CN108464312A - A kind of biochemical compound pesticide preparation and preparation method thereof of prevention beet armyworm - Google Patents

A kind of biochemical compound pesticide preparation and preparation method thereof of prevention beet armyworm Download PDF

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Publication number
CN108464312A
CN108464312A CN201810237989.6A CN201810237989A CN108464312A CN 108464312 A CN108464312 A CN 108464312A CN 201810237989 A CN201810237989 A CN 201810237989A CN 108464312 A CN108464312 A CN 108464312A
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China
Prior art keywords
pesticide
parts
preparation
prevention
beet armyworm
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CN201810237989.6A
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Chinese (zh)
Inventor
蒲侠
陈铧耀
周新华
舒绪刚
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Zhongkai University of Agriculture and Engineering
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Zhongkai University of Agriculture and Engineering
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Priority to CN201810237989.6A priority Critical patent/CN108464312A/en
Publication of CN108464312A publication Critical patent/CN108464312A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N63/00Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates
    • A01N63/10Animals; Substances produced thereby or obtained therefrom
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/28Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/34Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof

Abstract

The present invention relates to technical field of pesticide, disclose a kind of biochemical compound pesticide preparation and preparation method thereof of prevention beet armyworm.The pesticidal preparations include the following components of parts by weight:5 10 parts of biological pesticide, 15 parts of chemical pesticide, 20 30 parts of solvent, 5 15 parts of dispersant, 14 parts of dispersion aids, 13 parts of antisettling agent, 0.1 0.5 parts of antifreezing agent, 40 60 parts of water, 0.1 0.5 parts of preservative.The present invention is by insect virus pesticide and chemical pesticide mixture, and it is fast both to have given full play to chemical pesticide desinsection speed, the wide advantage of insecticidal spectrum, but remain viral insecticide low toxicity, lasting period length feature, significantly reduce the usage amount of chemical pesticide.Environment-friendly type preparation is made in biological pesticide and chemical pesticide mixture by the present invention --- and suspending agent makes insect virus pesticide become real environment friendly agricultural, not only efficiently can quickly kill off the insect pests, but also can reduce production cost.

