CN108504237A - A kind of antiseptic and rustproof insulating moulding coating of water-based metal - Google Patents
A kind of antiseptic and rustproof insulating moulding coating of water-based metal Download PDFInfo
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- CN108504237A CN108504237A CN201810355207.9A CN201810355207A CN108504237A CN 108504237 A CN108504237 A CN 108504237A CN 201810355207 A CN201810355207 A CN 201810355207A CN 108504237 A CN108504237 A CN 108504237A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
- C08K2003/2272—Ferric oxide (Fe2O3)
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/327—Aluminium phosphate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/28—Nitrogen-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
- C08K7/24—Expanded, porous or hollow particles inorganic
- C08K7/28—Glass
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention provides a kind of antiseptic and rustproof insulating moulding coating of water-based metal, and raw material includes following components by weight：30 40 parts of silicon benzene lotion, 10 20 parts of iron oxide red, 36 parts of trbasic zinc phosphate, 13 parts of aluminium triphosphate, 5 10 parts of mica powder, 36 parts of titanium dioxide, 10 20 parts of talcum powder, 36 parts of hollow glass micropearl, 0.1 0.3 parts of sodium nitrite composite corrosion inhibitor, 0.3 0.5 parts of wetting agent, 0.5 1.0 parts of dispersant, 0.2 0.5 parts of antifoaming agent, 1.0 2.5 parts of coalescents, 0.5 0.8 parts of thickener, 13 parts of antifreezing agent, 20 30 parts of deionized water.
Description
Technical field
The present invention relates to a kind of coating, and in particular to a kind of antiseptic and rustproof insulating moulding coating of water-based metal and preparation method thereof.
Background technology
" insulating moulding coating "：Refer to a kind of blocking to grow up in recent years, reflection, the function of radiating sunlight near-infrared heat
Property water paint, enables roof insulation cool down, energy-saving.With heat-insulated, waterproof, antirust, anti-corrosion, short time limit, quick spy
Property, replace water sprinkler system, heat-preservation cotton, foam sponge, interlayer iron sheet etc. comprehensively.Insulating moulding coating mainly has from the classification of characteristic principle
Three kinds, isolation conduction type insulating moulding coating, reflective insulation coating and Radiation Heat-insulated Paint.In addition to the heat-insulated painting of above-mentioned three types
Have there is a kind of thermal insulation paint in material, external heat insulating function coating, other than having the advantages of above-mentioned insulating moulding coating, more
Has peculiar heat insulation effect.Insulating moulding coating can be divided into 3 kinds of isolation-type, reflection-type and radial pattern according to insulating mechanism, wherein hindering
Belong to thick matter traditional coating every type insulating moulding coating, insulating mechanism is that impedance heat is transmitted, technology relative maturity；Radiation type heat-insulation
Coating be the sunshine light heat that building absorbs is emitted to certain wavelength in air by the form of radiation reach every
Heat drop temperature；The insulating mechanism of reflective insulation coating is reflected sunlight.
Currently, insulating moulding coating type is various, it is widely used in many fields.The big portion in existing insulating moulding coating
Point be all single effect insulating moulding coating it is relatively more, there are no it is a it is qualified, security performance is high, have antiseptic property, prevent
The sale of the antiseptic and rustproof insulating moulding coating of water-based metal of performance of becoming rusty and the several functions of insulating moulding coating.
Invention content
The purpose of the present invention provides a kind of antiseptic and rustproof insulating moulding coating of water-based metal, the one kind aiming at existing issue
The antiseptic and rustproof insulating moulding coating of water-based metal is using aqueous silicon benzene lotion as film forming matter, the iron oxide red of addition, trbasic zinc phosphate, trimerization phosphorus
Simultaneously part of auxiliary is added in sour aluminium, mica powder, titanium dioxide, talcum powder, hollow glass micropearl, sodium nitrite composite corrosion inhibitor, prepares
A kind of obtained antiseptic and rustproof insulating moulding coating of water-based metal.A kind of this kind of antiseptic and rustproof insulating moulding coating of water-based metal not only has good
Good resistance to salt water, acid resistance, alkali resistance, resistance to neutral salt spray and high adhesion force, and with also with good reflectivity,
The advantages that thermal insulation, the feature of environmental protection, dicoration, anticorrosive property, rust-preventing characteristic.
