CN108504044A - A kind of floor heat resistant and wear resistant composite material and preparation method - Google Patents
A kind of floor heat resistant and wear resistant composite material and preparation method Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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Abstract
The invention discloses a kind of floor heat resistant and wear resistant composite materials, include the curing agent methyl ethyl ketone peroxide of the epoxy resin 501A of the solid material of the clear red mud of 190~210 parts by weight, 1800~1885 parts by weight, 1100~1300 parts by weight, 250~270 parts by weight epoxy resin 501B, 60~70 parts by weight nano silicon oxides, the SiC nano-powder of 545~595 parts by weight, the 80FA barras of 180~210 parts by weight, the polymethyl methacrylate polybutadiene polystyrene copolymer of 150~200 parts by weight, the polyvinyl chloride of 5~8 parts by volume, 2~6 parts by volume；The correspondence of wherein parts by weight and parts by volume is g/mL.The floor of the present invention meets environmental requirement, and using the floor surface hard wear resistant of floor heat resistant and wear resistant composite material, weatherability and corrosion-resistant strong and light.
Description
Technical field
The present invention relates to the preparation methods and its material of floor heat resistant and wear resistant composite material.
Background technology
Reinforced composite wooden floor is the earth material of prevalence in recent years.Official's scientific name：Proofing paper laminated wood floor.It
It is to dose glue, preservative, additive after log crushing, formed through hot press high temperature and pressure compression process, therefore it breaks
The physical arrangement of log overcomes the weakness of log stability difference.The intensity height of composite floor board, uniform specification, wearing coefficient be high,
Anti-corrosion, mothproof and good decorating effect overcome the scar section on log surface, small holes caused by worms, aberration problem.Compoiste wood floor is not necessarily to japanning
Waxing, use scope is wide, easily arranges, and is the earth material for being most suitable for Modern Family's rhythm of life.In addition the timber of composite floor board
Utilization rate is high, is good environment-friendly materials.Existing floor quality is poor, and corrosion-resistant and fire resistance is poor, and mechanical performance cannot
Meet needs.
Invention content
The technical problem to be solved by the present invention is to overcome the existing defects, provides a kind of light, corrosion resistant novel floor
With heat resistant and wear resistant composite material.
In order to solve the above technical problem, the present invention provides the following technical solutions：
A kind of floor heat resistant and wear resistant composite material, includes each component of following number：
The clear red muds of 190~210 parts by weight, the solid material of 1800~1885 parts by weight, 1100~1300 parts by weight
Epoxy resin 501A, 250~270 parts by weight epoxy resin 501B, 60~70 parts by weight nano silicon oxides, 545~595 parts by weight
SiC nano-powder, the 80FA barras of 180~210 parts by weight, the polymethyl methacrylate-of 150~200 parts by weight it is poly-
The curing agent methyl ethyl ketone peroxide of butadiene-polystyrene copolymer, the polyvinyl chloride of 5~8 parts by volume, 2~6 parts by volume；Its
The correspondence of middle parts by weight and parts by volume is g/mL.
Further, floor heat resistant and wear resistant composite material, includes each component of following number：
1200 parts of epoxy resin 501A, the ring of the clear red mud of 200 parts by weight, the solid material of 1840 parts by weight, parts by weight
The 80FA of 260 parts of oxygen resin 501B, the nano silicon oxide of 65 parts by weight, the SiC nano-powder of 570 parts by weight, 195 parts by weight
The polychlorostyrene of barras, 150~200 parts by weight polymethyl methacrylates-polybutadienes-polystyrene copolymer, 6.8 parts by volume
The curing agent methyl ethyl ketone peroxide of ethylene, 2~6 parts by volume；The correspondence of wherein parts by weight and parts by volume is g/mL.
