CN108487897B - Device and method for removing hydrogen sulfide by oil well casing pipe spraying - Google Patents

Device and method for removing hydrogen sulfide by oil well casing pipe spraying Download PDF

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Publication number
CN108487897B
CN108487897B CN201810481536.8A CN201810481536A CN108487897B CN 108487897 B CN108487897 B CN 108487897B CN 201810481536 A CN201810481536 A CN 201810481536A CN 108487897 B CN108487897 B CN 108487897B
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China
Prior art keywords
valve
gate valve
sleeve
power fluid
liquid
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CN201810481536.8A
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CN108487897A (en
Inventor
袁长忠
张学超
潘永强
张守献
徐鹏
徐闯
冯逸茹
曹嫣镔
宋永亭
林军章
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China Petroleum and Chemical Corp
Sinopec Research Institute of Petroleum Engineering Shengli Co
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China Petroleum and Chemical Corp
Sinopec Research Institute of Petroleum Engineering Shengli Co
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Priority to CN201810481536.8A priority Critical patent/CN108487897B/en
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    • EFIXED CONSTRUCTIONS
    • E21EARTH DRILLING; MINING
    • E21BEARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/34Arrangements for separating materials produced by the well

Abstract

The invention discloses a device and a method for removing hydrogen sulfide by sleeve spraying, wherein the device consists of an outer cylinder, a movable spray pipe, a advancing mechanism, a retreating mechanism, a positioning mechanism and a liquid inlet gate valve; the outer cylinder is connected between the liquid inlet gate valve and the sleeve gate valve through a clamp, the movable spray pipe is positioned in the outer cylinder, and the advancing mechanism is positioned between the retreating mechanism and the positioning mechanism. The device stretches a nozzle with a spraying function into an oil sleeve annulus in the well flushing process, a well flushing liquid containing a desulfurizing agent and provided by a well flushing pump truck and having certain kinetic energy is atomized by the nozzle, fine fog drops are formed in the oil sleeve annulus, and the gas-liquid contact area is increased, so that the gas-phase hydrogen sulfide is thoroughly removed. The problem of current well flushing in-process sleeve pipe hydrogen sulfide removes inefficiency is solved.