It is a further object of the present invention to provide the preparation methods of the antiseptic and rustproof insulating moulding coating of this kind of water-based metal.
Above-mentioned purpose to realize the present invention, a kind of antiseptic and rustproof insulating moulding coating of water-based metal of the present invention use following technical side
Case：A kind of antiseptic and rustproof insulating moulding coating of water-based metal, raw material include following components by weight：30-40 parts of silicon benzene lotion,
10-20 parts of iron oxide red, 3-6 parts of trbasic zinc phosphate, 1-3 parts of aluminium triphosphate, 5-10 parts of mica powder, 3-6 parts of titanium dioxide, talcum powder
10-20 parts, 3-6 parts of hollow glass micropearl, 0.1-0.3 parts of sodium nitrite composite corrosion inhibitor, 0.3-0.5 parts of wetting agent, dispersant
0.5-1.0 parts, 0.2-0.5 parts of antifoaming agent, 1.0-2.5 parts of coalescents, 0.5-0.8 parts of thickener, 1-3 parts of antifreezing agent,
20-30 parts of deionized water.
Further, the titanium dioxide is rutile type titanium white, and grain size is 100~150 μm.
Further, the talcum powder was 1000-1500 mesh sieve pulvis.
Further, the hollow glass micropearl is the hollow beads of 50~100 μm of grain size.
Further, the dispersant is 731A dispersants and calgon, and the best weight ratio of the two is 4：
3。
Further, the antifoaming agent is the mixing of one or both of organic silicon defoamer, mineral oil antifoam agent.
Further, the antifreezing agent is ethylene glycol.
Further, preparation method includes the following steps：
S10, as required weigh formula in amount material；
S11, wetting agent, dispersant, part antifoaming agent, part thickener is added in water successively, stirs evenly, oxygen is then added
Change iron oxide red, trbasic zinc phosphate, aluminium triphosphate, mica powder, titanium dioxide, the uniform 20-30min of talcum powder color stuffing high-speed stirred；
It S12 and then hollow glass micropearl is added under conditions of middling speed is dispersed with stirring 10-20min, then be added under stirring at low speed
Silicon benzene lotion, sodium nitrite composite corrosion inhibitor, coalescents, antifreezing agent, remaining antifoaming agent, finally add remaining thickener
Viscosity is adjusted, is filtered to get a kind of antiseptic and rustproof insulating moulding coating of water-based metal.
It is compared with the prior art, the invention has the advantages that：
1, it is closed hollow ball using hollow glass micropearl in a kind of antiseptic and rustproof insulating moulding coating of water-based metal of the present invention, it is internal
It is vacuum either N2, CO2 gas, there is sound insulation, heat-insulated, insulation characterisitic, its ball shape can provide than sheet, needle-shaped
And the better mobility of irregular shape filler particle, make coating that there is isotropism, so that stress is uniformly dispersed, painting can be reduced
Stress cracking of the layer because of generation of expanding with heat and contract with cold.Wherein hollow glass micropearl has lower thermal coefficient, is added in coating empty
Heart glass microballoon plays the role of reflective insulation；
2, the heat-insulated painting obtained by the preparation of hollow glass micropearl is added in a kind of antiseptic and rustproof insulating moulding coating of water-based metal of the present invention
Material is the heat insulation function coating that a kind of heat preservation and insulation is excellent, environmental-friendly, by the heat insulating coatings coating every
The research of thermal effect is that heat insulating coatings performance prepared by color stuffing is stable, heat insulating function is strong with vacuum glass microballoon etc., makees
It is used for insulating layer of external wall of building, is a kind of effective power-economizing method, be especially 58 μm of left sides in the grain size of hollow glass microballoon
When right, insulating moulding coating has suitable thermal conductivity, the thermal conductivity than the hollow glass microballoon insulating moulding coating of other grain sizes low 6-
