CN108504122A - A kind of high-performance environmentally-friendly type wallpaper and preparation method thereof - Google Patents
A kind of high-performance environmentally-friendly type wallpaper and preparation method thereof Download PDFInfo
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- CN108504122A CN108504122A CN201810308555.0A CN201810308555A CN108504122A CN 108504122 A CN108504122 A CN 108504122A CN 201810308555 A CN201810308555 A CN 201810308555A CN 108504122 A CN108504122 A CN 108504122A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L97/00—Compositions of lignin-containing materials
- C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/322—Ammonium phosphate
- C08K2003/323—Ammonium polyphosphate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
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- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
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- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Paper (AREA)
Abstract
The invention discloses a kind of high-performance environmentally-friendly type wallpapers, include the raw material of following parts by weight:32 38 parts of paper pulp, 24 28 parts of modification of microcrystalline starch, 12 14 parts of polytetrafluoroethylene (PTFE), 8 12 parts of ammonium polyphosphate, 7 11 parts of carboxyethyl cellulose, 6 10 parts of nano zine oxide, 6 10 parts of nano-titanium dioxide, 13 parts of melamine, 26 parts of antifoaming agent, 12 parts of flame-retardant additive.The object of the present invention is to provide a kind of high-performance environmentally-friendly type wallpapers, the environmental protection wall paper, not only have the performances such as wear-resisting, fire-retardant, heat preservation, have excellent performance simultaneously, have higher use value and good application prospect.
Description
Technical field
The present invention relates to wallpaper technical fields, and in particular to a kind of high-performance environmentally-friendly type wallpaper and preparation method thereof.
Background technology
Wallpaper, also referred to as wallpaper, it is a kind of quite extensive house decorative material of application, because wallpaper has color more
A variety of other house decorative materials such as sample, pattern be abundant, luxurious style, safety and environmental protection, easy for construction, affordable can not compare
Quasi- feature, therefore obtained in developed countries and regions such as America and Europe, Southeast Asia, Japan considerable degree of universal, wallpaper is divided into very much
Class, such as coating wallpaper, overlay film wallpaper, embossing wallpaper, usually produce body paper, then adding through different processes with bleached wood pulp
Modeling is covered on work processing, such as coating, printing, embossing or surface, is dispatched from the factory after last cut, packaging.Because with certain intensity, U.S.
The appearance of sight and good water repelling property are widely used in the interior decoration etc. of house, office, hotel;Wallpaper type is divided into paper
Base rubber cotton, pure paper, PVC wallpaper, cloth primer face, metal class wallpaper, wall paper, flock-wallpaper, foam wallpaper.
Existing Chinese patent literature(Publication number:104911957B)Disclose a kind of ecology adding phosphogypsum dihydrate whisker
Functional form wallpaper base stock and preparation method thereof is made by the raw material of following weight component percentage meter:Paper pulp 60%-80%, two
Water ester exchange at phosphorus 9%-17%, conditioning agent 8%-15%, starch 1%-3%, sizing agent 1%-2%, wet strength agent 0.1%-
1%, inorganic assistant 1%-2%;Wherein conditioning agent is modification infusorial earth or modified meerschaum, whiteness >=95%, above-mentioned raw materials conjunction
Meter 100%, though there are many wallpaper function, effect also needs to further increase.
Invention content
In view of the drawbacks of the prior art, the object of the present invention is to provide a kind of high-performance environmentally-friendly type wallpaper, the environmental protection walls
Paper not only has the performances such as wear-resisting, fire-retardant, heat preservation, has excellent performance simultaneously, before having higher use value and good application
Scape.
The present invention solves technical problem and adopts the following technical scheme that:
The present invention provides a kind of high-performance environmentally-friendly type wallpapers, include the raw material of following parts by weight:
32-38 parts of paper pulp, 24-28 parts of modification of microcrystalline starch, 12-14 parts of polytetrafluoroethylene (PTFE), 8-12 parts of ammonium polyphosphate, carboxyethyl are fine
Tie up 7-11 parts of element, 6-10 parts of nano zine oxide, 6-10 parts of nano-titanium dioxide, 1-3 parts of melamine, 2-6 parts of antifoaming agent, fire-retardant
1-2 parts of additive.
