CN108525499A - Reverse spray tower and bubble tower series operation desulphurization system adjustment control method - Google Patents

Reverse spray tower and bubble tower series operation desulphurization system adjustment control method Download PDF

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Publication number
CN108525499A
CN108525499A CN201810418333.4A CN201810418333A CN108525499A CN 108525499 A CN108525499 A CN 108525499A CN 201810418333 A CN201810418333 A CN 201810418333A CN 108525499 A CN108525499 A CN 108525499A
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CN
China
Prior art keywords
tower
reverse spray
spray tower
bubble
bubble tower
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810418333.4A
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Chinese (zh)
Inventor
曹建军
唐小健
卓华
甘超齐
王九崇
程江
张强
孙灏
付林
沈艳梅
张辉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
China Shenhua Energy Co Ltd
Beijing Guohua Electric Power Co Ltd
Shenhua Guohua Beijing Electric Power Research Institute Co Ltd
Guangdong Guohua Yuedian Taishan Power Generation Co Ltd
Original Assignee
China Shenhua Energy Co Ltd
Beijing Guohua Electric Power Co Ltd
Shenhua Guohua Beijing Electric Power Research Institute Co Ltd
Guangdong Guohua Yuedian Taishan Power Generation Co Ltd
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Publication date
Application filed by China Shenhua Energy Co Ltd, Beijing Guohua Electric Power Co Ltd, Shenhua Guohua Beijing Electric Power Research Institute Co Ltd, Guangdong Guohua Yuedian Taishan Power Generation Co Ltd filed Critical China Shenhua Energy Co Ltd
Priority to CN201810418333.4A priority Critical patent/CN108525499A/en
Publication of CN108525499A publication Critical patent/CN108525499A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/78Liquid phase processes with gas-liquid contact
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treating Waste Gases (AREA)

Abstract

The present invention relates to flue gas desulfurization technique field, a kind of reverse spray tower and bubble tower series operation desulphurization system adjustment control method are disclosed, is included the following steps:It connects reverse spray tower at bubble tower smoke inlet end, the reverse spray tower is one or in parallel multiple;Sulfur-containing smoke gas initially enters the reverse spray tower, and desulphurization reaction is carried out with sprayed slurry in the reverse spray tower, enters back into the bubble tower and carries out desulphurization reaction, flue gas up to standard is discharged by demister;The sprayed slurry is pumped out by an at least frequency conversion slurry circulating pump out of described bubble tower, according to the payload of generating set, is controlled the frequency of the frequency conversion slurry circulating pump and/or is adjusted the liquid level of the bubble tower, to adjust desulfuration efficiency.The present invention uses reverse spray tower and the concatenated high efficiency flue gas desulfurization technology of bubble tower, can desulfuration efficiency be increased to 98.5% or more by being bubbled the 95 97% of tower process originally, to meet the requirement of the increasing environmentally friendly minimum discharge standard of country at present.

