CN1084460C - Exhaust gas treatment apparatus for use in incineration equipment - Google Patents

Exhaust gas treatment apparatus for use in incineration equipment Download PDF

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Publication number
CN1084460C
CN1084460C CN95120263A CN95120263A CN1084460C CN 1084460 C CN1084460 C CN 1084460C CN 95120263 A CN95120263 A CN 95120263A CN 95120263 A CN95120263 A CN 95120263A CN 1084460 C CN1084460 C CN 1084460C
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CN
China
Prior art keywords
heat exchanger
waste gas
emission
control equipment
thermoregulator
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN95120263A
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Chinese (zh)
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CN1132331A (en
Inventor
友野裕
堀田隆一
古寺雅晴
前田信广
村川忠夫
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Hitachi Zosen Corp
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Hitachi Zosen Corp
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Publication date
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Publication of CN1132331A publication Critical patent/CN1132331A/en
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Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F19/00Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers
    • F28F19/02Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers by using coatings, e.g. vitreous or enamel coatings
    • F28F19/04Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers by using coatings, e.g. vitreous or enamel coatings of rubber; of plastics material; of varnish
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/006Layout of treatment plant
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2215/00Preventing emissions
    • F23J2215/10Nitrogen; Compounds thereof
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2217/00Intercepting solids
    • F23J2217/10Intercepting solids by filters
    • F23J2217/101Baghouse type
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2219/00Treatment devices
    • F23J2219/10Catalytic reduction devices
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2900/00Special arrangements for conducting or purifying combustion fumes; Treatment of fumes or ashes
    • F23J2900/15081Reheating of flue gases

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Chimneys And Flues (AREA)
  • Incineration Of Waste (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
  • Filtering Of Dispersed Particles In Gases (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Treating Waste Gases (AREA)

Abstract

An exhaust gas treatment apparatus for use in an incineration equipment is provided which comprises: a temperature adjuster (11) for cooling exhaust gas discharged from an incinerator (2) ; a bag filter (12) for removing dust from the exhaust gas cooled by the temperature adjuster (11) ; and a denitrator (14) for catalytically denitrating the exhaust gas supplied from the dust collector, the temperature adjuster (11) having a first heat exchanger (21) for cooling the exhaust gas of a high temperature discharged from the incinerator (2) with air and a second heat exchanger (22) for heating the exhaust gas of a lower temperature supplied from the bag filter (12) with the high-temperature exhaust gas discharged from the incinerator (2).

