CN108485229A - A kind of flame-retardant polyphenyl ether resin alloy and preparation method thereof - Google Patents
A kind of flame-retardant polyphenyl ether resin alloy and preparation method thereof Download PDFInfo
- Publication number
- CN108485229A CN108485229A CN201711368719.0A CN201711368719A CN108485229A CN 108485229 A CN108485229 A CN 108485229A CN 201711368719 A CN201711368719 A CN 201711368719A CN 108485229 A CN108485229 A CN 108485229A
- Authority
- CN
- China
- Prior art keywords
- weight
- parts
- halogen
- polyphenyl ether
- flame
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
- C08L71/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
- C08L71/12—Polyphenylene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/22—Halogen free composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention discloses a kind of flame-retardant polyphenyl ether resin alloy and preparation method thereof, wherein the flame-retardant polyphenyl ether resin alloy, it is composed of the following components：30 50 parts by weight of polyphenyleneoxide resins, 60 90 parts by weight of styrene resinoids, 10 60 parts by weight carboxylic carbon nano-tubes, 5 20 parts by weight halogen-free flame retardants, 15 parts by weight bulking agents and 23 parts by weight processing aids；The halogen-free flame retardants is made of carboxylic carbon nano-tube nano particle, phosphorus series non-halogen fire retardant, melamine, expansible graphite and metal oxide nanoparticles；The processing aid is made of antioxidant, lubricant and releasing agent.Not only flame retardant rating meets requirement to flame-retardant polyphenyl ether resin alloy in the present invention, but also the mechanical performance of resin alloy is barely affected when fire retardant additive amount is less than the 25% of resin alloy quality.
Description
Technical field
The present invention relates to resin alloy field, it is related specifically to a kind of flame-retardant polyphenyl ether resin alloy and preparation method thereof.
Background technology
Polyphenylene oxide resin has many excellent performances, for example, mechanical performance, hydrolysis, acid-alkali-corrosive-resisting, heat resistance,
Dimensional stability etc., product are widely employed for electronic apparatus, auto parts and components, water treatment facilities, chemical industry etc.
Field.Although the heat resistance and mechanical strength of Polyphenyl ether alloy material are especially excellent, there is also some fatal defects,
Such as poor fluidity, oil resistivity are poor, stress cracking is serious etc..Polyphenyl ether alloy material can be solved by a series of modification
Poor fluidity, the problems such as oil resistivity is poor, stress cracking is serious, but needing the flame retardant rating of assertive evidence polyphenylene oxide resin alloy
On the basis of, also to ensure the mechanical performance of polyphenylene oxide resin alloy not by larger impact, this point is at present also than relatively difficult to achieve.
Invention content
In view of this, the purpose of the present invention is to provide a kind of flame-retardant polyphenyl ether resin alloy and preparation method thereof, this hair
Not only flame retardant rating meets requirement to flame-retardant polyphenyl ether resin alloy in bright, but also is closed less than resin in fire retardant additive amount
Golden amount 25% when resin alloy mechanical performance be barely affected.
In order to solve the above technical problems, the technical solution adopted by the present invention is as follows：A kind of flame-retardant polyphenyl ether resin alloy, by
Following components forms：30-50 parts by weight of polyphenyleneoxide resin, 60-90 parts by weight of styrene resinoid, 10-60 parts by weight carboxylated
Carbon nanotube, 15-40 parts by weight halogen-free flame retardants, 1-5 parts by weight bulking agent and 2-3 parts by weight processing aids；The Halogen resistance
Agent is fired by 7-18 parts by weight carboxylic carbon nano-tubes nano particle, 10-24 parts by weight phosphorus series non-halogens fire retardant, 3-12 parts by weight three
Poly cyanamid, 30-48 parts by weight expansible graphite and 12-27 parts by weight of metal oxide nano particles composition；The processing aid
It is made of 2 parts by weight antioxidant, 6 parts by weight lubricants and 3 parts by weight releasing agents.
Above-mentioned flame-retardant polyphenyl ether resin alloy, the carboxylic carbon nano-tube are 60- by 2-8 parts by weight carboxyl molar fractions
80% carboxylated single-layer carbon nano-tube and the carboxylated multilayer carbon nanotube that 1-5 parts by weight carboxyl molar fractions are 50-80% form；
The carboxylic carbon nano-tube nano particle is by the carboxylated single-layer carbon nano-tube nano particle that carboxyl molar fraction is 50-80%
With the carboxylated multilayer carbon nanotube nano particle composition that carboxyl molar fraction is 40-60%.
Above-mentioned flame-retardant polyphenyl ether resin alloy, the carboxylic carbon nano-tube nano particle is by 6-9 parts by weight carboxylated lists
Layer carbon nanotube particle and 3-6 parts by weight multilayer carbon nanotube nano particles composition.
Above-mentioned flame-retardant polyphenyl ether resin alloy, the phosphorus series non-halogen fire retardant is by 1-6 parts by weight polyphosphate, 2-8 weight
Part phospha phosphine oxide and 3-6 parts by weight phosphonate esters composition.
Above-mentioned flame-retardant polyphenyl ether resin alloy, the metal oxide is by 2-3 parts by weight of titanium dioxide nano particle, 3-8
Part by weight of zinc oxide nano particle and 4-10 parts by weight of alumina nano particles composition.
Above-mentioned flame-retardant polyphenyl ether resin alloy, the antioxidant are 0.6-1.2 parts by weight of lemon acid, the life of 1.5-2 parts by weight
Educate the mixture of phenol and 1.0-2.0 parts by weight phosphite esters；The lubricant is 1-4 parts by weight Lanthanum Stearate, 1.8-3.2 weight
The mixture of part zinc stearate, 2-4 weight account polyethylenes wax and 1.2-2.6 parts by weight pentaerythritol stearates；The demoulding
Agent is the mixture of 1-4 weight silicone oil release agent and 2-5 parts by weight microwaxes.
Above-mentioned flame-retardant polyphenyl ether resin alloy, the styrene resin are by 8-20 parts by weight average weight-molecular masses
High impact polystyrene, the 10-20 parts by weight average weight-molecular masses of 200000-300000g/mol is 180000-
The styrene-acrylonitrile copolymer and 5-16 parts by weight average weight-molecular masses of 300000g/mol is 220000-360000g/
The methacrylate of mol-styrol copolymer composition.