Description

Reverse spray tower and bubble tower series operation desulphurization system adjustment control method
Technical field
The invention belongs to flue gas desulfurization technique fields, more particularly to a kind of reverse spray tower and bubble tower series operation desulfurization system System adjustment control method.
Background technology
Bubble tower flue gas desulfurization technique:Boiler smoke first passes through gas cooler cooling, flue gas cooling before entering bubble tower Device top is equipped with slurries spraying layer, flue gas in gas cooler with enter bubble tower after sprayed slurry fair current combination cooling, The sulfur dioxide in flue gas is removed by bubble tower, is then discharged into air by chimney after demister removes droplet.Bubble tower Inlet flue gas cooler has the characteristics that flue gas flow rate is high, and using flue gas and slurries co-current contact mode, main function is fast Quickly cooling is but, less efficient to sulfur dioxide removal.In the Limestone-gypsum Wet Flue Gas Desulfurization Process technique being widely used at present, it is bubbled Tower has the characteristics that desulfuration efficiency is stable, load adaptability is strong, operation adjustment is simple, but bubble tower desulfuration efficiency is generally stablized 95-97% cannot meet the requirement of the increasing environmentally friendly minimum discharge standard of country at present.Due to existing bubbling Tower System National environmental protection minimum discharge requirement cannot be met, newly-built spray column investment is larger again, from the point of view of investment reduction, to drum Bubble column reuses, by increase reverse spray tower, make reverse spray tower connect to form new desulphurization system with bubble tower, reach meet it is ultralow The requirement of discharge and optimal working point is reached by adjustment control method.
Application publication number discloses a kind of using adverse current opposite-flushing type turbulence washing tower for the patent of invention of CN106139866A Waste gas treatment process and device, exhaust gas enters the inverse spray rinsing pipe of countercurrent washing tower through heat exchanger, inverse with the level-one of upward jet flow Spray, the inverse spray of two level or the inverse spray of three-level absorb fluid circulation and are in contact to obtain blend absorbent, then fair current enters countercurrent washing tower Bottom, into bubble cleaning area, which is liquidated using gas-liquid, increases contact specific surface area of the exhaust gas with absorbing liquid, is formed rapid Foamed cleaning area is flowed, the inverse spray of innovative design three-level absorbs fluid circulation, and nominal situation enables level-one or the inverse spray of two level recycles, and gives up Wave starts building the inverse spray of condition three-level while to start, simple in structure, mass-transfer efficiency is high, floor space is small.But the three-level of the invention is inverse Upper level can influence absorption processing of the next stage against spray system to exhaust gas against spray system when spraying Cascade System, while opening, and influence Desulfurization effect, and desulfuration efficiency cannot be adjusted control.
Invention content
It is de- with bubble tower series operation the purpose of the invention is to overcome the deficiencies of the prior art and provide a kind of reverse spray tower Sulphur system adjustment control method, the adjustment control method can be improved desulfuration efficiency by the 95-97% for being bubbled tower process originally To 98.5% or more, to meet the requirement of the increasing environmentally friendly minimum discharge standard of country at present.
To achieve the goals above, a kind of reverse spray tower of present invention offer and bubble tower series operation desulphurization system adjusting control Method includes the following steps:
(1) it connects reverse spray tower at bubble tower smoke inlet end, the reverse spray tower is one or in parallel multiple;
(2) sulfur-containing smoke gas initially enters the reverse spray tower, and desulphurization reaction is carried out with sprayed slurry in the reverse spray tower, then Desulphurization reaction is carried out into the bubble tower, flue gas up to standard is discharged by demister;
The sprayed slurry is pumped out by an at least frequency conversion slurry circulating pump out of described bubble tower, according to generating set Payload controls the frequency of the frequency conversion slurry circulating pump and/or adjusts the liquid level of the bubble tower, to adjust desulfurization effect Rate.
Preferably, the tower body bottom of the bubble tower is equipped with slurries pipeline, and the slurries pipeline is connected with the reverse spray tower It connects, the frequency conversion slurry circulating pump is located on the slurries pipeline.
Preferably, slurry reflux pipe is equipped between the bubble tower and the reverse spray tower, slurry reflux pipe one end is set In reverse spray tower bottom, the other end extends to the slurry pool of the bubble tower from the reverse spray tower bottom angled.
Preferably, the reverse spray tower is four, and the frequency conversion slurry circulating pump is three, three frequency conversion serum recycles Parallel connection of pumps.