Description

Device and method for removing hydrogen sulfide by oil well casing pipe spraying
Technical Field
The invention relates to a device and a method for treating hydrogen sulfide in an oil well, in particular to a device and a method for removing hydrogen sulfide by spraying an oil well casing.
Background
In the thermal recovery of heavy oil, sulfur compounds in crude oil are converted to hydrogen sulfide by thermal cracking, with the production of crude oil, and therefore, significant amounts of hydrogen sulfide are present in the well casing. For the production well, the sleeve gas containing hydrogen sulfide is mainly treated by adopting a mode of emptying and burning or returning an oil pipeline. Incineration technology, which is to make the waste water containing H at well site 2 S, mixing the sleeve gas and natural gas, directly igniting, and mixing H 2 S is burnt out, although the technology can eliminate H 2 S, but produces SO 2 The pollution to the atmospheric environment is caused; the return oil pipeline is mainly communicated with an oil sleeve or a booster pump, and the sleeve gas is conveyed to the oil pipeline and enters the joint station for desulfurization treatment. For an operation well, a well is usually washed before operation, and for an oil well containing hydrogen sulfide, most of the current oil field is treated by directly injecting strong alkali solution (sodium hydroxide solution with the pH value of 11) into a casing by using a pump truck, and the annular cross section of an oil sleeve is about 5-6 times of that of the oil sleeve due to no throttling measure in the injection process, so that after the well washing solution flows into the annular of the oil sleeve from the oil sleeve, the well washing solution cannot form a full flow state and flows down along the inner wall of the casing in a small flow mode, the contact area of the well washing solution and the casing gas is small, the mass transfer efficiency is low, the hydrogen sulfide removal effect in the gas phase in the casing is poor, and when the well washing is finished, the hydrogen sulfide-containing casing gas with a certain height still exists at the upper part of the casing, so that when an oil outlet pipe is started, the life of operators is safe.
Disclosure of Invention
The invention provides a device and a method for removing hydrogen sulfide by spraying an oil well casing, which aims at the defects of the prior art. The device solves the problem that the efficiency of removing the sleeve hydrogen sulfide in the existing well flushing process is low.
The invention discloses a device for removing hydrogen sulfide by spraying a sleeve, which is characterized by comprising an outer cylinder 1, a movable spray pipe 2, a advancing mechanism 3, a retreating mechanism 4, a positioning mechanism 5 and a liquid inlet gate valve 6; the outer cylinder 1 is connected between the liquid inlet gate valve 6 and the sleeve gate valve through a clamp, the movable spray pipe 2 is positioned inside the outer cylinder 1, and the advancing mechanism 3 is positioned between the retreating mechanism 4 and the positioning mechanism 5.
The outer cylinder 1 consists of a shell 11, a first sealing mechanism 12 and a second sealing mechanism 13; the first sealing mechanism 12 and the second sealing mechanism 13 are respectively positioned on the inlet side and the outlet side of the inner wall of the sleeve, and the distance between the first sealing mechanism 12 and the second sealing mechanism 13 is 400-500mm.
The movable spray pipe 2 consists of a liquid inlet pipe 21, a spray hole 22, a spray head 23 and a third sealing mechanism 24; the spraying holes 22 are positioned at the outlet end of the movable spraying pipe 2, the spraying holes 22 are uniformly distributed on the plane and are U-shaped, and the spraying holes 22 are vertically downward; the spray hole 22 is connected with the spray head 23 through an interface, the spray head 23 is in the shape of a cylinder, and the inner cavity of the spray head consists of two cones and a cylinder; the third sealing mechanism 24 is mounted on the outer wall of the inlet pipe 21 between the first sealing mechanism 12 and the second sealing mechanism 13.
The advancing mechanism 3 consists of an advancing power liquid inlet valve 31, an advancing power liquid emptying valve 32, an advancing power liquid pipeline 33 and an advancing power liquid cavity 34; the forward power fluid inlet valve 31 and the forward power fluid discharge valve 32 are arranged on a forward power fluid pipeline 33, and the forward power fluid pipeline 33 passes through the outer shell 11 and is connected with the forward power fluid cavity 34; the forward power fluid chamber 34 is composed of the inner wall of the housing 11, the outer wall of the fluid intake pipe 21, the first seal mechanism 12 and the third seal mechanism 24.
