CN108455889A - The coral aggregate reinforcing slurries of chlorion can be cured in a kind of phosphor aluminate cement base - Google Patents
The coral aggregate reinforcing slurries of chlorion can be cured in a kind of phosphor aluminate cement base Download PDFInfo
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- CN108455889A CN108455889A CN201810131457.4A CN201810131457A CN108455889A CN 108455889 A CN108455889 A CN 108455889A CN 201810131457 A CN201810131457 A CN 201810131457A CN 108455889 A CN108455889 A CN 108455889A
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- Prior art keywords
- slurries
- aluminate cement
- coral aggregate
- phosphor aluminate
- chlorion
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/10—Coating or impregnating
- C04B20/12—Multiple coating or impregnating
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Farming Of Fish And Shellfish (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The coral aggregate that chlorion can be cured the invention discloses a kind of phosphor aluminate cement base strengthens slurries, it includes infiltration slurries and cladding slurries, and the composition mass percent for permeating slurries is：Phosphor aluminate cement 70%~85%, penetrant crystalline material 1%~4%, clay matter mineral admixture 10%~25%, adjustable solidification agent 0.4%~2%, the ratio of mud are 0.6~0.75；Cladding slurries group be as mass percent：Phosphor aluminate cement 70%~85%, clay matter mineral admixture 10%~25%, adjustable solidification agent 0.4%~2%, the ratio of mud are 0.5~0.6；By infiltration slurries and cladding slurries processing after can be obtained can direct applied coral aggregate, solve puzzlement direct applied two hang-up of coral aggregate, can be applied to isolated island building construction, the military architecture in ocean area etc..
Description
Technical field
The coral aggregate that chlorion can be cured the present invention provides a kind of phosphor aluminate cement base strengthens slurries.
Background technology
For far from the engineering construction on the island of land, required raw material are required to go over from transcontinental shipments, transport in this way
Defeated cost is very high.If can gather materials on the spot, raw material can be solved the problems, such as.China possesses wide marine site, this
The islands and reefs being much made of coral reef are distributed in a little marine sites.Some researches show that the main component of coral reef is aragonite and high magnesium side
Xie Shi, total ingredients calcium carbonate content reach 96% or more.If bone is made by a series of manufacture crafts in these coral reefs
Material is used for concrete batching, has very important Practical significance to the engineering construction on China island.So far there are many grind
Personnel are studied carefully to the direct using a large amount of research work has been done of coral aggregate, if number of patent application is CN201610973322.3 mono-
The seawater coral aggregate concrete building block of the anti-accumulation of salt in the surface soil of kind, the invention consolidate salt agent to cure invading in coral using addition coral aggregate
Corrosion ion, the invention may be implemented coral as aggregate indirect application, but there is no aggregate is directly handled, make
Coral aggregate application range becomes smaller；Number of patent application is a kind of seawater coral aggregate concretes of CN20160274695.1, by outer
Add agent such as consolidate salt agent, antifoaming agent come eliminate coral aggregate carrying erosion carbon dioxide and in producing concrete due to slurry
The bubble that the gap of coral aggregate generates is squeezed, but the effect of this method is limited, it doesn't solve the problem fundamentally.And this
The coral aggregate that chlorion can be cured in a kind of phosphor aluminate cement base that invention provides strengthens slurries, can fundamentally solve to ask
Topic can solve two hang-ups of coral aggregate application, can be cured and strengthen coral aggregate, have extremely wide application prospect.
Invention content
For problems of the prior art, the present invention provides a kind of phosphor aluminate cement bases, and chlorion can be cured
Coral aggregate strengthens slurries.
The present invention uses following technical scheme：
The coral aggregate reinforcing slurries of chlorion can be cured in a kind of phosphor aluminate cement base, it includes that infiltration slurries and 22 cover
Slurries two parts；It is described infiltration slurries mass percentage composition be：Phosphor aluminate cement 70%~85%, penetrant crystalline material
1%~4%, clay matter mineral admixture 10%~25%, adjustable solidification agent 0.4%~2%, the ratio of mud are 0.6~0.75；The packet
The mass percentage composition for covering slurries is：Phosphor aluminate cement 70%~85%, is adjusted clay matter mineral admixture 10%~25%
Solidifying agent 0.4%~2%, the ratio of mud are 0.5~0.6.