28%；When hollow glass microballoon content is less than 10%, heat reflectivity is dramatically increased with the increase of hollow glass microbead content；When
After hollow glass microbead content reaches 10%, the increase reduced rate of coating heat reflectivity, when hollow glass microbead content reaches
When 12%, the heat reflectivity value highest of coating continues growing the content of coating hollow glass microbead, heat reflectivity almost no longer increases
Greatly.Therefore hollow glass microbead content be 10%-12% when, coating have best heat reflectivity；
3, the iron oxide red that is added in a kind of antiseptic and rustproof insulating moulding coating of water-based metal of the present invention, trbasic zinc phosphate, aluminium triphosphate and
Sodium nitrite composite corrosion inhibitor is certainly as the antiseptic and rustproof insulating moulding coating of a kind of water-based metal that antiseptic and rustproof substance is prepared
Dryness coating, performance technologies index test result is better than red lead phenolic aldehyde room rust coating and lead red alcohol acid antirusting paint.The coating
With good resistance to salt water, corrosion resistance, paint film adhesion is strong, tough and tensile secured, can be matched with all kinds of paints；And with water
Nonhazardous, non-ignitable not quick-fried for solvent, environmental pollution is few.Convenient for storage transport and construction application, securely and reliably.The paint application
Extensively, the anticorrosive coating on the surfaces such as big machinery, vehicle, ship, bridge, boiler storage tank；
4, the antiseptic and rustproof insulating moulding coating of a kind of water-based metal of the invention not only has good resistance to salt water, acid resistance, alkaline-resisting
Property, resistance to neutral salt spray and high adhesion force, and with also with good reflectivity, thermal insulation, the feature of environmental protection, dicoration, anti-
The advantages that corrosivity, rust-preventing characteristic.
Specific implementation mode
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiments, to the present invention
It is further elaborated.The specific embodiments described herein are merely illustrative of the present invention, is not used to limit
The present invention.
Embodiment 1
A kind of antiseptic and rustproof insulating moulding coating of water-based metal, raw material include following components by weight：30 parts of silicon benzene lotion, oxidation
10 parts of iron oxide red, 3 parts of trbasic zinc phosphate, 1 part of aluminium triphosphate, 5 parts of mica powder, 3 parts of titanium dioxide, 10 parts of talcum powder, hollow glass micropearl
3 parts, 0.1 part of sodium nitrite composite corrosion inhibitor, 0.3 part of wetting agent, 0.5 part of dispersant, 0.2 part of antifoaming agent, coalescents 1.0
Part, 0.5 part of thickener, 1 part of antifreezing agent, 20 parts of deionized water.
The titanium dioxide is rutile type titanium white, and grain size is 100 μm.
The talcum powder was 1000 mesh sieve pulvis.
The hollow glass micropearl is the hollow beads of 50 μm of grain size.
The dispersant is 731A dispersants and calgon, and the best weight ratio of the two is 4：3.
The antifoaming agent is organic silicon defoamer.
The antifreezing agent is ethylene glycol.
Preparation method includes the following steps：
S10, as required weigh formula in amount material；
S11, wetting agent, dispersant, part antifoaming agent, part thickener is added in water successively, stirs evenly, oxygen is then added
Change iron oxide red, trbasic zinc phosphate, aluminium triphosphate, mica powder, titanium dioxide, the uniform 20min of talcum powder color stuffing high-speed stirred；
It S12 and then hollow glass micropearl is added under conditions of middling speed is dispersed with stirring 10min, then silicon is added under stirring at low speed
Benzene lotion, sodium nitrite composite corrosion inhibitor, coalescents, antifreezing agent, remaining antifoaming agent finally add remaining thickener tune
Viscosity is saved, is filtered to get a kind of antiseptic and rustproof insulating moulding coating of water-based metal.