Further, the solid material includes each component of following parts by weight：
Preferably, the solid material includes each component of following parts by weight：
The preparation method of floor heat resistant and wear resistant composite material, including following steps：
(1) polyvinyl chloride for weighing the clear red mud and 0.5~1 parts by volume of 190~210 parts by weight, after stirring,
The curing agent methyl ethyl ketone peroxide of 0.5~1 parts by volume is added, after mixing；
(3) solid material of 450~500 parts by weight is proportionally prepared, the SiC that 230~250 parts by weight are then added receives
Rice flour end, the 80FA barras of 75~85 parts by weight, the polyvinyl chloride of 2.0~3.5 parts by volume and 0.5~3 parts by weight peroxidating
Methyl ethyl ketone is uniformly mixed；
(4) 75~100 parts by weight polymethyl methacrylates-polybutadienes-polystyrene copolymer is put, 100~120
DEG C heating 3~10 minutes；
(5) solid material that 450~500 parts by weight are prepared according still further to ratio, is then added the SiC of 230~250 parts by weight
Nanometer powder, the 80FA barras of 75~85 parts by weight, the polyvinyl chloride of 2.0~3.5 parts by volume and 0.5~3 parts by weight peroxide
Change methyl ethyl ketone to be uniformly mixed；
(6) 75~100 parts by weight polymethyl methacrylates-polybutadienes-polystyrene copolymer is put, 100~120
DEG C heating 3~10 minutes；
(7) according still further to ratio prepare the solid materials of 170~185 parts by weight, 85~95 parts by weight SiC nano-powder,
The 80FA barras of 30~40 parts by weight, the polyvinyl chloride of 0.5~1.5 parts by volume and 0.5~3 parts by weight methyl ethyl ketone peroxide,
It is uniformly mixed, 100~120 DEG C are heated 3~10 minutes；
(8) it proportionally weighs and mixes 700 prefabricated parts by weight solids materials, the asphalt mixtures modified by epoxy resin of 1100~1300 parts by weight
Fat 501A, 250~270 parts by weight epoxy resin 501B and 60~70 parts by weight nano silicon oxides stir；
(9) it is sent into high-speed kneading machine, 6-15min is mediated at 80-120 DEG C, after mediating material cooling, be sent into twin-screw
Extruder is granulated to get the insulating materials of the present invention；
Further, the polyvinyl chloride of the clear red mud and 0.8 parts by volume of 200 parts by weight is weighed in the step (3), fully
It is used after stirring evenly.
Further, proportionally weighed in described (4) and step (6) mix 480 prefabricated parts by weight solid material,
The SiC nano-powder of 240 parts by weight, the 80FA barras of 80 parts by weight, the polyvinyl chloride of 3 parts by volume and 0.5~3 parts by weight mistake
Methyl Ethyl Ketone Oxidation uses after mixing.
Further, the solid material for mixing 180 prefabricated parts by weight, 90 parts by weight are proportionally weighed in described (8)
SiC nano-powder, the 80FA barras of 30 parts by weight, the polyvinyl chloride of 3 parts by volume and 0.5~3 parts by weight peroxidating first and second
Ketone uses after mixing.
The floor of the present invention meets environmental requirement, and using the floor table of floor heat resistant and wear resistant composite material
Face hard wear resistant, weatherability and corrosion-resistant strong and light are readily transported, ageing resistance is strong, stable mechanical performance, anti-flammability
Can be good, resistant of high or low temperature is good, is readily produced, and can save production equipment input, is conducive to efficiency and produces, properties of product are stablized, quality
It is high.
Specific implementation mode
Hereinafter, preferred embodiments of the present invention will be described, it should be understood that preferred embodiment described herein is only used
In the description and interpretation present invention, it is not intended to limit the present invention.
Embodiment 1
A kind of floor heat resistant and wear resistant composite material, includes each component of following number：
The clear red mud of 190 parts by weight, the solid material of 1800 parts by weight, the epoxy resin 501A of 1100 parts by weight, 250 weights
It is soft to measure part epoxy resin 501B, 60 parts by weight nano silicon oxides, the SiC nano-powder of 545 parts by weight, the 80FA of 180 parts by weight
Resin, polymethyl methacrylate-polybutadienes-polystyrene copolymer of 150 parts by weight, the polyvinyl chloride of 5 parts by volume, 2
The curing agent methyl ethyl ketone peroxide of parts by volume；The correspondence of wherein parts by weight and parts by volume is g/mL.