Preferably, when the generating set load is less than 450MW, by the running frequency tune of the frequency conversion slurry circulating pump Section is 40-48Hz, and the bubble tower liquid level is adjusted to 120-200mm, the sprayed slurry pH value is adjusted to 4-5.3.
Preferably, when the generating set load is 500-600MW, by the running frequency of the frequency conversion slurry circulating pump It is adjusted to 40-42Hz, the bubble tower liquid level is adjusted to 90-100mm, the sprayed slurry pH value is adjusted to 5.2-5.6.
Preferably, when the generating set load is 600-630MW, by the running frequency of the frequency conversion slurry circulating pump It is adjusted to 38-39Hz, the bubble tower liquid level is adjusted to 80-90mm, the sprayed slurry pH value is adjusted to 5.3-5.9.
Preferably, each reverse spray tower accesses the smoke inlet end that component selectively accesses the bubble tower by selection.
Preferably, the selection access component includes the gas baffle being located at the smoke inlet of the reverse spray tower, described The smoke inlet that gas baffle is used to control the reverse spray tower opens or closes.
Preferably, the selection access component further includes entering or not entering the inverse spray for controlling the sprayed slurry The slurries control valve of tower.
Preferably, the slurries control valve is located at the slurries branch pipe for the slurries pipeline to be connect with the reverse spray tower On.
The present invention substitutes gas cooler using reverse spray tower, using reverse spray tower and the concatenated high-efficiency flue gas desulfurization work of bubble tower Desulfuration efficiency can be increased to 98.5% or more by skill by the 95-97% for being bubbled tower process originally, to meet national day at present The requirement for the environmentally friendly minimum discharge standard that benefit improves.
Description of the drawings
Fig. 1 is the structural schematic diagram of inventive desulfurization system.
Reference sign:
1 reverse spray tower, 2 slurries control valve
3 slurries branch pipe, 4 slurries pipeline
5 frequency conversion slurry circulating pump, 6 slurry reflux pipe
7 bubble tower, 8 demister
9 gas baffles
Specific implementation mode
It should be noted that in the absence of conflict, the feature in embodiment and embodiment in the present invention can To be combined with each other.
A kind of reverse spray tower of present invention offer and bubble tower series operation desulphurization system adjustment control method, Fig. 1 is reverse spray tower With the structural schematic diagram of bubble tower series operation desulphurization system, inventive desulfurization system adjustment control method includes the following steps:
(1) it connects reverse spray tower 1 at 7 smoke inlet end of bubble tower, the reverse spray tower 1 is one or in parallel multiple;
(2) sulfur-containing smoke gas initially enters the reverse spray tower 1, and desulphurization reaction is carried out with sprayed slurry in the reverse spray tower 1, It enters back into the bubble tower 7 and carries out desulphurization reaction, flue gas up to standard is discharged by demister 8;
The sprayed slurry is pumped out by an at least frequency conversion slurry circulating pump 5 out of the bubble tower 7, according to generating set Payload, control the frequency of the frequency conversion slurry circulating pump 5 and/or adjust the liquid level of the bubble tower 7, to adjust desulfurization Efficiency.
The present invention cannot meet the shape of national environmental protection minimum discharge requirement for existing bubble tower desulphurization system discharge index Condition, substituting gas cooler using reverse spray tower 1 can using 7 concatenated high efficiency flue gas desulfurization technology of reverse spray tower 1 and bubble tower Desulfuration efficiency is increased to 98.5% or more by the 95-97% for being bubbled tower process originally, is increasingly improved to meet country at present Environmentally friendly minimum discharge standard requirement.
The cardinal principle of reverse spray tower 1 is that flue gas enters at the top of tower body, and sprayed slurry passes through the inverse spraying nozzle in reverse spray tower 1 It is up sprayed from tower lower part, forms certain floating level layer, the sulfur dioxide in flue gas and sprayed slurry in 1 tower of reverse spray tower The mixing that liquidates comes into full contact with generation reactive absorption.
It is top-down, reverse spray tower into the flue gas in the gas cooler before bubble tower 7 from flue gas flow Flue gas flow in 1 tower is also top-down, and only the slurries injection direction of the two is different.Due to gas cooler slurries with Flue gas is fair current, therefore time of contact, and mixability is limited, and the principle of reverse spray tower 1 is then different, by reverse spray tower 1 The flue gas of interior high speed is liquidated and is mixed with the sprayed slurry fierceness of convection current, extends the hybrid reaction time in this section and increase liquid gas Than improving the desulfuration efficiency of this section.Gas cooler mainly plays the role of cooled flue gas, and the main function of reverse spray tower 1 is The effect of desulfurization is carried out, certainly due to needing to reach certain desulfuration efficiency, 1 sprayed slurry amount of reverse spray tower is also larger, naturally right The cooling effect of flue gas is also more preferable.Therefore original gas cooler is substituted with reverse spray tower 1, in the condition for ensureing cooling effect Under, local desulfuration efficiency can be more improved, bulk devulcanization efficiency is improved with this.In addition, reverse spray tower 1 be suitable for be arranged in place by The region of limit, especially suitable for desulfurizing fly ash project.
