CN107522929A - A kind of anlistatig high polymer material - Google Patents

A kind of anlistatig high polymer material Download PDF

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Publication number
CN107522929A
CN107522929A CN201710745618.4A CN201710745618A CN107522929A CN 107522929 A CN107522929 A CN 107522929A CN 201710745618 A CN201710745618 A CN 201710745618A CN 107522929 A CN107522929 A CN 107522929A
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CN
China
Prior art keywords
parts
molecular weight
polymer material
high polymer
glass fibre
Prior art date
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Pending
Application number
CN201710745618.4A
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Chinese (zh)
Inventor
潘征鹏
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Nantong Chengshan Polymer Material Co Ltd
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Nantong Chengshan Polymer Material Co Ltd
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Priority to CN201710745618.4A priority Critical patent/CN107522929A/en
Publication of CN107522929A publication Critical patent/CN107522929A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/04Antistatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/068Ultra high molecular weight polyethylene

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of anlistatig high polymer material, it is characterised in that:It is made up of the component of following mass parts:Ultra-high molecular weight polyethylene 80 90 part, poly- fragrant alkali 35 part, plasticizer 36 part, concentrated hydrochloric acid 13 part, propylene glycol ester terephthalate valeric acid butanediol 10 12 part, stalk ashes 25 part, poly- nonyl dianhydride 13 part, hydrogenated rosin 24 part, antioxidant RD 14 part, crosslinked starch 24 part, carbon black 13 part, sodium citrate 25 part and glass fibre 35 part of the molecular weight for 500 600 ten thousand.The high polymer material of the present invention is using ultra-high molecular weight polyethylene as base-material, the high polymer material produced has resistant to elevated temperatures performance, simultaneously, glass fibre is with the addition of in the present invention, it is big using the insulating properties possessed in itself and tensile strength of glass fibre, improve the antistatic and mechanical performance of high polymer material.