The solid material includes each component of following parts by weight：
The preparation method of floor heat resistant and wear resistant composite material, including following steps：
(1) polyvinyl chloride for weighing the clear red mud and 0.5~1 parts by volume of 190~210 parts by weight, after stirring,
The curing agent methyl ethyl ketone peroxide of 0.5~1 parts by volume is added, after mixing；
(3) solid material of 450~500 parts by weight is proportionally prepared, the SiC that 230~250 parts by weight are then added receives
Rice flour end, the 80FA barras of 75~85 parts by weight, the polyvinyl chloride of 2.0~3.5 parts by volume and 0.5~3 parts by weight peroxidating
Methyl ethyl ketone is uniformly mixed；
(4) 75~100 parts by weight polymethyl methacrylates-polybutadienes-polystyrene copolymer is put, 100~120
DEG C heating 3~10 minutes；
(5) solid material that 450~500 parts by weight are prepared according still further to ratio, is then added the SiC of 230~250 parts by weight
Nanometer powder, the 80FA barras of 75~85 parts by weight, the polyvinyl chloride of 2.0~3.5 parts by volume and 0.5~3 parts by weight peroxide
Change methyl ethyl ketone to be uniformly mixed；
(6) 75~100 parts by weight polymethyl methacrylates-polybutadienes-polystyrene copolymer is put, 100~120
DEG C heating 3~10 minutes；
(7) according still further to ratio prepare the solid materials of 170~185 parts by weight, 85~95 parts by weight SiC nano-powder,
The 80FA barras of 30~40 parts by weight, the polyvinyl chloride of 0.5~1.5 parts by volume and 0.5~3 parts by weight methyl ethyl ketone peroxide,
It is uniformly mixed, 100~120 DEG C are heated 3~10 minutes；
(8) it proportionally weighs and mixes 700 prefabricated parts by weight solids materials, the asphalt mixtures modified by epoxy resin of 1100~1300 parts by weight
Fat 501A, 250~270 parts by weight epoxy resin 501B and 60~70 parts by weight nano silicon oxides stir；
(9) it is sent into high-speed kneading machine, 6-15min is mediated at 80-120 DEG C, after mediating material cooling, be sent into twin-screw
Extruder be granulated to get.
Embodiment 2
A kind of floor heat resistant and wear resistant composite material, includes each component of following number：
The clear red mud of 210 parts by weight, the solid material of 1885 parts by weight, the epoxy resin 501A of 1300 parts by weight, 270 weights
It is soft to measure part epoxy resin 501B, 70 parts by weight nano silicon oxides, the SiC nano-powder of 595 parts by weight, the 80FA of 210 parts by weight
Resin, polymethyl methacrylate-polybutadienes-polystyrene copolymer of 200 parts by weight, the polyvinyl chloride of 8 parts by volume, 6
The curing agent methyl ethyl ketone peroxide of parts by volume；The correspondence of wherein parts by weight and parts by volume is g/mL.
The solid material includes each component of following parts by weight：
Its manufacture craft, including following steps：
(1) polyvinyl chloride for weighing the clear red mud and 0.5~1 parts by volume of 190~210 parts by weight, after stirring,
The curing agent methyl ethyl ketone peroxide of 0.5~1 parts by volume is added, after mixing；
(3) solid material of 450~500 parts by weight is proportionally prepared, the SiC that 230~250 parts by weight are then added receives
Rice flour end, the 80FA barras of 75~85 parts by weight, the polyvinyl chloride of 2.0~3.5 parts by volume and 0.5~3 parts by weight peroxidating
Methyl ethyl ketone is uniformly mixed；
(4) 75~100 parts by weight polymethyl methacrylates-polybutadienes-polystyrene copolymer is put, 100~120
DEG C heating 3~10 minutes；
(5) solid material that 450~500 parts by weight are prepared according still further to ratio, is then added the SiC of 230~250 parts by weight
Nanometer powder, the 80FA barras of 75~85 parts by weight, the polyvinyl chloride of 2.0~3.5 parts by volume and 0.5~3 parts by weight peroxide
Change methyl ethyl ketone to be uniformly mixed；
(6) 75~100 parts by weight polymethyl methacrylates-polybutadienes-polystyrene copolymer is put, 100~120
DEG C heating 3~10 minutes；
(7) according still further to ratio prepare the solid materials of 170~185 parts by weight, 85~95 parts by weight SiC nano-powder,
The 80FA barras of 30~40 parts by weight, the polyvinyl chloride of 0.5~1.5 parts by volume and 0.5~3 parts by weight methyl ethyl ketone peroxide,
It is uniformly mixed, 100~120 DEG C are heated 3~10 minutes；
(8) it proportionally weighs and mixes 700 prefabricated parts by weight solids materials, the asphalt mixtures modified by epoxy resin of 1100~1300 parts by weight
Fat 501A, 250~270 parts by weight epoxy resin 501B and 60~70 parts by weight nano silicon oxides stir；
(9) it is sent into high-speed kneading machine, 6-15min is mediated at 80-120 DEG C, after mediating material cooling, be sent into twin-screw
Extruder be granulated to get.