Description

Emission-control equipment for the incinerating apparatus use
The present invention relates to a kind of emission-control equipment, for example, for the emission-control equipment of apparatus for incinerating waste material use.
In known apparatus for incinerating waste material, the waste gas of discharging from incinerator is transported to bag dust filter, compiles cigarette ash by bag dust filter.
Usually, the temperature that is transported to the waste gas of bag dust filter should reduce, and therefore, by cooling exhaust of water column type thermoregulator exchange column, for example drops to 170 ℃ from 280 ℃.
Like this, compile after the cigarette ash in the cooling exhaust by bag dust filter, by heater heat exhaust gases again, catalytic denitration in denitrator then, again from the smoke stack emission to the atmosphere in.
Should be heated to about 230 ℃ because be used for the waste gas of catalytic denitration, so need heat again waste gas by heater.
In above-mentioned waste gas treatment process, waste gas is once cooling in the thermoregulator exchange column, and by the heater heating, effective utilization that this will influence waste-gas heat is very uneconomic then.
So, the purpose of this invention is to provide a kind of emission-control equipment for the incinerating apparatus use that can effectively utilize waste-gas heat.
According to characteristics of the present invention, the emission-control equipment that uses for incinerating apparatus comprises: be used to cool off the thermoregulator from the waste gas of incinerator discharge; Be used for from remove the control of dust equipment of dust by the thermoregulator waste gas cooled; Be used to make the denitrator of the exhaust fume catalytic denitration that dust arrester transfers out, thermoregulator has first heat exchanger that is used for the high-temp waste gas of discharging from incinerator by air cooling, and is used for by second heat exchanger of the high-temp waste gas heating of discharging from incinerator from the waste gas of the lower temperature of dust arrester output.
In above-mentioned emission-control equipment, there is one guiding by second heat exchanger to the middle heater that is used for heat exhaust gases that is provided with of the pipeline of the heat exhaust gases of denitrator.
In above-mentioned emission-control equipment and the part of contacted first heat exchanger of waste gas be coated with coating, in order to prevent the acid corrosion of dew point.
In above-mentioned emission-control equipment, make coating with the PFA resin.Method with baking vanish is coated with on the part of first heat exchanger with 200 μ m to the thick PFA resin of 1000 μ m.
In above-mentioned emission-control equipment, first and second heat exchangers are horizontal multi tube heat exchangers, and first heat exchanger is divided into whole two parts that are provided with, and is parallel to second heat exchanger.
According to said structure, the heat of the waste gas of discharging from incinerator by the second heat exchanger utilization is heated to the waste gas of exporting from dust arrester temperature required, is used for catalytic treatment.So emission-control equipment of the present invention is only more more economical by the common emission-control equipment of a waste gas cooled of heater heating than adopting.
In addition and the part of contacted first heat exchanger of waste gas be coated with 200 μ m to the thick PFA resin of 1000 μ m with the method for baking vanish, so can guarantee enough anticorrosive and thermal conductivity of induced damage resistive first heat exchanger not.
In addition, thermoregulator comprises two heat exchangers, and a heat exchanger is divided into whole two parts that are provided with and is parallel to another heat exchanger, and like this, the size of thermoregulator can be dwindled.
The accompanying drawing of consulting is as follows:
Fig. 1 is the block diagram of explanation emission-control equipment according to an embodiment of the invention.
Fig. 2 is the schematic diagram of the thermoregulator structure of explanation emission-control equipment.
Fig. 3 is the front view of the thermoregulator of explanation emission-control equipment.
Fig. 4 illustrates the side view of the thermoregulator of emission-control equipment.
Fig. 5 is explanation heat conductivility and anti-expansion character and the curve map that is coated with the relation of PFA resin thickness.
Fig. 6 is the front view of explanation thermoregulator change type.
Fig. 7 is the front view of the another kind of modification of explanation thermoregulator.
Fig. 8 is the schematic diagram that thermoregulator structure according to another embodiment of the invention is described.
To narrate one embodiment of the present of invention referring to figs. 1 through Fig. 8.
Fig. 1 is the emission-control equipment 1 that explanation is provided, for example emission-control equipment in apparatus for incinerating waste material.(other typical incinerating apparatus comprises: trade waste incinerating apparatus, cinder or cigarette ash melting appartus, TRT and oil refinery equipment) is in emission-control equipment 1, remove cigarette ash from the waste gas that trash burner 2 is discharged and analog and make exhaust gas denitration, be discharged into the atmosphere from chimney 3 then by in waste gas, adding catalyst.
