CN108485376A - A kind of water base plate paper of high speed ink and preparation method and application - Google Patents
A kind of water base plate paper of high speed ink and preparation method and application Download PDFInfo
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- CN108485376A CN108485376A CN201810318779.XA CN201810318779A CN108485376A CN 108485376 A CN108485376 A CN 108485376A CN 201810318779 A CN201810318779 A CN 201810318779A CN 108485376 A CN108485376 A CN 108485376A
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- ink
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
The invention belongs to ink formulations research, development and application technical fields, a kind of water base plate paper of high speed ink and preparation method and application are disclosed, the water base plate paper of high speed ink component example in mass ratio is made of mill base 40 48%, emulsion acrylic and acrylic ester copolymerization object 30 38%, wetting and dispersing levelling agent 3 5% and deionized water 17 27%；The component of mill base example in mass ratio is made of alkali solubility styrene-acrylic copolymer 30 38%, organic pigment 30 36%, deionized water 30 40%, antifoam additives 0.3 0.6%.Ink of the present invention is to be free of organic solvent using water as medium, thus volatile organic matter (VOC) measures very little, and substantially without odor when printing, property friendly to environment is good.
Description
Technical field
The invention belongs to ink formulations research, development and application technical fields, are related to a kind of water base plate paper of high speed
Ink and preparation method and application.
Background technology
Currently, the prior art commonly used in the trade is such：
Solvent-based ink is to be changed into solid print from liquid on printable fabric using the solvent volatilization in printing process
Image.With solvent-based ink print quality is good, print speed printing speed is fast and ink cost is also relatively low, thus it is still to adopt extensively so far
One major class ink.But dissolving base oil ink needs a large amount of organic solvents to vapor away and (generates a large amount of after printing
VOC), the solvent evaporateing into printing environment is such as without collecting and handling meeting to human body and environmental pollution and pollution.For many years
Come, develops many solvent recovery process and device, but these devices not only invest the big but also separation of recycling design and again profit
With still there is many difficult points.
Prior art is as follows：
The first step screens alkali solubility styrene-acrylic resin liquid, grinds the pigment dispersion for being made stable, i.e. color
Slurry.
Second step selects emulsion acrylate resin:As a result 200,000 or more molecular weight is selected, 60 DEG C of Tg points or more gather
Product emulsion is closed as combination resin.
The additives such as third step screening stabilization, long-acting wetting dispersing agent, levelling agent and antifoaming agent.
4th step ink formulations composition research and exploitation and formula composition optimization.
In conclusion problem of the existing technology is：
It is ink and the target that printing industry is struggled for many years, really this conversion with water-based inks substitution solvent ink
There are many difficulties.Although the water-based inks printed on uncoated paper industrialization already is (such as in the book and periodical printing glue of no coating
Printing on the materials such as millboard, corrugated paper, napkin paper and non-woven fabrics), but to the low high quality coating paper of permeability (such as weight pound
Glazed printing paper) and the materials such as plastics and metal foil material, solvent-based ink most of or using solvent volatile dry.Many essences
It is yet normal that the picture album, cosmetics, clothes, house of U.S. print the paper printed matters such as the paper-made advertising of volume, cigarette pack and first line
Useful solvent-based ink.These are referred to as paper gravure ink, water baseization of this kind of solvent-based ink with the ink of intaglio printing
It needs to capture.
Invention content
In view of the problems of the existing technology, the present invention provides the water base plate paper of a kind of high speed ink and preparation methods
And application.
The invention is realized in this way：A kind of water base plate paper of high speed ink, the water base plate paper of high speed ink
Component example in mass ratio is by mill base 40-48%, emulsion acrylic and acrylic ester copolymerization object 30-38%, wetting and dispersing stream
Flat agent 3-5% and deionized water 17-27% compositions；
The component of mill base example in mass ratio is by alkali solubility copolymer in cinnamic acrylic ester 30-38%, organic pigment
30-36%, deionized water 30-40%, antifoam additives 0.3-0.6% compositions.
Another object of the present invention is to provide a kind of preparation methods of the water base plate paper of high speed ink, including：
Step 1 screens alkali solubility copolymer in cinnamic acrylic ester, is disperseed with organic pigment, ground, and color is made
Slurry；
Step 2 selects glass transition temperature Tg more than 60 DEG C and compatible with alkali solubility copolymer in cinnamic acrylic ester
Property good emulsion acrylic and acrylic ester copolymerization object；
Step 3, selective wetting disperse levelling agent, antifoam additives；
Step 4 takes the mill base of preparation, adds emulsion acrylate polymer, wetting and dispersing levelling agent, deionized water,
Stirring, is mixed colours, quality testing, and high speed water base plate paper ink is made.
