CN108477172A - A kind of Herbicidal combinations containing trifluoro ketone grass ether and cyhalofop-butyl - Google Patents

A kind of Herbicidal combinations containing trifluoro ketone grass ether and cyhalofop-butyl Download PDF

Info

Publication number
CN108477172A
CN108477172A CN201810354231.0A CN201810354231A CN108477172A CN 108477172 A CN108477172 A CN 108477172A CN 201810354231 A CN201810354231 A CN 201810354231A CN 108477172 A CN108477172 A CN 108477172A
Authority
CN
China
Prior art keywords
cyhalofop
butyl
ether
herbicidal combinations
trifluoro ketone
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810354231.0A
Other languages
Chinese (zh)
Inventor
徐德锋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Changzhou University
Original Assignee
Changzhou University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Changzhou University filed Critical Changzhou University
Priority to CN201810354231.0A priority Critical patent/CN108477172A/en
Publication of CN108477172A publication Critical patent/CN108477172A/en
Pending legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
    • A01N39/02—Aryloxy-carboxylic acids; Derivatives thereof
    • A01N39/04—Aryloxy-acetic acids; Derivatives thereof

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention relates to a kind of Herbicidal combinations containing trifluoro ketone grass ether and cyhalofop-butyl, are related to technical field of herbicide production, and active ingredient is trifluoro ketone grass ether and cyhalofop-butyl.The weight part ratio of trifluoro ketone grass ether and cyhalofop-butyl in Herbicidal combinations is 1:0.1‑1:20.Trifluoro ketone grass ether and the cyhalofop-butyl compounding that the present invention uses, have the function of that efficient, wide spectrum prevents and kill off paddy field weed, expand herbicide spectral limit simultaneously, there is control effect to a variety of weeds such as direct seading rice field barnyard grass, green bristlegrass, Monochoria vaginalis, water amaranth, false loosestrife, mexicana, lady's-grass, moleplant seed, nutgrass flatsedge, convexutricle sedge herbs, on crop without influence, than two amount of herbicide kinds of trifluoro ketone grass ether and cyhalofop-butyl are used alone the effect of is good.

