CN108455711A - Circulating water sterilizing electrolytic descaling system - Google Patents

Circulating water sterilizing electrolytic descaling system Download PDF

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Publication number
CN108455711A
CN108455711A CN201810328477.0A CN201810328477A CN108455711A CN 108455711 A CN108455711 A CN 108455711A CN 201810328477 A CN201810328477 A CN 201810328477A CN 108455711 A CN108455711 A CN 108455711A
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CN
China
Prior art keywords
circulating water
scraper
water inlet
staving
electrolytic descaling
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201810328477.0A
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Chinese (zh)
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CN108455711B (en
Inventor
韩柏平
吴嵚磊
丁惠忠
胡晓
胡晓一
唐涛
朱永财
朱关慰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Han Baiping
Jiangsu Jiguantong Environmental Protection Technology Co ltd
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Jiangsu Ji Guan Tong Environmental Protection Polytron Technologies Inc
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Priority to CN201810328477.0A priority Critical patent/CN108455711B/en
Publication of CN108455711A publication Critical patent/CN108455711A/en
Application granted granted Critical
Publication of CN108455711B publication Critical patent/CN108455711B/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/467Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/4602Treatment of water, waste water, or sewage by electrochemical methods for prevention or elimination of deposits
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/02Non-contaminated water, e.g. for industrial water supply
    • C02F2103/023Water in cooling circuits
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/08Multistage treatments, e.g. repetition of the same process step under different conditions

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

The present invention relates to a kind of circulating water sterilizing electrolytic descaling systems, it is characterised in that:It includes pretreatment tank, bactericidal reaction heap, descaler and dirt pocket;The pretreatment tank, bactericidal reaction heap, descaler and dirt pocket are arranged in series, and constitute one group of circulating water sterilizing electrolytic descaling device;The bactericidal reaction heap it include light electrolysis bucket, water inlet manifold and outfall sewer;The light electrolysis bucket is vertically arranged, it includes staving, and water inlet pipe is arranged in staving lower part, and top is arranged outlet pipe, electrode plate assembly is arranged in the staving;The water inlet manifold and outfall sewer are arranged in parallel up and down, and the light electrolysis bucket is provided with multiple, and multiple light electrolysis buckets are arranged in the both sides of water inlet manifold and outfall sewer.Circulating water sterilizing electrolytic descaling system of the present invention, good descaling effect not will produce secondary water body pollution, environmental protection and energy saving.