Description

A kind of biochemical compound pesticide preparation and preparation method thereof of prevention beet armyworm
Technical field
The present invention relates to technical field of pesticide, the biochemical compound pesticide preparation of specifically a kind of prevention beet armyworm and Preparation method.
Background technology
Effective controlling plant diseases ensure that the important measures of stable high yield are proper use of insecticides.At present to phytopathy The prevention of insect pest is still based on chemical prevention, but long-term a large amount of unreasonable uses of chemical insecticide bring a series of ask Topic, such as pest all produce all kinds of chemical pesticides different degrees of drug resistance, and food excessive pesticide residues endanger pest day Enemy etc..Compared with chemical pesticide, biological pesticide has the advantages that very much:(1) nuisanceless, noresidue, safety and environmental protection;(2) environment Compatibility is good;(3) high specificity does not kill natural enemy and beneficial organism, to safety of human and livestock;(4) it is not likely to produce drug resistance.Therefore, Safety, less toxic, environment-friendly type biological pesticide are widelyd popularize, is ensured food safety, it is ensured that agriculture sustainable development is Guangdong Province An or even important development direction of whole nation development modern agriculture.Insect virus pesticide it is a kind of with insect be obligate host disease Malicious monoid is listed in the newest biological control skill of 21 century focus development and popularization and application as important a member of biological pesticide Art has the advantages that biological pesticide is all.However single viral insecticide often exists that desinsection speed is slow, insecticidal spectrum is narrow, effect The shortcomings of fruit is not prominent has fettered the use in the production of its large area significantly.
Due to the presence for the defects of insect virus pesticide insecticidal spectrum is narrow, insecticidal effect is slow, in these years entomiasis poisoning Worm agent occupation rate of market is not high always.To solve the problems, such as this, occur in the research of insect virus pesticide both at home and abroad main Two main flow directions insect viruses are recombinated first, by genetic engineering, improve insect viruses insecticidal activity or Expand its insecticidal spectrum, Wuhan University just once reported, recombinates, obtains to containing autographa california nuclear polyhedrosis virus using Bt The recombinant virus insecticidal effect obtained is significantly improved obviously to be expanded with insecticidal spectrum, but this method cost is big, and operation difficulty is high, arrives mesh Before until, China only has a kind of engineering strain-bollworm virus gene engineering strain three by industrialization production;Second is that passing through Dosage form compounds, and improves the insecticidal effect and insecticidal spectrum of viral insecticide, this is the hot spot of studies in China nearly ten years, with regard to 22 kinds of elder brothers For parasitosis poison from the point of view of 59 registration products of the Ministry of Agriculture, it is the complex agent type of insect viruses to have within nearly 3 years 13 registration products, is increased Long trend is apparent.Currently, the compounding type of pesticide include mainly the compounding of botanical pesticide and botanical pesticide, chemical pesticide with The compounding and botanical pesticide of chemical pesticide and the compounding of chemical pesticide.The wherein Recompounded pesticide of plant pesticide and chemical pesticide Refer to that plant pesticide and one or more chemical pesticides are mutually subjected to mixture, finds and pass through effective ingredients in plant and chemical pesticide Interaction between ingredient makes to generate synergistic effect each other.Currently, this Recompounded pesticide is also the research heat of novel pesticide exploitation Point.There have been some successful examples in the country about the research of plant pesticide and chemical pesticide compounding agent:Guangxi Zhuang Autonomous Region 4% nicotine-chlorine cyanogen the aqueous emulsion and autonomous region Gen Ju plant protection institute of materia medica development and production of the registered registration of work research institute 25% water amine-trifoliate jewelvine missible oil;The new sulphur Emulphors oil of 16.1% aloperine-of Qingdao of Shandong province benefit agrochemical plant produced and 13.6% aloperine-goes out how salty missible oil and plant pesticide factory of Inner Mongolia Linhe city and portion of province Weifang Lv Feng plant pesticides factory connection Close the 3.2% chlorine cyanogen chrysanthemum vinegar-kuh-seng missible oil and 1.8 cypermethrins-kuh-seng missible oil of development and production.The researchs such as Li Xuesheng find two kinds It is good to the field control effect of diamondback moth larvae that plant compounds aqueous emulsion;After Yao Yingjuan etc. extremely compounds bromine cyanogen chrysanthemum with grass-leaved sweetflag Synergistic effect is notable;Ge Hong etc. has found the synergistic effect that the compounding agent of matrine and avermectin does well to cabbage caterpillar;Poplar Quick jasmine etc. is research test worm with diamondback moth, hammers alkaloid into shape as active ingredient to lie prostrate hair stick, is mixed respectively with several common chemical pesticides Match, synergistic effect is apparent.