The clay matter mineral admixture is at least one of gold ore tailing, white Tungsten tailing.
The specific surface area ＞ 298m of the gold ore tailing2/ kg, the percentage of sieve residue ＜ 5% of 200 mesh of white Tungsten tailing sieve.
The strength grade of the phosphor aluminate cement is not less than 42.5 grades, surface area ＞ 320m2/kg。
The specifically used method for strengthening slurries is as follows：
1) by prefabricated infiltration slurries injection kiln basin, coral aggregate to be processed is put into kiln basin and is impregnated
Then 5min pulls coral aggregate out from kiln basin；
2) aggregate pulled out is stood into 1h~2h, can carries out in next step, permeating the thickness of slurries cladding at this time after air-drying
For 0.3mm~0.5mm；
3) cladding slurries injection is sprayed in mortar machine, the coral aggregate that will be obtained by step 2) processing is put into vibrating screen
In, it divides as the thickness of a particle；
4) vibrating screen is opened, starts spray coating slurries, a batch is changed after 1min；By processed coral aggregate
Stand 30min~1h, at this time coat slurries cladding thickness be 0.5mm~1mm, as phosphor aluminate cement base can be cured chlorine from
The coral aggregate of son.
The penetrant crystalline material is the product of XYPEX series, and ingredient includes cement, quartz sand, water and activity chemistry object
Matter.The penetrant crystalline material that the present invention uses is bought in Canadian XYPEX series penetrant crystalline material, and ingredient includes water
Mud, quartz sand, water and active chemistry.
Infiltration slurries used in the present invention ratio of mud itself is larger, good fluidity, can effectively fill up coral aggregate
Gap, and the XYPEX series penetrant crystalline materials in slurries are permeated, it contains cement, quartz sand and active chemistry
And water, cement, quartz sand and infiltration slurries in clay matter mineral admixture can be used as reactant provide Ca2+And SiO3 2-
It can react with unhydrated or insufficient aquation cementitious material, generate C-S-H gels, can effectively fill up remaining
Micro-pore；Active chemistry in penetrant crystalline material includes compound additive (by water-reducing agent, hydrophober, swelling agent group
At) and anionic catalyst (contain active SiO3 2-Ion), compound additive is dissolved in after water polymerization under certain condition and increases,
Or chemically reacted with the ion in inside concrete hole solution, it generates crystalline solid not soluble in water and blocks crack and capillary
Hole, or react with substances such as calcium hydroxide, aluminium hydroxides in concrete, insoluble needle-shaped ettringite is formed, outside
Add agent that will largely be consumed at hydration reaction initial stage；Active anion catalyst can occur with the calcium ion in concrete
Chelation forms short-term soluble complexes, but easily captures calcium ion by silicate, aluminate, is formed more stable insoluble
Object, later active material can form new free radical again, chelated again with calcium ion, then repeat this process, not only can be with
Promote aquation, and the progress chemically reacted under low reaction concentration can be promoted, generates C-S-H gels, also can effectively fill up
The place that cement slurry is not filled.In conclusion this infiltration slurries can more effectively be filled up inside coral aggregate
Hole improves the mechanical property of coral aggregate.