Description

A kind of Herbicidal combinations containing trifluoro ketone grass ether and cyhalofop-butyl
Technical field
The present invention relates to mixture of herbicides production technical fields, more particularly to a kind of to contain trifluoro ketone grass ether and cyhalofop-butyl It is used to prevent and kill off the Herbicidal combinations of paddy field weed for herbicide raw material.
Background technology
Chemical weed control is one of the main method of modern agriculture weeds Comprehensive Control.On the one hand, single kind herbicide is big Area uses, and causes weeds to develop immunity to drugs quickly.Meanwhile grass when agricultural weed generation is mutually complicated, grassy weed, broad-leaved The mixed life of a variety of weeds such as weeds, nutgrass flatsedge, the use of single kind herbicide cannot solve farmland weed, can show in a certain respect Defect and limitation.Variety classes herbicide mixture, has that herbicidal spectrum is wide, promotes practical control effect, delays the anti-medicine of weeds The advantages that property, time and labour saving.On the other hand, herbicide type is various, and different herbicide weeding principles are not quite similar.Some cases Under, it is possible to antagonism occur after herbicide active ingredient mixture, i.e., mixed actual effect is applied alone less than two kinds of herbicides The sum of effect, such as sulfonylurea herbicide is mixed with phenoxy carboxylic acid herbicides, sulfonylurea herbicide and fragrant phenoxy Phenoxy propionic acid herbicide mixture；In the case of other, although enhancing control of weeds effect after mixed, toxicity is produced, is threatened To crop safety, including work as stubble crop safety and succession crop safety, such as acetamide-group herbicides use meeting to talent arch soil phase crop Cause dead seedling, glyphosate in shallow root crop in the ranks using causing whole strain death of crop etc..Therefore, suitable herbicide is selected to carry out Mixture acquires a certain degree of difficulty to achieve the purpose that enhance herbicidal effect tool.
Trifluoro ketone grass ether is the pyrimidine salicylic acid high-efficiency broad spectrum researched and developed by the Nanjing bio tech ltd Hui Bo Herbicide for paddy field, chemical name：O- [bis- (the 4,6- dioxime base -2- bases oxygroup) benzoyls of 2,6-] oxime (3- trifluoros Methyl) acetophenone, English name：Ethanone,1-[3-(trifluoromethyl)phenyl]-o-[2,6-bis[(4,6- dimethoxy-2-pyrimidinyl)oxy]benzoyl]oxime；No. CAS：【1646642-77-4】, it is mainly used for anti-water removal The weeds such as barnyard grass in paddy field, moleplant seed, Monochoria vaginalis, water amaranth, false loosestrife, mexicana.Such herbicide is efficient with it, safe, wide Spectrum, high selectivity and the characteristics such as environmental-friendly are of great interest.(Chinese invention patent, CN104302629A)
The fragrant phenoxy phenoxy propionic acid weeding that cyhalofop-butyl is developed by Tao Nongke companies of the U.S. (Dow AgroSciences) Agent, chemical name：(R) -2- [4- itrile group -2- fluorophenoxies] phenoxy group] butyl propionate also known as a thousand pieces of gold.It is uptake and translocation weeding Agent is absorbed by the blade and leaf sheath of plant, and bast conduction, accumulation inhibits acetyl coenzyme A in the meristem zone of plant Carboxylase (ACC) makes aliphatic acid synthesis stop, and the growth division of cell cannot be normally carried out, and the structure containing fat such as membranous system is destroyed, Finally result in Plant death.It is mainly used for preventing and kill off important grassy weed, it is efficient to moleplant seed, have to low age barnyard grass certain Preventive effect can also prevent and kill off lady's-grass, green bristlegrass, eleusine indica, amur foxtail etc..It is invalid to sedge weed and broad leaved weed.
Single formulation weeding is not thorough, and often needs secondary or even medication three times, weeding cost higher.As country is to severe toxicity The pressure of pesticide disables, and in the case where ensureing medication effect, reduces environmental pollution, and reducing pesticide dosage becomes Agrochemicals A kind of trend.Variety classes herbicide mixture, has that herbicidal spectrum is wide, promotes practical herbicidal effect, reduces dosage, reduction at This, delays the drug resistance generated to weeds, is the important means of modern agriculture integrated control.
Invention content
The present invention is the project that Changzhou University cooperates with the Nanjing bio tech ltd Hui Bo, by trifluoro ketone grass ether It is furtherd investigate with the recipe determination of cyhalofop-butyl, finds trifluoro ketone grass ether and cyhalofop-butyl carrying out mixture, centainly mix There is synergistic effect, after further study, complete the present invention rice terrace annual grassy weeds with proportional region.
It is an object of the invention to overcome the problems, such as the effect that develops immunity to drugs to paddy field weed and actually prevent in the prior art Fruit is undesirable, provides a kind of less toxic, efficient, wide spectrum, safety herbicide for paddy field, is conducive to paddy field weed integrated control Herbicidal combinations.