Preferably, the high-performance environmentally-friendly type wallpaper includes the raw material of following parts by weight:
35 parts of paper pulp, 13 parts of polytetrafluoroethylene (PTFE), 10 parts of ammonium polyphosphate, 9 parts of carboxyethyl cellulose, is received 26 parts of modification of microcrystalline starch
8 parts of zinc oxide of rice, 8 parts of nano-titanium dioxide, 2 parts of melamine, 1.5 parts of flame-retardant additive.
Preferably, Microcrystalline Starch is placed in distilled water by the modification of microcrystalline starch preparation method, speed of agitator 65-
Temperature is upgraded to 75-85 DEG C by 75r/min, mixing time 25-35min, until Microcrystalline Starch is completely dissolved, then thereto
Polyethylene terephthalate, mass fraction is added as 98% ethyl alcohol, emulsifier, speed of agitator rises to 105-115r/min, after
Continuous stirring 35-45min is to get modification of microcrystalline starch.
Preferably, the emulsifier is p-Octylphenol polyoxyethylene ether.
Preferably, the antifoaming agent is dimethyl silicone polymer.
Preferably, the flame-retardant additive is aluminium hydroxide, antimony oxide according to weight ratio 1:The mixture of 4 compositions.
The present invention also provides a kind of preparation methods of high-performance environmentally-friendly type wallpaper, include the following steps:
Step 1 weighs each component raw material as required;
Homogenizer is added in paper pulp, modification of microcrystalline starch, polytetrafluoroethylene (PTFE), ammonium polyphosphate, carboxyethyl cellulose by step 2
In, speed of agitator 220-320r/min, mixing time is to obtain mixture A in 35-45 minutes;
Mixed at high speed is added in mixture A, nano zine oxide, nano-titanium dioxide, melamine, flame-retardant additive by step 4
In machine, be sufficiently stirred so that all material be uniformly mixed, mixing speed 350-450r/min, mixing time 45-55 minute, then general
Mixture is added in reaction kettle, is kept the temperature 55-65 minutes at being 145-155 DEG C in temperature, is placed in mold and cools down to get invention
High-performance environmentally-friendly type wallpaper.
Preferably, the preparation process of the high-performance environmentally-friendly type wallpaper is:
Step 1 weighs each component raw material as required;
Homogenizer is added in paper pulp, modification of microcrystalline starch, polytetrafluoroethylene (PTFE), ammonium polyphosphate, carboxyethyl cellulose by step 2
In, speed of agitator 300r/min, mixing time is to obtain mixture A in 40 minutes;
Mixed at high speed is added in mixture A, nano zine oxide, nano-titanium dioxide, melamine, flame-retardant additive by step 4
In machine, it is sufficiently stirred so that all material is uniformly mixed, mixing speed 400r/min, mixing time 50 minutes, then by mixture
It is added in reaction kettle, keeps the temperature 60 minutes at being 150 DEG C in temperature, be placed in mold the high performance ring cooled down to get invention
Guarantor's type wallpaper.
Compared with prior art, the present invention has following advantageous effect:
(1)A kind of high-performance environmentally-friendly type wallpaper of the present invention, Microcrystalline Starch have short chain straight chain microstructure, in ethyl alcohol, right
Octylphenol polyoxyethylene ether assists lower chain extension to be combined with polyethylene terephthalate, polyethylene terephthalate energy
Enough high temperature resistants, have excellent physical mechanical property, and wearability is good, and property is still stablized under long-time service, polytetrafluoroethylene (PTFE)
With ageing resistance, corrosion resistance, the chemical stability of wallpaper is further enhanced.
(2)A kind of high-performance environmentally-friendly type wallpaper of the present invention, nano zine oxide, the nano-titanium dioxide of addition improve wall
The weatherability of paper, ammonium polyphosphate, melamine further improve the anti-flammability of wallpaper, while flame-retardant additive of the present invention is hydrogen
The mixture of aluminium oxide, antimony oxide composition, can play synergistic effect, keep the flame retardant property of wallpaper big on the original basis
Big raising.
(3)A kind of high-performance environmentally-friendly type wallpaper of invention, the environmental protection wall paper not only have the property such as wear-resisting, fire-retardant, heat preservation
Can, it has excellent performance simultaneously, there is higher use value and good application prospect.
Specific implementation mode
With reference to specific embodiment, technical scheme in the embodiment of the invention is clearly and completely described, shows
So, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the reality in the present invention
Example is applied, every other embodiment obtained by those of ordinary skill in the art without making creative efforts all belongs to
In the scope of protection of the invention.
