CN108484125A - A kind of production method of the ceramic with catalysis - Google Patents
A kind of production method of the ceramic with catalysis Download PDFInfo
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- CN108484125A CN108484125A CN201810492111.7A CN201810492111A CN108484125A CN 108484125 A CN108484125 A CN 108484125A CN 201810492111 A CN201810492111 A CN 201810492111A CN 108484125 A CN108484125 A CN 108484125A
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- catalysis
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- 239000000919 ceramic Substances 0.000 title claims abstract description 56
- 238000006555 catalytic reaction Methods 0.000 title claims abstract description 23
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 20
- 239000007788 liquid Substances 0.000 claims abstract description 19
- 230000003197 catalytic effect Effects 0.000 claims abstract description 18
- 239000011449 brick Substances 0.000 claims abstract description 12
- 238000003756 stirring Methods 0.000 claims abstract description 4
- 238000000465 moulding Methods 0.000 claims abstract description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 16
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 16
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 claims description 16
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 claims description 8
- 229910000476 molybdenum oxide Inorganic materials 0.000 claims description 8
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 8
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 claims description 8
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 8
- 229910052939 potassium sulfate Inorganic materials 0.000 claims description 8
- 235000011151 potassium sulphates Nutrition 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 8
- 239000000377 silicon dioxide Substances 0.000 claims description 8
- 229910001923 silver oxide Inorganic materials 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000011787 zinc oxide Substances 0.000 claims description 8
- 229910000166 zirconium phosphate Inorganic materials 0.000 claims description 8
- LEHFSLREWWMLPU-UHFFFAOYSA-B zirconium(4+);tetraphosphate Chemical compound [Zr+4].[Zr+4].[Zr+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LEHFSLREWWMLPU-UHFFFAOYSA-B 0.000 claims description 8
- AEJIMXVJZFYIHN-UHFFFAOYSA-N copper;dihydrate Chemical compound O.O.[Cu] AEJIMXVJZFYIHN-UHFFFAOYSA-N 0.000 claims description 7
- 239000008367 deionised water Substances 0.000 claims description 7
- 229910021641 deionized water Inorganic materials 0.000 claims description 7
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims description 7
- 229910000402 monopotassium phosphate Inorganic materials 0.000 claims description 7
- 235000019796 monopotassium phosphate Nutrition 0.000 claims description 7
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 claims description 7
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 7
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 7
- 238000003723 Smelting Methods 0.000 claims description 6
- 238000002844 melting Methods 0.000 claims description 6
- 230000008018 melting Effects 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 5
- 238000010304 firing Methods 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- SEGLCEQVOFDUPX-UHFFFAOYSA-N di-(2-ethylhexyl)phosphoric acid Chemical compound CCCCC(CC)COP(O)(=O)OCC(CC)CCCC SEGLCEQVOFDUPX-UHFFFAOYSA-N 0.000 claims 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 239000011591 potassium Substances 0.000 claims 1
- 241001122767 Theaceae Species 0.000 abstract description 11
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract description 6
- 229910021529 ammonia Inorganic materials 0.000 abstract description 3
- 235000009508 confectionery Nutrition 0.000 abstract description 3
- 239000005416 organic matter Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- 230000035622 drinking Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
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- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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Abstract
The invention discloses a kind of production methods of the ceramic with catalysis, include the following steps：Catalytic liquid is added into ceramic batch, and stirs evenly；Ceramic body is made using the ceramic batch for adding catalytic liquid；The ceramic body made is put into kiln and is fired, the molding of a period of time postcooling is fired, to which ceramic be made.Ceramic made from the production method of ceramic using the present invention has catalysis, wineglass or teacup such as with catalysis or wall brick, wineglass can be catalyzed the wine in cup, so that wine is more mellow and palatable, improve the quality of wine, teacup can be catalyzed the tea in cup, so that tea is more sweet and palatable, improve the quality of tea, wall brick is attached on the interior wall of lavatory, and ammonia and other foul gas in lavatory can be catalytically decomposed in wall brick, purifies the air in lavatory, therefore people’s lives demand is met, improves people’s lives quality.
Description
Technical field
The invention belongs to ceramic technology fields, are related to a kind of production method of the ceramic with catalysis.
Background technology
Ceramics are all liked by broad masses very much all the time, are component parts important in human lives.Ceramics
It is widely used, by the difference of purposes, domestic ceramics, architectural pottery etc. can be divided into, domestic ceramics has：Tableware, tea set, drinking utensils, tank,
Disk, dish, bowl etc., architectural pottery has：Wall brick, sanitary ware etc..Currently, the function of common domestic ceramics and architectural pottery all compares
It is more traditional and single.
Invention content
The object of the present invention is to provide a kind of production methods of ceramic, using ceramic made from the production method
With catalysis, to meet people’s lives demand.
In order to solve the above-mentioned technical problem, the technical solution adopted by the present invention is：A kind of ceramic system with catalysis
The production method of product, includes the following steps：
A. catalytic liquid is added into ceramic batch, and stirs evenly；
B. ceramic body is made using the ceramic batch for adding catalytic liquid；
C. the ceramic body made in step B is put into kiln and is fired, fire the molding of a period of time postcooling, to
Ceramic is made.