The back mechanism 4 consists of a back power fluid inlet valve 41, a back power fluid emptying valve 42, a back power fluid pipeline 43 and a back power fluid cavity 44; the back-up power fluid inlet valve 41 and the back-up power fluid discharge valve 42 are installed on a back-up power fluid pipeline 43, and the back-up power fluid pipeline 43 passes through the outer shell 11 and is connected with a back-up power fluid cavity 44; the retreating power fluid chamber 44 is composed of the inner wall of the housing 11, the outer wall of the fluid intake pipe 21, the second seal mechanism 13, and the third seal mechanism 24.
The positioning mechanism 5 consists of a threaded positioning pin 51, a positioning pin threaded hole 52 and a positioning hole 53; the threaded locating pin 51 is in threaded connection with a locating pin threaded hole 52, and the locating pin threaded hole is positioned at the left side of the first sealing mechanism 12 by 5-10 mm; the positioning hole 53 is positioned on the outer wall of the liquid inlet pipe 21, and the distance between the positioning hole and the leftmost end of the liquid inlet pipe 21 is 20-30 mm.
In addition, the invention also discloses a method for removing hydrogen sulfide by spraying the sleeve, which is characterized by comprising the following steps:
(1) The inlet of the outer cylinder 1 is connected with the liquid inlet gate valve 6 by a clamp, the outlet of the outer cylinder 1 is connected with the sleeve gate valve, the liquid inlet gate valve 6, the advancing mechanism 3 and the retreating mechanism 4 are connected with a pump truck, and all valves are closed.
(2) Firstly, a sleeve gate valve is opened, secondly, a forward power fluid inlet valve 31 and a backward power fluid discharge valve 42 are opened, the movable spray pipe 2 is slowly pushed into the oil sleeve annulus of the sleeve through the sleeve gate valve by using fluid provided by a pump truck as power fluid, and then a threaded positioning pin 51 is screwed into a positioning hole 53 through a positioning pin threaded hole 52.
(3) The forward power fluid inlet valve 31 and the backward power fluid discharge valve 42 are closed, the inlet gate valve 6 is opened, the pump truck is used for enabling the well washing fluid containing the desulfurizing agent to reach the spray holes 22 through the inlet gate valve 6 and the inner cavity of the movable spray pipe 2, fine mist drops are formed after passing through the spray head 23, and the mist drops are sprayed into an oil sleeve annulus along the vertical downward direction.
(4) After spraying is finished, the liquid inlet gate valve 6 is closed, the threaded locating pin 51 is screwed out of the locating pin threaded hole 52, then the forward power liquid discharging valve 32 and the backward power liquid inlet valve 41 are opened, and the liquid provided by the pump truck is used as power liquid to retract the movable spray pipe 2 into the outer cylinder 1.
(5) Closing the backward power fluid inlet valve 41, then closing the sleeve gate valve, opening the backward power fluid discharge valve 42, and discharging the power fluid in the backward power fluid cavity 44; the liquid inlet gate valve 6, the advancing mechanism 3 and the retreating mechanism 4 are detached from the pipeline connected with the pump truck.
(6) And respectively removing the clamping hoops of the outer cylinder 1, the liquid inlet gate valve 6 and the sleeve gate valve, and ending the treatment.
Compared with the prior art, the invention has the following advantages:
(1) The spray head can extend into the annular space of the oil sleeve and spray along the vertical downward direction, an effective spray space is established in the annular space, the contact rate of the desulfurizing agent and the hydrogen sulfide is improved, and the desulfurization rate of the hydrogen sulfide in the sleeve can reach more than 99.9 percent;
(2) No extra large-scale desulfurization equipment is needed, desulfurization is realized in the well flushing process, and the treatment cost is saved;
(3) Simple implementation process, simple operation, safety and reliability.
Drawings
Fig. 1 is a schematic structural view of the present invention.
FIG. 2 is a graph showing the distribution of spray orifices according to the present invention.
Fig. 3 is a cross-sectional view of the spray head of the present invention.
Detailed Description
The invention will be further described with reference to figures 1, 2 and 3.
As shown in figures 1, 2 and 3, a device for removing hydrogen sulfide by sleeve spraying comprises an outer cylinder 1, a movable spray pipe 2, a advancing mechanism 3, a retreating mechanism 4, a positioning mechanism 5 and a liquid inlet gate valve 6; the outer cylinder 1 is connected between the liquid inlet gate valve 6 and the sleeve gate valve through a clamp, the movable spray pipe 2 is positioned inside the outer cylinder 1, and the advancing mechanism 3 is positioned between the retreating mechanism 4 and the positioning mechanism 5.