Above-mentioned flame-retardant polyphenyl ether resin alloy, the bulking agent are composed of the following components：20-30 parts by weight alkadienes is oligomeric
Object, 2-15 parts by weight maleic anhydride and 1-12 parts by weight of acrylic acid；The diene hydrocarbon oligomer is divided by 2-7 parts by weight weight is opposite
The butadiene oligomer and 1-5 parts by weight average weight-molecular masses that protonatomic mass is 800-2000g/mol are 1500-3000g/
The pentadiene oligomer of mol.
The preparation method of above-mentioned flame-retardant polyphenyl ether resin alloy, includes the following steps：
（1）According to preparing raw material as following formula：30-50 parts by weight of polyphenyleneoxide resin, 60-90 parts by weight of styrene resinoid, 10-
60 parts by weight carboxylic carbon nano-tubes, 15-40 parts by weight halogen-free flame retardants, 1-5 parts by weight bulking agent and the processing of 2-3 parts by weight help
Agent；The halogen-free flame retardants is fire-retardant by 7-18 parts by weight carboxylic carbon nano-tubes nano particle, 10-24 parts by weight phosphorus series non-halogens
Agent, 3-12 parts by weight melamine, 30-48 parts by weight expansible graphite and 12-27 parts by weight of metal oxide nano particle groups
At；The processing aid is made of 2 parts by weight antioxidant, 6 parts by weight lubricants and 3 parts by weight releasing agents；
（2）By step（1）In halogen-free flame retardants in carboxylic carbon nano-tube nano particle and metal oxide in carbon atom
Ultrasonic mixing 10-20 minutes in the alkane that number is 8-11, is then dried to obtain initial mixture, then by initial mixture,
Phosphorus series non-halogen fire retardant and expansible graphite are mixed to get halogen-free flame retardants；
（3）By step（1）In ready polyphenylene oxide resin, styrene resin be put into super mixer and premix 5-10 points
Then clock sequentially adds step（2）In halogen-free flame retardants obtained and step（1）Ready bulking agent and processing aid,
Premix 20-30 minutes, then by premix by double screw extruder extruding pelletization, barrel temperature is 190-220 DEG C.
The preparation method of above-mentioned flame-retardant polyphenyl ether resin alloy, barrel temperature are 206 DEG C.
Beneficial effects of the present invention are as follows：
Metal oxide is distributed to as homogeneously as possible in resin alloy system using the suction-operated of carbon nanotube, to really
The uniformity for the anti-flammability of polyphenylene oxide resin alloy in invention of breaking even, while improving resin alloy using the carboxyl in carbon nanotube
The compatibility of middle polyphenylene oxide resin and styrene resin can also utilize the Malaysia in the carboxyl and bulking agent in carbon nanotube
Polymerization occurs for acid anhydrides, acrylic acid to improve or maintain the mechanical performance of polyphenylene oxide resin alloy.
Specific implementation mode
In order to illustrate more clearly of the present invention, with reference to preferred embodiment, the present invention is described further.Ability
Field technique personnel should be appreciated that following specifically described content is illustrative and be not restrictive, this should not be limited with this
The protection domain of invention.
Embodiment 1
In the present embodiment, poly- flame-retardant polyphenyl ether resin alloy is composed of the following components：
36 parts by weight of polyphenyleneoxide resins；
72 parts by weight of styrene resinoids, the styrene resin are 200000- by 14 parts by weight average weight-molecular masses
The high impact polystyrene of 300000g/mol, the benzene that 16 parts by weight average weight-molecular masses are 180000-300000g/mol
Ethylene-propylene lonitrile copolymer and the methacrylic acid that 13 parts by weight average weight-molecular masses are 220000-360000g/mol
Ester-styrol copolymer composition；
35 parts by weight carboxylic carbon nano-tubes, the carboxylic carbon nano-tube are 60-80% carboxylics by 6 parts by weight carboxyl molar fractions
Base single-layer carbon nano-tube and the carboxylated multilayer carbon nanotube that 2 parts by weight carboxyl molar fractions are 50-80% form；
15 parts by weight halogen-free flame retardants, the halogen-free flame retardants is by 12 parts by weight carboxylic carbon nano-tube nano particles, 17 weight
Part phosphorus series non-halogen fire retardant, 9 parts by weight melamines, 36 parts by weight expansible graphites and 24 parts by weight of metal oxide nanometers
Grain composition；Wherein, the carboxylic carbon nano-tube nano particle is by 7 parts by weight carboxylated single-layer carbon nano-tube nano particles and 3
Parts by weight multilayer carbon nanotube nano particle forms, and the phosphorus series non-halogen fire retardant is by 4 parts by weight polyphosphates, 4 parts by weight phosphorus
Miscellaneous phosphine oxide and 4 parts by weight phosphonate esters composition, the metal oxide is by 2 parts by weight of titanium dioxide nano particles, 4 parts by weight oxygen
Change zinc nanoparticles and 4 parts by weight of alumina nano particles composition；
3 parts by weight bulking agents, the bulking agent are composed of the following components：28 parts by weight diene hydrocarbon oligomers, 12 parts by weight Malaysias
Acid anhydrides and 12 parts by weight of acrylic acid；The diene hydrocarbon oligomer is 800-2000g/mol by 6 parts by weight average weight-molecular masses
Butadiene oligomer and 1 parts by weight average weight-molecular mass be 1500-3000g/mol pentadiene oligomer；
2.8 parts by weight processing aids, the processing aid are demoulded by 2 parts by weight antioxidant, 6 parts by weight lubricants and 3 parts by weight
Agent forms；Wherein, the antioxidant is the mixed of 1 parts by weight of lemon acid, 1.8 parts by weight tocopherols and 1.6 parts by weight phosphite esters
Close object；The lubricant is 1.8 parts by weight Lanthanum Stearates, 2.4 parts by weight zinc stearates, 3.6 weight account polyethylene waxes and 2.1 weights
Measure the mixture of part pentaerythritol stearate；The releasing agent is 3.2 weight silicone oil release agent and 3.6 parts by weight microwaxes
Mixture.