Description

A kind of anlistatig high polymer material
Technical field
The invention belongs to technical field of macromolecules, and in particular to a kind of anlistatig high polymer material.
Background technology
At present, the rapid development of modern industrial society, the utilization of high polymer material is more and more extensive, major colleges and universities, research Mechanism is both provided with high polymer material research center, and high polymer material is the material being made up of the higher compound of relative molecular mass Material, including rubber, plastics, fiber, coating, adhesive and polymer-based composite, macromolecule are forms existing for life.Institute Some life entities can be regarded as high molecular set.At present, good mechanical property, high temperature resistant and anlistatig macromolecule material are gone back Material.
The content of the invention
In view of the defects and deficiencies of the prior art, the present invention intends to provide a kind of good mechanical property, resistant to elevated temperatures Anlistatig high polymer material, to solve the problems, such as proposed in background technology.
To achieve the above object, the technical solution adopted by the present invention is:A kind of anlistatig high polymer material, its innovative point It is:It is made up of the component of following mass parts:Molecular weight be 500-600 ten thousand ultra-high molecular weight polyethylene 80-90 parts, gather fragrant alkali 3-5 parts, plasticizer 3-6 parts, concentrated hydrochloric acid 1-3 parts, propylene glycol ester terephthalate-valeric acid butanediol 10-12 parts, stalk ashes 2- 5 parts, poly- nonyl dianhydride 1-3 parts, hydrogenated rosin 2-4 parts, antioxidant RD1-4 parts, crosslinked starch 2-4 parts, carbon black 1-3 parts, citron Sour sodium 2-5 parts and glass fibre 3-5 parts.
Further, a kind of anlistatig high polymer material, is made up of the component of following mass parts:Molecular weight is 500- 6000000 ultra-high molecular weight polyethylene 82-88 parts, gather fragrant alkali 3-4 parts, plasticizer 4-5 parts, concentrated hydrochloric acid 1-2 parts, terephthaldehyde Acid propylene glycol ester-valeric acid butanediol 10-11 parts, stalk ashes 3-4 parts, poly- nonyl dianhydride 1-3 parts, hydrogenated rosin 2-3 parts, antioxygen Agent RD2-3 parts, crosslinked starch 2-3 parts, carbon black 2-3 parts, sodium citrate 3-4 parts and glass fibre 3-4 parts.
Further, a kind of anlistatig high polymer material, is made up of the component of following mass parts:Molecular weight is 500- 6000000 85 parts of ultra-high molecular weight polyethylene, gather fragrant 3 parts of alkali, 4 parts of plasticizer, 2 parts of concentrated hydrochloric acid, propylene glycol ester terephthalate- 11 parts of valeric acid butanediol, 4 parts of stalk ashes, 3 parts of poly- nonyl dianhydride, 3 parts of hydrogenated rosin, antioxidant RD3 parts, crosslinked starch 2 Part, 2 parts of carbon black, 4 parts of sodium citrate and 4 parts of glass fibre.
The present invention has the beneficial effect that:The high polymer material of the present invention, as base-material, is given birth to using ultra-high molecular weight polyethylene The high polymer material of output has resistant to elevated temperatures performance, meanwhile, glass fibre is with the addition of in the present invention, utilizes the sheet of glass fibre The insulating properties and tensile strength that body possesses are big, improve the antistatic and mechanical performance of high polymer material.
Embodiment
Present embodiment use technical scheme be:
Embodiment 1
A kind of anlistatig high polymer material, is made up of the component of following mass parts:Molecular weight is the super of 500-600 ten thousand 80 parts of High molecular weight polyethylene, gather fragrant 3 parts of alkali, 3 parts of plasticizer, 1 part of concentrated hydrochloric acid, propylene glycol ester terephthalate-valeric acid fourth two 10 parts of alcohol, 2 parts of stalk ashes, 1 part of poly- nonyl dianhydride, 2 parts of hydrogenated rosin, antioxidant RD1 parts, 2 parts of crosslinked starch, 1 part of carbon black, 3 parts of 2 parts of sodium citrate and glass fibre.
Embodiment 2
A kind of anlistatig high polymer material, is made up of the component of following mass parts:Molecular weight is the super of 500-600 ten thousand 90 parts of High molecular weight polyethylene, gather fragrant 5 parts of alkali, 6 parts of plasticizer, 3 parts of concentrated hydrochloric acid, propylene glycol ester terephthalate-valeric acid fourth two 12 parts of alcohol, 5 parts of stalk ashes, 3 parts of poly- nonyl dianhydride, 4 parts of hydrogenated rosin, antioxidant RD4 parts, 4 parts of crosslinked starch, 3 parts of carbon black, 5 parts of 5 parts of sodium citrate and glass fibre.
Embodiment 3
A kind of anlistatig high polymer material, is made up of the component of following mass parts:Molecular weight is the super of 500-600 ten thousand 85 parts of High molecular weight polyethylene, gather fragrant 3 parts of alkali, 4 parts of plasticizer, 2 parts of concentrated hydrochloric acid, propylene glycol ester terephthalate-valeric acid fourth two 11 parts of alcohol, 4 parts of stalk ashes, 3 parts of poly- nonyl dianhydride, 3 parts of hydrogenated rosin, antioxidant RD3 parts, 2 parts of crosslinked starch, 2 parts of carbon black, 4 parts of 4 parts of sodium citrate and glass fibre.
Using ultra-high molecular weight polyethylene as base-material, the high polymer material produced has the high polymer material of the present invention Have resistant to elevated temperatures performance, meanwhile, the present invention in the addition of glass fibre, using glass fibre the insulating properties possessed in itself and Tensile strength is big, improves the antistatic and mechanical performance of high polymer material.
It is described above, it is merely illustrative of the technical solution of the present invention and unrestricted, those of ordinary skill in the art are to this hair The other modifications or equivalent substitution that bright technical scheme is made, without departing from the spirit and scope of technical solution of the present invention, It all should cover among scope of the presently claimed invention.