Embodiment 2
A kind of antiseptic and rustproof insulating moulding coating of water-based metal, raw material include following components by weight：40 parts of silicon benzene lotion, oxygen
Change 20 parts of iron oxide red, 6 parts of trbasic zinc phosphate, 3 parts of aluminium triphosphate, 10 parts of mica powder, 6 parts of titanium dioxide, 20 parts of talcum powder, hollow glass
6 parts of microballon, 0.3 part of sodium nitrite composite corrosion inhibitor, 0.5 part of wetting agent, 1.0 parts of dispersant, 0.5 part of antifoaming agent, film forming help
2.5 parts of agent, 0.8 part of thickener, 3 parts of antifreezing agent, 30 parts of deionized water.
The titanium dioxide is rutile type titanium white, and grain size is 150 μm.
The talcum powder was 1500 mesh sieve pulvis.
The hollow glass micropearl is the hollow beads of 100 μm of grain size.
The dispersant is 731A dispersants and calgon, and the best weight ratio of the two is 4：3.
The antifoaming agent is mineral oil antifoam agent.
The antifreezing agent is ethylene glycol.
Preparation method includes the following steps：
S10, as required weigh formula in amount material；
S11, wetting agent, dispersant, part antifoaming agent, part thickener is added in water successively, stirs evenly, oxygen is then added
Change iron oxide red, trbasic zinc phosphate, aluminium triphosphate, mica powder, titanium dioxide, the uniform 30min of talcum powder color stuffing high-speed stirred；
It S12 and then hollow glass micropearl is added under conditions of middling speed is dispersed with stirring 20min, then silicon is added under stirring at low speed
Benzene lotion, sodium nitrite composite corrosion inhibitor, coalescents, antifreezing agent, remaining antifoaming agent finally add remaining thickener tune
Viscosity is saved, is filtered to get a kind of antiseptic and rustproof insulating moulding coating of water-based metal.
Embodiment 3
A kind of antiseptic and rustproof insulating moulding coating of water-based metal, raw material include following components by weight：35 parts of silicon benzene lotion, oxidation
15 parts of iron oxide red, 5 parts of trbasic zinc phosphate, 2 parts of aluminium triphosphate, 6 parts of mica powder, 5 parts of titanium dioxide, 15 parts of talcum powder, hollow glass micropearl
5 parts, 0.2 part of sodium nitrite composite corrosion inhibitor, 0.4 part of wetting agent, 0.6 part of dispersant, 0.4 part of antifoaming agent, coalescents 1.5
Part, 0.6 part of thickener, 2 parts of antifreezing agent, 25 parts of deionized water.
The titanium dioxide is rutile type titanium white, and grain size is 130 μm.
The talcum powder was 1100- mesh sieve pulvis.
The hollow glass micropearl is the hollow beads of 58 μm of grain size.
The dispersant is 731A dispersants and calgon, and the best weight ratio of the two is 4：3.
The antifoaming agent is organic silicon defoamer.
The antifreezing agent is ethylene glycol.
Preparation method includes the following steps：
S10, as required weigh formula in amount material；
S11, wetting agent, dispersant, part antifoaming agent, part thickener is added in water successively, stirs evenly, oxygen is then added
Change iron oxide red, trbasic zinc phosphate, aluminium triphosphate, mica powder, titanium dioxide, the uniform 25min of talcum powder color stuffing high-speed stirred；
It S12 and then hollow glass micropearl is added under conditions of middling speed is dispersed with stirring 15min, then silicon is added under stirring at low speed
Benzene lotion, sodium nitrite composite corrosion inhibitor, coalescents, antifreezing agent, remaining antifoaming agent finally add remaining thickener tune
Viscosity is saved, is filtered to get a kind of antiseptic and rustproof insulating moulding coating of water-based metal.