（1）Prepare raw material according to above-mentioned formula；
（2）By step（1）In halogen-free flame retardants in carboxylic carbon nano-tube nano particle and metal oxide in carbon atom
Ultrasonic mixing 10 minutes, is then dried to obtain initial mixture, then by initial mixture, phosphorus system in the alkane that number is 8-11
Halogen-free flame retardants and expansible graphite are mixed to get halogen-free flame retardants；
（3）By step（1）In ready polyphenylene oxide resin, styrene resin be put into super mixer and premix 5-10 points
Then clock sequentially adds step（2）In halogen-free flame retardants obtained and step（1）Ready bulking agent and processing aid,
Premix 30 minutes, then by premix by double screw extruder extruding pelletization, barrel temperature is 195 DEG C.
Step（3）Flame-retardant polyphenyl ether resin alloy obtained is denoted as alloy 1.
Embodiment 2
In the present embodiment, poly- flame-retardant polyphenyl ether resin alloy is composed of the following components：
42 parts by weight of polyphenyleneoxide resins；
67 parts by weight of styrene resinoids, the styrene resin are 200000- by 19 parts by weight average weight-molecular masses
The high impact polystyrene of 300000g/mol, the benzene that 10 parts by weight average weight-molecular masses are 180000-300000g/mol
Ethylene-propylene lonitrile copolymer and the methacrylate-that 9 parts by weight average weight-molecular masses are 220000-360000g/mol
Styrol copolymer forms；
48 parts by weight carboxylic carbon nano-tubes, the carboxylic carbon nano-tube are 60-80% carboxylics by 8 parts by weight carboxyl molar fractions
Base single-layer carbon nano-tube and the carboxylated multilayer carbon nanotube that 1 parts by weight carboxyl molar fraction is 50-80% form；
2 parts by weight halogen-free flame retardants, the halogen-free flame retardants is by 7 parts by weight carboxylic carbon nano-tube nano particles, 22 parts by weight
Phosphorus series non-halogen fire retardant, 4 parts by weight melamines, 42 parts by weight expansible graphites and 16 parts by weight of metal oxide nano particles
Composition；Wherein, the carboxylic carbon nano-tube nano particle is by 9 parts by weight carboxylated single-layer carbon nano-tube nano particles and 4 weights
Part multilayer carbon nanotube nano particle composition is measured, the phosphorus series non-halogen fire retardant is by 1 parts by weight polyphosphate, 8 parts by weight phosphas
Phosphine oxide and 3 parts by weight phosphonate esters composition, the metal oxide are aoxidized by 3 parts by weight of titanium dioxide nano particles, 6 parts by weight
Zinc nanoparticles and 9 parts by weight of alumina nano particles composition；
3 parts by weight bulking agents, the bulking agent are composed of the following components：23 parts by weight diene hydrocarbon oligomers, 8 parts by weight of maleic
Acid anhydride and 2 parts by weight of acrylic acid；The diene hydrocarbon oligomer is 800-2000g/mol's by 2 parts by weight average weight-molecular masses
Butadiene oligomer and the pentadiene oligomer that 2 parts by weight average weight-molecular masses are 1500-3000g/mol；
2.8 parts by weight processing aids, the processing aid are demoulded by 2 parts by weight antioxidant, 6 parts by weight lubricants and 3 parts by weight
Agent forms；Wherein, the antioxidant is 0.8 parts by weight of lemon acid, 1.5 parts by weight tocopherols and 1.2 parts by weight phosphite esters
Mixture；The lubricant is 3.2 parts by weight Lanthanum Stearates, 3 parts by weight zinc stearates, 2.2 weight account polyethylene waxes and 1.6 weights
Measure the mixture of part pentaerythritol stearate；The releasing agent is 1.6 weight silicone oil release agent and 4.8 parts by weight microwaxes
Mixture.
（1）Prepare raw material according to above-mentioned formula；
（2）By step（1）In halogen-free flame retardants in carboxylic carbon nano-tube nano particle and metal oxide in carbon atom
Ultrasonic mixing 10 minutes, is then dried to obtain initial mixture, then by initial mixture, phosphorus system in the alkane that number is 8-11
Halogen-free flame retardants and expansible graphite are mixed to get halogen-free flame retardants；
（3）By step（1）In ready polyphenylene oxide resin, styrene resin be put into super mixer and premix 5-10 points
Then clock sequentially adds step（2）In halogen-free flame retardants obtained and step（1）Ready bulking agent and processing aid,
Premix 30 minutes, then by premix by double screw extruder extruding pelletization, barrel temperature is 195 DEG C.
Step（3）Flame-retardant polyphenyl ether resin alloy obtained is denoted as alloy 2.
Embodiment 3
In the present embodiment, poly- flame-retardant polyphenyl ether resin alloy is composed of the following components：
30 parts by weight of polyphenyleneoxide resins；
80 parts by weight of styrene resinoids, the styrene resin are 200000- by 8 parts by weight average weight-molecular masses
The high impact polystyrene of 300000g/mol, the benzene that 17 parts by weight average weight-molecular masses are 180000-300000g/mol
Ethylene-propylene lonitrile copolymer and the methacrylic acid that 12 parts by weight average weight-molecular masses are 220000-360000g/mol
Ester-styrol copolymer composition；
26 parts by weight carboxylic carbon nano-tubes, the carboxylic carbon nano-tube are 60-80% carboxylics by 2 parts by weight carboxyl molar fractions
Base single-layer carbon nano-tube and the carboxylated multilayer carbon nanotube that 4 parts by weight carboxyl molar fractions are 50-80% form；
26 parts by weight halogen-free flame retardants, the halogen-free flame retardants is by 14 parts by weight carboxylic carbon nano-tube nano particles, 10 weight
Part phosphorus series non-halogen fire retardant, 11 parts by weight melamines, 30 parts by weight expansible graphites and 27 parts by weight of metal oxide nanometers
Particle forms；Wherein, the carboxylic carbon nano-tube nano particle by 6 parts by weight carboxylated single-layer carbon nano-tube nano particles and
6 parts by weight multilayer carbon nanotube nano particles form, and the phosphorus series non-halogen fire retardant is by 5 parts by weight polyphosphates, 2 parts by weight phosphorus
Miscellaneous phosphine oxide and 5 parts by weight phosphonate esters composition, the metal oxide is by 2 parts by weight of titanium dioxide nano particles, 8 parts by weight oxygen
Change zinc nanoparticles and 8 parts by weight of alumina nano particles composition；
2 parts by weight bulking agents, the bulking agent are composed of the following components：29 parts by weight diene hydrocarbon oligomers, 2 parts by weight of maleic
Acid anhydride and 8 parts by weight of acrylic acid；The diene hydrocarbon oligomer is 800-2000g/mol's by 2 parts by weight average weight-molecular masses
Butadiene oligomer and the pentadiene oligomer that 5 parts by weight average weight-molecular masses are 1500-3000g/mol；
3 parts by weight processing aids, the processing aid is by 2 parts by weight antioxidant, 6 parts by weight lubricants and 3 parts by weight releasing agents
Composition；Wherein, the antioxidant is the mixing of 1.1 parts by weight of lemon acid, 2 parts by weight tocopherols and 1.8 parts by weight phosphite esters
Object；The lubricant is 1.7 parts by weight Lanthanum Stearates, 1.8 parts by weight zinc stearates, 3.1 weight account polyethylene waxes and 2.5 weight
The mixture of part pentaerythritol stearate；The releasing agent is 2.4 weight silicone oil release agent and 2.4 parts by weight microwaxes
Mixture.