Claims (3)

  1. A kind of 1. anlistatig high polymer material, it is characterised in that:It is made up of the component of following mass parts:Molecular weight is 500- 6000000 ultra-high molecular weight polyethylene 80-90 parts, gather fragrant alkali 3-5 parts, plasticizer 3-6 parts, concentrated hydrochloric acid 1-3 parts, terephthalic acid (TPA) Propylene glycol ester-valeric acid butanediol 10-12 parts, stalk ashes 2-5 parts, poly- nonyl dianhydride 1-3 parts, hydrogenated rosin 2-4 parts, antioxidant RD 1-4 parts, crosslinked starch 2-4 parts, carbon black 1-3 parts, sodium citrate 2-5 parts and glass fibre 3-5 parts.
  2. A kind of 2. anlistatig high polymer material according to claim 1, it is characterised in that:By the component of following mass parts Composition:Molecular weight is 500-600 ten thousand ultra-high molecular weight polyethylene 82-88 parts, poly- fragrant alkali 3-4 parts, plasticizer 4-5 parts, dense salt Sour 1-2 parts, propylene glycol ester terephthalate-valeric acid butanediol 10-11 parts, stalk ashes 3-4 parts, poly- nonyl dianhydride 1-3 parts, hydrogenation Rosin 2-3 parts, antioxidant RD 2-3 parts, crosslinked starch 2-3 parts, carbon black 2-3 parts, sodium citrate 3-4 parts and glass fibre 3-4 Part.
  3. A kind of 3. anlistatig high polymer material according to claim 1, it is characterised in that:By the component of following mass parts Composition:85 parts of ultra-high molecular weight polyethylene that molecular weight is 500-600 ten thousand, gather fragrant 3 parts of alkali, be 4 parts of plasticizer, 2 parts of concentrated hydrochloric acid, right Benzene dicarboxylic acid trimethylene glycol ester -11 parts of valeric acid butanediol, 4 parts of stalk ashes, 3 parts of poly- nonyl dianhydride, 3 parts of hydrogenated rosin, antioxidant 4 parts of 3 parts of RD, 2 parts of crosslinked starch, 2 parts of carbon black, 4 parts of sodium citrate and glass fibre.
CN201710745618.4A 2017-08-26 2017-08-26 A kind of anlistatig high polymer material Pending CN107522929A (en)

Priority Applications (1)

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CN201710745618.4A CN107522929A (en) 2017-08-26 2017-08-26 A kind of anlistatig high polymer material

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108707243A (en) * 2018-06-20 2018-10-26 安徽申科塑业有限公司 A kind of novel high polymer plastic cement

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102432939A (en) * 2011-11-07 2012-05-02 中国蓝星(集团)股份有限公司 Antistatic flame-retardant ultra high molecular weight polyethylene composition and preparation method thereof
CN106750785A (en) * 2016-12-13 2017-05-31 无锡市四方达高分子材料有限公司 Macromolecular material
CN107151362A (en) * 2017-05-19 2017-09-12 江苏祥生新能源科技有限公司 The preparation method in environment-protection flame-proof electrostatic resistance superhigh molecular weight polyethylene pipe road

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102432939A (en) * 2011-11-07 2012-05-02 中国蓝星(集团)股份有限公司 Antistatic flame-retardant ultra high molecular weight polyethylene composition and preparation method thereof
CN106750785A (en) * 2016-12-13 2017-05-31 无锡市四方达高分子材料有限公司 Macromolecular material
CN107151362A (en) * 2017-05-19 2017-09-12 江苏祥生新能源科技有限公司 The preparation method in environment-protection flame-proof electrostatic resistance superhigh molecular weight polyethylene pipe road

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108707243A (en) * 2018-06-20 2018-10-26 安徽申科塑业有限公司 A kind of novel high polymer plastic cement

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