Technical solution：To achieve the above object, the present invention provides a kind of weeding containing trifluoro ketone grass ether and cyhalofop-butyl Composition, active ingredient are trifluoro ketone grass ether and cyhalofop-butyl, and the weight part ratio of trifluoro ketone grass ether and cyhalofop-butyl is 1: 0.1-1:20。
The Herbicidal combinations of the present invention are prepared into a variety of doses used on suitable modern agriculture rice terrace by known method Type, relatively good has suspending agent, dispersibility oil-suspending agent or wettable powder.
The Herbicidal combinations of the present invention contain the usual auxiliaries of amount of herbicide preparation, including solvent, emulsifier, wetting agent, One or more of stabilizer, by stages agent, thickener, antifoaming agent, antifreezing agent, disintegrant, binder, filler, medium etc. are mixed It closes, is known substance, can be varied from, be not particularly limited according to different situations.
Herbicidal combinations provided by the invention, generally use are watered spray method use, can use Modern Agriculture as needed Other applied in industry use technology.
Herbicidal combinations provided by the invention, when in use should be after rice seedling to before jointing, and rice terrace is annual miscellaneous It is used before careless 5 leaves.
The method have the advantages that：
1, composition shows apparent synergistic effect, and the effect compared to single use is obviously improved.
2, composition expands herbicide controlling spectrum, can prevent grassy weed, broad leaved weed effect simultaneously.
3, the shortcomings that composition can overcome long-term single use weeds to easy to produce drug resistance.Extend the use of compound Service life has great significance to the integrated control of herbicide resistance.
4, composition production is simple for process, reduces material use, reduces the dosage of compound, reduce and be produced into This.
Specific implementation mode
It is clear in order to make the objectives, technical solutions, and advantages of the present invention be more clear, present invention following specific examples It illustrates, but the present invention is by no means limited to these examples.It is as described below to be only the preferred embodiment of the present invention, it is only used for describing The present invention should not be understood as the limitation of the scope of the present invention.It should be pointed out that institute all within the spirits and principles of the present invention The all any modification, equivalent and improvement etc. done, should all be included in the protection scope of the present invention.
In the examples below, unless otherwise stated, all percentages are weight percentage.
The auxiliary agent used in the present invention can be at least one of emulsifier, dispersant, wetting agent, filler.
The emulsifier being used in the present invention can be existing various emulsifiers, such as selected from Sorbitan alcohol ester Fat acid esters, polyoxyethylene fatty acid ester, polyoxyethylene fatty acid diester, alkyl phenol polyoxyethylene ether, castor oil polyoxyethylene ether, At least one of PULLRONIC F68 block polymer ether, polyoxyethylene diphenyl ether, ester type siloxanes.
The dispersant being used in the present invention can be selected from lignosulfonates, Sodium Polyacrylate, naphthalene sulfonate, Alkylnaphthalene sulfonate, alkamide taurine salt, polycarboxylate, the sodium salt of alkyl naphthalene sulfonic acid condensation polymer and alkyl naphthalene sulfonic acid formaldehyde At least one of polymer.The dispersant is preferably alkylnaphthalene sulfonate, polycarboxylate or alkyl naphthalene sulfonic acid oxymethylene polymerization Object.
The wetting agent being used in the present invention can be selected from lauryl sodium sulfate, neopelex, Fatty alcohol polyglycol ether sulfate, fatty alcohol polyoxyethylene ether, alkyl naphthalene sulfonic acid formaldehyde condensation products, alkylnaphthalene sulfonate, nonyl At least one of base phenol polyethenoxy ether or sorbitan fatty acid ester polyoxyethylene ether.The wetting agent is preferably ten Dialkyl benzene sulfonic acids sodium, fatty alcohol polyoxyethylene ether, alkyl naphthalene sulfonic acid formaldehyde condensation products or alkylnaphthalene sulfonate.
Below by embodiment, the invention will be further described.
In the following Examples and Comparative Examples, trifluoro ketone grass ether and cyhalofop-butyl Herbicidal combination are detected by liquid chromatograph Trifluoro ketone grass ether in object and cyhalofop-butyl content；Trifluoro ketone grass ether and cyhalofop-butyl composition are detected by CIPAC methods Stability.
Embodiment 1
1, test material：Barnyard grass (Echinochloa crusgalli), moleplant seed (Leptochloa chinensis), Monochoria vaginalis (Monochora vaginalis), water amaranth (Ammannia baccifera), false loosestrife (Ludwigia prostrata)。
2, medicament and preparation are tested：
The trifluoro ketone grass ether and cyhalofop-butyl active compound that certain mass is weighed with assay balance, with solvent (acetone, DMF or File mark etc. in DMSO) the small preparation of missible oil for being configured to 1.0-5.0% is dissolved, then with the steaming containing 0.1-0.25%TW-80 Distilled water is diluted to a certain concentration gradient.