No matter in conclusion botanical pesticide or chemical pesticide, the final direction that they develop all is safe and efficient, side Just economical.It is new that biochemical Recompounded pesticide is biological pesticide and chemical pesticide or other biogenic pesticides are combined by a certain percentage Dosage form has both the double dominant that biological pesticide is less toxic, low-residual and chemical pesticide are high-effect, highly selective, while again than changing Chemistry security is learned, it is more quick-acting than biological pesticide, or even therefore effect more taller than single dose chemical pesticide is increasingly becoming pesticide market Main product, and be expected to continue leading China's pesticide market in following 10 years, have a extensive future.
Insect virus pesticide and chemical pesticide mixture are prepared a kind of low for this present situation of existing Pesticide use Malicious, efficient, environmentally protective pesticidal preparations.The pesticidal preparations had not only played the characteristics of efficient chemical insecticide, quick-acting, wide spectrum, but also Retain viral insecticide safely, be not likely to produce the characteristics of drug resistance, provide one for the pest resistance to insecticide problem of getting worse and cut Real feasible approach.
Invention content
The object of the present invention is to provide a kind of biochemical compound pesticide preparations and preparation method thereof of prevention beet armyworm.The agriculture Medicine preparation can play the characteristics of efficient chemical insecticide, quick-acting, wide spectrum and viral insecticide safely, be not likely to produce it is anti- , there is beet armyworm in the characteristics of pharmacological property excellent preventive and therapeutic effect.
The present invention to achieve the above object, takes following technical scheme to be achieved:
A kind of biochemical compound pesticide preparation of prevention beet armyworm, includes the following components of parts by weight:Biological pesticide 5- 10 parts, 1-5 parts of chemical pesticide, 20-30 parts of solvent, 5-15 parts of dispersant, 1-4 parts of dispersion aids, 1-3 parts of antisettling agent is antifreeze 0.1-0.5 parts of agent, 40-60 parts of water, 0.1-0.5 parts of preservative.
Preferably, the biological pesticide is insect virus pesticide.
Preferably, the chemical pesticide is emamectin benzoate, meter Man, tebufenozide, capillary, cypermethrin class, flubenzuron, children of going out One or more kinds of combinations in urea.
Preferably, the solvent is one in acetone, methanol, ethyl alcohol, ethyl acetate, trichloroethanes, cyclohexanone, isobutanol Kind or more than one combination.
Preferably, the dispersant is lauryl sodium sulfate, P-TOLUENE SULFO ACID 99's sodium, fatty alcohol polyoxyethylene ether, polycarboxylic acids One or more kinds of combinations in salt.
Preferably, the dispersion aids is organosilicon.
Preferably, the antisettling agent is one or more kinds of combinations in aluminium-magnesium silicate, xanthans.
Preferably, the antifreezing agent is one or more kinds of combinations in ethylene glycol, propylene glycol, glycerine, urea.
Preferably, the preservative is one or more kinds of combinations in potassium sorbate, sodium benzoate, formaldehyde.
Another object of the present invention is to disclose a kind of preparation method of above-mentioned biochemical compound pesticide preparation, including following step Suddenly:
(1) at normal temperatures, organic phase solution is made in solvent in biological pesticide, chemical pesticide stirring and dissolving;
(2) dispersant, dispersion aids, preservative, antifreezing agent are dissolved in the water, aqueous phase solution is made;
(3) manufactured organic phase solution is added drop-wise in aqueous phase solution, stirs, is then evaporated under reduced pressure, remove solvent phase; To mixed liquor A;
(4) antisettling agent is added in mixed liquor A, the aqueous suspension pesticide system to form stable homogeneous is sheared by cutter Agent.
Preferably, in step (4) cutter shear velocity be 100r/min~1200r/min, shear time be 20min~ 1h。
Compared with prior art, beneficial effects of the present invention are as follows:
For the present invention by insect virus pesticide and chemical pesticide mixture, it is fast both to have given full play to chemical pesticide desinsection speed, The wide advantage of insecticidal spectrum, and remain viral insecticide low toxicity, the feature that the lasting period is grown, significantly reduce the use of chemical pesticide Amount.
Environment-friendly type preparation is made in insect virus pesticide and chemical pesticide mixture by the present invention --- and suspending agent makes entomiasis Malicious insecticide becomes real environment friendly agricultural, not only efficiently can quickly kill off the insect pests, but also can reduce production cost.This works as satisfaction Demand of the preceding biology pesticide market to environment-friendly and low-toxicity biological pesticide, accelerates the development of insect virus pesticide, has important Meaning.