Emission-control equipment 1 comprises: the thermoregulator 11 that is used for the waste gas of discharging from trash burner is cooled to predetermined temperature (about 170 ℃ of the bag dust filter acceptable of for example, narrating below); Be used for from the bag dust filter (dust arrester) 12 of removing dust by thermoregulator 11 waste gas cooled, be used for the waste gas of carrying by waste line 13 from bag dust filter 12 is used the denitrator 14 of predetermined catalyst denitration and the burners that are used for heat exhaust gases (heater) 15 that are provided with in the middle of waste line 13.
Thermoregulator 11 comprises first heat exchanger 21 that is used for the high-temp waste gas of discharging from trash burner by air cooling and is used for by second heat exchanger 22 of high-temp waste gas heating from the waste gas of the lower temperature of bag dust filter 12 outputs.Second heat exchanger 22 is arranged on the upstream of first heat exchanger 21 in the waste gas flow process.
As shown in Figure 2, heat exchanger 21 and 22 is horizontal multi tube heat exchanger (package types), as being flowed by stream of the waste gas as shown in the arrow and air among Fig. 2.
More precisely, high-temp waste gas is input to the housing 22 of second heat exchanger 22 that one side is provided with in the upstream aIn, and be input into the pipeline 22 of second heat exchanger 22 from the waste gas of the lower temperature of bag dust filter 12 output b
The waste gas of exporting from the housing 22a of second heat exchanger 22 is input among the housing 21a of first heat exchanger 21 that is arranged on downstream one side, and the cooling air is input into the pipeline 21 of first heat exchanger 21 b
Shown in the enlarged drawing of Fig. 2, the pipeline 21 of first heat exchanger 21 that contacts with waste gas bThe inner surface of outer surface, housing and tube sheet and other parts be coated with coating 23 (for example fluorocarbon resin coating or ceramic coating), in order to prevent the acid corrosion of dew point.Like this, just can prevent pipeline 21 bOuter surface and the corrosion of similar portions.In this embodiment, the structure of first heat exchanger 21 is in order to make waste gas can flow into housing 21 aInside, this is because the coating of the outer surface of pipeline 21b is easier than the coating of its inner surface.
For preventing the acid corrosion of dew point, particularly will be described the fluorocarbon resin coating of the outer surface of the pipeline 21b that is used for covering first heat exchanger 21 to coating 23.Coating can also be applied to and the tube sheet of contacted first heat exchanger 21 of waste gas and the inner surface of housing and other parts.
More precisely, the method by baking vanish is coated with 200 μ m to the thick preferably 200 μ m of 1000 μ m to the thick PFA resin of 400 μ m (copolymer of tetrafluoroethene and perfluoroalkyl vinyl ethers) at the outer surface of the pipeline 21b of first heat exchanger 21.The typical material of pipeline 21b comprises mild steel and stainless steel.
Be the scope of benchmark and coating layer thickness preferably situation from 200 μ ms to 400 μ ms to use the PFA resin as coating with reference to table 1 explanation.
Table one
The denitration of the antiacid corrosion heat resistance of resin
PFA is fabulous fabulous
FEP is preferable fabulous
PTFE is bad preferable fabulous
PCTFE is fabulous bad fabulous
(25.4mm φ) is coated with various fluorocarbon resin and carries out corrosion resistance test, thermal cycle load test and bend test on steel pipe.Object of reference as fluorocarbon resin is tetrafluoroethene and hexafluoropropylene copolymer (FEP), polytetrafluoroethylene (PTFE) and polytrifluorochloroethylene (PCTFE).Corrosion resistance test is carried out in the most violent use occasion of simulation under the condition of sulfuric acid 80% (under 140 ℃ of temperature) and 20% chloric acid (boiling point).By the thermal cycle load test is carried out in cooling (to 0 ℃) and heating (to 200 ℃) repeatedly.Result of the test is as shown in table 1, and as can be seen from Table 1, the PFA resin all is being fabulous aspect antiacid burn into heat resistance and the denitration.
Secondly, under test temperature lifting and heat conductivility condition, how the thickness of observing the PFA resin in acid dip influences anti-expansion character.In this case, be coated with the PFA resin and test as substrate to have the thick stainless steel of 1.5mm, its result of the test as shown in Figure 5.
As can be seen from Figure 5, the resin-coated thickness of PFA preferably 200 μ m is more preferably 300 μ m to 400 μ m to 400 μ m, and it can be at the needs of not considering to satisfy under the heat conductivility situation anticorrosive and anti-expansion character.
Under the simulated conditions of actual use occasion, carry out corrosion resistance test, in this test, be coated with 200 μ m and stand the dipping of the chloric acid (boiling point) of 80% sulfuric acid (140 ℃) and 20%, and cool off its inner surface by air to steel pipe (25.4mm φ) outer surface of the thick PFA resin of 400 μ m.In addition, carry out thermal cycling test under the simulated conditions of actual use occasion, in this test, the outer surface of steel pipe is cool to room temperature and be heated to 180 ℃ repeatedly, and cools off its inner surface with air.These test announcements have 200 μ m and present fabulous performance to the thick PFA resinous coat of 400 μ m.