（1）Prepare raw material according to above-mentioned formula；
（2）By step（1）In halogen-free flame retardants in carboxylic carbon nano-tube nano particle and metal oxide in carbon atom
Ultrasonic mixing 20 minutes, is then dried to obtain initial mixture, then by initial mixture, phosphorus system in the alkane that number is 8-11
Halogen-free flame retardants and expansible graphite are mixed to get halogen-free flame retardants；
（3）By step（1）In ready polyphenylene oxide resin, styrene resin be put into super mixer and premix 5-10 points
Then clock sequentially adds step（2）In halogen-free flame retardants obtained and step（1）Ready bulking agent and processing aid,
Premix 30 minutes, then by premix by double screw extruder extruding pelletization, barrel temperature is 200 DEG C.
Step（3）Flame-retardant polyphenyl ether resin alloy obtained is denoted as alloy 3.
Embodiment 4
In the present embodiment, poly- flame-retardant polyphenyl ether resin alloy is composed of the following components：
39 parts by weight of polyphenyleneoxide resins；
60 parts by weight of styrene resinoids, the styrene resin are 200000- by 17 parts by weight average weight-molecular masses
The high impact polystyrene of 300000g/mol, the benzene that 13 parts by weight average weight-molecular masses are 180000-300000g/mol
Ethylene-propylene lonitrile copolymer and the methacrylate-that 5 parts by weight average weight-molecular masses are 220000-360000g/mol
Styrol copolymer forms；
54 parts by weight carboxylic carbon nano-tubes, the carboxylic carbon nano-tube are 60-80% carboxylics by 7 parts by weight carboxyl molar fractions
Base single-layer carbon nano-tube and the carboxylated multilayer carbon nanotube that 5 parts by weight carboxyl molar fractions are 50-80% form；
40 parts by weight halogen-free flame retardants, the halogen-free flame retardants is by 9 parts by weight carboxylic carbon nano-tube nano particles, 15 parts by weight
Phosphorus series non-halogen fire retardant, 3 parts by weight melamines, 48 parts by weight expansible graphites and 24 parts by weight of metal oxide nano particles
Composition；Wherein, the carboxylic carbon nano-tube nano particle is by 8 parts by weight carboxylated single-layer carbon nano-tube nano particles and 4 weights
Part multilayer carbon nanotube nano particle composition is measured, the phosphorus series non-halogen fire retardant is by 2 parts by weight polyphosphates, 6 parts by weight phosphas
Phosphine oxide and 6 parts by weight phosphonate esters composition, the metal oxide are aoxidized by 2 parts by weight of titanium dioxide nano particles, 4 parts by weight
Zinc nanoparticles and 10 parts by weight of alumina nano particles composition；
1 parts by weight bulking agent, the bulking agent are composed of the following components：21 parts by weight diene hydrocarbon oligomers, 10 parts by weight Malaysias
Acid anhydrides and 3 parts by weight of acrylic acid；The diene hydrocarbon oligomer is 800-2000g/mol by 7 parts by weight average weight-molecular masses
Butadiene oligomer and 2 parts by weight average weight-molecular masses be 1500-3000g/mol pentadiene oligomer；
2 parts by weight processing aids, the processing aid is by 2 parts by weight antioxidant, 6 parts by weight lubricants and 3 parts by weight releasing agents
Composition；Wherein, the antioxidant is the mixing of 0.6 parts by weight of lemon acid, 1.6 parts by weight tocopherols and 2 parts by weight phosphite esters
Object；The lubricant is 1 parts by weight Lanthanum Stearate, 2.9 parts by weight zinc stearates, 2 weight account polyethylene waxes and 1.2 parts by weight seasons
The mixture of penta tetrol stearate；The releasing agent is the mixture of 1 weight silicone oil release agent and 4 parts by weight microwaxes.
（1）Prepare raw material according to above-mentioned formula；
（2）By step（1）In halogen-free flame retardants in carboxylic carbon nano-tube nano particle and metal oxide in carbon atom
Ultrasonic mixing 20 minutes, is then dried to obtain initial mixture, then by initial mixture, phosphorus system in the alkane that number is 8-11
Halogen-free flame retardants and expansible graphite are mixed to get halogen-free flame retardants；
（3）By step（1）In ready polyphenylene oxide resin, styrene resin be put into super mixer and premix 5-10 points
Then clock sequentially adds step（2）In halogen-free flame retardants obtained and step（1）Ready bulking agent and processing aid,
Premix 30 minutes, then by premix by double screw extruder extruding pelletization, barrel temperature is 200 DEG C.
Step（3）Flame-retardant polyphenyl ether resin alloy obtained is denoted as alloy 4.
