxygen barrier prevent material internal from burning, and non-flammable compressive gas NH3 can be discharged in pyrolytic process and reach resistance to dilute fuel gas
Combustion suppression cigarette purpose, while the metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent of the present invention has additive amount low, and flame-retardant smoke inhibition is efficient etc.
Advantage, while the type anti-flaming smoke-inhibiting agent soda acid is mild, corrosion is relatively low, using hydro-thermal combination boric acid fusion method side of the present invention
Metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent prepared by method can carry out crystallization at relatively low temperatures, be conducive to improve gold
Belong to the yield of boron ammonium phosphate salt anti-flaming smoke-inhibiting agent, while product purity obtained is high, good dispersion, and without soda acid in reaction process
Discharging of waste liquid, consuming little energy.
Specific implementation mode
With reference to embodiment, the invention will be further described, but the present invention is not limited to these instances, and is being de-
Under the premise of from present inventive concept, carried out by it is any improvement be within the scope of the present invention.
Embodiment 1
A kind of metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent preparation method of the present invention, includes the following steps：Step 1, raw material are matched
System：Accurately each raw material component is weighed by following weight：3-7 parts of boron source, 8.719 parts of source metal, 20.404 parts of source of ammonium, deionization
10 parts of water；
Step 2, reacting processing：Load weighted medicament is added in the stainless steel cauldron with polytetrafluoroethyllining lining, then
It is added into reaction kettle and has weighed deionized water；
Step 3, room temperature cooling：Reaction kettle is put into baking oven, oven temperature is set as 100 DEG C ~ 220 DEG C, isothermal reaction 1 ~ 5
It is cooled down in room temperature after it；
Step 4, washing are filtered and are dried：It is washed repeatedly with deionized water for removing unreacted excessive boric acid, filters, dry
It is dry, you can to obtain metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent.
With excessive boron source and source metal and source of ammonium preparation raw material in step 1；Use liner for polytetrafluoro in step 3
The reaction kettle of ethylene；The product obtained to step 4 with deionized water in step 5 is washed repeatedly to remove excessive boron
Source；Most metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent is obtained through the suction filtration and the step of drying afterwards.Using hydro-thermal of the present invention
Crystallization can be carried out at relatively low temperatures in conjunction with metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent prepared by boric acid fusion method method
Reaction is conducive to the yield for improving metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent, while product purity obtained is high, good dispersion,
And it is discharged without acid-base waste fluid in reaction process, consuming little energy；The metal boron ammonium phosphate salt flame-retardant smoke inhibition manufactured by this method
Agent has good flame-proof smoke-suppressing to wood fibre in wood plastic composite and plastic substrate, and the duct for being similar to molecular sieve is tied
Structure and bigger serface have stronger absorption and catalytic capability, can be catalyzed to form fine and close carbon-coating heat insulation oxygen and prevent in material
Portion burns, and can discharge non-flammable compressive gas NH3 in pyrolytic process and reach flame-retardant smoke inhibition purpose, while this hair to dilute fuel gas
Bright metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent has many advantages, such as that additive amount is low, and flame-retardant smoke inhibition is efficient, while the type is fire-retardant
Smoke suppressant soda acid is mild, and corrosion is relatively low.
Embodiment 2
Present embodiment is boric acid difference lies in the boron source in the step 1 with specific implementation mode 1；The source of ammonium is
(NH4)2HPO4；The source metal is metal oxide, metal halide and its one or more of salt or metal salt.
Embodiment 3
Difference lies in the molar ratios of metallic element and P elements in the step 1 with specific implementation mode 1 or 2 for present embodiment
More than or equal to 1:4 and be less than or equal to 1:1；The molar ratio of boron element and P elements is more than or equal to 3:1 and be less than or equal to 8:1；Go from
The molar ratio of sub- water and P elements is more than or equal to 5:1 and be less than or equal to 10:1.
Embodiment 4
Difference lies in the molar ratios of metallic element and P elements in the step 1 to be for present embodiment and specific implementation mode 3
1:2.2；The molar ratio of boron element and P elements is 5:1；Deionized water and the molar ratio of P elements are 8:1.
Embodiment 5
Present embodiment is 180 DEG C difference lies in the temperature of the isoperibol with specific implementation mode 4, the reaction time 3
It.With this condition, product is obtained by the reaction, crystal particles are evenly distributed, and crystal form is more complete.