Representative susceptible weeds seed is selected according to single dose herbicidal spectrum, culture to 3 leaves is spare, and selection is numbered Weeds cauline leaf process after, be placed on incubated at room temperature 20 days in illumination box, calculate control effect (fresh weight).
Investigation method：Test process 20 is born, and visual assessment medicament is to plant strain growth inhibitions, deformity, yellow, rotten, bad It waits indefinitely influence degree, and claims aerial part fresh weight, calculate fresh weight resistance rate (%)
Fresh weight resistance rate P (%)=[(control fresh weight-processing fresh weight)/control fresh weight] * 100
Synergy evaluation method:Amount of herbicide mode of application (NY/T1155.7-2006) is evaluated with Gowing methods, Formula is as follows：
In formula：
X is trifluoro ketone grass ether dosage when being P to Weed-control effect rate；
Y is cyhalofop-butyl dosage when being Q to Weed-control effect rate；
E0When for trifluoro ketone grass ether dosage being P to when Weed-control effect rate+cyhalofop-butyl dosage is Q to Weed-control effect rate；E is The practical preventive effect of Mixed Pharmacy
Evaluation criterion：E-E0Value>10% is summation action；
E-E0Value<- 10% is antagonism；
E-E0Value >=10% is synergistic effect.
Test result shows and (is shown in Table 1, table 2, table 3, table 4), and trifluoro ketone grass ether is with cyhalofop-butyl mixture to barnyard grass, a thousand pieces of gold Son, Monochoria vaginalis, water amaranth E-E0Value >=10% illustrates that trifluoro ketone grass ether is combined as synergistic effect with cyhalofop-butyl.
1 trifluoro ketone grass ether of table measures the synergy of barnyard grass with cyhalofop-butyl Herbicidal combinations
2 trifluoro ketone grass ether of table measures the synergy of moleplant seed with cyhalofop-butyl Herbicidal combinations
3 trifluoro ketone grass ether of table measures the synergy of Monochoria vaginalis with cyhalofop-butyl Herbicidal combinations
4 trifluoro ketone grass ether of table measures the synergy of water amaranth with cyhalofop-butyl Herbicidal combinations
Embodiment 2
25% trifluoro ketone grass ether-cyhalofop-butyl suspending agent：Trifluoro ketone grass ether 5%, cyhalofop-butyl 20%, polyoxyethylene nonyl phenyl second Alkene ether 4%, nonylphenol polyoxyethylene ether 4%, lauryl sodium sulfate 3%, bentonite 3%, xanthans 0.3%, propylene glycol 6%, organic silicon defoamer 0.3%, deionized water adds to 100%.
Above-mentioned formula is subjected to precomminution in proportion, adds in sand mill and is ground, allocated after high shear mixing 20% trifluoro ketone grass ether-cyhalofop-butyl suspending agent is made.
The 20% trifluoro ketone grass ether-dispersible oil-suspending agent of cyhalofop-butyl：Trifluoro ketone grass ether 5%, cyhalofop-butyl 15%, 12 Alkyl benzene calcium sulfonate 4%, castor oil polyoxyethylene ether 4%, sodium lignin sulfonate 3%, soybean oil 8%, organobentonite 3%, Methyl oleate adds to 100%.Above-mentioned material is subjected to precomminution in proportion, adds in sand mill and is ground, cut through height Obtained 20% trifluoro ketone grass ether-cyhalofop-butyl suspending agent is allocated after cutting mixing.
20% trifluoro ketone grass ether-cyhalofop-butyl wettable powder：Trifluoro ketone grass ether 10%, cyhalofop-butyl 10%, lignin Sodium sulfonate 8%, pull open powder NNO4%, white carbon 2%, nonylphenol polyoxyethylene ether 3%, bentonite 5%, precipitated calcium carbonate supplement To 100%.Above-mentioned material is carried out in proportion to enter mixer after coarse crushing to be uniformly mixed, is prepared into after air-flow crushing 20% trifluoro ketone grass ether-cyhalofop-butyl wettable powder.
Embodiment 3
Test period：July 22 in 2017 is Japanese, and rice is thrown after cultivation 15 days, and the rice striking root phase, most grassy weed is long To 4 leaves, broad leaved weed grows to 4 leaves, and nutgrass flatsedge grows to 5-8CM
Test site：Jintan City of Jiangsu Province gold cities and towns villages Lian Cheng
Reagent agent and processing：
- 15% dispersible oil-suspending agent of cyhalofop-butyl of 5% trifluoro ketone grass ether, dosage 20 (g a.i./ha) (1#)
- 15% dispersible oil-suspending agent of cyhalofop-butyl of 5% trifluoro ketone grass ether, dosage 30 (g a.i./ha) (2#)
- 15% dispersible oil-suspending agent of cyhalofop-butyl of 5% trifluoro ketone grass ether, dosage 40 (g a.i./ha) (3#) comparison medicine Agent and dispenser dosage：
The 5% dispersible oil-suspending agent of trifluoro ketone grass ether, dosage 30 (g a.i./ha) (4#)
The dispersible oil-suspending agent of 15% cyhalofop-butyl, dosage 40 (g a.i./ha) (5#)
Test result is shown in Table 5, and -15% dispersible oil-suspending agent of cyhalofop-butyl of 5% trifluoro ketone grass ether prevents and kill off rice terrace 1 year Raw weeds effective 92.59%, hence it is evident that be better than trifluoro ketone grass ether, the single dose that cyhalofop-butyl respectively compares.Each medicament is equal during experiment Generation poisoning is had no, to rice safety.
20 days investigation results after table 5, medicine