Further, the step 1, specifically includes：
Example takes alkali solubility copolymer in cinnamic acrylic ester 30-38%, organic pigment 30-36%, deionization in mass ratio
Water 30-40%, antifoam additives 0.3-0.6%；After 12-24 hours soaking, 1500 revs/min are disperseed 30-40 minutes, and upper machine is ground
The roads 3-4 are ground, until fineness≤15um, is made mill base.
Further, the step 4, specifically includes：
Mill base 40-48%, addition 30-38% molecular weight is taken to be more than the emulsion-type propylene of 60 DEG C of 200,000 or more, Tg points or more
Acid ester polymer, then add wetting and dispersing levelling agent 3-5%, deionized water 17-27%；600-800 revs/min of stirring 20-30
Minute, it is mixed colours, quality testing, high speed water base plate paper ink is made.
Another object of the present invention is to provide a kind of paper using the water base plate paper of the high speed ink printing.
Advantages of the present invention and good effect are：
Ink colors concentration of the present invention is high, and rate of drying is fast, and under equal conditions test uses, 220 ms/min of print speed printing speed
It can be completely dried, and the print speed printing speed of former solvent-based ink is 240 ms/min, relatively；
This ink can use printing plate depth 30-35um (originally printing plate depth 40-45um), accelerate ink on paper
Rate of drying, this is also one of an important factor for water-based inks adapt to high speed printing.
Transferability is good, and especially shallow version linked network printing, pattern line is clearly clearly demarcated, folds color chromatography effect than former solvent type oil
Black is more life-like.
With very low VOC and very low residual smell, the target of ink water baseization is realized.
Market Ji effectiveness forecasting analysis：
With production-scale expansion and every cost optimization, by perfect sales platform, 2018-the year two thousand twenty of product
Market Forecast Analysis it is as follows：
As can be seen from the above table, increasingly mature with product processes technology, production cost will decline year by year, obtain
Extraordinary economic benefit.
Social environment benefit：
The water base plate paper of high speed ink is the new product of emphasis research and development of the present invention, and industrialized implementation will directly create life
Production, sale provide multiple jobs with management position.
Inking amount of the present invention is small, and modern printing plate depth 30-35um, more shallow than original 40-45um, printing plate depth can save ink
Use cost 10% or so；It is more better than former solvent-based ink true to nature to fold color chromatography effect for shallow version printing clear patterns；This hair
It is bright that there is very low VOC and very low smell, realize the target of ink water baseization.
The water base plate paper of high speed provided in an embodiment of the present invention ink, big using amount of pigment, color depth is high, and flows
Dynamic property is good, and viscosity does not increase, the mill base of excellent storage stability, particularly important to screening copolymer in cinnamic acrylic ester resin.
Description of the drawings
Fig. 1 is the preparation method flow chart of the water base plate paper of high speed provided in an embodiment of the present invention ink.
Specific implementation mode
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiments, to the present invention
It is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to
Limit the present invention.
The preparation method of the water base plate paper of the high speed ink of the present invention includes：
First, alkali solubility copolymer in cinnamic acrylic ester is screened, is divided through special process with high-quality organic pigment
It dissipates, grinding, colour saturation height, the mill base of fluid stable is made；
Secondly, select glass transition temperature (Tg) more than 60 DEG C and compatible with alkali solubility copolymer in cinnamic acrylic ester
Property good emulsion acrylic and acrylic ester copolymerization object, to improve the rate of drying of ink and the physical mechanical property of ink film
Such as hardness, mechanical strength, wearability and heat resistance.
Again, excellent various of selection the additive such as stable wetting and dispersing of production, storage, levelling and defoaming effect help
Agent, with improve the printability of ink such as pigment wettability, dispersibility, stability, ink flowing and levelability, eliminate foam with
And improve the performance of ink film.
Finally, the optimization of the manufacturing process and formula composition of ink is analyzed.
Ink product colour saturation of the present invention is high, and when storage does not swell, do not thicken, and fluid stable, volatile dry speed is fast,
It tests and uses under equal conditions, 220 ms/min of print speed printing speed can be completely dried, and the print speed printing speed of former solvent-based ink is 240
M/min, relatively；The present invention can be suitble to use under the preceding dike that can reach the image color and colour saturation required by user
The printing plate of printing plate depth 30-35um prints, the version depth than original 40-45um, the version depth reduced using depression capacity and
Printing ink moisture evaporation capacity is set largely to reduce, it is highly advantageous to improving print speed printing speed.