Embodiment 3
1200 parts of epoxy resin 501A, the ring of the clear red mud of 200 parts by weight, the solid material of 1840 parts by weight, parts by weight
The 80FA of 260 parts of oxygen resin 501B, the nano silicon oxide of 65 parts by weight, the SiC nano-powder of 570 parts by weight, 235 parts by weight
Barras, 175 parts by weight polymethyl methacrylates-polybutadienes-polystyrene copolymer, 6.8 parts by volume polyvinyl chloride,
The curing agent methyl ethyl ketone peroxide of 2~6 parts by volume；The correspondence of wherein parts by weight and parts by volume is g/mL.
The solid material includes each component of following parts by weight：
The preparation method of floor heat resistant and wear resistant composite material, including following steps：
(1) polyvinyl chloride for weighing the clear red mud and 0.5~1 parts by volume of 190~210 parts by weight, after stirring,
The curing agent methyl ethyl ketone peroxide of 0.5~1 parts by volume is added, after mixing；
(3) solid material of 450~500 parts by weight is proportionally prepared, the SiC that 230~250 parts by weight are then added receives
Rice flour end, the 80FA barras of 75~85 parts by weight, the polyvinyl chloride of 2.0~3.5 parts by volume and 0.5~3 parts by weight peroxidating
Methyl ethyl ketone is uniformly mixed；
(4) 75~100 parts by weight polymethyl methacrylates-polybutadienes-polystyrene copolymer is put, 100~120
DEG C heating 3~10 minutes；
(5) solid material that 450~500 parts by weight are prepared according still further to ratio, is then added the SiC of 230~250 parts by weight
Nanometer powder, the 80FA barras of 75~85 parts by weight, the polyvinyl chloride of 2.0~3.5 parts by volume and 0.5~3 parts by weight peroxide
Change methyl ethyl ketone to be uniformly mixed；
(6) 75~100 parts by weight polymethyl methacrylates-polybutadienes-polystyrene copolymer is put, 100~120
DEG C heating 3~10 minutes；
(7) according still further to ratio prepare the solid materials of 170~185 parts by weight, 85~95 parts by weight SiC nano-powder,
The 80FA barras of 30~40 parts by weight, the polyvinyl chloride of 0.5~1.5 parts by volume and 0.5~3 parts by weight methyl ethyl ketone peroxide,
It is uniformly mixed, 100~120 DEG C are heated 3~10 minutes；
(8) it proportionally weighs and mixes 700 prefabricated parts by weight solids materials, the asphalt mixtures modified by epoxy resin of 1100~1300 parts by weight
Fat 501A, 250~270 parts by weight epoxy resin 501B and 60~70 parts by weight nano silicon oxides stir；
(9) it is sent into high-speed kneading machine, 6-15min is mediated at 80-120 DEG C, after mediating material cooling, be sent into twin-screw
Extruder be granulated to get.
Finally it should be noted that：The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention,
Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still may be used
With technical scheme described in the above embodiments is modified or equivalent replacement of some of the technical features.
All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in the present invention's
Within protection domain.
Claims (8)
1. a kind of floor heat resistant and wear resistant composite material, which is characterized in that include each component of following number：
The epoxy of the clear red mud of 190~210 parts by weight, the solid material of 1800~1885 parts by weight, 1100~1300 parts by weight
Resin 501A, 250~270 parts by weight epoxy resin 501B, 60~70 parts by weight nano silicon oxides, 545~595 parts by weight
The poly- fourth of polymethyl methacrylate-of SiC nano-powder, the 80FA barras of 180~210 parts by weight, 150~200 parts by weight
The curing agent methyl ethyl ketone peroxide of diene-polystyrene copolymer, the polyvinyl chloride of 5~8 parts by volume, 2~6 parts by volume；Wherein
The correspondence of parts by weight and parts by volume is g/mL.
2. a kind of floor heat resistant and wear resistant composite material as described in claim 1, which is characterized in that including following number
Each component：
1200 parts of epoxy resin 501A, the asphalt mixtures modified by epoxy resin of the clear red mud of 200 parts by weight, the solid material of 1840 parts by weight, parts by weight
The soft trees of 80FA of 260 parts of fat 501B, the nano silicon oxide of 65 parts by weight, the SiC nano-powder of 570 parts by weight, 195 parts by weight
The polychlorostyrene second of fat, 150~200 parts by weight polymethyl methacrylates-polybutadienes-polystyrene copolymer, 6.8 parts by volume
The curing agent methyl ethyl ketone peroxide of alkene, 2~6 parts by volume；The correspondence of wherein parts by weight and parts by volume is g/mL.