Description

Circulating water sterilizing electrolytic descaling system
Technical field
The present invention relates to circulation electrolysis treated sterilization descalling techniques, and in particular to a kind of circulating water sterilizing electricity Scaler system is solved, the water treatment of recirculating cooling water system is suitable for.
Background technology
Circulating water treatment scaler system be suitable for industrial circulation water treatment, cold water process, central air-conditioning circulating water treatment, Numerous circulating water cooling treatment fields such as power plant cycle water process.The scale removal of circulation, inhibition, sterilization are usually adopted at present Chemically or electronic technology method.It is to increase the chemical drugs such as antisludging agent, preservative in recirculated water using chemical method Agent, it is not only costly, but also due to introducing new chemical agent, secondary pollution can be caused to water body;It is handled using electronic technology Method, such as electronic scale remover apparatus for eliminating sludge scale removal effect be not intuitive, effect unobvious, cannot fundamentally control loop water system The problems such as system fouling, corrosion, bacterium algae are grown, water quality deterioration, cycles of concentration is exceeded cannot make circulation be in excellent always Stable state.
Invention content
The purpose of the present invention is to overcome the above shortcomings and to provide a kind of good descaling effects, without adding chemical reagent, environmental protection Energy-efficient circulating water sterilizing electrolytic descaling system.
The object of the present invention is achieved like this:A kind of circulating water sterilizing electrolytic descaling system, it includes pretreatment tank, kills Bacterium reactor, descaler and dirt pocket;The pretreatment tank, bactericidal reaction heap, descaler and dirt pocket are arranged in series, and constitute one Group circulating water sterilizing electrolytic descaling device;
The bactericidal reaction heap it include light electrolysis bucket, water inlet manifold and outfall sewer;The light electrolysis bucket is vertically arranged, it is wrapped Staving is included, water inlet pipe is arranged in staving lower part, and top is arranged outlet pipe, electrode plate assembly is arranged in the staving;
The water inlet manifold and outfall sewer are arranged in parallel up and down, and the light electrolysis bucket is provided with multiple, multiple light electrolysis Bucket is arranged in the both sides of water inlet manifold and outfall sewer;
Multigroup circulating water sterilizing electrolytic descaling device is provided in the system, multigroup circulating water sterilizing electrolytic descaling device is parallel Arrangement.
The water inlet pipe of each light electrolysis bucket accesses water inlet manifold by branch pipe respectively, and outlet pipe is connect by branch pipe respectively Enter outfall sewer so that multiple light electrolysis bucket settings parallel with one another.
The descaler includes staving and the pellet electrode component that is set in staving, and end socket is arranged in the staving top, The end socket connects push rod, and the piston rod of the push rod connects cutter holder assembly;
The pellet electrode component is correspondingly arranged at the both sides of piston rod, and the pellet electrode component includes NN electrode slices and PP electricity Pole piece, the NN electrode slices and PP electrode slice interlaced arrangements, the pellet electrode component are fixed by mounting bracket;
The cutter holder assembly includes knife rest, scraper connecting rod, scraper and broach shell, and the scraper is arranged in pairs, tight by scraper connecting rod Paste two sides of the NN electrode slices, the broach shell is coated on the outside of each pair of scraper by scraper connecting rod, the knife rest with The end of piston rod is connected.
The scraper connecting rod is two, is arranged in parallel in the both ends of knife rest.
There are gap, gap 2-40mm with adjacent PP electrode slices for the scraper.Prevent scraper from contacting hair with PP electrode slices Raw short circuit.
Scraper connecting rod is corresponded on the side plate of the mounting bracket and is equipped with sliding slot, and by scraper connecting rod, mobile drive is scraped in sliding slot Knife moves.
Its workflow is:
Step 1: pretreatment
Accessing pending water is accessed into pretreatment tank processing, removes particulate matter, turbidity and organic matter in water body, pretreatment tank is using quartz Sand filler increases flocculant in pretreatment tank water inlet line when necessary;
Step 2: cell reaction is sterilized