The present invention is according to generating set load condition, by the frequency and the adjusting that control the frequency conversion slurry circulating pump 5 7 liquid level of the bubble tower adjusts desulfuration efficiency, and it is four which, which configures reverse spray tower 1, frequency conversion slurry circulating pump 5 It it is three, three frequency conversion slurry circulating pumps 5 are in parallel, and one of frequency conversion slurry circulating pump 5 is spare, the invention desulphurization system Specifically adjustment control method is:
When the load of the generating set is less than 450MW, the running frequency of the frequency conversion slurry circulating pump 5 is adjusted to 40-48Hz, 120-200mm is adjusted to by 7 liquid level of the bubble tower, and the sprayed slurry pH value is adjusted to 4-5.3.
When the load of the generating set is 500-600MW, the running frequency of the frequency conversion slurry circulating pump 5 is adjusted For 40-42Hz, 7 liquid level of the bubble tower is adjusted to 90-100mm, the sprayed slurry pH value is adjusted to 5.2-5.6.
When the load of the generating set is 600-630MW, the running frequency of the frequency conversion slurry circulating pump 5 is adjusted For 38-39Hz, 7 liquid level of the bubble tower is adjusted to 80-90mm, the sprayed slurry pH value is adjusted to 5.3-5.9.
Because desulfuration efficiency is contributed more in promotion of the raising of 7 small liquid level of bubble tower than 5 frequency of frequency conversion slurry circulating pump Obviously, therefore, under high load capacity (500-630MW) unusual service condition, 5 frequency of frequency conversion slurry circulating pump can be adjusted down, is carried 7 small liquid level of bubble tower is risen, by bubble tower 7 to the stronger absorbability of sulfur dioxide to ensure qualified discharge.
Preferably, the tower body bottom of the bubble tower 7 is equipped with slurries pipeline 4, the slurries pipeline 4 and the reverse spray tower 1 It is connected, the frequency conversion slurry circulating pump 5 is located on the slurries pipeline 4.
Preferably, slurry reflux pipe 6 is equipped between the bubble tower 7 and the reverse spray tower 1 so that reverse spray tower 1 and bubbling Tower 7 shares the slurry pool of 7 bottom of bubble tower, and after sprayed slurry completes spray in reverse spray tower 1, slurries pass through slurry reflux pipe 6 It is back to slurry pool, recirculates and uses after being focused on to slurries in slurry pool.It is further preferred that the slurries 6 one end of return duct is located at 1 bottom of reverse spray tower, and the other end extends to the slurries of the bubble tower 7 from 1 bottom angled of the reverse spray tower Pond.In this way, the slurries flowed out out of reverse spray tower 1 have preferable mobility in the slurry reflux pipe 6 being obliquely installed, can keep away Exempt from deposition of the slurries in return duct to block.
Preferably, each reverse spray tower 1 accesses the smoke inlet that component selectively accesses the bubble tower 7 by selection End.
Specifically, the selection access component includes the gas baffle 9 being located at the smoke inlet of the reverse spray tower 1, institute It states gas baffle 9 and is opened or closed for controlling the smoke inlet of the reverse spray tower 1.It can be by controlling the gas baffle 9 Folding angle and the liquid level of the bubble tower 7 adjust desulfuration efficiency.
Specifically, the selection access component further includes entering or not entering the inverse spray for controlling the sprayed slurry The slurries control valve 2 of tower 1.Further specifically, the slurries control valve 2 be located at for by the slurries pipeline 4 with it is described inverse It sprays on the slurries branch pipe 3 that tower 1 connects.
Component is accessed by the way that the selection is arranged, when the reverse spray tower 1 being connected in series with the bubble tower 7 is multiple in parallel When reverse spray tower, it can be stopped inverse by suitably closing one or more gas baffles 9 according to generating set load operating conditions The supply of flue gas in tower 1 is sprayed, while stopping spray in one or more reverse spray towers 1 by suitably closing the slurries control valve 2 The supply of leaching slurries achievees the purpose that energy-saving to stop the operation of one or more reverse spray towers 1.
The specific implementation mode of the present invention is described in detail above in association with attached drawing, still, the present invention is not limited thereto.It is all Within the spirit and principles in the present invention, any modification, equivalent replacement, improvement and so on should be included in the protection of the present invention Within the scope of.