Claims (7)

1. a kind of Herbicidal combinations containing trifluoro ketone grass ether and cyhalofop-butyl, which is characterized in that the Herbicidal combinations include Trifluoro ketone grass ether and cyhalofop-butyl, the wherein weight part ratio of trifluoro ketone grass ether and cyhalofop-butyl in Herbicidal combinations are 1: 0.1-1:20。
2. Herbicidal combinations as described in claim 1, which is characterized in that the Herbicidal combinations include trifluoro ketone grass ether, cyanogen Fluorine grass ester and auxiliary agent.
3. Herbicidal combinations as claimed in claim 2, which is characterized in that the auxiliary agent includes emulsifier, wetting agent, dispersion Agent, filler.
4. Herbicidal combinations as described in claim 1, which is characterized in that the dosage form that the Herbicidal combinations use includes suspending Agent, dispersibility oil-suspending agent or wettable powder.
5. Herbicidal combinations as claimed in claim 3, which is characterized in that the emulsifier be sorbitan fatty acid ester, Polyoxyethylene fatty acid ester, polyoxyethylene fatty acid diester, alkyl phenol polyoxyethylene ether, castor oil polyoxyethylene ether, polyoxy second At least one of alkene-polyoxypropylene block polymer ether, polyoxyethylene diphenyl ether, ester type siloxanes.
6. Herbicidal combinations as claimed in claim 3, which is characterized in that the dispersant is lignosulfonates, polypropylene Sour sodium, naphthalene sulfonate, alkylnaphthalene sulfonate, alkamide taurine salt, polycarboxylate, alkyl naphthalene sulfonic acid condensation polymer sodium salt or At least one of alkyl naphthalene sulfonic acid yuban.
7. Herbicidal combinations as claimed in claim 3, which is characterized in that the wetting agent is lauryl sodium sulfate, 12 Sodium alkyl benzene sulfonate, fatty alcohol polyglycol ether sulfate, fatty alcohol polyoxyethylene ether, alkyl naphthalene sulfonic acid formaldehyde condensation products, alkane At least one of base naphthalene sulfonate, nonylphenol polyoxyethylene ether or sorbitan fatty acid ester polyoxyethylene ether.
CN201810354231.0A 2018-04-19 2018-04-19 A kind of Herbicidal combinations containing trifluoro ketone grass ether and cyhalofop-butyl Pending CN108477172A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810354231.0A CN108477172A (en) 2018-04-19 2018-04-19 A kind of Herbicidal combinations containing trifluoro ketone grass ether and cyhalofop-butyl

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810354231.0A CN108477172A (en) 2018-04-19 2018-04-19 A kind of Herbicidal combinations containing trifluoro ketone grass ether and cyhalofop-butyl

Publications (1)

Publication Number Publication Date
CN108477172A true CN108477172A (en) 2018-09-04

Family

ID=63312619

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810354231.0A Pending CN108477172A (en) 2018-04-19 2018-04-19 A kind of Herbicidal combinations containing trifluoro ketone grass ether and cyhalofop-butyl