The cladding slurries of the present invention can be fixed the chlorion in coral aggregate by two ways, and one is physics
Absorption：Micropore in cement slurry can fix chlorion by way of physical absorption；Another kind is chemical reaction method：Cladding
The main component of slurries is phosphor aluminate cement, containing a large amount of calcium aluminates, and is also contained in clay matter mineral admixture a large amount of
Alundum (Al2O3) can occur chemical reaction with chlorion and generate Friedel salt (3CaoAl2O3·CaCl2·10H2O) and
Kuzel salt (3CaoAl2O3·0.5CaSO4·0.5CaCl2·10H2O), a large amount of chlorion, while both can be cured
The generation of salt can also optimize slurry pore structure, improve compactness.And due to there is hydrated product generation, moreover it is possible to make cladding slurries with
Coral aggregate combines even closer, not easily to fall off, and it is phosphor aluminate cement, phosphorus aluminic acid to coat the main component in slurries
The intensity of salt cement is very high, and the intensity of coral aggregate can be improved after package coral aggregate.And permeate the main component of slurries
It is also phosphor aluminate cement, it equally can be in the internal curing chlorion of aggregate.
It is an advantage of the invention that：By coral aggregate after the cladding slurries of the present invention and infiltration slurries intensive treatment,
Mechanical strength is significantly improved, and best crush values test result shows≤18%, can directly be used as general aggregate,
There is boundless application prospect.Chlorion and internal exhausted big portion have been eliminated for the more original aggregate of coral aggregate
Divide gap, solves puzzlement direct applied two hang-up of coral aggregate, have a extensive future.
Specific implementation mode
With reference to specific embodiment, the present invention is described in further detail.
Embodiment 1
The coral aggregate reinforcing slurries of chlorion can be cured in a kind of phosphor aluminate cement base, it includes infiltration slurries and cladding
Slurries two parts；Infiltration slurries are made of phosphor aluminate cement, clay matter mineral admixture, penetrant crystalline material and adjustable solidification agent；
Cladding slurries are made of phosphor aluminate cement, clay matter mineral admixture, adjustable solidification agent；Its specific following institute of mass percentage composition
Show：
Wherein, infiltration slurries use 0.6 the ratio of mud, cladding slurries use 0.5 the ratio of mud, phosphor aluminate cement it is strong
It spends grade and is not less than 42.5 grades, surface area ＞ 320m2/kg。
The penetrant crystalline material is the product of XYPEX series, and ingredient includes cement, quartz sand, water and activity chemistry object
Matter.
The clay matter mineral admixture is gold ore tailing and white Tungsten tailing according to 1：The mixture of 1 mass ratio composition.
The adjustable solidification agent is sodium lignin sulfonate, boric acid, citric acid are used in mixed way with arbitrary ratio.
The specific intensifying method of coral aggregate is as follows：
1) by prefabricated infiltration slurries injection kiln basin, coral aggregate to be processed is put into kiln basin and is impregnated
Then 5min pulls coral aggregate out from kiln basin；
2) aggregate pulled out is stood into 1h~2h, can carries out in next step, permeating the thickness of slurries cladding at this time after air-drying
For 0.3mm~0.5mm；
3) cladding slurries injection is sprayed in mortar machine, the coral aggregate that will be obtained by step 2) processing is put into vibrating screen
In, it divides as the thickness of a particle；
4) vibrating screen is opened, starts spray coating slurries, a batch is changed after 1min；By processed coral aggregate
Stand 30min~1h, at this time coat slurries cladding thickness be 0.5mm~1mm, as phosphor aluminate cement base can be cured chlorine from
The coral aggregate of son.
The coral aggregate that finally above-mentioned intensifying method is prepared, screens out more than 19.0mm and less than 9.50mm
Remainder particulate is weighed 3 groups of 3000g samples and is tested for crush values, finally calculates to obtain crush values≤19% after tested by grain.And not
The processed coral aggregate crush values directly chosen are≤32%.
Embodiment 2
The coral aggregate reinforcing slurries of chlorion can be cured in a kind of phosphor aluminate cement base, it includes infiltration slurries and cladding
Slurries two parts；Infiltration slurries are made of phosphor aluminate cement, clay matter mineral admixture, penetrant crystalline material and adjustable solidification agent；
Cladding slurries are made of phosphor aluminate cement, clay matter mineral admixture, adjustable solidification agent；Its specific following institute of mass percentage composition
Show：
Wherein, infiltration slurries use 0.65 ratio of mud, cladding slurries to use 0.55 ratio of mud, phosphor aluminate cement
Strength grade is not less than 42.5 grades, surface area ＞ 320m2/kg。
The penetrant crystalline material is the product of XYPEX series, and ingredient includes cement, quartz sand, water and activity chemistry object
Matter.