It is that method with machinery is coated with steel pipe with the PTFE resin that another kind presents good erosion-resisting typical heat pipe, and still, the PTFE resinous coat has relatively poor adhesion property to steel pipe, and the result causes reducing thermal conductivity and anticorrosive effect.In addition, even the mechanical damage little to the PTFE resinous coat also will cause resin-coated big tearing.In addition, if be subjected to thermal cycle, the PTFE resin also is easy to relax.
To narrate the structure of thermoregulator 11 more accurately with reference to Fig. 3 and Fig. 4.
In thermoregulator 11, the top in framework 31 is provided with second heat exchanger, 22, the first heat exchangers 21 and is divided into two parts 21 that mutual polyphone ground connects AWith 21 B, and be arranged on the bottom of second heat exchanger 22 abreast.If two heat exchangers respectively have identical size, approximately be the twice of second heat exchanger 22 as the second above-mentioned heat exchanger as the length of first heat exchanger, 21, the first heat exchangers 21 so.But in this embodiment, first heat exchanger 21 is divided into the two parts that are arranged on second heat exchanger, 22 bottoms abreast, so that can dwindle the size of adjuster 11.
For example, known emission-control equipment can be handled from trash burner with 4000NM 3The waste gas that the speed of/hr is discharged has 10 except that needing one m(height) * 2.5 mTo the water column type thermoregulator exchange column of 3m (diameter), also need a heat exchanger with 2 * 2 * 5 (height) size.In contrast to this, the thermoregulator according to two heat exchangers 21,22 of present embodiment only accounts for 2.5 m* 1.8 m* 2.5 mThe space of (height).Therefore, with known temperature adjuster exchange column and the heat exchanger specific energy size of dwindling thermoregulator 11 mutually.
The air that has absorbed heat from useless device in first heat exchanger 21 is transported to from the waste gas that denitrator 14 is discharged, and makes the unlikely discharge from chimney 3 as white cigarette of exhaust gas discharged.(definition of so-called herein " white cigarette " is meant and includes steam in waste gas, because of its temperature is lower, so look and be white in color.Because to the influence of environment, the dialogue cigarette takes preventive measures).
From the high-temp waste gas (for example 280 ℃) that trash burner is discharged, flow through second heat exchanger 22 and first heat exchanger 21, so its temperature is lower.For example, calcium hydroxide adds in the waste gas cooled, approximately is 170 ℃ at heat exchanger 22,21 in the way of bag dust filter 12.After utilizing bag dust filter 12 to remove cigarette ash from waste gas, waste gas heats in second heat exchanger 22.After this, waste gas heats again, for example is heated to about 230 ℃ by being arranged on waste line 13 middle heaters 15, and is transported to denitrator 14 catalytic denitrations.
In order to prevent the generation of white cigarette, the air by the cooling exhaust heat absorption in first heat exchanger 21 is transported to from the waste gas that denitrator 14 is discharged, and waste gas is discharged from chimney 3 then.
The waste gas of discharging from bag dust filter 12 from the heat handle of the waste gas of trash burner discharge by the second heat exchanger utilization is heated to the temperature required catalytic denitration that is used for.Therefore, emission-control equipment of the present invention than adopt the common emission-control equipment economy only utilize a cooling exhaust of heater heating many.
In addition, because thermoregulator 11 has two heat exchangers 21,22 that are provided with vertically therein, a heat exchanger 21 is divided into the two parts that are arranged in parallel, and is parallel to another heat exchanger 22, so the size of thermoregulator 11 can be dwindled widely.
In the above-described embodiments, though first heat exchanger is divided into the two parts that are arranged on the second heat exchanger bottom abreast, two parts 21 of first heat exchanger 21 AWith 21 BCan be arranged on the top of second heat exchanger abreast, as shown in Figure 6, perhaps two parts 21 AWith 21 BCan be parallel to each other and be arranged on a side of 22 of second heat exchanger vertically, as shown in Figure 7.
In addition, though the foregoing description adopts is the housing 22 that high-temp waste gas is transported to second heat exchanger 22 aBut high-temp waste gas also can be transported to the pipeline 22 of second heat exchanger 22 b, as shown in Figure 8.Yet, be the dust of removing on the inner surface of second heat exchanger 22, the cigarette ash that for example in waste gas, adheres to, structure as shown in Figure 2 makes and is flowing in pipeline 22 bThe waste gas of outside can be easy to clear operation.
In addition, in the above-described embodiments, though be used in the middle of the waste line 13 of direct exhaust from second heat exchanger to denitrator burner (heater) being set, burner can not necessarily need.
Although narrated the present invention above, must understand and to make all changes and not exceed scope of the present invention the present invention by specific embodiments of the invention.