Embodiment 5
In the present embodiment, poly- flame-retardant polyphenyl ether resin alloy is composed of the following components：
46 parts by weight of polyphenyleneoxide resins；
76 parts by weight of styrene resinoids, the styrene resin are 200000- by 12 parts by weight average weight-molecular masses
The high impact polystyrene of 300000g/mol, the benzene that 20 parts by weight average weight-molecular masses are 180000-300000g/mol
Ethylene-propylene lonitrile copolymer and the methacrylic acid that 16 parts by weight average weight-molecular masses are 220000-360000g/mol
Ester-styrol copolymer composition；
10 parts by weight carboxylic carbon nano-tubes, the carboxylic carbon nano-tube are 60-80% carboxylics by 3 parts by weight carboxyl molar fractions
Base single-layer carbon nano-tube and the carboxylated multilayer carbon nanotube that 3 parts by weight carboxyl molar fractions are 50-80% form；
37 parts by weight halogen-free flame retardants, the halogen-free flame retardants is by 18 parts by weight carboxylic carbon nano-tube nano particles, 24 weight
Part phosphorus series non-halogen fire retardant, 12 parts by weight melamines, 37 parts by weight expansible graphites and 18 parts by weight of metal oxide nanometers
Particle forms；Wherein, the carboxylic carbon nano-tube nano particle by 7 parts by weight carboxylated single-layer carbon nano-tube nano particles and
5 parts by weight multilayer carbon nanotube nano particles form, and the phosphorus series non-halogen fire retardant is by 6 parts by weight polyphosphates, 3 parts by weight phosphorus
Miscellaneous phosphine oxide and 3 parts by weight phosphonate esters composition, the metal oxide is by 3 parts by weight of titanium dioxide nano particles, 3 parts by weight oxygen
Change zinc nanoparticles and 9 parts by weight of alumina nano particles composition；
4 parts by weight bulking agents, the bulking agent are composed of the following components：20 parts by weight diene hydrocarbon oligomers, 6 parts by weight of maleic
Acid anhydride and 9 parts by weight of acrylic acid；The diene hydrocarbon oligomer is 800-2000g/mol's by 4 parts by weight average weight-molecular masses
Butadiene oligomer and the pentadiene oligomer that 3 parts by weight average weight-molecular masses are 1500-3000g/mol；
2.7 parts by weight processing aids, the processing aid are demoulded by 2 parts by weight antioxidant, 6 parts by weight lubricants and 3 parts by weight
Agent forms；Wherein, the antioxidant is 1.2 parts by weight of lemon acid, 1.7 parts by weight tocopherols and 1.5 parts by weight phosphite esters
Mixture；The lubricant is 2.6 parts by weight Lanthanum Stearates, 3.2 parts by weight zinc stearates, 4 weight account polyethylene waxes and 2.6 weights
Measure the mixture of part pentaerythritol stearate；The releasing agent is 2.9 weight silicone oil release agent and 5 parts by weight microwaxes
Mixture.
（1）Prepare raw material according to above-mentioned formula；
（2）By step（1）In halogen-free flame retardants in carboxylic carbon nano-tube nano particle and metal oxide in carbon atom
Ultrasonic mixing 20 minutes, is then dried to obtain initial mixture, then by initial mixture, phosphorus system in the alkane that number is 8-11
Halogen-free flame retardants and expansible graphite are mixed to get halogen-free flame retardants；
（3）By step（1）In ready polyphenylene oxide resin, styrene resin be put into super mixer and premix 5-10 points
Then clock sequentially adds step（2）In halogen-free flame retardants obtained and step（1）Ready bulking agent and processing aid,
Premix 30 minutes, then by premix by double screw extruder extruding pelletization, barrel temperature is 205 DEG C.
Step（3）Flame-retardant polyphenyl ether resin alloy obtained is denoted as alloy 5.
Embodiment 6
In the present embodiment, poly- flame-retardant polyphenyl ether resin alloy is composed of the following components：
50 parts by weight of polyphenyleneoxide resins；
90 parts by weight of styrene resinoids, the styrene resin are 200000- by 20 parts by weight average weight-molecular masses
The high impact polystyrene of 300000g/mol, the benzene that 18 parts by weight average weight-molecular masses are 180000-300000g/mol
Ethylene-propylene lonitrile copolymer and the methacrylic acid that 11 parts by weight average weight-molecular masses are 220000-360000g/mol
Ester-styrol copolymer composition；
60 parts by weight carboxylic carbon nano-tubes, the carboxylic carbon nano-tube are 60-80% carboxylics by 5 parts by weight carboxyl molar fractions
Base single-layer carbon nano-tube and the carboxylated multilayer carbon nanotube that 2 parts by weight carboxyl molar fractions are 50-80% form；
23 parts by weight halogen-free flame retardants, the halogen-free flame retardants is by 8 parts by weight carboxylic carbon nano-tube nano particles, 13 parts by weight
Phosphorus series non-halogen fire retardant, 6 parts by weight melamines, 46 parts by weight expansible graphites and 21 parts by weight of metal oxide nano particles
Composition；Wherein, the carboxylic carbon nano-tube nano particle is by 6 parts by weight carboxylated single-layer carbon nano-tube nano particles and 4 weights
Part multilayer carbon nanotube nano particle composition is measured, the phosphorus series non-halogen fire retardant is by 3 parts by weight polyphosphates, 6 parts by weight phosphas
Phosphine oxide and 6 parts by weight phosphonate esters composition, the metal oxide are aoxidized by 3 parts by weight of titanium dioxide nano particles, 8 parts by weight
Zinc nanoparticles and 10 parts by weight of alumina nano particles composition；
2 parts by weight bulking agents, the bulking agent are composed of the following components：30 parts by weight diene hydrocarbon oligomers, 15 parts by weight Malaysias
Acid anhydrides and 4 parts by weight of acrylic acid；The diene hydrocarbon oligomer is 800-2000g/mol by 5 parts by weight average weight-molecular masses
Butadiene oligomer and 3 parts by weight average weight-molecular masses be 1500-3000g/mol pentadiene oligomer；
2.6 parts by weight processing aids, the processing aid are demoulded by 2 parts by weight antioxidant, 6 parts by weight lubricants and 3 parts by weight
Agent forms；Wherein, the antioxidant is the mixed of 1 parts by weight of lemon acid, 1.9 parts by weight tocopherols and 1.9 parts by weight phosphite esters
Close object；The lubricant is 4 parts by weight Lanthanum Stearates, 2 parts by weight zinc stearates, 2.7 weight account polyethylene waxes and 1.9 parts by weight
The mixture of pentaerythritol stearate；The releasing agent is the mixing of 4 weight silicone oil release agent and 4.5 parts by weight microwaxes
Object.
（1）Prepare raw material according to above-mentioned formula；
（2）By step（1）In halogen-free flame retardants in carboxylic carbon nano-tube nano particle and metal oxide in carbon atom
Ultrasonic mixing 20 minutes, is then dried to obtain initial mixture, then by initial mixture, phosphorus system in the alkane that number is 8-11
Halogen-free flame retardants and expansible graphite are mixed to get halogen-free flame retardants；
（3）By step（1）In ready polyphenylene oxide resin, styrene resin be put into super mixer and premix 5-10 points
Then clock sequentially adds step（2）In halogen-free flame retardants obtained and step（1）Ready bulking agent and processing aid,
Premix 30 minutes, then by premix by double screw extruder extruding pelletization, barrel temperature is 205 DEG C.