3. such as a kind of floor of claims 1 or 2 any one of them heat resistant and wear resistant composite material, which is characterized in that described
Solid material includes each component of following parts by weight：
4. such as a kind of floor of claims 1 or 2 any one of them heat resistant and wear resistant composite material, which is characterized in that described
Solid material includes each component of following parts by weight：
5. a kind of such as claim 1-2 any one of them floor preparation method of heat resistant and wear resistant composite material, feature
It is, including following steps：
(1) polyvinyl chloride for weighing the clear red mud and 0.5~1 parts by volume of 190~210 parts by weight after stirring, then adds
Enter the curing agent methyl ethyl ketone peroxide of 0.5~1 parts by volume, after mixing；
(3) solid material of 450~500 parts by weight is proportionally prepared, the SiC nano powders of 230~250 parts by weight are then added
End, the 80FA barras of 75~85 parts by weight, the polyvinyl chloride of 2.0~3.5 parts by volume and 0.5~3 parts by weight peroxidating first and second
Ketone is uniformly mixed；
(4) 75~100 parts by weight polymethyl methacrylates-polybutadienes-polystyrene copolymer is put, 100~120 DEG C add
Heat 3~10 minutes；
(5) solid material that 450~500 parts by weight are prepared according still further to ratio, is then added the SiC nanometers of 230~250 parts by weight
Powder, the 80FA barras of 75~85 parts by weight, the polyvinyl chloride of 2.0~3.5 parts by volume and 0.5~3 parts by weight peroxidating first
Ethyl ketone is uniformly mixed；
(6) 75~100 parts by weight polymethyl methacrylates-polybutadienes-polystyrene copolymer is put, 100~120 DEG C add
Heat 3~10 minutes；
(7) according still further to ratio prepare the solid materials of 170~185 parts by weight, the SiC nano-powder of 85~95 parts by weight, 30~
The 80FA barras of 40 parts by weight, the polyvinyl chloride of 0.5~1.5 parts by volume and 0.5~3 parts by weight methyl ethyl ketone peroxide, mixing
Uniformly, it heats 3~10 minutes for 100~120 DEG C；
(8) it proportionally weighs and mixes 700 prefabricated parts by weight solids materials, the epoxy resin of 1100~1300 parts by weight
501A, 250~270 parts by weight epoxy resin 501B and 60~70 parts by weight nano silicon oxides stir；
(9) it is sent into high-speed kneading machine, 6-15min is mediated at 80-120 DEG C, after mediating material cooling, be sent into twin-screw extrusion
Machine is granulated to get the insulating materials of the present invention.
6. the floor as claimed in claim 5 preparation method of heat resistant and wear resistant composite material, which is characterized in that the step
(3) polyvinyl chloride that the clear red mud and 0.8 parts by volume of 200 parts by weight are weighed in, uses after stirring.
7. the floor as claimed in claim 5 preparation method of heat resistant and wear resistant composite material, which is characterized in that (4)
With proportionally weighed in step (6) mix the solid materials of 480 prefabricated parts by weight, 240 parts by weight SiC nano-powder,
The 80FA barras of 80 parts by weight, the polyvinyl chloride of 3 parts by volume and 0.5~3 parts by weight methyl ethyl ketone peroxide make after mixing
With.
8. the floor as claimed in claim 5 preparation method of heat resistant and wear resistant composite material, which is characterized in that (8)
In proportionally weigh the mixing solid material of 180 prefabricated parts by weight, the SiC nano-powder of 90 parts by weight, 30 parts by weight
80FA barras, the polyvinyl chloride of 3 parts by volume and 0.5~3 parts by weight methyl ethyl ketone peroxide, use after mixing.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2022238721A1 (en) * | 2021-05-14 | 2022-11-17 | Robot Floor Ltd | A resin for a floor for automated guided vehicles |
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| CN106838497A (en) * | 2017-01-13 | 2017-06-13 | 江苏必得科技股份有限公司 | A kind of inner insulation metal soft pipe and its production technology |
| CN107337833A (en) * | 2017-07-06 | 2017-11-10 | 湖州中林国际贸易有限公司 | A kind of preparation method for mixing plastic-wood floor material |
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Effective date of registration: 20200826 Address after: 225500 Jiangsu Province, Taizhou City Industrial Zone Jiangyan Zhang Dian Zhen concentrated area Applicant after: Taizhou Huali New Material Co.,Ltd. Address before: 225500 Jiangsu Province, Taizhou City Industrial Zone Jiangyan Zhang Dian Zhen concentrated area Applicant before: JIANGSU HUAJUN NEW MATERIAL Co.,Ltd. |
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