CN108485062A - A kind of non-fluorine material of high temperature resistant for phase-changing energy storage material encapsulation - Google Patents
A kind of non-fluorine material of high temperature resistant for phase-changing energy storage material encapsulation Download PDFInfo
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- CN108485062A CN108485062A CN201810255167.0A CN201810255167A CN108485062A CN 108485062 A CN108485062 A CN 108485062A CN 201810255167 A CN201810255167 A CN 201810255167A CN 108485062 A CN108485062 A CN 108485062A
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0023—Use of organic additives containing oxygen
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0066—Use of inorganic compounding ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/08—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing carbon dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/02—CO2-releasing, e.g. NaHCO3 and citric acid
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
- C08J2323/12—Polypropene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2361/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
- C08J2361/04—Condensation polymers of aldehydes or ketones with phenols only
- C08J2361/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
Abstract
The invention discloses it is a kind of for phase-changing energy storage material encapsulation the non-fluorine material of high temperature resistant, including component have acrylic resin, phenolic resin, oxireme, propylene oxide, butylated hydroxy anisole, glass fibre, tert-butyl hydroquinone, benzoic acid, titanium dioxide, potassium sorbate, talcum powder, photosensitizer, foaming agent and plasticizer.Through the above way, the non-fluorine material of high temperature resistant for phase-changing energy storage material encapsulation of the present invention, the use environment of content can fully be met, have the characteristics that heat safe, load both horizontally and vertically can be resisted, has enough mechanical strengths, has a wide range of applications, service life is long, and the failure of phase-changing energy storage material will not be caused because of breakage or the cracking of material.
Description
Technical field
The present invention relates to the field of containers of storage phase-changing energy storage material, are sealed for phase-changing energy storage material more particularly to one kind
The non-fluorine material of high temperature resistant of dress.
Background technology
Phase-change material refers to varying with temperature and changing state of matter and can provide the substance of latent heat.Change physical property
Process is known as phase transition process, and at this moment phase-change material will absorb or discharge a large amount of latent heat.The phase-change accumulation energy refers to substance in phase
It absorbs or releases energy in change procedure, exactly this characteristic, which constitutes phase-changing energy storage material, has widely applied theoretical base
Plinth.Phase-changing energy storage material will become energy-saving and environment-friendly best environmentally protective carrier, be widely used in human lives.Exactly because
For the extensive application of phase-changing energy storage material, storing the container of phase-changing energy storage material also becomes demand and becomes heavy.Existing storage
Container is unable to reach heat safe effect, and application effect is bad.
Invention content
The invention mainly solves the technical problem of providing a kind of high temperature resistant for phase-changing energy storage material encapsulation is non-fluorine-containing
Material, using effect are good.
In order to solve the above technical problems, one aspect of the present invention is：It provides a kind of for phase-change accumulation energy material
Expect encapsulation the non-fluorine material of high temperature resistant, including component have acrylic resin, phenolic resin, oxireme, propylene oxide, fourth
Base hydroxyanisole, glass fibre, tert-butyl hydroquinone, benzoic acid, titanium dioxide, potassium sorbate, talcum powder, photosensitizer,
The content of foaming agent and plasticizer, the non-fluorine material each component of high temperature resistant is：In terms of mass parts, acrylic resin 60-80
Part, 60-80 parts of phenolic resin, 30-40 parts of oxireme, 35-45 parts of propylene oxide, butylated hydroxy anisole 0.5-1.5
Part, 10-17 parts of glass fibre, 1-3 parts of tert-butyl hydroquinone, 1-3 parts of benzoic acid, 7-14 parts of titanium dioxide, sorbic acid
2-4 parts of potassium, 12-18 parts of talcum powder, 0.4-1.2 parts of photosensitizer, 15-22 parts of foaming agent, 10-16 parts of plasticizer.