Ink of the present invention is to be free of organic solvent using water as medium, thus volatile organic matter (VOC) measures very little, print
Substantially without odor when brush, property friendly to environment is good.
The present invention use combined based on emulsion-type copolymer and alkali solubility copolymer in cinnamic acrylic ester it is compound
Type binder system.Wherein the first constituent element water solubility copolymer is a kind of alkali solubility copolymer in cinnamic acrylic ester, this total
Polymers is water-soluble in alkaline system, and this resin has good compatibility to pigment, under the assistance of addition dispersant
The mill base of stable high concentrations can be made.It is volatilized using ammonia and/or low-molecular weight amines after printing, is precipitated from water rapidly,
And it is converted into solid polymer.Also being introduced in this interpolymer molecule structure has unsaturated bond, and it is anti-can to carry out certain crosslinking
The mechanical strength of solidification ink film should be helped to improve.
The present invention selects the second constituent element of the acrylic acid and ACRYLATE COPOLYMER EMULSION of intermediate molecular weight as binder.
Emulsion polymer structural stability is good, is advantageously used for ink storage stability, lotion dehydration demulsification film forming in printing process.Due to
Emulsion state polymer can have the ink film that is formed in this way than water-soluble high more molecular weight in mechanical strength, alkali resistance and resistance to
It is chemically much better.
Emulsion-type copolymer and alkali-soluble copolymer have his own strong points in aspect of performance, and ink manufacturers are selective polymer
Structure, composition and compatibility carry out coordinated balance, and here it is the key technologies of ink manufacturers.The present invention uses in experimental basis
The molecular weight of acrylic acid ester emulsion polymer is selected to be more than 200,000 and glass transition temperature Tg>60 DEG C, this is key technology of the present invention
One of.
Solvent-based ink is easier to realize high speed printing, because the latent heat of vaporization of solvent is relatively low, organic solvent is printing
It is readily volatilized after brush, however the latent heat of vaporization of water is more much bigger than organic solvent, therefore the evaporation rate of water directly determines printing
Speed.Printing house is had using properly increasing environment temperature and increasing printing machine surrounding air flow rate to improving print speed printing speed
Certain effect, but these measure energy consumptions are relatively high.Printing house claims thus, and to produce pigment concentration relatively high for ink factory
Water-based inks, such printing house, which can change the depth of galley, shallow (such as to be changed depression on printing plate shallow, changes from 40-45 μm
It it is 30-35 μm).Here it is printed using high pigment levels ink and with scrobicula cave printing plate.
Improving pigment concentration in ink can be such that ink rheology varies widely, and viscosity improves rapidly, and mobility is deteriorated,
This is also the difficult point in ink manufacture.
The alkali resistance and the property in terms of color that the present invention analyzes pigment in the selection of binder, binder is to pigment
The compatibility of particle.Thus these factors are had been contemplated that in printed article colour saturation and chromaticity measurement result.Finally in reality
In printing experiment, print speed printing speed is made to reach 220 ms/min and 240 ms/min of common solvent-based ink print speed printing speed relatively.
The water base plate paper of high speed provided in an embodiment of the present invention ink component example in mass ratio is by mill base 40-48%, breast
Liquid type acrylic acid and acrylic ester copolymerization object 30-38%, wetting and dispersing levelling agent 3-5% and deionized water 17-27% groups
At；
The component of mill base example in mass ratio is by alkali solubility copolymer in cinnamic acrylic ester 30-38%, organic pigment
30-36%, deionized water 30-40%, antifoam additives 0.3-0.6% compositions.
The invention will be further described below in conjunction with the accompanying drawings.
As shown in Figure 1, the preparation method of the water base plate paper of high speed provided in an embodiment of the present invention ink, including：
S101：Alkali solubility copolymer in cinnamic acrylic ester is screened, disperseed with organic pigment, ground, color is made
Slurry；
S102：Select glass transition temperature Tg be more than 60 DEG C and with alkali solubility copolymer in cinnamic acrylic ester compatibility
Good emulsion acrylic and acrylic ester copolymerization object；
S103：Selective wetting disperses levelling agent, antifoam additives；
S104：The mill base of preparation, addition emulsion acrylate polymer, wetting and dispersing levelling agent, deionized water is taken to stir
It mixes, is mixed colours, quality testing, high speed water base plate paper ink is made.
