CN108485169A - Super-strong deformation memory anti-prick explosion-proof material for tire - Google Patents

Super-strong deformation memory anti-prick explosion-proof material for tire Download PDF

Info

Publication number
CN108485169A
CN108485169A CN201810437395.XA CN201810437395A CN108485169A CN 108485169 A CN108485169 A CN 108485169A CN 201810437395 A CN201810437395 A CN 201810437395A CN 108485169 A CN108485169 A CN 108485169A
Authority
CN
China
Prior art keywords
parts
proof
tire
explosion
superpower
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810437395.XA
Other languages
Chinese (zh)
Inventor
王�锋
隋海涛
李明
郑龙跃
王晓坤
鉴继超
孙建磊
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shandong Linglong Tyre Co Ltd
Original Assignee
Shandong Linglong Tyre Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shandong Linglong Tyre Co Ltd filed Critical Shandong Linglong Tyre Co Ltd
Priority to CN201810437395.XA priority Critical patent/CN108485169A/en
Publication of CN108485169A publication Critical patent/CN108485169A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C08L53/025Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/003Additives being defined by their diameter
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention relates to a puncture-proof and explosion-proof material with super-strong deformation memory for tires. The composite material comprises the following raw materials in parts by weight: 48-56 parts of elastomer, 15-23 parts of tackifier, 9-15 parts of softener, 1.5-3.2 parts of anti-aging agent, 2-3 parts of coupling agent and 9-15 parts of filler; the filler is fly ash glass beads. The fly ash glass beads are hollow glass beads with the particle size of 1-20 mu m. Has the advantages that: the invention aims to provide a tire self-sealing rubber material which has enough high-temperature strength but has no reduction of the spraying performance of the rubber material on the premise of controlling the cost; the fly ash glass beads are used as a filler, a certain sizing material reinforcing effect can be provided, the cost and the ejection performance are superior to those of a carbon black sizing material, the waste materials of a power plant can be effectively recycled, and the environment protection is facilitated.