Claims (7)

1. the emission-control equipment that is used for incinerating apparatus comprises: be used to cool off the thermoregulator from the waste gas of incinerator discharge; Be used for from remove the dust arrester of dust by the thermoregulator waste gas cooled; Be used to make the denitrator of the exhaust fume catalytic denitration that dust arrester transfers out, it is characterized in that; Thermoregulator has first heat exchanger that is used for the high-temp waste gas of discharging from incinerator by air cooling and second heat exchanger of the waste gas of the lower temperature that is used for transferring out from dust arrester by the high-temp waste gas heating of discharging from incinerator.
2. emission-control equipment according to claim 1 is characterized in that: the heater that is provided for heat exhaust gases in the pipeline that the waste gas by second heat exchanger heats is directed to denitrator.
3. emission-control equipment according to claim 1 is characterized in that: be coated with the part of contacted first heat exchanger of waste gas and coat, to prevent the acid corrosion of dew point.
4. emission-control equipment according to claim 2 is characterized in that: be coated with the part of contacted first heat exchanger of waste gas and coat, to prevent the acid corrosion of dew point.
5. emission-control equipment according to claim 3 is characterized in that: the PFA resin is coated 200 μ ms to 1000 μ ms thick PFA resin with the part of contacted first heat exchanger of waste gas by the method for baking vanish as coating.
6. emission-control equipment according to claim 4 is characterized in that: the PFA resin is coated 200 μ ms to 1000 μ ms thick PFA resin with the part of contacted first heat exchanger of waste gas by the method for baking vanish as coating.
7. according to each the described emission-control equipment in the claim 1 to 6, it is characterized in that: first and second heat exchangers are horizontal multi tube heat exchangers, and first heat exchanger is divided into whole two parts that are provided with, and is parallel to second heat exchanger.
CN95120263A 1994-11-30 1995-11-27 Exhaust gas treatment apparatus for use in incineration equipment Expired - Fee Related CN1084460C (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP295437/94 1994-11-30
JP29543794 1994-11-30
JP7047692A JP3051040B2 (en) 1994-11-30 1995-03-08 Exhaust gas treatment equipment in incineration equipment
JP47692/95 1995-03-08

Publications (2)

Publication Number Publication Date
CN1132331A CN1132331A (en) 1996-10-02
CN1084460C true CN1084460C (en) 2002-05-08

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Application Number Title Priority Date Filing Date
CN95120263A Expired - Fee Related CN1084460C (en) 1994-11-30 1995-11-27 Exhaust gas treatment apparatus for use in incineration equipment

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EP (1) EP0715122B1 (en)
JP (1) JP3051040B2 (en)
KR (1) KR100188311B1 (en)
CN (1) CN1084460C (en)
AT (1) ATE189050T1 (en)
DE (1) DE69514628T2 (en)
DK (1) DK0715122T3 (en)
TW (1) TW285709B (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6071116A (en) 1997-04-15 2000-06-06 American Air Liquide, Inc. Heat recovery apparatus and methods of use
KR100354920B1 (en) * 1999-07-23 2002-09-30 (주)오토엠아이티 Heat decomposition peant for the contaminated wastes
DE102011114292A1 (en) * 2011-09-23 2013-03-28 Eisenmann Ag Thermal post-combustion system and method for operating such
KR101652164B1 (en) * 2014-07-10 2016-09-09 주식회사 포스코건설 Particles pre-treatment process device of boiler and exhausting gas treatment method of heating power station using the same
CN104930533B (en) * 2015-06-29 2017-09-15 上海宝钢节能环保技术有限公司 Flue gas reheater for sintering denitrating flue gas
CN108072039A (en) * 2017-12-29 2018-05-25 河南永煤碳纤维有限公司 A kind of carbon fiber production emission-control equipment and method
JP6678265B1 (en) * 2019-02-28 2020-04-08 月島機械株式会社 Apparatus and method for treating flue gas

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4193180A (en) * 1977-03-02 1980-03-18 Resistoflex Corporation Method of forming a heat exchanger
JPS5678619A (en) * 1979-11-30 1981-06-27 Mitsubishi Kakoki Kaisha Ltd Waste gas treating method of incineration furnace or the like
DE3177143D1 (en) * 1981-04-09 1990-02-15 Heat Exchanger Ind Inc METHOD FOR PRODUCING A HEAT EXCHANGER AND HEAT EXCHANGER ACCORDING TO THIS METHOD.
DE3627086A1 (en) * 1986-08-09 1988-02-11 Steag Ag Process and arrangement for removing nitrogen oxides from flue gases
DE3730255A1 (en) * 1987-09-09 1989-03-23 Siemens Ag Combustion plant
JPH05293335A (en) * 1992-04-20 1993-11-09 Takuma Co Ltd Treating equipment for exhaust gas of waste incinerator and treatment of exhaust gas

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JPH08210617A (en) 1996-08-20
DE69514628T2 (en) 2000-08-10
TW285709B (en) 1996-09-11
JP3051040B2 (en) 2000-06-12
DE69514628D1 (en) 2000-02-24
CN1132331A (en) 1996-10-02
DK0715122T3 (en) 2000-06-13
EP0715122A2 (en) 1996-06-05
ATE189050T1 (en) 2000-02-15
EP0715122A3 (en) 1997-02-12
KR100188311B1 (en) 1999-06-01
KR960018349A (en) 1996-06-17
EP0715122B1 (en) 2000-01-19

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