Specific implementation mode
With reference to embodiment, the invention will be further described, but it should be recognized that embodiment is not to this hair Bright claimed range is construed as limiting.
Embodiment 1-5
A kind of biochemical compound pesticide preparation of prevention beet armyworm, formula are as shown in table 1:
The biochemical compound pesticide preparation formula table parts by weight of table 1
Wherein, biological pesticide is insect virus pesticide.Chemical pesticide is emamectin benzoate, meter Man, tebufenozide, capillary, chlorine One or more kinds of combinations in Cyano chrysanthemate class, flubenzuron, d ichlorbenzuron.Solvent be acetone, methanol, ethyl alcohol, ethyl acetate, One or more kinds of combinations in trichloroethanes, cyclohexanone, isobutanol.Dispersant is lauryl sodium sulfate, to benzene sulphur One or more kinds of combinations in sour sodium, fatty alcohol polyoxyethylene ether, polycarboxylate.Dispersion aids is organosilicon.It is anti-heavy Depressant prescription is one or more kinds of combinations in aluminium-magnesium silicate, xanthans.Antifreezing agent is ethylene glycol, propylene glycol, glycerine, urine One or more kinds of combinations in element.Preservative is one or more kinds of in potassium sorbate, sodium benzoate, formaldehyde Combination.
Embodiment 6
A kind of biochemical compound pesticide preparation of prevention beet armyworm, by weight, including 7 parts of biological pesticide, chemical agriculture 3 parts of medicine, 30 parts of solvent, 7 parts of dispersant, 1 part of dispersion aids, 1 part of antisettling agent, 0.3 part of antifreezing agent, 50 parts of water, preservative 0.3 Part.
Biological pesticide is insect virus pesticide, and chemical pesticide is tebufenozide, and solvent is acetone, and dispersant is dodecyl Sodium sulphate, dispersion aids are organosilicon, and preservative is sodium benzoate, and antisettling agent is aluminium-magnesium silicate, and antifreezing agent is ethylene glycol.
Embodiment 7
The preparation method of biochemical compound pesticide preparation, includes the following steps disclosed in embodiment 1-6:
(1) at normal temperatures, organic phase solution is made in solvent in biological pesticide, chemical pesticide stirring and dissolving;
(2) dispersant, dispersion aids, preservative, antifreezing agent are dissolved in the water, aqueous phase solution is made;
(3) in a kettle high-speed stirred (mixing speed 700r/min) while, manufactured organic phase solution is delayed Slowly it is added dropwise into aqueous phase solution, is then evaporated under reduced pressure, remove solvent phase, obtain mixed liquor A;
(4) antisettling agent is added in mixed liquor A, opens cutter and carries out high speed shear (shear velocity 100r/min ~1200r/min), 20min-1h is sheared, the aqueous suspension pesticidal preparations of stable homogeneous are formed.
In use, aqueous suspension pesticidal preparations obtained are diluted with water 500 times, spray.
Formula in 1-6 of the embodiment of the present invention is as follows to the control effect of beet armyworm:
It is determined that the compounded combination of insect viruses+emamectin benzoate (chemical pesticide) has synergistic effect using total malicious factorization method, The total malicious factor of insect viruses+emamectin benzoate combination is 61.34 (the poison factor, which is more than 20, altogether has synergistic effect), is shown as relatively strong Synergistic effect.
With reference to the method for Mansour, insect virus pesticide and tebufenozide are caused into 25% (LC of test worm25) dosage with 1: Beet exigua larvae at the beginning of 1 mixing 3 ages of post-processing, processing method are identical as the toxicity test of single dose.Obtain insect viruses+tebufenozide The total malicious factor of combination is 44.80, shows as stronger synergistic effect.
The prepared Recompounded pesticide aqueous suspension agent of embodiment 1-6 formulas, for suspensibility up to 88%, thermal stability is good, to examination Sample has carried out field control effectiveness test, the results showed that:When Recompounded pesticide aqueous suspension agent dosage is 10-30g/667m2When, on vegetables Beet exigua larvae all have preferable preventive and therapeutic effect, highest preventive effect appears in medicine latter week, average preventive effect 90% with On.Two weeks after medicine, 65% or more is remained to the average preventive effect of beet exigua larvae, shows good lasting effect.
It is provided for the embodiments of the invention technical solution above to be described in detail, specific case used herein The principle and embodiment of the embodiment of the present invention are expounded, the explanation of above example is only applicable to help to understand this The principle of inventive embodiments;Meanwhile for those of ordinary skill in the art, embodiment according to the present invention, in specific embodiment party There will be changes in formula and application range, in conclusion the content of the present specification should not be construed as limiting the invention.