Description

A kind of superpower shape changing memory power pricking-proof explosion-proof material of tire
Technical field
The present invention relates to a kind of self-styled sizing materials of tire, and in particular to a kind of superpower shape changing memory power pricking-proof explosion-proof material of tire Material.
Background technology
Traditional runflat sizing material uses pressure-sensitive hot melt adhesive system, and effect is after tyre puncture, and self-styled sizing material expands back into Bullet blocks cut, and is bonded under inner pressure of tire.But its tensile strength and toughness are relatively low, and increase and drop with temperature Low very fast, particularly with All-steel tire, its inner cavity temperature is higher than 60 DEG C throughout the year, and traditional self-styled sizing material is only capable of resisting at this temperature Diameter 6mm nail punctures below, cannot play effective explosion-proof effect.Further runflat sizing material is generally using filling one Quantitative carbon black substitutes calcium carbonate or improves the above problem using the stronger polymer of cohesive force, but carbon black price is compared with carbonic acid Calcium is expensive, is unfavorable for control cost;The addition stronger polymer of cohesive force can reduce sizing material cryogenic property, and can increase ejection atomization Difficulty.Therefore, it is necessary to propose effective technical solution, solve the above problems.
Invention content
The present invention in view of the above shortcomings of the prior art, provides a kind of tire superpower shape changing memory power pricking-proof explosion-proof material Material.The material can ensure sizing material sealing performance at high operating temperatures and can improve the discharge performance of sizing material.
The technical solution that the present invention solves above-mentioned technical problem is as follows:
A kind of superpower shape changing memory power pricking-proof explosion-proof material of tire, includes the raw material of following parts by weight:Elastomer 48 ~56 parts, 15 parts~23 parts of tackifier, 9 parts~15 parts of softening agent, 1.5 parts~3.2 parts of anti-aging agent, 2 parts~3 parts of coupling agent, fill out Fill 9 parts~15 parts of agent;The filler is powder coal ash glass-microballons.
Preferably, the powder coal ash glass-microballons are the hollow glass micropearls that grain size is 1~20 μm.
Preferably, the elastomer is SBS thermoplastic elastomer (TPE)s, SIS thermoplastic elastomer (TPE)s, chlorination butadiene-isoamyl two At least one of alkene-butadiene copolymer.
Preferably, the tackifier are at least one of unsaturated hydrocarbons tackifier resin, PIB.
Preferably, the softening agent is naphthenic oil, aromatic naphtha, pine tar, diethyl phthalate and liquid polybutadiene At least one of alkene.
Advantageous effect:It is a kind of with sufficiently high temperature intensity the purpose of the present invention is under the premise of cost control, providing, but The self-styled sizing material of the undiminished tire of sizing material discharge performance;Using powder coal ash glass-microballons as filler, can provide certain Sizing material reinforcing effect, and cost and discharge performance are superior compared with addition carbon black sizing material, and can effectively recycle power plant's waste material, to environment Protection is advantageous.
Specific implementation mode
The present invention relates to a kind of superpower shape changing memory power pricking-proof explosion-proof materials of tire, more precisely, the present invention relates to It can ensure certain reinforcing effect in the case where controlling material cost, to ensure sizing material leakproofness at high operating temperatures The self-styled sizing material of tire of the discharge performance of sizing material can and can be improved.Sizing material cost can control, and sizing material has sufficiently high temperature intensity, But sizing material discharge performance does not reduce.
Embodiment 1:
A kind of superpower shape changing memory power pricking-proof explosion-proof material of tire, raw material includes thermoplastic elastomer SBS 10g, chlorine Change butadiene-isoprene-butadiene copolymer 40kg, terpene resin 10g, PIB10g, naphthenic oil 15g, fine coal gray glass is micro- Pearl 15g, coupling agent 3g, anti-aging agent 3g.
Embodiment 2:
A kind of superpower shape changing memory power pricking-proof explosion-proof material of tire, raw material includes chlorination butadiene-isoprene-fourth Diene copolymers 10kg, SIS thermoplastic elastomer (TPE) 40g, terpene resin 20g, PIB:2g, naphthenic oil 10g, powder coal ash glass-microballons 9g, coupling agent 2g, anti-aging agent 1.5g.
The present invention can be summarized with others without prejudice to the concrete form of the spirit or essential characteristics of the present invention.Therefore, nothing By from the point of view of which point, the embodiment above of the invention can only all be considered the description of the invention and cannot limit this hair Bright, claims indicate the scope of the present invention, and above-mentioned explanation does not point out the scope of the present invention, therefore, with this Any change in the comparable meaning and scope of claims of invention is all considered as being included in the claim of the present invention In the range of book.

Claims (5)

1. a kind of superpower shape changing memory power pricking-proof explosion-proof material of tire, which is characterized in that include the raw material of following parts by weight: 48~56 parts of elastomer, 15 parts~23 parts of tackifier, 9 parts~15 parts of softening agent, 1.5 parts~3.2 parts of anti-aging agent, 2 parts of coupling agent ~3 parts, 9 parts~15 parts of filler;
The filler is powder coal ash glass-microballons.
2. the superpower shape changing memory power pricking-proof explosion-proof material of tire as described in claim 1, which is characterized in that the flyash Glass microballoon is the hollow glass micropearl that grain size is 1~20 μm.
3. the superpower shape changing memory power pricking-proof explosion-proof material of tire as described in claim 1, which is characterized in that the elastomer For at least one in SBS thermoplastic elastomer (TPE)s, SIS thermoplastic elastomer (TPE)s, chlorination butadiene-isoprene-butadiene copolymer Kind.
4. the superpower shape changing memory power pricking-proof explosion-proof material of tire as described in claim 1, which is characterized in that the tackifier For at least one of unsaturated hydrocarbons tackifier resin, PIB.
5. the superpower shape changing memory power pricking-proof explosion-proof material of tire as described in claim 1, which is characterized in that the softening agent For at least one of naphthenic oil, aromatic naphtha, pine tar, diethyl phthalate and liquid polybutadiene.
CN201810437395.XA 2018-05-09 2018-05-09 Super-strong deformation memory anti-prick explosion-proof material for tire Pending CN108485169A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810437395.XA CN108485169A (en) 2018-05-09 2018-05-09 Super-strong deformation memory anti-prick explosion-proof material for tire

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810437395.XA CN108485169A (en) 2018-05-09 2018-05-09 Super-strong deformation memory anti-prick explosion-proof material for tire

Publications (1)