The step S101, specifically includes：
Example takes alkali solubility copolymer in cinnamic acrylic ester 30-38%, organic pigment 30-36%, deionization in mass ratio
Water 30-40%, antifoam additives 0.3-0.6%；After 12-24 hours soaking, 1500 revs/min are disperseed 30-40 minutes, and upper machine is ground
The roads 3-4 are ground, until fineness≤15um, is made mill base.
The step S104, specifically includes：
Mill base 40-48%, addition 30-38% molecular weight is taken to be more than the emulsion-type propylene of 60 DEG C of 200,000 or more, Tg points or more
Acid ester polymer, then add wetting and dispersing levelling agent 3-5%, deionized water 17-27%；600-800 revs/min of stirring 20-30
Minute, it is mixed colours, quality testing, high speed water base plate paper ink is made.
With reference to specific embodiment, the invention will be further described.
Embodiment 1：
The preparation method of the water base plate paper of high speed provided in an embodiment of the present invention ink, including：
The first step takes 30g copolymer in cinnamic acrylic ester, 36g organic pigments, 0.6g antifoaming agent, 33.4g water purifications, leaching
High-speed stirred dispersion (1500 revs/min) 30 minutes after bubble 12 hours, grinding 4 obtain the mill base of high concentration；
Second step, takes 40g mill bases, 38g emulsion acrylate resins, 3g wetting and dispersing leveling auxiliary agents, 19g water purifications, in
Speed is dispersed with stirring (600-800 revs/min) 20-30 minutes, obtains the water base plate paper of high speed ink.
Embodiment 2：
The preparation method of the water base plate paper of high speed provided in an embodiment of the present invention ink, including：
The first step takes 32g copolymer in cinnamic acrylic ester, 34g organic pigments, 0.5g antifoaming agent, 33.5g water purifications, leaching
High-speed stirred dispersion (1500 revs/min) 30 minutes after bubble 12 hours, grinding 4 obtain the mill base of high concentration；
Second step, takes 42g mill bases, 35g emulsion acrylate resins, 3.7g wetting and dispersing leveling auxiliary agents, and 19.3g is net
Water, moderate-speed mixer disperse (600-800 revs/min) 20-30 minutes, obtain the water base plate paper of high speed ink.
Embodiment 3：
The preparation method of the water base plate paper of high speed provided in an embodiment of the present invention ink, including：
The first step takes 35g copolymer in cinnamic acrylic ester, 32g organic pigments, 0.4g antifoaming agent, 32.6g water purifications, leaching
High-speed stirred dispersion (1500 revs/min) 30 minutes after bubble 12 hours, grinding 4 obtain the mill base of high concentration；
Second step, takes 45g mill bases, 32g emulsion acrylate resins, 4.3g wetting and dispersing leveling auxiliary agents, and 18.7g is net
Water, moderate-speed mixer disperse (600-800 revs/min) 20-30 minutes, obtain the water base plate paper of high speed ink.
Embodiment 4：
The preparation method of the water base plate paper of high speed provided in an embodiment of the present invention ink, including：
The first step takes 38g copolymer in cinnamic acrylic ester, 30g organic pigments, 0.3g antifoaming agent, 31.7g water purifications, leaching
High-speed stirred dispersion (1500 revs/min) 30 minutes after bubble 12 hours, grinding 4 obtain the mill base of high concentration；
Second step, takes 48g mill bases, 30g emulsion acrylate resins, 5g wetting and dispersing leveling auxiliary agents, 17g water purifications, in
Speed is dispersed with stirring (600-800 revs/min) 20-30 minutes, obtains the water base plate paper of high speed ink.
High speed water base plate paper ink is made in the method for the present invention, and volatile dry color depth is high, rate of drying is fast, printing
220 ms/min of speed, close with 240 ms/min of solvent type, ink transferability is good, especially shallow version wire mark brush, pattern lines
Item is clearly clearly demarcated, and folded color chromatography effect is more more life-like than former solvent borne ink, and inking amount is few, printing depth 30-35um, than original
Carry out the shallow of prior art 40-45um, is saved than original use cost with ink amount.
With reference to concrete analysis, the invention will be further described.
The water base plate paper of high speed provided in an embodiment of the present invention ink, by copolymer in cinnamic acrylic ester and lotion
Type acrylate presses 50 respectively:50、40:60、33:67、25:75、20:80 ratio carries out a series of tests, matches in detail
Such as following table：
Table 1
Description of the process：1. material " 1 ", " 2 ", " 3 " are dispersed through, Grinding manufacturing is at mill base；
2. add materials " 4 ", " 5 ", " 6 " under moderate-speed mixer, it is modulated into ink product.