Step（3）Flame-retardant polyphenyl ether resin alloy obtained is denoted as alloy 6.
Embodiment 7
In the present embodiment, poly- flame-retardant polyphenyl ether resin alloy is composed of the following components：
45 parts by weight of polyphenyleneoxide resins；
82 parts by weight of styrene resinoids, the styrene resin are 200000- by 16 parts by weight average weight-molecular masses
The high impact polystyrene of 300000g/mol, the benzene that 16 parts by weight average weight-molecular masses are 180000-300000g/mol
Ethylene-propylene lonitrile copolymer and the methacrylic acid that 16 parts by weight average weight-molecular masses are 220000-360000g/mol
Ester-styrol copolymer composition；
36 parts by weight carboxylic carbon nano-tubes, the carboxylic carbon nano-tube are 60-80% carboxylics by 4 parts by weight carboxyl molar fractions
Base single-layer carbon nano-tube and the carboxylated multilayer carbon nanotube that 1 parts by weight carboxyl molar fraction is 50-80% form；
24 parts by weight halogen-free flame retardants, the halogen-free flame retardants is by 16 parts by weight carboxylic carbon nano-tube nano particles, 16 weight
Part phosphorus series non-halogen fire retardant, 8 parts by weight melamines, 45 parts by weight expansible graphites and 13 parts by weight of metal oxide nanometers
Grain composition；Wherein, the carboxylic carbon nano-tube nano particle is by 9 parts by weight carboxylated single-layer carbon nano-tube nano particles and 3
Parts by weight multilayer carbon nanotube nano particle forms, and the phosphorus series non-halogen fire retardant is by 3 parts by weight polyphosphates, 8 parts by weight phosphorus
Miscellaneous phosphine oxide and 6 parts by weight phosphonate esters composition, the metal oxide is by 2.4 parts by weight of titanium dioxide nano particles, 7.2 weight
Part Zinc oxide nanoparticle and 9.6 parts by weight of alumina nano particles composition；
4.6 parts by weight bulking agents, the bulking agent are composed of the following components：24 parts by weight diene hydrocarbon oligomers, 9 parts by weight Malaysias
Acid anhydrides and 3.6 parts by weight of acrylic acid；The diene hydrocarbon oligomer is 800-2000g/ by 3 parts by weight average weight-molecular masses
The butadiene oligomer of mol and the pentadiene oligomer that 1 parts by weight average weight-molecular mass is 1500-3000g/mol；
2.4 parts by weight processing aids, the processing aid are demoulded by 2 parts by weight antioxidant, 6 parts by weight lubricants and 3 parts by weight
Agent forms；Wherein, the antioxidant is 0.9 parts by weight of lemon acid, 1.8 parts by weight tocopherols and 1.8 parts by weight phosphite esters
Mixture；The lubricant is 3 parts by weight Lanthanum Stearates, 2.4 parts by weight zinc stearates, 3.6 weight account polyethylene waxes and 2.4 weights
Measure the mixture of part pentaerythritol stearate；The releasing agent is 3 weight silicone oil release agent and 4.8 parts by weight microwaxes
Mixture.
（1）Prepare raw material according to above-mentioned formula；
（2）By step（1）In halogen-free flame retardants in carboxylic carbon nano-tube nano particle and metal oxide in carbon atom
Ultrasonic mixing 20 minutes, is then dried to obtain initial mixture, then by initial mixture, phosphorus system in the alkane that number is 8-11
Halogen-free flame retardants and expansible graphite are mixed to get halogen-free flame retardants；
（3）By step（1）In ready polyphenylene oxide resin, styrene resin be put into super mixer and premix 5-10 points
Then clock sequentially adds step（2）In halogen-free flame retardants obtained and step（1）Ready bulking agent and processing aid,
Premix 30 minutes, then by premix by double screw extruder extruding pelletization, barrel temperature is 206 DEG C.
Step（3）Flame-retardant polyphenyl ether resin alloy obtained is denoted as alloy 7.
Comparative example
In the present embodiment, flame-retardant polyphenyl ether resin alloy is composed of the following components：PPOLXR050：21.5wt%, ABS：12wt%,
Glass fibre：6wt%, metaphenylene tetraphenyl diphosphate：10wt%, polyphosphoric acid melamine：10wt%, KartonG1650：
5wt%, polyphenylene ether-polyester compatilizer（CMG-W-02）：10wt%, antioxidant：0.3wt%, lubricant：0.2wt%.
The preparation method of flame-retardant polyphenyl ether resin alloy in the present embodiment is closed with the flame-retardant polyphenyl ether resin in embodiment 7
The preparation method of gold is identical, and the flame-retardant polyphenyl ether resin alloy prepared is denoted as comparative alloy.
Mechanical performance and glossiness test：
To made from embodiment 1-11 and comparative example 1 polycarbonate styrene resinoid alloy carry out physical mechanical property test and
Glossiness is tested, and the results are shown in Table 1：
Extension test：It is tested according to ASTM D638 standards；
Elongation at break：It is tested according to ASTM D638 standards；
Bending strength：It is tested according to ASTM D790 standards；
Bending modulus：It is tested according to ASTM D790 standards
Impact strength：It is tested according to ASTM D256 standards；
Flame retardant property：It is tested according to UL-94 standards.