In a preferred embodiment of the present invention, the content of the non-fluorine material each component of the high temperature resistant is：With mass parts
Meter, 70 parts of acrylic resin, 70 parts of phenolic resin, 35 parts of oxireme, 40 parts of propylene oxide, butylated hydroxy anisole 1
Part, slides 14 parts of glass fibre, 2 parts of tert-butyl hydroquinone, 2 parts of benzoic acid, 11 parts of titanium dioxide, 3 parts of potassium sorbate
15 parts of mountain flour, 0.9 part of photosensitizer, 18 parts of foaming agent, 13 parts of plasticizer.
In a preferred embodiment of the present invention, the photosensitizer is made of Benzophenone and dimethoxybenzoin, the benzene
The mass ratio of ketone and the dimethoxybenzoin is 1:0.2-0.4.
In a preferred embodiment of the present invention, the foaming agent is made of sodium bicarbonate, silica and carbon black, the carbon
The mass ratio of sour hydrogen sodium, the silica and the carbon black is 1:0.5-0.7:0.3-0.5.
In a preferred embodiment of the present invention, the plasticizer is di-n-octyl phthalate, phthalic acid two
Isobutyl ester or diisooctyl phthalate.
In a preferred embodiment of the present invention, the weight average molecular weight of the acrylic resin is 13000-15000.
In a preferred embodiment of the present invention, the weight average molecular weight of the phenolic resin is 10000-12000.
The beneficial effects of the invention are as follows：The non-fluorine material of high temperature resistant for phase-changing energy storage material encapsulation of the present invention, energy
Enough use environments for fully meeting content, have the characteristics that heat safe, can resist load both horizontally and vertically, have
Enough mechanical strengths, have a wide range of applications, and service life is long, phase transformation will not be caused to store up because of breakage or the cracking of material
The failure of energy material.
Specific implementation mode
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common
All other embodiment that technical staff is obtained without making creative work belongs to the model that the present invention protects
It encloses.
Embodiment one：
There is provided it is a kind of for phase-changing energy storage material encapsulation the non-fluorine material of high temperature resistant, including component have acrylic resin, phenol
Urea formaldehyde, oxireme, propylene oxide, butylated hydroxy anisole, glass fibre, tert-butyl hydroquinone, benzoic acid, titanium white
Powder, potassium sorbate, talcum powder, photosensitizer, foaming agent and plasticizer.The content of the non-fluorine material each component of high temperature resistant is：
In terms of mass parts, 70 parts of acrylic resin, 70 parts of phenolic resin, 35 parts of oxireme, 40 parts of propylene oxide, butylhydroxy
1 part of anisole, 14 parts of glass fibre, 2 parts of tert-butyl hydroquinone, 2 parts of benzoic acid, 11 parts of titanium dioxide, potassium sorbate
3 parts, 15 parts of talcum powder, 0.9 part of photosensitizer, 18 parts of foaming agent, 13 parts of plasticizer.
Wherein, the weight average molecular weight of the acrylic resin is 13000.The weight average molecular weight of the phenolic resin is
11000.The photosensitizer is made of Benzophenone and dimethoxybenzoin, the quality of the Benzophenone and the dimethoxybenzoin
Than being 1:0.3.The foaming agent is made of sodium bicarbonate, silica and carbon black, the sodium bicarbonate, the silica and described
The mass ratio of carbon black is 1:0.6:0.5.The plasticizer is diisobutyl phthalate.
Embodiment two：
There is provided it is a kind of for phase-changing energy storage material encapsulation the non-fluorine material of high temperature resistant, including component have acrylic resin, phenol
Urea formaldehyde, oxireme, propylene oxide, butylated hydroxy anisole, glass fibre, tert-butyl hydroquinone, benzoic acid, titanium white
Powder, potassium sorbate, talcum powder, photosensitizer, foaming agent and plasticizer.The content of the non-fluorine material each component of high temperature resistant is：
In terms of mass parts, 60 parts of acrylic resin, 80 parts of phenolic resin, 30 parts of oxireme, 45 parts of propylene oxide, butylhydroxy
0.5 part of anisole, 17 parts of glass fibre, 1 part of tert-butyl hydroquinone, 3 parts of benzoic acid, 7 parts of titanium dioxide, sorbic acid
4 parts of potassium, 12 parts of talcum powder, 1.2 parts of photosensitizer, 15 parts of foaming agent, 16 parts of plasticizer.