Claims (10)

1. a kind of biochemical compound pesticide preparation of prevention beet armyworm, which is characterized in that the following components including parts by weight:It is raw 5-10 parts of object pesticide, 1-5 parts of chemical pesticide, 20-30 parts of solvent, 5-15 parts of dispersant, 1-4 parts of dispersion aids, antisettling agent 1-3 Part, 0.1-0.5 parts of antifreezing agent, 40-60 parts of water, 0.1-0.5 parts of preservative.
2. a kind of biochemical compound pesticide preparation of prevention beet armyworm according to claim 1, which is characterized in that the life Object pesticide is insect virus pesticide.
3. a kind of biochemical compound pesticide preparation of prevention beet armyworm according to claim 1, which is characterized in that describedization Medicine of learning to farm is the one or more in emamectin benzoate, meter Man, tebufenozide, capillary, cypermethrin class, flubenzuron, d ichlorbenzuron Combination.
4. a kind of biochemical compound pesticide preparation of prevention beet armyworm according to claim 1, which is characterized in that described molten Agent is one or more kinds of combinations in acetone, methanol, ethyl alcohol, ethyl acetate, trichloroethanes, cyclohexanone, isobutanol.
5. a kind of biochemical compound pesticide preparation of prevention beet armyworm according to claim 1, which is characterized in that described point Powder is one or more kinds of in lauryl sodium sulfate, P-TOLUENE SULFO ACID 99's sodium, fatty alcohol polyoxyethylene ether, polycarboxylate Combination.
6. a kind of biochemical compound pesticide preparation of prevention beet armyworm according to claim 1, which is characterized in that described to help Dispersant is organosilicon.
7. a kind of biochemical compound pesticide preparation of prevention beet armyworm according to claim 1, which is characterized in that described anti- Sedimentation agent is one or more kinds of combinations in aluminium-magnesium silicate, xanthans.
8. a kind of biochemical compound pesticide preparation of prevention beet armyworm according to claim 1, which is characterized in that described anti- Jelly agent is one or more kinds of combinations in ethylene glycol, propylene glycol, glycerine, urea.
9. a kind of biochemical compound pesticide preparation of prevention beet armyworm according to claim 1, which is characterized in that described anti- Rotten agent is one or more kinds of combinations in potassium sorbate, sodium benzoate, formaldehyde.
10. a kind of preparation method of compound pesticide preparation biochemical as described in any one of claim 1~9, which is characterized in that including Following steps:
(1) at normal temperatures, organic phase solution is made in solvent in biological pesticide, chemical pesticide stirring and dissolving;
(2) dispersant, dispersion aids, preservative, antifreezing agent are dissolved in the water, aqueous phase solution is made;
(3) manufactured organic phase solution is added drop-wise in aqueous phase solution, stirs, is then evaporated under reduced pressure, remove solvent phase;It is mixed Close liquid A;
(4) antisettling agent is added in mixed liquor A, the aqueous suspension pesticidal preparations to form stable homogeneous is sheared by cutter.
CN201810237989.6A 2018-03-22 2018-03-22 A kind of biochemical compound pesticide preparation and preparation method thereof of prevention beet armyworm Pending CN108464312A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111117971A (en) * 2020-01-19 2020-05-08 苏州米迪生物技术有限公司 Domestication method and application of nuclear polyhedrosis virus suitable for yellow poplar silk wild borer
CN111735939A (en) * 2020-06-08 2020-10-02 仲恺农业工程学院 Kit, special feed bottle and method for rapidly identifying drug resistance of spodoptera frugiperda
CN115299446A (en) * 2022-06-29 2022-11-08 陕西美邦药业集团股份有限公司 Chlorfenapyr-containing nano suspending agent composition

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Publication number Priority date Publication date Assignee Title
CN1650718A (en) * 2005-02-18 2005-08-10 李建中 Insecticide composition containing methyl amino Avermectin and nucleo type polyhedron viruse
CN101204161A (en) * 2007-12-11 2008-06-25 海南利蒙特生物农药有限公司 Viral suspension formulation pesticide with emamectin-benzoate
CN101496526A (en) * 2009-03-24 2009-08-05 广州市生物防治站 Pesticide suspending agent containing Spodoptera exigua nucleopolyhedrovirus and Tebufenozide

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1650718A (en) * 2005-02-18 2005-08-10 李建中 Insecticide composition containing methyl amino Avermectin and nucleo type polyhedron viruse
CN101204161A (en) * 2007-12-11 2008-06-25 海南利蒙特生物农药有限公司 Viral suspension formulation pesticide with emamectin-benzoate
CN101496526A (en) * 2009-03-24 2009-08-05 广州市生物防治站 Pesticide suspending agent containing Spodoptera exigua nucleopolyhedrovirus and Tebufenozide

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111117971A (en) * 2020-01-19 2020-05-08 苏州米迪生物技术有限公司 Domestication method and application of nuclear polyhedrosis virus suitable for yellow poplar silk wild borer
CN111735939A (en) * 2020-06-08 2020-10-02 仲恺农业工程学院 Kit, special feed bottle and method for rapidly identifying drug resistance of spodoptera frugiperda
CN115299446A (en) * 2022-06-29 2022-11-08 陕西美邦药业集团股份有限公司 Chlorfenapyr-containing nano suspending agent composition
CN115299446B (en) * 2022-06-29 2024-02-27 陕西美邦药业集团股份有限公司 Nanometer suspending agent composition containing chlorfenapyr

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