Publication Number Publication Date
CN108485169A true CN108485169A (en) 2018-09-04

Family

ID=63354281

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810437395.XA Pending CN108485169A (en) 2018-05-09 2018-05-09 Super-strong deformation memory anti-prick explosion-proof material for tire

Country Status (1)

Country Link
CN (1) CN108485169A (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1935894A (en) * 2005-09-21 2007-03-28 张海龙 Polymer self-repair sealing material
CN103044841A (en) * 2013-01-09 2013-04-17 无锡安睿驰科技有限公司 Macromolecular synthesized memory sizing material
CN103571174A (en) * 2012-07-26 2014-02-12 苏州克路新材料有限公司 Formula and use method of MSR rubber for tubeless tire
CN103834335A (en) * 2013-08-13 2014-06-04 洛阳骏腾能源科技有限公司 High-molecular elastic material with anti-explosion property
CN103849286A (en) * 2013-10-15 2014-06-11 洛阳骏腾能源科技有限公司 High polymer explosion-proof material used for tyre safety

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1935894A (en) * 2005-09-21 2007-03-28 张海龙 Polymer self-repair sealing material
CN103571174A (en) * 2012-07-26 2014-02-12 苏州克路新材料有限公司 Formula and use method of MSR rubber for tubeless tire
CN103044841A (en) * 2013-01-09 2013-04-17 无锡安睿驰科技有限公司 Macromolecular synthesized memory sizing material
CN103834335A (en) * 2013-08-13 2014-06-04 洛阳骏腾能源科技有限公司 High-molecular elastic material with anti-explosion property
CN103849286A (en) * 2013-10-15 2014-06-11 洛阳骏腾能源科技有限公司 High polymer explosion-proof material used for tyre safety

Similar Documents

Publication Publication Date Title
US9662844B2 (en) Self-sealing composition for an inflatable article
CN105037976B (en) Room temperature is to 200 DEG C using vacuum bag sealing joint strip and preparation method thereof
CN103805020A (en) High-molecular hot-melt adhesive for preventing air leakage of automobile tyre, and manufacturing method of high-molecular hot-melt adhesive
CN105237835A (en) Rubber material for wear-proof sealing part
CN103849284A (en) Macromolecule self-glue rubber for preventing automobile tire flat and manufacturing method thereof
WO2018205326A1 (en) Adhesive-free bottle cap gasket and/or padding and preparation method therefor
CN101768294B (en) Cord thread rubber compound for basic layer of automobile tire
CN103819996A (en) Application and preparing method of macromolecular self-sealing hot melt adhesive
CN108485169A (en) Super-strong deformation memory anti-prick explosion-proof material for tire
CN201206050Y (en) Tearing-resistan high temperature resistant conveyer band
CN106905894A (en) A kind of refractory seals glue composition and refractory seals adhesive tape and preparation method thereof
CN101280077A (en) Regenerative vulcanized butadiene nitrile rubber and preparation thereof
CN1931910A (en) Puncture resistant leak-less material for tyre without inner tuber and its prepn process
CN103805021A (en) Macromolecular hot melt adhesive with self-repair function and manufacturing method thereof
CN107641283A (en) A kind of spraying glue of anti-tie flat
CN103849292A (en) Self-sealed tire adhesive and preparation method thereof
CN103849104A (en) Macromolecular self-sealing tire leakage repairing material
CN103805109A (en) Automatic adhering wrapping explosion-prevention polymer sealing rubber powder for improving vehicle tire performances
CN103805111A (en) High-molecular automatic adhering and wrapping rubber powder for improving safety performance of automobile tire
CN103805113A (en) Self-sealed tyre leak-repairing glue and preparation method thereof
CN103804836A (en) Elasticity-proof, leakage-proof and prick-resistant macromolecular material for automobile tyres
CN103820062A (en) Self-sealing polymer hot melt adhesive capable of enabling automobile tire to have anti-explosive performance as well as preparation method and application of self-sealing polymer hot melt adhesive
CN103802612A (en) Polymer self-sealing reperforating material sprayed on inner wall of automobile tire
CN109593242A (en) A kind of oblique heavy truck tire tread compound
CN113135692B (en) Preparation method of anti-aging modified asphalt concrete

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20180904

RJ01 Rejection of invention patent application after publication