The clay matter mineral admixture is gold ore tailing.
The adjustable solidification agent is sodium lignin sulfonate, boric acid, citric acid are used in mixed way with arbitrary ratio.
The specific intensifying method of coral aggregate is as follows：
1) by prefabricated infiltration slurries injection kiln basin, coral aggregate to be processed is put into kiln basin and is impregnated
Then 5min pulls coral aggregate out from kiln basin；
2) aggregate pulled out is stood into 1h~2h, can carries out in next step, permeating the thickness of slurries cladding at this time after air-drying
For 0.3mm~0.5mm；
3) cladding slurries injection is sprayed in mortar machine, the coral aggregate that will be obtained by step 2) processing is put into vibrating screen
In, it divides as the thickness of a particle；
4) vibrating screen is opened, starts spray coating slurries, a batch is changed after 1min；By processed coral aggregate
Stand 30min~1h, at this time coat slurries cladding thickness be 0.5mm~1mm, as phosphor aluminate cement base can be cured chlorine from
The coral aggregate of son.
The coral aggregate that finally above-mentioned intensifying method is prepared, screens out more than 19.0mm and less than 9.50mm
Remainder particulate is weighed 3 groups of 3000g samples and is tested for crush values, finally calculates to obtain crush values≤19% after tested by grain.And not
The processed coral aggregate crush values directly chosen are≤32%.
Embodiment 3
The coral aggregate reinforcing slurries of chlorion can be cured in a kind of phosphor aluminate cement base, it includes infiltration slurries and cladding
Slurries two parts；Infiltration slurries are made of phosphor aluminate cement, clay matter mineral admixture, penetrant crystalline material and adjustable solidification agent；
Cladding slurries are made of phosphor aluminate cement, clay matter mineral admixture, adjustable solidification agent；Its specific following institute of mass percentage composition
Show：
Wherein, infiltration slurries use 0.75 ratio of mud, cladding slurries to use 0.6 ratio of mud, phosphor aluminate cement
Strength grade is not less than 42.5 grades, surface area ＞ 320m2/kg。
The penetrant crystalline material is the product of XYPEX series, and ingredient includes cement, quartz sand, water and activity chemistry object
Matter.
The clay matter mineral admixture is white Tungsten tailing.
The adjustable solidification agent is sodium lignin sulfonate, boric acid, citric acid are used in mixed way with arbitrary ratio.
The specific intensifying method of coral aggregate is as follows：
1) by prefabricated infiltration slurries injection kiln basin, coral aggregate to be processed is put into kiln basin and is impregnated
Then 5min pulls coral aggregate out from kiln basin；
2) aggregate pulled out is stood into 1h~2h, can carries out in next step, permeating the thickness of slurries cladding at this time after air-drying
For 0.3mm~0.5mm；
3) cladding slurries injection is sprayed in mortar machine, the coral aggregate that will be obtained by step 2) processing is put into vibrating screen
In, it divides as the thickness of a particle；
4) vibrating screen is opened, starts spray coating slurries, a batch is changed after 1min；By processed coral aggregate
Stand 30min~1h, at this time coat slurries cladding thickness be 0.5mm~1mm, as phosphor aluminate cement base can be cured chlorine from
The coral aggregate of son.
The coral aggregate that finally above-mentioned intensifying method is prepared, screens out more than 19.0mm and less than 9.50mm
Remainder particulate is weighed 3 groups of 3000g samples and is tested for crush values, finally calculates to obtain crush values≤18% after tested by grain.And not
The processed coral aggregate crush values directly chosen are≤32%.