Country Status (1)

Country Link
CN (1) CN108477172A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101999361A (en) * 2010-12-27 2011-04-06 陕西韦尔奇作物保护有限公司 Herbicide composition containing cyhalofop-butyl and pyrimidyloxy (sulfur) benzoate
CN102273459A (en) * 2011-06-21 2011-12-14 王从爱 Weeding composition containing pyribenzoxim and cyhalofopbutyl
CN102461511A (en) * 2010-11-19 2012-05-23 南京华洲药业有限公司 Mixed herbicide composition containing bispyribac-sodium and cyhalofop-butyl
CN104302629A (en) * 2013-12-03 2015-01-21 南京慧博生物科技有限公司 Novel herbicidal active pyridine salicylic acid compound, prepare method thereof, and purpose of being herbicidal

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102461511A (en) * 2010-11-19 2012-05-23 南京华洲药业有限公司 Mixed herbicide composition containing bispyribac-sodium and cyhalofop-butyl
CN101999361A (en) * 2010-12-27 2011-04-06 陕西韦尔奇作物保护有限公司 Herbicide composition containing cyhalofop-butyl and pyrimidyloxy (sulfur) benzoate
CN102273459A (en) * 2011-06-21 2011-12-14 王从爱 Weeding composition containing pyribenzoxim and cyhalofopbutyl
CN104302629A (en) * 2013-12-03 2015-01-21 南京慧博生物科技有限公司 Novel herbicidal active pyridine salicylic acid compound, prepare method thereof, and purpose of being herbicidal

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
上海市农业技术推广服务中心: "《农药安全使用手册》", 30 September 2009 *

Similar Documents

Publication Publication Date Title
CN102067836B (en) Herbicide composition containing cyhalofop-butyl and amides
CN101743988B (en) Herbicide composition for corn fields
CN103053610A (en) Glufosinate-aryloxyphenoxypropionic acid herbicide weeding composition
CN103931632A (en) Herbicidal composition containing pinoxaden and pyroxsulam
CN101999361A (en) Herbicide composition containing cyhalofop-butyl and pyrimidyloxy (sulfur) benzoate
CN102308814A (en) Weeding composition containing penoxsulam and metamifop for paddy field
CN104115861B (en) A kind of insecticide acaricide composition containing sulfur-phosphor and cyflumetofen
CN105494399B (en) The sulphur of ketone containing thiophene is grand and the Herbicidal combinations of benzene flumetsulam
CN102669114B (en) A kind of prothioconazoles that contains is with the composition pesticide of hymexazo
CN102405916A (en) Herbicidal composition containing fenoxaprop-P-ethyl and bentazone
CN108477172A (en) A kind of Herbicidal combinations containing trifluoro ketone grass ether and cyhalofop-butyl
CN104286010B (en) Composition pesticide containing sulfur-phosphor and Bifenazate
CN106973957A (en) A kind of dispersible oil-suspending agent containing the careless amine of fluorine ketone sulphur and cyhalofop-butyl
CN107361066A (en) A kind of Herbicidal combinations of Han You metamifops
CN102302027B (en) Herbicidal composition containing florasulam
CN105145608A (en) Pesticide composition containing pretilachlor and oxaziclomefone and sulfonylureas herbicide
CN109221213A (en) A kind of Herbicidal combinations containing chlorine fluorine pyridine ester and ethoxysulfuron
CN104222112A (en) Weeding composition for paddy field
CN110100835A (en) A kind of mixed herbicidal composite containing trifluoro ketone grass ether and pyrazosulfuron
CN108477196A (en) A kind of phonetic benzyl ternary herbicide of ring and its application
CN107372559A (en) A kind of rice weeding composition
CN106106508A (en) Herbicidal combinations and application thereof
CN108739834B (en) Weeding composition containing penoxsulam
CN102150665A (en) Herbicidal composition containing cyhalofop-butyl and triazines
CN106106458B (en) The Herbicidal combinations of dichloroquinoline humulone and mefenacet

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20180904

WD01 Invention patent application deemed withdrawn after publication