Cell reaction sterilization uses skid-mounted type cell reaction heap, is arranged in parallel and is constituted by multiple vertical light electrolysis buckets, described micro- It includes staving to be electrolysed bucket, and electrode plate assembly is vertically arranged in the staving;Water inlet manifold by branch pipe respectively with each light electrolysis Bucket is connected, and the outlet pipe of each light electrolysis bucket is also incorporated into total outlet pipe;
Pretreated water enters cell reaction heap water inlet manifold, then respectively enters micro- electricity by the branch pipe being connected on manifold Bucket electrolytic sterilizing is solved, the dirt that microorganism causes has been blocked to converge into total outlet pipe later;Germicidal efficiency reaches 99.99%;
It is easy to change since each light electrolysis bucket is to be arranged in parallel, it does not influence to produce.
Step 3: descaler scale removal
Water after sterilization enters descaler, by electrolytic tank electrolysis scale removal;Electrolyzer electric pole surface generates OH-, pH value in host It increasing so that calcium ion is attached to electrode surface in water body, forms fouling, reduces the calcium ion entered in following cycle water body, It after electrode surface fouling, is periodically struck off using comb scraper, the incrustation scale being stripped off is flowed into flow in dirt pocket.
Following reaction occurs:
O2+2H2O+4e- → 4OH-
Step 4: dirt pocket scale removal
Bar type electrode assembly is arranged in tank body in descaler treated the water containing calcium carbonate crystal enters dirt pocket tank body, and It is filled with steel wire lump in tank body, is further electrolysed under electrode assembly effect, is adsorbed in steel wire ball surface after calcium ion electrolysis, slowly Slowly it grows up, treated, and water enters circulating system after water outlet outflow.
The present invention basic principle be:
When the saturation ratio of solution is more than certain numerical value, precipitation can just be formed.
According to the principle that easy incrustation ion preferentially removes, as long as the calcium ion of removal excessive portion, then the reaction of fouling It would not occur.Reaction is as follows:
Under electric field action, Ca2+Loose aragonite is formed by preferential precipitation.
Ca2++HCO3 -+OH- →CaCO3(s)+H2O
Most active part calcium ion is first removed, thus changes the saturation ratio of solution, and fouling is just no longer possibly realized.
Therefore, entirely without the whole Ca of removal that must go to war2+, it will be able to scale problems are eliminated, here it is of the invention only The characteristics of having.
The beneficial effects of the invention are as follows:
Circulating water sterilizing electrolytic descaling system of the present invention, bactericidal reaction heap light electrolysis bucket are vertically arranged, and using mode is connect soon, are pacified Dress is dismantled, is easy to maintenance quick.It is arranged in parallel, treating capacity is big, and does not influence system normal operation when replacement.It is set using manifold It sets, it is compact-sized, it takes up little area.Descaler internal electrolytic cell electrode surface generates OH-, and pH value increases in host so that in water body Calcium ion is attached to electrode surface, forms fouling, reduces the calcium ion entered in following cycle water body, after electrode surface fouling, It is periodically struck off using comb scraper, the incrustation scale being stripped off is flowed into flow in dirt pocket.Good descaling effect is not necessarily to additionization Learn reagent, environmental protection and energy saving.Good descaling effect, without adding chemical reagent, environmental protection and energy saving.
Description of the drawings
Fig. 1 is circulating water sterilizing electrolytic descaling system schematic of the present invention;
Fig. 2 is bactericidal reaction pile structure schematic diagram of the present invention;
Fig. 3 is descaler internal structure schematic diagram of the present invention;
Fig. 4 is Fig. 3 intermediate slide component installation structure schematic diagrames;
Fig. 5 is single scraper scheme of installation.
In figure:
Pre-process tank 1, bactericidal reaction heap 2, descaler 3, dirt pocket 4;
Light electrolysis bucket 2.1, water inlet manifold 2.2 and outfall sewer 2.3;
Staving 2.11, electrode plate assembly 2.12;Water inlet pipe 2.13, outlet pipe 2.14;
Push rod 3.1, cutter holder assembly 3.2, pellet electrode component 3.3;
Knife rest 3.21, scraper connecting rod 3.22, scraper 3.23 and broach shell 3.24.
Specific implementation mode
Referring to Fig. 1, circulating water sterilizing electrolytic descaling system of the invention, it includes pretreatment tank 1, bactericidal reaction heap 2, removes Dirty device 3 and dirt pocket 4;The pretreatment tank 1, bactericidal reaction heap 2, descaler 3 and dirt pocket 4 are arranged in series, and are constituted one group and are followed Ring water sterilizes electrolytic descaling device.Multigroup circulating water sterilizing electrolytic descaling device, preferably 2 groups are provided in the system.It is more Group circulating water sterilizing electrolytic descaling device parallel arrangement.