Above scheme prepares capability and performance test result is as follows the table of ink：
Table 2
As seen from the above table, copolymer in cinnamic acrylic ester presses 1 with emulsion acrylate resin in scheme three:2 collocation
Ratio, just dryness is good for ink, and ink storage does not thicken, and fluid is good, and transferring effect is good, is ideal
Feasible scheme.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention
All any modification, equivalent and improvement etc., should all be included in the protection scope of the present invention made by within refreshing and principle.
Claims (5)
1. a kind of water base plate paper of high speed ink, which is characterized in that the water base plate paper of high speed ink component presses quality
Ratio by mill base 40-48%, emulsion acrylic and acrylic ester copolymerization object 30-38%, wetting and dispersing levelling agent 3-5%,
And deionized water 17-27% compositions；
The component of mill base example in mass ratio is by alkali solubility copolymer in cinnamic acrylic ester 30-38%, organic pigment 30-
36%, deionized water 30-40%, antifoam additives 0.3-0.6% compositions.
2. a kind of preparation method of water base plate paper of high speed as described in claim 1 ink, which is characterized in that the high speed water
The preparation method of base intaglio plate paper printing ink includes：
Step 1 screens alkali solubility copolymer in cinnamic acrylic ester, is disperseed with organic pigment, ground, and mill base is made；
Step 2 selects glass transition temperature Tg more than 60 DEG C and good with alkali solubility copolymer in cinnamic acrylic ester compatibility
Emulsion acrylic and acrylic ester copolymerization object；
Step 3, selective wetting disperse levelling agent, antifoam additives；
Step 4 takes the mill base of preparation, addition emulsion acrylate polymer, wetting and dispersing levelling agent, deionized water to stir
It mixes, is mixed colours, quality testing, high speed water base plate paper ink is made.
3. the preparation method of the water base plate paper of high speed as claimed in claim 2 ink, which is characterized in that the step 1, tool
Body includes：
Example takes alkali solubility copolymer in cinnamic acrylic ester 30-38%, organic pigment 30-36%, deionized water in mass ratio
30-40%, antifoam additives 0.3-0.6%；After 12-24 hours soaking, 1500 revs/min are disperseed 30-40 minutes, upper machine grinding
The roads 3-4, until fineness≤15um, is made mill base.
4. the preparation method of the water base plate paper of high speed as claimed in claim 2 ink, which is characterized in that the step 4, tool
Body includes：
Mill base 40-48%, addition 30-38% molecular weight is taken to be more than the emulsion acrylate of 60 DEG C of 200,000 or more, Tg points or more
Polymer, then add wetting and dispersing levelling agent 3-5%, deionized water 17-27%；600-800 revs/min is stirred 20-30 minutes,
It is mixed colours, quality testing, high speed water base plate paper ink is made.
5. a kind of paper using the water base plate paper of high speed described in claim 1 ink printing.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112646419A (en) * | 2020-09-24 | 2021-04-13 | 东莞市万润涂料有限公司 | MY-C paper gravure ink with gradually changed colors and preparation method thereof |
| CN112680025A (en) * | 2020-11-27 | 2021-04-20 | 江苏唐彩新材料科技股份有限公司 | Water-based gravure frosted ink and preparation method thereof |
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| CN102304262A (en) * | 2010-05-28 | 2012-01-04 | 中山大学 | Self-crosslinked polyacrylate latex and preparation method thereof, and water-based paper ink |
| CN103194121A (en) * | 2013-03-18 | 2013-07-10 | 福建省利得彩环保科技有限公司 | Water-based gravure printing ink for thermal transfer printing |
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| CN102304262A (en) * | 2010-05-28 | 2012-01-04 | 中山大学 | Self-crosslinked polyacrylate latex and preparation method thereof, and water-based paper ink |
| CN103194121A (en) * | 2013-03-18 | 2013-07-10 | 福建省利得彩环保科技有限公司 | Water-based gravure printing ink for thermal transfer printing |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112646419A (en) * | 2020-09-24 | 2021-04-13 | 东莞市万润涂料有限公司 | MY-C paper gravure ink with gradually changed colors and preparation method thereof |
| CN112680025A (en) * | 2020-11-27 | 2021-04-20 | 江苏唐彩新材料科技股份有限公司 | Water-based gravure frosted ink and preparation method thereof |
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Application publication date: 20180904 |