Embodiment 1.
A kind of high-performance environmentally-friendly type wallpaper of the present embodiment, includes the raw material of following parts by weight:
32 parts of paper pulp, 24 parts of modification of microcrystalline starch, 12 parts of polytetrafluoroethylene (PTFE), 8 parts of ammonium polyphosphate, carboxyethyl cellulose 7 part, nanometer
6 parts of zinc oxide, 6 parts of nano-titanium dioxide, 1 part of melamine, 2 parts of antifoaming agent, 1 part of flame-retardant additive.
Microcrystalline Starch is placed in distilled water by the modification of microcrystalline starch preparation method of the present embodiment, speed of agitator 65r/
Temperature is upgraded to 75 DEG C by min, mixing time 25min, until Microcrystalline Starch is completely dissolved, is then added thereto poly- to benzene
Naphthalate, mass fraction are 98% ethyl alcohol, emulsifier, and speed of agitator rises to 105r/min, continue to stir 35min, i.e.,
Obtain modification of microcrystalline starch.
The emulsifier of the present embodiment is p-Octylphenol polyoxyethylene ether.
The antifoaming agent of the present embodiment is dimethyl silicone polymer.
The flame-retardant additive of the present embodiment is aluminium hydroxide, antimony oxide according to weight ratio 1:The mixture of 4 compositions.
A kind of preparation method of high-performance environmentally-friendly type wallpaper of the present embodiment, includes the following steps:
Step 1 weighs each component raw material as required;
Homogenizer is added in paper pulp, modification of microcrystalline starch, polytetrafluoroethylene (PTFE), ammonium polyphosphate, carboxyethyl cellulose by step 2
In, speed of agitator 220r/min, mixing time is to obtain mixture A in 35 minutes;
Mixed at high speed is added in mixture A, nano zine oxide, nano-titanium dioxide, melamine, flame-retardant additive by step 4
In machine, it is sufficiently stirred so that all material is uniformly mixed, mixing speed 350r/min, mixing time 45 minutes, then by mixture
It is added in reaction kettle, keeps the temperature 55 minutes at being 145 DEG C in temperature, be placed in mold the high performance ring cooled down to get invention
Guarantor's type wallpaper.
Embodiment 2.
A kind of high-performance environmentally-friendly type wallpaper of the present embodiment, includes the raw material of following parts by weight:
38 parts of paper pulp, 14 parts of polytetrafluoroethylene (PTFE), 12 parts of ammonium polyphosphate, 11 parts of carboxyethyl cellulose, is received 28 parts of modification of microcrystalline starch
10 parts of zinc oxide of rice, 10 parts of nano-titanium dioxide, 3 parts of melamine, 6 parts of antifoaming agent, 1-2 parts of flame-retardant additive.
Microcrystalline Starch is placed in distilled water by the modification of microcrystalline starch preparation method of the present embodiment, speed of agitator 75r/
Temperature is upgraded to 85 DEG C by min, mixing time 35min, until Microcrystalline Starch is completely dissolved, is then added thereto poly- to benzene
Naphthalate, mass fraction are 98% ethyl alcohol, emulsifier, and speed of agitator rises to 115r/min, continue to stir 45min, i.e.,
Obtain modification of microcrystalline starch.
The emulsifier of the present embodiment is p-Octylphenol polyoxyethylene ether.
The antifoaming agent of the present embodiment is dimethyl silicone polymer.
The flame-retardant additive of the present embodiment is aluminium hydroxide, antimony oxide according to weight ratio 1:The mixture of 4 compositions.
A kind of preparation method of high-performance environmentally-friendly type wallpaper of the present embodiment, includes the following steps:
Step 1 weighs each component raw material as required;
Homogenizer is added in paper pulp, modification of microcrystalline starch, polytetrafluoroethylene (PTFE), ammonium polyphosphate, carboxyethyl cellulose by step 2
In, speed of agitator 320r/min, mixing time is to obtain mixture A in 45 minutes;
Mixed at high speed is added in mixture A, nano zine oxide, nano-titanium dioxide, melamine, flame-retardant additive by step 4
In machine, it is sufficiently stirred so that all material is uniformly mixed, mixing speed 450r/min, mixing time 55 minutes, then by mixture
It is added in reaction kettle, keeps the temperature 65 minutes at being 155 DEG C in temperature, be placed in mold the high performance ring cooled down to get invention
Guarantor's type wallpaper.