Wherein, the weight average molecular weight of the acrylic resin is 15000.The weight average molecular weight of the phenolic resin is
12000.The photosensitizer is made of Benzophenone and dimethoxybenzoin, the quality of the Benzophenone and the dimethoxybenzoin
Than being 1: 0.4.The foaming agent is made of sodium bicarbonate, silica and carbon black, the sodium bicarbonate, the silica and institute
The mass ratio for stating carbon black is 1:0.5:0.3.The plasticizer is diisooctyl phthalate.
Embodiment three：
There is provided it is a kind of for phase-changing energy storage material encapsulation the non-fluorine material of high temperature resistant, including component have acrylic resin, phenol
Urea formaldehyde, oxireme, propylene oxide, butylated hydroxy anisole, glass fibre, tert-butyl hydroquinone, benzoic acid, titanium white
Powder, potassium sorbate, talcum powder, photosensitizer, foaming agent and plasticizer.The content of the non-fluorine material each component of high temperature resistant is：
In terms of mass parts, 80 parts of acrylic resin, 60 parts of phenolic resin, 40 parts of oxireme, 35 parts of propylene oxide, butylhydroxy
1.5 parts of anisole, 10 parts of glass fibre, 3 parts of tert-butyl hydroquinone, 1 part of benzoic acid, 14 parts of titanium dioxide, sorbic acid
2 parts of potassium, 18 parts of talcum powder, 0.4 part of photosensitizer, 22 parts of foaming agent, 10 parts of plasticizer.
Wherein, the weight average molecular weight of the acrylic resin is 14000.The weight average molecular weight of the phenolic resin is
10000.The photosensitizer is made of Benzophenone and dimethoxybenzoin, the quality of the Benzophenone and the dimethoxybenzoin
Than being 1:0.2.The foaming agent is made of sodium bicarbonate, silica and carbon black, the sodium bicarbonate, the silica and described
The mass ratio of carbon black is 1: 0.7:0.4.The plasticizer is di-n-octyl phthalate.
The non-fluorine material of high temperature resistant for phase-changing energy storage material encapsulation that embodiment one, two, three obtains is subjected to resistance to pole
Limit temperature experiment, the results showed that the non-fluorine material of high temperature resistant of embodiment one, two, three can at 120 degrees Celsius normal use.
The non-fluorine material of high temperature resistant for phase-changing energy storage material encapsulation that embodiment one, two, three obtains is subjected to static load test, knot
Fruit shows the non-fluorine material of high temperature resistant of embodiment one, two, three in the case where size is 840mm*840mm*1500mm, static load
Charge values are all higher than 0.03Mpa.
The beneficial effects of the invention are as follows：
One, the non-fluorine material of high temperature resistant for phase-changing energy storage material encapsulation can fully meet the use ring of content
Border has the characteristics that heat safe；
Two, the non-fluorine material of high temperature resistant for phase-changing energy storage material encapsulation can resist load both horizontally and vertically
Lotus has enough mechanical strengths, has a wide range of applications；
Three, the non-fluorine material service life of high temperature resistant for phase-changing energy storage material encapsulation is long, will not be because of the broken of material
Damage or the failure for cracking and causing phase-changing energy storage material.
Example the above is only the implementation of the present invention is not intended to limit the scope of the invention, every to utilize this hair
Equivalent structure or equivalent flow shift made by bright description is applied directly or indirectly in other relevant technology necks
Domain is included within the scope of the present invention.