Wherein the outer cylinder 1 consists of a shell 11, a first sealing mechanism 12 and a second sealing mechanism 13; the first sealing mechanism 12 and the second sealing mechanism 13 are respectively positioned on the inlet side and the outlet side of the inner wall of the sleeve, and the distance between the first sealing mechanism 12 and the second sealing mechanism 13 is 400-500mm.
The movable spray pipe 2 consists of a liquid inlet pipe 21, a spray hole 22, a spray head 23 and a third sealing mechanism 24; the spraying holes 22 are positioned at the outlet end of the movable spraying pipe 2, the spraying holes 22 are uniformly distributed on the plane and are U-shaped, and the spraying holes 22 are vertically downward; the spray hole 22 is connected with the spray head 23 through an interface, the spray head 23 is in the shape of a cylinder, and the inner cavity of the spray head consists of two cones and a cylinder; the third sealing mechanism 24 is mounted on the outer wall of the inlet pipe 21 between the first sealing mechanism 12 and the second sealing mechanism 13.
The advancing mechanism 3 consists of an advancing power liquid inlet valve 31, an advancing power liquid discharging valve 32, an advancing power liquid pipeline 33 and an advancing power liquid cavity 34; the forward power fluid inlet valve 31 and the forward power fluid discharge valve 32 are arranged on a forward power fluid pipeline 33, and the forward power fluid pipeline 33 passes through the outer shell 11 and is connected with the forward power fluid cavity 34; the forward power fluid chamber 34 is composed of the inner wall of the housing 11, the outer wall of the fluid intake pipe 21, the first seal mechanism 12 and the third seal mechanism 24.
The back-up mechanism 4 consists of a back-up power fluid inlet valve 41, a back-up power fluid discharge valve 42, a back-up power fluid pipeline 43 and a back-up power fluid cavity 44; the back-up power fluid inlet valve 41 and the back-up power fluid discharge valve 42 are installed on a back-up power fluid pipeline 43, and the back-up power fluid pipeline 43 passes through the outer shell 11 and is connected with a back-up power fluid cavity 44; the retreating power fluid chamber 44 is composed of the inner wall of the housing 11, the outer wall of the fluid intake pipe 21, the second seal mechanism 13, and the third seal mechanism 24.
The positioning mechanism 5 consists of a threaded positioning pin 51, a positioning pin threaded hole 52 and a positioning hole 53; the threaded locating pin 51 is in threaded connection with a locating pin threaded hole 52, and the locating pin threaded hole is positioned at the left side of the first sealing mechanism 12 by 5-10 mm; the positioning hole 53 is positioned on the outer wall of the liquid inlet pipe 21, and the distance between the positioning hole and the leftmost end of the liquid inlet pipe 21 is 20-30 mm.
A method for removing hydrogen sulfide by spraying a sleeve, which is characterized by comprising the following steps:
(1) The inlet of the outer cylinder 1 is connected with the liquid inlet gate valve 6 by a clamp, the outlet of the outer cylinder 1 is connected with the sleeve gate valve, the liquid inlet gate valve 6, the advancing mechanism 3 and the retreating mechanism 4 are connected with a pump truck, and all valves are closed.
(2) Firstly, a sleeve gate valve is opened, secondly, a forward power fluid inlet valve 31 and a backward power fluid discharge valve 42 are opened, the movable spray pipe 2 is slowly pushed into the oil sleeve annulus of the sleeve through the sleeve gate valve by using fluid provided by a pump truck as power fluid, and then a threaded positioning pin 51 is screwed into a positioning hole 53 through a positioning pin threaded hole 52.
(3) The forward power fluid inlet valve 31 and the backward power fluid discharge valve 42 are closed, the inlet gate valve 6 is opened, the pump truck is used for enabling the well washing fluid containing the desulfurizing agent to reach the spray holes 22 through the inlet gate valve 6 and the inner cavity of the movable spray pipe 2, fine mist drops are formed after passing through the spray head 23, and the mist drops are sprayed into an oil sleeve annulus along the vertical downward direction.
(4) After spraying is finished, the liquid inlet gate valve 6 is closed, the threaded locating pin 51 is screwed out of the locating pin threaded hole 52, then the forward power liquid discharging valve 32 and the backward power liquid inlet valve 41 are opened, and the liquid provided by the pump truck is used as power liquid to retract the movable spray pipe 2 into the outer cylinder 1.
(5) Closing the backward power fluid inlet valve 41, then closing the sleeve gate valve, opening the backward power fluid discharge valve 42, and discharging the power fluid in the backward power fluid cavity 44; the liquid inlet gate valve 6, the advancing mechanism 3 and the retreating mechanism 4 are detached from the pipeline connected with the pump truck.
(6) And respectively removing the clamping hoops of the outer cylinder 1, the liquid inlet gate valve 6 and the sleeve gate valve, and ending the treatment.