Embodiment 3.
A kind of high-performance environmentally-friendly type wallpaper of the present embodiment, includes the raw material of following parts by weight:
35 parts of paper pulp, 13 parts of polytetrafluoroethylene (PTFE), 10 parts of ammonium polyphosphate, 9 parts of carboxyethyl cellulose, is received 26 parts of modification of microcrystalline starch
8 parts of zinc oxide of rice, 8 parts of nano-titanium dioxide, 2 parts of melamine, 1.5 parts of flame-retardant additive.
Microcrystalline Starch is placed in distilled water by the modification of microcrystalline starch preparation method of the present embodiment, speed of agitator 70r/
Temperature is upgraded to 80 DEG C by min, mixing time 30min, until Microcrystalline Starch is completely dissolved, is then added thereto poly- to benzene
Naphthalate, mass fraction are 98% ethyl alcohol, emulsifier, and speed of agitator rises to 110/min, continue to stir 40min, i.e.,
Obtain modification of microcrystalline starch.
The emulsifier of the present embodiment is p-Octylphenol polyoxyethylene ether.
The antifoaming agent of the present embodiment is dimethyl silicone polymer.
The flame-retardant additive of the present embodiment is aluminium hydroxide, antimony oxide according to weight ratio 1:The mixture of 4 compositions.
A kind of preparation method of high-performance environmentally-friendly type wallpaper of the present embodiment, includes the following steps:
Step 1 weighs each component raw material as required;
Homogenizer is added in paper pulp, modification of microcrystalline starch, polytetrafluoroethylene (PTFE), ammonium polyphosphate, carboxyethyl cellulose by step 2
In, speed of agitator 300r/min, mixing time is to obtain mixture A in 40 minutes;
Mixed at high speed is added in mixture A, nano zine oxide, nano-titanium dioxide, melamine, flame-retardant additive by step 4
In machine, it is sufficiently stirred so that all material is uniformly mixed, mixing speed 400r/min, mixing time 50 minutes, then by mixture
It is added in reaction kettle, keeps the temperature 60 minutes at being 150 DEG C in temperature, be placed in mold the high performance ring cooled down to get invention
Guarantor's type wallpaper.
It draws a conclusion by many experiments and performance test, a kind of high-performance environmentally-friendly type wallpaper of invention, the environmental protection wall
Paper not only has the performances such as wear-resisting, fire-retardant, heat preservation, has excellent performance simultaneously, before having higher use value and good application
Scape.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Profit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent requirements of the claims
Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiment being appreciated that.
Claims (8)
1. a kind of high-performance environmentally-friendly type wallpaper, which is characterized in that include the raw material of following parts by weight:
32-38 parts of paper pulp, 24-28 parts of modification of microcrystalline starch, 12-14 parts of polytetrafluoroethylene (PTFE), 8-12 parts of ammonium polyphosphate, carboxyethyl are fine
Tie up 7-11 parts of element, 6-10 parts of nano zine oxide, 6-10 parts of nano-titanium dioxide, 1-3 parts of melamine, 2-6 parts of antifoaming agent, fire-retardant
1-2 parts of additive.
2. a kind of high-performance environmentally-friendly type wallpaper according to claim 1, which is characterized in that the high-performance environmentally-friendly type
Wallpaper includes the raw material of following parts by weight:
35 parts of paper pulp, 13 parts of polytetrafluoroethylene (PTFE), 10 parts of ammonium polyphosphate, 9 parts of carboxyethyl cellulose, is received 26 parts of modification of microcrystalline starch
8 parts of zinc oxide of rice, 8 parts of nano-titanium dioxide, 2 parts of melamine, 1.5 parts of flame-retardant additive.
3. a kind of high-performance environmentally-friendly type wallpaper according to claim 1 or 2, which is characterized in that the modification of microcrystalline forms sediment
Microcrystalline Starch is placed in distilled water by powder, preparation method thereof, speed of agitator 65-75r/min, and mixing time 25-35min will be warm
Degree is upgraded to 75-85 DEG C, until Microcrystalline Starch is completely dissolved, polyethylene terephthalate, quality point are then added thereto
Number is 98% ethyl alcohol, emulsifier, and speed of agitator rises to 105-115r/min, continues to stir 35-45min to get modification of microcrystalline shallow lake
Powder.