Claims (7)
1. it is a kind of for phase-changing energy storage material encapsulation the non-fluorine material of high temperature resistant, which is characterized in that including component have poly- third
Olefine resin, oxireme, propylene oxide, butylated hydroxy anisole, glass fibre, tert-butyl hydroquinone, is rested in peace at phenolic resin
Fragrant acid, titanium dioxide, potassium sorbate, talcum powder, photosensitizer, foaming agent and plasticizer, the non-fluorine material each component of high temperature resistant
Content be：In terms of mass parts, 60-80 parts of acrylic resin, 60-80 parts of phenolic resin, 30-40 parts of oxireme, epoxy
35-45 parts of propylene, 0.5-1.5 parts of butylated hydroxy anisole, 10-17 parts of glass fibre, 1-3 parts of tert-butyl hydroquinone,
1-3 parts of benzoic acid, 7-14 parts of titanium dioxide, 2-4 parts of potassium sorbate, 12-18 parts of talcum powder, 0.4-1.2 parts of photosensitizer,
15-22 parts of foaming agent, 10-16 parts of plasticizer.
2. the non-fluorine material of high temperature resistant according to claim 1, which is characterized in that the non-fluorine material each group of high temperature resistant
Point content be：In terms of mass parts, 70 parts of acrylic resin, 70 parts of phenolic resin, 35 parts of oxireme, propylene oxide 40
Part, 1 part of butylated hydroxy anisole, 14 parts of glass fibre, 2 parts of tert-butyl hydroquinone, 2 parts of benzoic acid, titanium dioxide 11
Part, 3 parts of potassium sorbate, 15 parts of talcum powder, 0.9 part of photosensitizer, 18 parts of foaming agent, 13 parts of plasticizer.
3. the non-fluorine material of high temperature resistant according to claim 1, which is characterized in that the photosensitizer is by Benzophenone and rests in peace
The mass ratio of fragrant dimethyl ether composition, the Benzophenone and the dimethoxybenzoin is 1:0.2-0.4.
4. the non-fluorine material of high temperature resistant according to claim 1, which is characterized in that the foaming agent is by sodium bicarbonate, oxygen
The mass ratio of SiClx and carbon black composition, the sodium bicarbonate, the silica and the carbon black is 1:0.5-0.7:0.3-0.5.
5. the non-fluorine material of high temperature resistant according to claim 1, which is characterized in that the plasticizer is phthalic acid two
N-octyl, diisobutyl phthalate or diisooctyl phthalate.
6. the non-fluorine material of high temperature resistant according to claim 1, which is characterized in that the Weight-average molecular of the acrylic resin
Amount is 13000-15000.
7. the non-fluorine material of high temperature resistant according to claim 1, which is characterized in that the weight average molecular weight of the phenolic resin
For 10000-12000.
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| CN201810255167.0A CN108485062A (en) | 2018-03-27 | 2018-03-27 | A kind of non-fluorine material of high temperature resistant for phase-changing energy storage material encapsulation |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810255167.0A CN108485062A (en) | 2018-03-27 | 2018-03-27 | A kind of non-fluorine material of high temperature resistant for phase-changing energy storage material encapsulation |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA786400A (en) * | 1968-05-28 | Yamada Nobuo | Modified polypropylene fibers and the method for preparing the same | |
| US5952425A (en) * | 1996-12-31 | 1999-09-14 | Advanced Elastomer Systems, L.P. | Preferred structure of phenolic resin curative for thermoplastic vulcanizate |
| CN103788493A (en) * | 2014-02-28 | 2014-05-14 | 苏州瑞邦塑胶有限公司 | Formula of reinforced polypropylene plastic |
| CN107189210A (en) * | 2017-06-27 | 2017-09-22 | 苏州菱慧电子科技有限公司 | A kind of polymer composite |
-
2018
- 2018-03-27 CN CN201810255167.0A patent/CN108485062A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA786400A (en) * | 1968-05-28 | Yamada Nobuo | Modified polypropylene fibers and the method for preparing the same | |
| US5952425A (en) * | 1996-12-31 | 1999-09-14 | Advanced Elastomer Systems, L.P. | Preferred structure of phenolic resin curative for thermoplastic vulcanizate |
| CN103788493A (en) * | 2014-02-28 | 2014-05-14 | 苏州瑞邦塑胶有限公司 | Formula of reinforced polypropylene plastic |
| CN107189210A (en) * | 2017-06-27 | 2017-09-22 | 苏州菱慧电子科技有限公司 | A kind of polymer composite |
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Application publication date: 20180904 |