Further, the catalytic liquid includes the component of following parts by weight：The component of following parts by weight：2-4 parts of molybdenum oxide,
5-8 parts of zinc oxide, 3-5 parts of potassium sulfate, 4-7 parts of Kocide SD, 5-7 parts of potassium dihydrogen phosphate, 6-9 parts of sodium oxide molybdena, basic zirconium phosphate 3-6
Part, 2-4 parts of silver oxide, 3-6 parts of molybdenum sulfide, 3-5 parts of cerium oxide, 8-10 parts of silica, 50-60 parts of deionized water.
Further, the parts by weight of the catalytic liquid each component are：3 parts of molybdenum oxide, 6 parts of zinc oxide, 3 parts of potassium sulfate, hydrogen
4 parts of copper oxide, 6 parts of potassium dihydrogen phosphate, 7 parts of sodium oxide molybdena, 4 parts of basic zirconium phosphate, 3 parts of silver oxide, 3.5 parts of molybdenum sulfide, 3 parts of cerium oxide,
9 parts of silica, 55 parts of deionized water.
Further, the preparation method of the catalytic liquid：Using nano-level grinder by powdered molybdenum oxide, zinc oxide,
Potassium sulfate, Kocide SD, potassium dihydrogen phosphate, sodium oxide molybdena, basic zirconium phosphate, silver oxide, molybdenum sulfide, cerium oxide, silica are ground respectively
Wear into nanometer powder；The nanometer powder of each component obtained is mixed, and is uniformly mixing to obtain mixture；It will be described mixed
It closes material and puts into progress melting in smelting furnace, smelting temperature is 1200 DEG C；Deionized water is added into the mixture after melting, stirs
It mixes and uniformly obtains the catalytic liquid.
Further, the ratio of ceramic batch and catalytic liquid is to add 0.5L per 20kg ceramic batch to urge in the step A
Change liquid.
Further, the firing temperature in the step C is 1300 DEG C, and the firing time is 12 hours.
Further, the ceramic is wineglass or teacup or wall brick.
Advantageous effect of the present invention：Ceramic made from the production method of ceramic using the present invention, ceramic
Hole in solidification have a nanometer powder with catalysis, therefore the ceramic has catalysis, such as has catalysis work(
The wineglass or teacup or wall brick of energy, wineglass can be catalyzed the wine in cup, the organic matter in wine be catalytically decomposed, so that wine more alcohol
It is thick and palatable, improve the quality of wine；Teacup can be catalyzed the tea in cup, and the organic matter in tea is catalytically decomposed, so that
Tea is more sweet and palatable, improves the quality of tea；Wall brick is attached on the interior wall of lavatory, and wall brick can be catalytically decomposed in lavatory
Ammonia and other foul gas purify the air in lavatory.Therefore, the production method of ceramic using the present invention is made
Ceramic have catalysis, meet people’s lives demand, improve people’s lives quality.
Specific implementation mode
The following is a clear and complete description of the technical scheme in the embodiments of the invention, it is clear that described embodiment
Only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field
The every other embodiment that art personnel are obtained without creative efforts belongs to the model that the present invention protects
It encloses.
The production method of the ceramic with catalysis of the present embodiment, includes the following steps：
Step A. is added catalytic liquid into ceramic batch, and the ratio of ceramic batch and catalytic liquid is to add per 20kg ceramic batch
Add 0.5L catalytic liquids, then stirs evenly；
Step B. makes ceramic body using the ceramic batch for adding catalytic liquid；
The ceramic body made in step B is put into kiln and fires by step C., and firing temperature is 1300 DEG C, fires 12
Hour postcooling molding, to which ceramic be made, ceramic is wineglass or teacup or wall brick.
The preparation method of catalytic liquid is as follows：
Weigh powdered molybdenum oxide 3kg, zinc oxide 6kg, potassium sulfate 3kg, Kocide SD 4kg, potassium dihydrogen phosphate 6kg,
Sodium oxide molybdena 7kg, basic zirconium phosphate 4kg, silver oxide 3kg, molybdenum sulfide 3.5kg, cerium oxide 3kg, silica 9kg, and weigh deionization
Water 55kg；
Using nano-level grinder by powdered molybdenum oxide, zinc oxide, potassium sulfate, Kocide SD, potassium dihydrogen phosphate, oxidation
Sodium, basic zirconium phosphate, silver oxide, molybdenum sulfide, cerium oxide, silica are ground into nanometer powder respectively；
The nanometer powder of each component obtained is mixed, and is uniformly mixing to obtain mixture；By the mixture
It puts into and carries out melting in smelting furnace, smelting temperature is 1200 DEG C；
Deionized water is added into the mixture after melting, is uniformly mixing to obtain catalytic liquid.