Claims (5)
1. the coral aggregate that chlorion can be cured in a kind of phosphor aluminate cement base strengthens slurries, which is characterized in that it includes infiltration
Slurries and 22 cover slurries two parts；It is described infiltration slurries mass percentage composition be：Phosphor aluminate cement 70%~85% oozes
Saturating crystalline material 1%~4%, clay matter mineral admixture 10%~25%, adjustable solidification agent 0.4%~2%, the ratio of mud is 0.6~
0.75；It is described cladding slurries mass percentage composition be：Phosphor aluminate cement 70%~85%, clay matter mineral admixture
10%~25%, adjustable solidification agent 0.4%~2%, the ratio of mud are 0.5~0.6.
2. the coral aggregate that chlorion can be cured in phosphor aluminate cement base according to claim 1 strengthens slurries, feature
It is, the clay matter mineral admixture is at least one of gold ore tailing, white Tungsten tailing.
3. the coral aggregate that chlorion can be cured in phosphor aluminate cement base according to claim 2 strengthens slurries, feature
It is, the specific surface area ＞ 298m of the gold ore tailing2/ kg, the percentage of sieve residue ＜ 5% of 200 mesh of white Tungsten tailing sieve.
4. the coral aggregate that chlorion can be cured in phosphor aluminate cement base according to claim 1 strengthens slurries, feature
It is, the strength grade of the phosphor aluminate cement is not less than 42.5 grades, surface area ＞ 320m2/kg。
5. the coral aggregate that chlorion can be cured in phosphor aluminate cement base according to claim 1 strengthens slurries, feature
It is, the specifically used method for strengthening slurries is as follows：
1) by prefabricated infiltration slurries injection kiln basin, coral aggregate to be processed is put into kiln basin and impregnates 5min,
Then coral aggregate is pulled out from kiln basin；
2) aggregate pulled out is stood into 1h~2h, can be carried out after air-drying in next step, the thickness for permeating slurries cladding at this time is
0.3mm~0.5mm；
3) cladding slurries injection being sprayed in mortar machine, the coral aggregate that will be obtained by step 2) processing is put into vibrating screen,
It divides as the thickness of a particle；
4) vibrating screen is opened, starts spray coating slurries, a batch is changed after 1min；Processed coral aggregate is stood
30min~1h, the cladding thickness for coating slurries at this time are 0.5mm~1mm, and chlorion can be cured in as phosphor aluminate cement base
Coral aggregate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810131457.4A CN108455889B (en) | 2018-02-09 | 2018-02-09 | Phosphoaluminate cement-based coral aggregate reinforced slurry capable of curing chloride ions |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810131457.4A CN108455889B (en) | 2018-02-09 | 2018-02-09 | Phosphoaluminate cement-based coral aggregate reinforced slurry capable of curing chloride ions |
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| CN108455889B CN108455889B (en) | 2020-12-25 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110272221A (en) * | 2019-05-27 | 2019-09-24 | 深圳大学 | A kind of preparation method of modified coral sand concrete |
| CN110451918A (en) * | 2019-08-28 | 2019-11-15 | 辽宁科大中驰镁建材科技有限公司 | A kind of boron mud chlorine oxygen magnesium marine ecology fish shelter and preparation method thereof |
| CN113780734A (en) * | 2021-08-06 | 2021-12-10 | 中国建筑材料科学研究总院有限公司 | Method for determining using amount of cladding material in coral aggregate modification treatment and modification method |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110272221A (en) * | 2019-05-27 | 2019-09-24 | 深圳大学 | A kind of preparation method of modified coral sand concrete |
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| CN110451918A (en) * | 2019-08-28 | 2019-11-15 | 辽宁科大中驰镁建材科技有限公司 | A kind of boron mud chlorine oxygen magnesium marine ecology fish shelter and preparation method thereof |
| CN110451918B (en) * | 2019-08-28 | 2021-09-14 | 辽宁科大中驰镁建材科技有限公司 | Boric sludge magnesium oxychloride marine ecological fish reef and preparation method thereof |
| CN113780734A (en) * | 2021-08-06 | 2021-12-10 | 中国建筑材料科学研究总院有限公司 | Method for determining using amount of cladding material in coral aggregate modification treatment and modification method |
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