Embodiment 6
Metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent uses any one of specific implementation mode 1 to 5 metal boron ammonium phosphate salt
The preparation method of anti-flaming smoke-inhibiting agent is made；The metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent is (NH4) [ZnBP2O8], (NH4) 16
[Zn16B8P24O96], NH4M [BP2O8 (OH)]（Wherein M=Fe, Al, Sc, In, Ga）With NH4 (M) (H2O) 2
[BP2O8]·H2O（Wherein M=Zn, Cu, Fe, Ni, Mg, Mn, Co, Ca, Cd）One or more of combination.
Embodiment 7
An embodiment of the present invention provides a kind of preparation method of metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent, this method is accurate first
4.089g ZnCl2,8.716g (NH4) 2HPO4 and 20.404g H3BO3 are weighed, load weighted medicament is then added to band
Have in the stainless steel cauldron of polytetrafluoroethyllining lining, 10ml deionized waters are then added into reaction kettle again.Raw material proportioning is pressed
Molar ratio according to Zn and P is 1:The molar ratio of 2.2, B and P is 5:1, H2O with P molar ratios be 8:1；Reaction kettle is put into baking oven
In, oven temperature is set as 200 °C, and isothermal reaction cools down after 5 days in room temperature, is then washed repeatedly with deionized water for removing
Unreacted excess boric acid, filters, drying, you can obtain metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent (NH4) [ZnBP2O8].
Embodiment 8
An embodiment of the present invention provides a kind of preparation method of metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent, this method is first will
6.585g Zn (OAC) 22H2O, 8.716g (NH4) 2HPO4 and 20.404g H3BO3 are added directly into after precise
In stainless steel cauldron with polytetrafluoroethylene (PTFE), 10ml deionized waters are then added into kettle again；The raw material proportioning is pressed
Molar ratio according to Zn and P is 1:The molar ratio of 2.2, B and P is 5:1, H2O with P molar ratios be 8:1；Reaction kettle is put into baking oven
In, temperature setting is 180 °C, and isothermal reaction cools down after 5 days in room temperature, is then washed repeatedly with deionized water not anti-for removing
The excessive boric acid answered filters, drying, you can obtain metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent (NH4) 16 [Zn16B8P24O96].
Embodiment 9
An embodiment of the present invention provides a kind of preparation method of metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent, this method is accurate first
3.802g FeCl24H2O, 8.716g (NH4) 2HPO4 and 20.404g H3BO3 are weighed, then connects and is added to poly- four
In the stainless steel cauldron of vinyl fluoride lining, 10ml deionized waters are then added into kettle again；Raw material proportioning is rubbed according to Zn's and P
You are than being 1:The molar ratio of 2.2, B and P is 5:1, H2O with P molar ratios be 8:1；Reaction kettle is put into baking oven, temperature setting is
200 °C, isothermal reaction cools down after 5 days in room temperature, is then washed repeatedly with deionized water for removing unreacted excessive boric acid,
It filters, drying, you can obtain metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent NH4Fe III [BP2O8 (OH)].
Embodiment 10
An embodiment of the present invention provides a kind of preparation method of metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent, this method is accurate first
6.099g MgCl26H2O, 8.716g (NH4) 2HPO4 and 20.404g H3BO3 are weighed, then connects and is added to poly- four
In the stainless steel cauldron of vinyl fluoride lining, 10ml deionized waters are then added into kettle again；Raw material proportioning is rubbed according to Zn's and P
You are than being 1:The molar ratio of 2.2, B and P is 5:1, H2O with P molar ratios be 8:1；Reaction kettle is put into baking oven, temperature setting is
200 °C, isothermal reaction cools down after 5 days in room temperature, is then washed repeatedly with deionized water for removing unreacted excessive boric acid,
It filters, drying, you can obtain metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent NH4Mg (H2O) 2 [BP2O8] H2O.
Above content is only to present inventive concept example and explanation, affiliated those skilled in the art couple
Described specific embodiment does various modifications or additions or substitutes by a similar method, without departing from invention
Conceive or beyond the scope defined by this claim, is within the scope of protection of the invention.
Claims (9)
1. a kind of metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent preparation method, it is characterised in that：Include the following steps：
Step 1, raw material are prepared：Accurately each raw material component is weighed by following weight：3-7 parts of boron source, 8.719 parts of source metal, ammonium
20.404 parts of source, 10 parts of deionized water；
Step 2, reacting processing：Load weighted medicament is added in the stainless steel cauldron with polytetrafluoroethyllining lining, then
It is added into reaction kettle and has weighed deionized water；
Step 3, room temperature cooling：Reaction kettle is put into baking oven, oven temperature is set as 100 DEG C ~ 220 DEG C, isothermal reaction 1 ~ 5
It is cooled down in room temperature after it；
Step 4, washing are filtered and are dried：It is washed repeatedly with deionized water for removing unreacted excessive boric acid, filters, dry
It is dry, you can to obtain metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent.