The interior solidification of hole of ceramic made from the production method of ceramic using the present invention, ceramic has tool
Have a nanometer powder of catalysis, therefore the ceramic has a catalysis, such as wineglass with catalysis or teacup or
Wall brick, wineglass can be catalyzed the wine in cup, and the organic matter being catalytically decomposed in wine improves so that wine is more mellow and palatable
The quality of wine；Teacup can be catalyzed the tea in cup, and the organic matter in tea is catalytically decomposed, so that tea is more sweet and can
Mouthful, improve the quality of tea；Wall brick is attached on the interior wall of lavatory, and ammonia and other stenches in lavatory can be catalytically decomposed in wall brick
Gas purifies the air in lavatory.Therefore, ceramic made from the production method of ceramic using the present invention has and urges
Change function, meets people’s lives demand, improve people’s lives quality.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention
With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.
Claims (7)
1. a kind of production method of the ceramic with catalysis, which is characterized in that include the following steps：
A. catalytic liquid is added into ceramic batch, and stirs evenly；
B. ceramic body is made using the ceramic batch for adding catalytic liquid；
C. the ceramic body made in step B is put into kiln and is fired, fire the molding of a period of time postcooling, to be made
Ceramic.
2. a kind of production method of ceramic with catalysis according to claim 1, which is characterized in that described
Catalytic liquid includes the component of following parts by weight：The component of following parts by weight：2-4 parts of molybdenum oxide, 5-8 parts of zinc oxide, potassium sulfate 3-5
Part, 4-7 parts of Kocide SD, 5-7 parts of potassium dihydrogen phosphate, 6-9 parts of sodium oxide molybdena, 3-6 parts of basic zirconium phosphate, 2-4 parts of silver oxide, molybdenum sulfide 3-
6 parts, 3-5 parts of cerium oxide, 8-10 parts of silica, 50-60 parts of deionized water.
3. a kind of production method of ceramic with catalysis according to claim 2, which is characterized in that described
The parts by weight of catalytic liquid each component are：3 parts of molybdenum oxide, 6 parts of zinc oxide, 3 parts of potassium sulfate, 4 parts of Kocide SD, potassium dihydrogen phosphate 6
Part, 7 parts of sodium oxide molybdena, 4 parts of basic zirconium phosphate, 3 parts of silver oxide, 3.5 parts of molybdenum sulfide, 3 parts of cerium oxide, 9 parts of silica, deionized water 55
Part.
4. a kind of production method of ceramic with catalysis according to claim 2, which is characterized in that described
The preparation method of catalytic liquid：Using nano-level grinder by powdered molybdenum oxide, zinc oxide, potassium sulfate, Kocide SD, di(2-ethylhexyl)phosphate
Hydrogen potassium, sodium oxide molybdena, basic zirconium phosphate, silver oxide, molybdenum sulfide, cerium oxide, silica are ground into nanometer powder respectively；It will be obtained each
The nanometer powder of component mixes, and is uniformly mixing to obtain mixture；The mixture is put into smelting furnace and is carried out
Melting, smelting temperature are 1200 DEG C；Deionized water is added into the mixture after melting, is uniformly mixing to obtain the catalytic liquid.
5. a kind of production method of ceramic with catalysis according to claim 1, which is characterized in that described
The ratio of ceramic batch and catalytic liquid is to add 0.5L catalytic liquids per 20kg ceramic batch in step A.
6. a kind of production method of ceramic with catalysis according to claim 1, which is characterized in that described
Firing temperature in step C is 1300 DEG C, and the firing time is 12 hours.
7. a kind of production method of ceramic with catalysis according to claim 1, which is characterized in that described
Ceramic is wineglass or teacup or wall brick.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110563441A (en) * | 2019-09-12 | 2019-12-13 | 浙江碧岩环保科技有限公司 | Catalytic carbon pottery and preparation process thereof |
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|---|---|---|---|---|
| GB776480A (en) * | 1954-02-15 | 1957-06-05 | Rohm & Haas | Improvements in or relating to quaternary ammonium compound |
| CN103113084A (en) * | 2013-03-05 | 2013-05-22 | 周云山 | Anion ceramsite for ageing white spirit, preparation method of anion ceramsite and white spirit ageing equipment |
| CN105084880A (en) * | 2014-05-10 | 2015-11-25 | 佛山市百瑞新材料技术有限公司 | Efficient catalytic porous ceramic |
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2018
- 2018-05-22 CN CN201810492111.7A patent/CN108484125A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB776480A (en) * | 1954-02-15 | 1957-06-05 | Rohm & Haas | Improvements in or relating to quaternary ammonium compound |
| CN103113084A (en) * | 2013-03-05 | 2013-05-22 | 周云山 | Anion ceramsite for ageing white spirit, preparation method of anion ceramsite and white spirit ageing equipment |
| CN105084880A (en) * | 2014-05-10 | 2015-11-25 | 佛山市百瑞新材料技术有限公司 | Efficient catalytic porous ceramic |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110563441A (en) * | 2019-09-12 | 2019-12-13 | 浙江碧岩环保科技有限公司 | Catalytic carbon pottery and preparation process thereof |
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