Referring to Fig. 2, the bactericidal reaction heap 2 it include light electrolysis bucket 2.1, water inlet manifold 2.2 and outfall sewer 2.3;Institute It states light electrolysis bucket 2.1 to be vertically arranged, it includes staving 2.11, and water inlet pipe 2.13, top setting water outlet is arranged in 2.11 lower part of staving Pipe 2.14, the staving is interior to be arranged electrode plate assembly 2.12;
The water inlet manifold 2.2 and about 2.3 outfall sewer are arranged in parallel, the light electrolysis bucket 2.1 be provided with it is multiple, it is multiple The light electrolysis bucket 2.1 is arranged in the both sides of water inlet manifold 2.2 and outfall sewer 2.3;
The water inlet pipe 2.13 of each light electrolysis bucket 2.1 accesses water inlet manifold 2.2 by branch pipe respectively, and outlet pipe 2.14 is distinguished Outfall sewer 2.3 is accessed by branch pipe so that multiple 2.1 settings parallel with one another of the light electrolysis bucket.
Referring to Fig. 3, the descaler 3 includes staving and the pellet electrode component 3.3 being set in staving, the staving top End setting end socket, the end socket connect push rod 3.1, and the piston rod of the push rod 3.1 connects cutter holder assembly 3.2;
The pellet electrode component 3.3 is correspondingly arranged at the both sides of piston rod, and the pellet electrode component 3.3 includes NN electrode slices With PP electrode slices, the NN electrode slices and PP electrode slice interlaced arrangements, the pellet electrode component 3.3 are fixed by mounting bracket;
The cutter holder assembly 3.2 includes knife rest 3.21, scraper connecting rod 3.22, scraper 3.23 and broach shell 3.24, the scraper 3.23 It is arranged in pairs, two sides of the NN electrode slices is close to by scraper connecting rod 3.22, the broach shell 3.24 passes through scraper connecting rod 3.22 are coated on the outside of each pair of scraper 3.23, and the knife rest 3.21 is connected with the end of piston rod.
The scraper connecting rod 3.22 is two, is arranged in parallel in the both ends of knife rest 3.21.
There are gap, gap 2-40mm with adjacent PP electrode slices for the scraper 3.23.Prevent scraper from being connect with PP electrode slices The raw short circuit of triggering.
Scraper connecting rod 3.22 is corresponded on the side plate of the mounting bracket and is equipped with sliding slot, is moved in sliding slot by scraper connecting rod 3.22 It is dynamic that scraper 3.23 is driven to move.
When work:
Step 1: pretreatment
Accessing pending water is accessed into pretreatment tank processing, removes particulate matter, turbidity and organic matter in water body, pretreatment tank is using quartz Sand filler increases flocculant in pretreatment tank water inlet line when necessary;
Step 2: cell reaction is sterilized
Cell reaction sterilization uses skid-mounted type cell reaction heap, is arranged in parallel and is constituted by multiple vertical light electrolysis buckets, described micro- It includes staving to be electrolysed bucket, and electrode plate assembly is vertically arranged in the staving;Water inlet manifold by branch pipe respectively with each light electrolysis Bucket is connected, and the outlet pipe of each light electrolysis bucket is also incorporated into total outlet pipe;
Pretreated water enters cell reaction heap water inlet manifold, then respectively enters micro- electricity by the branch pipe being connected on manifold After solving bucket electrolytic sterilizing, total outlet pipe is converged into;Germicidal efficiency reaches 99.99%;
It is easy to change since each light electrolysis bucket is to be arranged in parallel, it does not influence to produce.
Step 3: descaler scale removal
Water after sterilization enters descaler, by electrolytic tank electrolysis scale removal;Electrolyzer electric pole surface generates OH-, pH value in host It increasing so that calcium ion is attached to electrode surface in water body, forms fouling, reduces the calcium ion entered in following cycle water body, It after electrode surface fouling, is periodically struck off using comb scraper, the incrustation scale being stripped off is flowed into flow in dirt pocket.
Following reaction occurs:
O2+2H2O+4e- → 4OH-
Step 4: dirt pocket scale removal
Bar type electrode assembly is arranged in tank body in descaler treated the water containing calcium carbonate crystal enters dirt pocket tank body, and It is filled with steel wire lump in tank body, is further electrolysed under electrode assembly effect, is adsorbed in steel wire ball surface after calcium ion electrolysis, slowly Slowly it grows up, treated, and water enters circulating system after water outlet outflow.
Since the calcium ion of easy fouling is trapped, the follow-up water into circulating system can be to avoid scale formation.Scale removal Effect is good, not will produce secondary water body pollution.