1 alloy 1-7 of table and comparative alloy performance test
| Comparative alloy | Alloy 1 | Alloy 2 | Alloy 3 | Alloy 4 | Alloy 5 | Alloy 6 | Alloy 7 | |
| Tensile strength（MPa） | 108 | 162 | 184 | 154 | 181 | 129 | 176 | 172 |
| Elongation at break（%） | 1.6 | 2.9 | 2.2 | 3.1 | 2.4 | 3.8 | 2.6 | 3.2 |
| Bending strength（MPa） | 142 | 214 | 268 | 196 | 263 | 167 | 254 | 236 |
| Bending modulus（MPa） | 5408 | 7236 | 8120 | 7106 | 8405 | 6938 | 8003 | 7846 |
| Impact strength（MPa） | 74 | 132 | 156 | 124 | 152 | 106 | 146 | 149 |
| Flame retardant rating | V0 | V1 | V1 | V0 | V0 | V0 | V0 | V0 |
According to the data in table 1, carboxylic carbon nano-tube in the present invention, carboxylic carbon nano-tube nano particle suction-operated can
To promote the dispersion of metal oxide, metal oxide and expansible graphite and phosphorus series non-halogen fire retardant synergistic effect are improved,
So that the apparent dosage of fire retardant reduces, while using on carboxylic carbon nano-tube and carboxylic carbon nano-tube nano particle
Carboxyl reacts with maleic anhydride and acrylic acid, is conducive to carboxylic carbon nano-tube and carboxylic carbon nano-tube nano particle
Dispersion, while also helping polyphenylene oxide resin and ABS is further uniformly dispersed, improve compatibility between the two, improve tree
The performance uniformity of fat alloy so that flame-retardant polyphenyl ether resin alloy has under the premise of with preferable flame retardant property in the present invention
There is preferable mechanical performance.
And Lanthanum Stearate, the zinc stearate in the present invention can not only play the role of lubricant, can also improve polyphenyl
The crystallinity of ether resin, and can not only be improved between polyphenylene oxide resin and ABS using the diene hydrocarbon oligomer in compatilizer
Compatibility, can also improve the degree of cross linking of flame-retardant polyphenyl ether resin alloy, while be additionally favorable for the dispersion of polyphenylene oxide resin crystallization, have
Conducive to the performance uniformity of raising flame-retardant polyphenyl ether resin alloy.
The above embodiment of the present invention be only to clearly illustrate example of the present invention, and not be to the present invention
The restriction of embodiment can also make on the basis of the above description for those of ordinary skill in the art
Other various forms of variations or variation here can not be exhaustive all embodiments, every skill for belonging to the present invention
Row of the obvious changes or variations that art scheme is extended out still in protection scope of the present invention.
Claims (10)
1. a kind of flame-retardant polyphenyl ether resin alloy, which is characterized in that composed of the following components：30-50 parts by weight of polyphenyleneoxide resin,
60-90 parts by weight of styrene resinoid, 10-60 parts by weight carboxylic carbon nano-tube, 15-40 parts by weight halogen-free flame retardants, 1-5 weights
Measure part bulking agent and 2-3 parts by weight processing aids；The halogen-free flame retardants is by 7-18 parts by weight carboxylic carbon nano-tube nanometers
Grain, 10-24 parts by weight phosphorus series non-halogens fire retardant, 3-12 parts by weight melamine, 30-48 parts by weight expansible graphite and 12-27
Parts by weight of metal oxide nano particle forms；The processing aid is by 2 parts by weight antioxidant, 6 parts by weight lubricants and 3 weight
Part releasing agent composition.
2. flame-retardant polyphenyl ether resin alloy according to claim 1, which is characterized in that the carboxylic carbon nano-tube is by 2-
8 parts by weight carboxyl molar fractions are 60-80% carboxylated single-layer carbon nano-tube and 1-5 parts by weight carboxyl molar fractions are 50-80%
Carboxylated multilayer carbon nanotube composition；The carboxylic carbon nano-tube nano particle is by the carboxylic that carboxyl molar fraction is 50-80%
Base single-layer carbon nano-tube nano particle and the carboxylated multilayer carbon nanotube nano particle group that carboxyl molar fraction is 40-60%
At.
3. flame-retardant polyphenyl ether resin alloy according to claim 2, which is characterized in that the carboxylic carbon nano-tube nanometer
Particle is made of 6-9 parts by weight carboxylated single-layer carbon nano-tube nano particle and 3-6 parts by weight multilayer carbon nanotube nano particles.
4. flame-retardant polyphenyl ether resin alloy according to claim 1, which is characterized in that the phosphorus series non-halogen fire retardant is by 1-
6 parts by weight polyphosphates, 2-8 parts by weight phospha phosphine oxides and 3-6 parts by weight phosphonate esters composition.
5. flame-retardant polyphenyl ether resin alloy according to claim 1, which is characterized in that the metal oxide is by 2-3 weights
Measure part titania nanoparticles, 3-8 part by weight of zinc oxide nano particle and 4-10 parts by weight of alumina nano particles composition.
6. according to any flame-retardant polyphenyl ether resin alloys of claim 1-5, which is characterized in that the antioxidant is 0.6-
The mixture of 1.2 parts by weight of lemon acid, 1.5-2 parts by weight tocopherol and 1.0-2.0 parts by weight phosphite esters；The lubricant is
1-4 parts by weight Lanthanum Stearate, 1.8-3.2 parts by weight zinc stearate, 2-4 weight account polyethylenes wax and 1.2-2.6 parts by weight seasons penta
The mixture of tetrol stearate；The releasing agent is the mixing of 1-4 weight silicone oil release agent and 2-5 parts by weight microwaxes
Object.
7. according to any flame-retardant polyphenyl ether resin alloys of claim 1-5, which is characterized in that the styrene resin
High impact polystyrene, 10-20 parts by weight by 8-20 parts by weight average weight-molecular masses for 200000-300000g/mol
The styrene-acrylonitrile copolymer and 5-16 parts by weight weight that average weight-molecular mass is 180000-300000g/mol are opposite
The methacrylate that molecular mass is 220000-360000g/mol-styrol copolymer composition.
8. according to any flame-retardant polyphenyl ether resin alloys of claim 1-5, which is characterized in that the bulking agent is by following
Group is grouped as：20-30 parts by weight diene hydrocarbon oligomer, 2-15 parts by weight maleic anhydride and 1-12 parts by weight of acrylic acid；Described two
Olefin oligomer is by the butadiene oligomer and 1-5 parts by weight that 2-7 parts by weight average weight-molecular masses are 800-2000g/mol
Average weight-molecular mass is the pentadiene oligomer of 1500-3000g/mol.