Claims (11)

1. a kind of reverse spray tower and bubble tower series operation desulphurization system adjustment control method, which is characterized in that include the following steps:
(1) in bubble tower (7) smoke inlet end series connection reverse spray tower (1), the reverse spray tower (1) is one or in parallel multiple;
(2) sulfur-containing smoke gas initially enters the reverse spray tower (1), and desulphurization reaction is carried out with sprayed slurry in the reverse spray tower (1), It enters back into the bubble tower (7) and carries out desulphurization reaction, flue gas up to standard is discharged by demister (8);
The sprayed slurry is pumped out by an at least frequency conversion slurry circulating pump (5) out of the bubble tower (7), according to generating set Payload, control the frequency of the frequency conversion slurry circulating pump (5) and/or adjust the liquid level of the bubble tower (7), to adjust Desulfuration efficiency.
2. reverse spray tower according to claim 1 and bubble tower series operation desulphurization system adjustment control method, feature exist In the tower body bottom of the bubble tower (7) is equipped with slurries pipeline (4), and the slurries pipeline (4) is connected with the reverse spray tower (1) It connects, the frequency conversion slurry circulating pump (5) is located on the slurries pipeline (4).
3. reverse spray tower according to claim 1 and bubble tower series operation desulphurization system adjustment control method, feature exist In equipped with slurry reflux pipe (6) between the bubble tower (7) and the reverse spray tower (1), described slurry reflux pipe (6) one end is set In reverse spray tower (1) bottom, the other end extends to the slurry pool of the bubble tower (7) from the reverse spray tower (1) bottom angled.
4. reverse spray tower according to claim 1 and bubble tower series operation desulphurization system adjustment control method, feature exist In the reverse spray tower (1) is four, and the frequency conversion slurry circulating pump (5) is three, three frequency conversion slurry circulating pumps (5) It is in parallel.
5. reverse spray tower according to claim 4 and bubble tower series operation desulphurization system adjustment control method, feature exist In, when the load of the generating set be less than 450MW when, the running frequency of the frequency conversion slurry circulating pump (5) is adjusted to 40- The liquid level of 48Hz, the bubble tower (7) are adjusted to 120-200mm, and the sprayed slurry pH value is adjusted to 4-5.3.
6. reverse spray tower according to claim 4 and bubble tower series operation desulphurization system adjustment control method, feature exist In, when the load of the generating set be 500-600MW when, the running frequency of the frequency conversion slurry circulating pump (5) is adjusted to 40-42Hz, 90-100mm is adjusted to by the liquid level of the bubble tower (7), and the sprayed slurry pH value is adjusted to 5.2-5.6.
7. reverse spray tower according to claim 4 and bubble tower series operation desulphurization system adjustment control method, feature exist In, when the load of the generating set be 600-630MW when, the running frequency of the frequency conversion slurry circulating pump (5) is adjusted to The bubble tower (7) liquid level is adjusted to 80-90mm, the sprayed slurry pH value is adjusted to 5.3-5.9 by 38-39Hz.
8. reverse spray tower according to claim 2 and bubble tower series operation desulphurization system adjustment control method, feature exist In each reverse spray tower (1) accesses the smoke inlet end that component selectively accesses the bubble tower (7) by selection.
9. reverse spray tower according to claim 8 and bubble tower series operation desulphurization system adjustment control method, feature exist In the selection access component includes the gas baffle (9) being located at the smoke inlet of the reverse spray tower (1), the flue gas gear The smoke inlet that plate (9) is used to control the reverse spray tower (1) opens or closes.
10. reverse spray tower according to claim 8 and bubble tower series operation desulphurization system adjustment control method, feature exist In the selection access component further includes the slurries for entering or not entering the reverse spray tower (1) for controlling the sprayed slurry Control valve (2).
11. reverse spray tower according to claim 10 and bubble tower series operation desulphurization system adjustment control method, feature It is, the slurries control valve (2) is located at the slurries branch pipe for the slurries pipeline (4) to connect with the reverse spray tower (1) (3) on.
CN201810418333.4A 2018-05-04 2018-05-04 Reverse spray tower and bubble tower series operation desulphurization system adjustment control method Pending CN108525499A (en)

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CN201810418333.4A CN108525499A (en) 2018-05-04 2018-05-04 Reverse spray tower and bubble tower series operation desulphurization system adjustment control method

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110813053A (en) * 2019-12-19 2020-02-21 厦门市兆泰云智能科技有限公司 Lithium battery combustion flue gas treatment system for charging station and treatment method thereof
CN115246735A (en) * 2022-08-01 2022-10-28 河北浩锐陶瓷制品有限公司 Production process of energy-saving environment-friendly ceramic tile

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201058282Y (en) * 2007-07-03 2008-05-14 杨东 Sea water desulfurization system
CN202263522U (en) * 2011-10-25 2012-06-06 华电环保系统工程有限公司 Flue gas desulfurization serial-column device

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201058282Y (en) * 2007-07-03 2008-05-14 杨东 Sea water desulfurization system
CN202263522U (en) * 2011-10-25 2012-06-06 华电环保系统工程有限公司 Flue gas desulfurization serial-column device

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110813053A (en) * 2019-12-19 2020-02-21 厦门市兆泰云智能科技有限公司 Lithium battery combustion flue gas treatment system for charging station and treatment method thereof
CN110813053B (en) * 2019-12-19 2021-12-03 厦门市兆泰云智能科技有限公司 Processing method of lithium battery combustion flue gas processing system for charging station
CN115246735A (en) * 2022-08-01 2022-10-28 河北浩锐陶瓷制品有限公司 Production process of energy-saving environment-friendly ceramic tile

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