2. a kind of metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent preparation method according to claim 1, it is characterised in that：The gold
The ZnCl that category source is 4.089 parts2, the source of ammonium is 8.716 parts of (NH4)2HPO4, the boron source is 20.404 parts of H3BO3,
The raw material proportioning is 1 according to the molar ratio of Zn and P:The molar ratio of 2.2, B and P is 5:1, H2O is 8 with P molar ratios:1；It is described
Oven temperature is set as 200 °C, and the metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent is (NH4)[ZnBP2O8]。
3. a kind of metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent preparation method according to claim 1, it is characterised in that：The gold
The Zn (OAC) that category source is 6.585 parts2·2H2The O, (NH that the source of ammonium is 8.716 parts4)2HPO4, the boron source is 20.404
The H of part3BO3, the raw material proportioning is 1 according to the molar ratio of Zn and P:The molar ratio of 2.2, B and P is 5:1, H2O and P molar ratios
It is 8:1, the oven temperature is set as 180 °C, and the metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent is (NH4)16
[Zn16B8P24O96]。
4. a kind of metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent preparation method according to claim 1, it is characterised in that：The gold
The FeCl that category source is 3.802 parts2·4H2The O, (NH that the source of ammonium is 8.716 parts4)2HPO4, the boron source is 20.404 parts
H3BO3, raw material proportioning is 1 according to the molar ratio of Zn and P:The molar ratio of 2.2, B and P is 5:1, H2O is 8 with P molar ratios:1, institute
It states oven temperature and is set as 200 °C, the metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent is NH4·FeⅢ [BP2O8(OH)]。
5. a kind of metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent preparation method according to claim 1, it is characterised in that：The gold
The MgCl that category source is 6.099 parts2·6H2The O, (NH that the source of ammonium is 8.716 parts4)2HPO4, the boron source is 20.404 parts
H3BO3, raw material proportioning is 1 according to the molar ratio of Zn and P:The molar ratio of 2.2, B and P is 5:1, H2O is 8 with P molar ratios:1, institute
It states oven temperature and is set as 200 °C, the metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent is NH4·Mg (H2O)2[BP2O8]·H2O。
6. a kind of metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent preparation method according to claim 1, it is characterised in that：The boron
Source is boric acid, and the source of ammonium is (NH4)2HPO4；The source metal is metal oxide, metal halide and its salt or metal salt
One or more of.
7. a kind of metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent preparation method according to claim 1, it is characterised in that：The step
The molar ratio of metallic element and P elements is more than or equal to 1 in rapid one:4 and be less than or equal to 1:1, the molar ratio of boron element and P elements
More than or equal to 3:1 and be less than or equal to 8:1, the molar ratio of deionized water and P elements is more than or equal to 5:1 and be less than or equal to 10:1.
8. a kind of metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent preparation method according to claim 1, it is characterised in that：The step
The molar ratio of metallic element and P elements is 1 in rapid one:2.2, the molar ratio of boron element and P elements is 5:1, deionized water with
The molar ratio of P elements is 8:1.