Claims (3)

1. The device for removing the hydrogen sulfide by spraying the sleeve is characterized by comprising an outer barrel, a movable spray pipe, a advancing mechanism, a retreating mechanism, a positioning mechanism and a liquid inlet gate valve; the outer cylinder is connected between the liquid inlet gate valve and the sleeve gate valve through a clamp, the movable spray pipe is positioned in the outer cylinder, the advancing mechanism is positioned between the retreating mechanism and the positioning mechanism, and the outer cylinder consists of a shell, a first sealing mechanism and a second sealing mechanism; the first sealing mechanism and the second sealing mechanism are respectively positioned at the inlet side and the outlet side of the inner wall of the sleeve, the distance between the first sealing mechanism and the second sealing mechanism is 400-500mm, and the movable spray pipe consists of a liquid inlet pipe, a spray hole, a spray head and a third sealing mechanism; the spraying holes are positioned at the outlet end of the movable spraying pipe, are uniformly distributed on a plane and are U-shaped, and are vertically downward; the spray hole is connected with the spray head through an interface, the spray head is in a cylindrical shape, and the inner cavity of the spray head consists of two cones and a cylinder; the third sealing mechanism is arranged on the outer wall of the liquid inlet pipe and is positioned between the first sealing mechanism and the second sealing mechanism, and the back-off mechanism consists of a back-off power liquid inlet valve, a back-off power liquid emptying valve, a back-off power liquid pipeline and a back-off power liquid cavity; the backward power fluid inlet valve and the backward power fluid discharge valve are arranged on a backward power fluid pipeline, and the backward power fluid pipeline penetrates through the outer shell and is connected with the backward power fluid cavity; the retreating power liquid cavity consists of an inner wall of the shell, an outer wall of the liquid inlet pipe, a second sealing mechanism and a third sealing mechanism; the positioning mechanism consists of a threaded positioning pin, a positioning pin threaded hole and a positioning hole; the threaded locating pin is in threaded connection with a locating pin threaded hole, and the locating pin threaded hole is positioned at the left side of the first sealing mechanism by 5-10 mm; the positioning hole is positioned on the outer wall of the liquid inlet pipe, and the distance between the positioning hole and the leftmost end of the liquid inlet pipe is 20-30 mm.
2. The device for removing hydrogen sulfide by spraying a sleeve according to claim 1, wherein the advancing mechanism comprises an advancing power liquid inlet valve, an advancing power liquid discharging valve, an advancing power liquid pipeline and an advancing power liquid cavity; the forward power fluid inlet valve and the forward power fluid vent valve are arranged on a forward power fluid pipeline, and the forward power fluid pipeline passes through the outer shell and is connected with the forward power fluid cavity; the advancing power liquid cavity consists of an inner wall of the shell, an outer wall of the liquid inlet pipe, a first sealing mechanism and a third sealing mechanism.
3. A method for the spray removal of hydrogen sulphide from a casing according to any of claims 1 to 2, comprising in particular the steps of:
(1) The inlet of the outer cylinder is connected with a liquid inlet gate valve by a clamp, the outlet of the outer cylinder is connected with a sleeve gate valve, the liquid inlet gate valve, the advancing mechanism and the retreating mechanism are connected with a pump truck, and all valves are closed;
(2) Firstly, opening a sleeve gate valve, secondly, opening a forward power fluid inlet valve and a backward power fluid discharge valve, using fluid provided by a pump truck as power fluid to slowly push a movable spray pipe into an oil sleeve annulus of a sleeve through the sleeve gate valve, and then screwing a threaded positioning pin into a positioning hole through a positioning pin threaded hole;
(3) Closing a forward power fluid inlet valve and a backward power fluid discharge valve, opening a fluid inlet gate valve, enabling the well washing fluid containing the desulfurizing agent to reach a spray hole through an inner cavity of the fluid inlet gate valve and a movable spray pipe by using a pump truck, forming fine mist drops after passing through a spray head, and spraying the mist drops into an oil sleeve annulus along the vertical downward direction;
(4) Closing a liquid inlet gate valve after spraying is finished, screwing out a threaded locating pin from a locating pin threaded hole, opening a forward power liquid emptying valve and a backward power liquid inlet valve, and completely returning the movable spray pipe into the outer cylinder by using liquid provided by a pump truck as power liquid;
(5) Closing a backward power fluid inlet valve, then closing a sleeve gate valve, opening a backward power fluid emptying valve, and discharging power fluid in a backward power fluid cavity; removing pipelines connected with the pump truck by the liquid inlet gate valve, the advancing mechanism and the retreating mechanism;
(6) And respectively removing the hoops of the outer cylinder, the liquid inlet gate valve and the sleeve gate valve, and ending the treatment.
CN201810481536.8A 2018-05-18 2018-05-18 Device and method for removing hydrogen sulfide by oil well casing pipe spraying Active CN108487897B (en)

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CN103563880A (en) * 2013-11-14 2014-02-12 哈尔滨工程大学 Pesticide spraying machine
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CA2411643A1 (en) * 2001-11-13 2003-05-12 Baker Hughes Incorporated Fracturing fluids for delayed flow back operations
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CN206794293U (en) * 2017-04-10 2017-12-26 成都大漠石油技术有限公司 It is a kind of to be used to remove the device for being attached to paraffin in petroleum pipeline
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