4. a kind of high-performance environmentally-friendly type wallpaper according to claim 3, which is characterized in that the emulsifier is to octyl
Phenol polyoxyethylene ether.
5. a kind of high-performance environmentally-friendly type wallpaper according to claim 1, which is characterized in that the antifoaming agent is poly- diformazan
Radical siloxane.
6. a kind of high-performance environmentally-friendly type wallpaper according to claim 1, which is characterized in that the flame-retardant additive is hydrogen
Aluminium oxide, antimony oxide are according to weight ratio 1:The mixture of 4 compositions.
7. a kind of method preparing high-performance environmentally-friendly type wallpaper as claimed in any one of claims 1 to 6, which is characterized in that packet
Include following steps:
Step 1 weighs each component raw material as required;
Homogenizer is added in paper pulp, modification of microcrystalline starch, polytetrafluoroethylene (PTFE), ammonium polyphosphate, carboxyethyl cellulose by step 2
In, speed of agitator 220-320r/min, mixing time is to obtain mixture A in 35-45 minutes;
Mixed at high speed is added in mixture A, nano zine oxide, nano-titanium dioxide, melamine, flame-retardant additive by step 4
In machine, be sufficiently stirred so that all material be uniformly mixed, mixing speed 350-450r/min, mixing time 45-55 minute, then general
Mixture is added in reaction kettle, is kept the temperature 55-65 minutes at being 145-155 DEG C in temperature, is placed in mold and cools down to get invention
High-performance environmentally-friendly type wallpaper.
8. a kind of preparation method of high-performance environmentally-friendly type wallpaper according to claim 7, which is characterized in that the preparation
Step is:
Step 1 weighs each component raw material as required;
Homogenizer is added in paper pulp, modification of microcrystalline starch, polytetrafluoroethylene (PTFE), ammonium polyphosphate, carboxyethyl cellulose by step 2
In, speed of agitator 300r/min, mixing time is to obtain mixture A in 40 minutes;
Mixed at high speed is added in mixture A, nano zine oxide, nano-titanium dioxide, melamine, flame-retardant additive by step 4
In machine, it is sufficiently stirred so that all material is uniformly mixed, mixing speed 400r/min, mixing time 50 minutes, then by mixture
It is added in reaction kettle, keeps the temperature 60 minutes at being 150 DEG C in temperature, be placed in mold the high performance ring cooled down to get invention
Guarantor's type wallpaper.
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CN201810308555.0A CN108504122A (en) | 2018-04-09 | 2018-04-09 | A kind of high-performance environmentally-friendly type wallpaper and preparation method thereof |
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Cited By (1)
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CN110042701A (en) * | 2019-03-29 | 2019-07-23 | 广东福美新材料科技有限公司 | A kind of moisture retardant impregnated paper and preparation method thereof |
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CN107177146A (en) * | 2017-07-26 | 2017-09-19 | 合肥梵腾环保科技有限公司 | A kind of weather-resistance flame-retardant high-performance glass surface protection film and preparation method thereof |
CN107186996A (en) * | 2017-05-31 | 2017-09-22 | 江苏大海塑料股份有限公司 | A kind of preparation method of flame retardant type PVC wallpaper |
CN107201160A (en) * | 2017-07-19 | 2017-09-26 | 安徽三品技术服务有限公司 | A kind of mould proof PVC wallpaper of waterproof |
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CN104163027A (en) * | 2014-07-14 | 2014-11-26 | 天津泰立得塑胶制品有限公司 | Non-toxic environmental protection digital painting wallpaper preparation method and application thereof |
CN106905641A (en) * | 2017-04-18 | 2017-06-30 | 东莞市祺龙电业有限公司 | A kind of wallpaper cloth is material modified and preparation method thereof with PVC |
CN107186996A (en) * | 2017-05-31 | 2017-09-22 | 江苏大海塑料股份有限公司 | A kind of preparation method of flame retardant type PVC wallpaper |
CN107201160A (en) * | 2017-07-19 | 2017-09-26 | 安徽三品技术服务有限公司 | A kind of mould proof PVC wallpaper of waterproof |
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CN110042701B (en) * | 2019-03-29 | 2023-09-15 | 广东福美新材料科技有限公司 | Moistureproof flame-retardant impregnated paper and preparation method thereof |
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Application publication date: 20180907 |