9. a kind of metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent preparation method according to claim 1, it is characterised in that：The gold
Category boron ammonium phosphate salt anti-flaming smoke-inhibiting agent is (NH4)[ZnBP2O8], (NH4)16[Zn16B8P24O96], NH4·M [BP2O8(OH)]
（Wherein M=Fe, Al, Sc, In, Ga）And NH4·(X) (H2O)2[BP2O8]·H2O（Wherein X=Zn, Cu, Fe, Ni, Mg, Mn,
Co, Ca, Cd）One or more of combination.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810216764.2A CN108529638A (en) | 2018-03-16 | 2018-03-16 | A kind of metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810216764.2A CN108529638A (en) | 2018-03-16 | 2018-03-16 | A kind of metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent preparation method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108529638A true CN108529638A (en) | 2018-09-14 |
Family
ID=63484157
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810216764.2A Pending CN108529638A (en) | 2018-03-16 | 2018-03-16 | A kind of metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108529638A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103333366A (en) * | 2013-06-24 | 2013-10-02 | 西南科技大学 | Layered double metal hydroxide based antiflaming smoke suppressant, preparation method thereof and antiflaming smoke suppressing compound material modified by using antiflaming smoke suppressant |
| CN104927086A (en) * | 2015-06-10 | 2015-09-23 | 安徽建筑大学 | Flame-retardant smoke-suppression agent and preparation method thereof |
| CN107286494A (en) * | 2016-03-31 | 2017-10-24 | 苏州奥凯高分子材料股份有限公司 | Phosphomolybdic acid zinc fire-resistant smoke-inhibiting PVC sheet material |
-
2018
- 2018-03-16 CN CN201810216764.2A patent/CN108529638A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103333366A (en) * | 2013-06-24 | 2013-10-02 | 西南科技大学 | Layered double metal hydroxide based antiflaming smoke suppressant, preparation method thereof and antiflaming smoke suppressing compound material modified by using antiflaming smoke suppressant |
| CN104927086A (en) * | 2015-06-10 | 2015-09-23 | 安徽建筑大学 | Flame-retardant smoke-suppression agent and preparation method thereof |
| CN107286494A (en) * | 2016-03-31 | 2017-10-24 | 苏州奥凯高分子材料股份有限公司 | Phosphomolybdic acid zinc fire-resistant smoke-inhibiting PVC sheet material |
Non-Patent Citations (3)
| Title |
|---|
| MIN LI ETC.: "Open-Framework Manganese(II) and Cobalt(II) Borophosphates with Helical Chains: Structures, Magnetic, and Luminescent Properties", 《INORGANIC CHEMISTRY》 * |
| RÜDIGER KNIEP ETC.: "K[ZnBP2O8] and A[ZnBP2O8] (A=NH4+，Rb+, Cs+): Zincoborophosphates as a New Class of Compounds with Tetrahedral Framework Structures", 《ANGEW. CHEM. INT. ED. 》 * |
| YA-XI HUANG ETC.: "Open-Framework Borophosphates: (NH4)0.4FeII0.55FeIII0.5(H2O)2[BP2O8]•0.6H2O and NH4FeIII[BP2O8(OH)]", 《CHEM. MATER.》 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102321274B (en) | Hydrotalcite-ammonium polyphosphate halogen-free flame retardant and preparation method thereof | |
| CN100567456C (en) | A kind of fire retardant and preparation method thereof | |
| CN103012904B (en) | Halogen-free flame-retardant master batch | |
| CN102975251B (en) | Flame retardant for wood as well as preparation method and applications of flame retardant for wood | |
| CN101362835A (en) | Surface treating method of magnesium hydrate combustion inhibitor | |
| CN107189478A (en) | A kind of straw refuse regenerated environment protecting abrasion resistant fire blocking sheet material and preparation method thereof | |
| CN107117927B (en) | A kind of environmental protection flame retardant stalk board | |
| CN102838815A (en) | Preparation method for flame-retardant foamed polystyrene resin | |
| CN104210002B (en) | A kind of composite flame-retardant agent, preparation method and its usage | |
| CN102975250A (en) | Wood modifier and preparation method thereof | |
| CN108034074A (en) | A kind of metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent and preparation method thereof | |
| CN108529638A (en) | A kind of metal boron ammonium phosphate salt anti-flaming smoke-inhibiting agent preparation method | |
| CN109054098A (en) | A kind of piperazine modified lignin resin/aluminum phosphate dual cladding red phosphorus combustion inhibitor and its application in HIPS | |
| CN105984888A (en) | Process for preparing hydrogen cyanamide by utilizing urea | |
| CN102975246B (en) | Wood treatment agent and preparation method thereof | |
| CN103496681A (en) | Method for preparing aluminum hypophosphite | |
| CN110845779A (en) | Modified composite flame-retardant TPO resin and preparation method thereof | |
| CN105907033A (en) | Preparation method of flame-retardant artificial stone containing nano perovskite oxide | |
| CN102942796B (en) | Flame retardant wood composite door core material and preparation method thereof | |
| CN102975252A (en) | Wood treatment agent and preparation method thereof | |
| CN106589510B (en) | A kind of preparation method of fire-resistant cable material | |
| CN101805619B (en) | Method for preparing nitrogen-phosphorus fire retardant | |
| CN108358513A (en) | A kind of Environment-friendlywear-resistant wear-resistant heat-insulating and fire-proof composite board and preparation method thereof | |
| CN108003694A (en) | The composition and preparation method of a kind of water-borne acrylic coatings halogen-free expanded flame-retardant agent | |
| CN104647542A (en) | High-efficiency eco-friendly smoke-inhibition timber fire retardant and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20180914 |
|
| WD01 | Invention patent application deemed withdrawn after publication |