9. the preparation method of flame-retardant polyphenyl ether resin alloy according to any one of claims 1-8, which is characterized in that including as follows
Step：
（1）According to preparing raw material as following formula：30-50 parts by weight of polyphenyleneoxide resin, 60-90 parts by weight of styrene resinoid, 5-
20 parts by weight halogen-free flame retardants, 1-5 parts by weight bulking agent and 2-3 parts by weight processing aids；The halogen-free flame retardants is by carboxylated
Carbon nanotube particle, phosphorus series non-halogen fire retardant, melamine, expansible graphite and metal oxide nanoparticles composition；
The processing aid is made of antioxidant, lubricant and releasing agent；
（2）By step（1）In halogen-free flame retardants in carboxylic carbon nano-tube nano particle and metal oxide in carbon atom
Ultrasonic mixing 10-20 minutes in the alkane that number is 8-11, is then dried to obtain initial mixture, then by initial mixture,
Phosphorus series non-halogen fire retardant and expansible graphite are mixed to get halogen-free flame retardants；
（3）By step（1）In ready polyphenylene oxide resin, styrene resin be put into super mixer and premix 5-10 points
Then clock sequentially adds step（2）In halogen-free flame retardants obtained and step（1）Ready bulking agent and processing aid,
Premix 20-30 minutes, then by premix by double screw extruder extruding pelletization, barrel temperature is 190-220 DEG C.
10. the preparation method that flame-retardant polyphenyl ether resin according to claim 9 closes, which is characterized in that barrel temperature 206
℃。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711368719.0A CN108485229A (en) | 2017-12-19 | 2017-12-19 | A kind of flame-retardant polyphenyl ether resin alloy and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711368719.0A CN108485229A (en) | 2017-12-19 | 2017-12-19 | A kind of flame-retardant polyphenyl ether resin alloy and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108485229A true CN108485229A (en) | 2018-09-04 |
Family
ID=63343996
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711368719.0A Pending CN108485229A (en) | 2017-12-19 | 2017-12-19 | A kind of flame-retardant polyphenyl ether resin alloy and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108485229A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102382448A (en) * | 2011-09-07 | 2012-03-21 | 上海日之升新技术发展有限公司 | Halogen free inflaming retardant polyphenylene oxide alloy and preparation method thereof |
| CN102702722A (en) * | 2012-07-06 | 2012-10-03 | 上海日之升新技术发展有限公司 | Halogen-free flame-retardant reinforced polyphenylether/ABS (acrylonitrile-butadiene-styrene) alloy and preparation method thereof |
| CN102702723A (en) * | 2012-07-06 | 2012-10-03 | 上海日之升新技术发展有限公司 | Halogen-free flame-retardant polyphenylether/ABS (acrylonitrile-butadiene-styrene) alloy and preparation method thereof |
| CN105623172A (en) * | 2014-11-10 | 2016-06-01 | 合肥杰事杰新材料股份有限公司 | Flame-retardant high-anti-impact modified polystyrene resin and preparation method thereof |
-
2017
- 2017-12-19 CN CN201711368719.0A patent/CN108485229A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102382448A (en) * | 2011-09-07 | 2012-03-21 | 上海日之升新技术发展有限公司 | Halogen free inflaming retardant polyphenylene oxide alloy and preparation method thereof |
| CN102702722A (en) * | 2012-07-06 | 2012-10-03 | 上海日之升新技术发展有限公司 | Halogen-free flame-retardant reinforced polyphenylether/ABS (acrylonitrile-butadiene-styrene) alloy and preparation method thereof |
| CN102702723A (en) * | 2012-07-06 | 2012-10-03 | 上海日之升新技术发展有限公司 | Halogen-free flame-retardant polyphenylether/ABS (acrylonitrile-butadiene-styrene) alloy and preparation method thereof |
| CN105623172A (en) * | 2014-11-10 | 2016-06-01 | 合肥杰事杰新材料股份有限公司 | Flame-retardant high-anti-impact modified polystyrene resin and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 张书华等: "《高性能电缆材料及其应用技术》", 30 November 2015 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Pracella et al. | Morphology and properties tuning of PLA/cellulose nanocrystals bio-nanocomposites by means of reactive functionalization and blending with PVAc | |
| JP4869255B2 (en) | Flame retardant thermoplastic resin composition and article comprising the same | |
| Xia et al. | Role of poly (ethylene glycol) grafted silica nanoparticle shape in toughened PLA-matrix nanocomposites | |
| CN103497441A (en) | Polyphenyl ether resin alloy material, and preparation method and application thereof | |
| CN101735403A (en) | Polymer compositions containing phosphates | |
| CN107663366A (en) | CNT strengthens halogen-free flame retardant PC/ABS composite material and its products formed | |
| CN109666283A (en) | Thermoplastic resin composition, solar electrical energy generation module connection structural bodies | |
| US20230203293A1 (en) | Low-density abs composites | |
| Bao et al. | Synthesis of a novel flame retardant with phosphaphenanthrene and phosphazene double functional groups and flame retardancy of poly (lactic acid) composites | |
| CN108485229A (en) | A kind of flame-retardant polyphenyl ether resin alloy and preparation method thereof | |
| Zhang et al. | Constructing flame retardant silica nanoparticles through styrene maleic anhydride copolymer grafting for PC/ABS composites | |
| CN104277410A (en) | Preparation method of flame-retardant electroplating ABS for shell of electronic apparatus | |
| CN104693748A (en) | Flame-retardant modified PC/PBT alloy and preparation method thereof | |
| CN108504064A (en) | Mobility PC/ABS composite materials and its molded product | |
| CN110922691A (en) | Halogen-free flame-retardant polystyrene master batch and preparation method thereof | |
| CN105315603B (en) | A kind of flame-retardant thermoplastic elastomer composition | |
| Tsai et al. | Effect of Organic Nano Carboncapsule Incorporated Modified Clay on Fire‐Retardancy of PMMA Nanocomposites | |
| CN1990551A (en) | Preparation method of flame-proof nylon and ABS alloy material | |
| CN103173013A (en) | Polyphenylene sulfide/styrene alloy material and preparation method thereof | |
| Gallego et al. | How do the shape of clay and type of modifier affect properties of polymer blends? | |
| Gao et al. | Terminal group effects of DOPO-conjugated flame retardant on polyamide 6: Thermal stability, flame retardancy and mechanical performances | |
| KR20050114459A (en) | Polycarbonate/abs resin nanocomposites containing montmorillonite | |
| CN104419141A (en) | Glass fiber reinforced halogen-free flame retardant and antistatic PBT/PET alloy | |
| CN108276749B (en) | Halogen-free flame retardant and resin alloy containing same | |
| JP2003526717A5 (en) |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20180904 |
|
| WD01 | Invention patent application deemed withdrawn after publication |