Claims (7)

1. a kind of circulating water sterilizing electrolytic descaling system, it is characterised in that:It includes pretreatment tank, bactericidal reaction heap, descaler And dirt pocket;The pretreatment tank, bactericidal reaction heap, descaler and dirt pocket are arranged in series, and constitute one group of circulating water sterilizing electricity Solve apparatus for eliminating sludge;
The bactericidal reaction heap it include light electrolysis bucket, water inlet manifold and outfall sewer;The light electrolysis bucket is vertically arranged, it is wrapped Staving is included, water inlet pipe is arranged in staving lower part, and top is arranged outlet pipe, electrode plate assembly is arranged in the staving;
The water inlet manifold and outfall sewer are arranged in parallel up and down, and the light electrolysis bucket is provided with multiple, multiple light electrolysis Bucket is arranged in the both sides of water inlet manifold and outfall sewer.
2. a kind of circulating water sterilizing electrolytic descaling system according to claim 1, it is characterised in that:It is arranged in the system There are multigroup circulating water sterilizing electrolytic descaling device, multigroup circulating water sterilizing electrolytic descaling device parallel arrangement.
3. a kind of circulating water sterilizing electrolytic descaling system according to claim 1, it is characterised in that:Each light electrolysis The water inlet pipe of bucket accesses water inlet manifold by branch pipe respectively, and outlet pipe accesses outfall sewer by branch pipe respectively so that Duo Gesuo State the setting parallel with one another of light electrolysis bucket.
4. a kind of circulating water sterilizing electrolytic descaling system according to claim 1, it is characterised in that:The descaler includes End socket is arranged in staving and the pellet electrode component being set in staving, the staving top, and the end socket connects push rod, described to push away The piston rod of bar connects cutter holder assembly;
The pellet electrode component is correspondingly arranged at the both sides of piston rod, and the pellet electrode component includes NN electrode slices and PP electricity Pole piece, the NN electrode slices and PP electrode slice interlaced arrangements, the pellet electrode component are fixed by mounting bracket;
The cutter holder assembly includes knife rest, scraper connecting rod, scraper and broach shell, and the scraper is arranged in pairs, tight by scraper connecting rod Paste two sides of the NN electrode slices, the broach shell is coated on the outside of each pair of scraper by scraper connecting rod, the knife rest with The end of piston rod is connected.
5. a kind of circulating water sterilizing electrolytic descaling system according to claim 4, it is characterised in that:The scraper connecting rod is Two, it is arranged in parallel in the both ends of knife rest.
6. a kind of circulating water sterilizing electrolytic descaling system according to claim 4, it is characterised in that:The scraper with it is adjacent There are gap, gap 2-40mm for PP electrode slices.
7. a kind of circulating water sterilizing electrolytic descaling system according to claim 4, it is characterised in that:The side of the mounting bracket Scraper connecting rod is corresponded on plate and is equipped with sliding slot, and scraper movement is driven by the way that scraper connecting rod is mobile in sliding slot.
CN201810328477.0A 2018-04-13 2018-04-13 Circulating water sterilization electrolysis descaling system Active CN108455711B (en)

Priority Applications (1)

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CN201810328477.0A CN108455711B (en) 2018-04-13 2018-04-13 Circulating water sterilization electrolysis descaling system

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Application Number Priority Date Filing Date Title
CN201810328477.0A CN108455711B (en) 2018-04-13 2018-04-13 Circulating water sterilization electrolysis descaling system

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CN108455711A true CN108455711A (en) 2018-08-28
CN108455711B CN108455711B (en) 2024-02-23

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109231600A (en) * 2018-11-12 2019-01-18 上海辨洁环保科技有限公司 A kind of industrial circulating water dirt purification device and its descaling method
CN111423035A (en) * 2020-05-07 2020-07-17 西安西热水务环保有限公司 Chemical-free electric method combined treatment process system and method for circulating water of thermal power plant

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201169550Y (en) * 2008-02-22 2008-12-24 山东良成环保工程有限公司 Micro-electrolysis dirty-proof bactericidal finishing apparatus
CN201506733U (en) * 2009-09-14 2010-06-16 山东良成环保工程有限公司 Module combination horizontal-type cycling water comprehensive water treatment device
CN105668713A (en) * 2016-03-11 2016-06-15 上海丁香环境科技有限公司 Linear motion type water treatment device for scraper descaling
CN208234603U (en) * 2018-04-13 2018-12-14 江苏济冠通环保科技股份有限公司 Circulating water sterilizing electrolytic descaling system

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201169550Y (en) * 2008-02-22 2008-12-24 山东良成环保工程有限公司 Micro-electrolysis dirty-proof bactericidal finishing apparatus
CN201506733U (en) * 2009-09-14 2010-06-16 山东良成环保工程有限公司 Module combination horizontal-type cycling water comprehensive water treatment device
CN105668713A (en) * 2016-03-11 2016-06-15 上海丁香环境科技有限公司 Linear motion type water treatment device for scraper descaling
CN208234603U (en) * 2018-04-13 2018-12-14 江苏济冠通环保科技股份有限公司 Circulating water sterilizing electrolytic descaling system

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109231600A (en) * 2018-11-12 2019-01-18 上海辨洁环保科技有限公司 A kind of industrial circulating water dirt purification device and its descaling method
CN111423035A (en) * 2020-05-07 2020-07-17 西安西热水务环保有限公司 Chemical-free electric method combined treatment process system and method for circulating water of thermal power plant
CN111423035B (en) * 2020-05-07 2024-04-26 西安西热水务环保有限公司 Combined treatment process system and method for circulating water of thermal power plant through chemical-free electrotechnology

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Effective date of registration: 20210112

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