Example the above is only the implementation of the present invention is not intended to limit the scope of the invention, every to utilize this hair
Equivalent structure or equivalent flow shift made by bright description is applied directly or indirectly in other relevant technology necks
Domain is included within the scope of the present invention.
Claims (8)
1. a kind of antiseptic and rustproof insulating moulding coating of water-based metal, which is characterized in that its raw material includes following components by weight：Silicon benzene
30-40 parts of lotion, 10-20 parts of iron oxide red, 3-6 parts of trbasic zinc phosphate, 1-3 parts of aluminium triphosphate, 5-10 parts of mica powder, titanium dioxide
3-6 parts, 10-20 parts of talcum powder, 3-6 parts of hollow glass micropearl, 0.1-0.3 parts of sodium nitrite composite corrosion inhibitor, wetting agent 0.3-
0.5 part, 0.5-1.0 parts of dispersant, 0.2-0.5 parts of antifoaming agent, 1.0-2.5 parts of coalescents, 0.5-0.8 parts of thickener,
1-3 parts of antifreezing agent, 20-30 parts of deionized water.
2. according to the antiseptic and rustproof insulating moulding coating of a kind of water-based metal described in claim 1, it is characterised in that：The titanium white
Powder is rutile type titanium white, and grain size is 100~150 μm.
3. according to the antiseptic and rustproof insulating moulding coating of a kind of water-based metal described in claim 1, it is characterised in that：The talcum
Powder was 1000-1500 mesh sieve pulvis.
4. according to the antiseptic and rustproof insulating moulding coating of a kind of water-based metal described in claim 1, it is characterised in that：Described is hollow
Glass microballoon is the hollow beads of 50~100 μm of grain size.
5. according to the antiseptic and rustproof insulating moulding coating of a kind of water-based metal described in claim 1, it is characterised in that：The dispersion
Agent is 731A dispersants and calgon, and the best weight ratio of the two is 4：3.
6. according to the antiseptic and rustproof insulating moulding coating of a kind of water-based metal described in claim 1, it is characterised in that：It is described to disappear
Infusion is the mixing of one or both of organic silicon defoamer, mineral oil antifoam agent.
7. according to the antiseptic and rustproof insulating moulding coating of a kind of water-based metal described in claim 1, it is characterised in that：Described is antifreeze
Agent is ethylene glycol.
8. according to the antiseptic and rustproof insulating moulding coating of a kind of water-based metal described in claim 1, it is characterised in that：Preparation method
Include the following steps：
S10, as required weigh formula in amount material；
S11, wetting agent, dispersant, part antifoaming agent, part thickener is added in water successively, stirs evenly, oxygen is then added
Change iron oxide red, trbasic zinc phosphate, aluminium triphosphate, mica powder, titanium dioxide, the uniform 20-30min of talcum powder color stuffing high-speed stirred；
It S12 and then hollow glass micropearl is added under conditions of middling speed is dispersed with stirring 10-20min, then be added under stirring at low speed
Silicon benzene lotion, sodium nitrite composite corrosion inhibitor, coalescents, antifreezing agent, remaining antifoaming agent, finally add remaining thickener
Viscosity is adjusted, is filtered to get a kind of antiseptic and rustproof insulating moulding coating of water-based metal.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810355207.9A CN108504237A (en) | 2018-04-19 | 2018-04-19 | A kind of antiseptic and rustproof insulating moulding coating of water-based metal |
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| CN201810355207.9A CN108504237A (en) | 2018-04-19 | 2018-04-19 | A kind of antiseptic and rustproof insulating moulding coating of water-based metal |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110172285A (en) * | 2019-06-17 | 2019-08-27 | 大余松瀛化工有限公司 | A kind of antiseptic and rustproof insulating moulding coating of water-based metal |
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2018
- 2018-04-19 CN CN201810355207.9A patent/CN108504237A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110172285A (en) * | 2019-06-17 | 2019-08-27 | 大余松瀛化工有限公司 | A kind of antiseptic and rustproof insulating moulding coating of water-based metal |
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