CN108445592A - A kind of superelevation weatherability optical cable - Google Patents
A kind of superelevation weatherability optical cable Download PDFInfo
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- CN108445592A CN108445592A CN201810248801.8A CN201810248801A CN108445592A CN 108445592 A CN108445592 A CN 108445592A CN 201810248801 A CN201810248801 A CN 201810248801A CN 108445592 A CN108445592 A CN 108445592A
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- oversheath
- weatherability
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- 230000003287 optical effect Effects 0.000 title claims abstract description 51
- 239000004952 Polyamide Substances 0.000 claims abstract description 27
- 229920002647 polyamide Polymers 0.000 claims abstract description 27
- 229910001120 nichrome Inorganic materials 0.000 claims abstract description 23
- 229920001971 elastomer Polymers 0.000 claims abstract description 20
- 239000003063 flame retardant Substances 0.000 claims abstract description 19
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000004433 Thermoplastic polyurethane Substances 0.000 claims abstract description 15
- 239000000806 elastomer Substances 0.000 claims abstract description 15
- 239000013307 optical fiber Substances 0.000 claims abstract description 15
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims abstract 3
- 150000001875 compounds Chemical class 0.000 claims description 16
- 229920000573 polyethylene Polymers 0.000 claims description 12
- 229920002943 EPDM rubber Polymers 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 9
- 239000004698 Polyethylene Substances 0.000 claims description 7
- 239000000835 fiber Substances 0.000 claims description 7
- -1 polyethylene Polymers 0.000 claims description 7
- 239000004925 Acrylic resin Substances 0.000 claims description 6
- 238000004132 cross linking Methods 0.000 claims description 6
- 239000004800 polyvinyl chloride Substances 0.000 claims description 6
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 6
- 230000005855 radiation Effects 0.000 claims description 2
- 229910018487 Ni—Cr Inorganic materials 0.000 claims 1
- 229910045601 alloy Inorganic materials 0.000 claims 1
- 239000000956 alloy Substances 0.000 claims 1
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 claims 1
- 238000009413 insulation Methods 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 4
- 238000004078 waterproofing Methods 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 12
- 229920003225 polyurethane elastomer Polymers 0.000 description 9
- 239000005060 rubber Substances 0.000 description 5
- 239000013535 sea water Substances 0.000 description 5
- 238000004891 communication Methods 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 238000007654 immersion Methods 0.000 description 4
- JAWMENYCRQKKJY-UHFFFAOYSA-N [3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-ylmethyl)-1-oxa-2,8-diazaspiro[4.5]dec-2-en-8-yl]-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]methanone Chemical compound N1N=NC=2CN(CCC=21)CC1=NOC2(C1)CCN(CC2)C(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F JAWMENYCRQKKJY-UHFFFAOYSA-N 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 230000003628 erosive effect Effects 0.000 description 3
- 101100536251 Mus musculus Tmem120a gene Proteins 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 230000004584 weight gain Effects 0.000 description 2
- 235000019786 weight gain Nutrition 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000009510 drug design Methods 0.000 description 1
- 238000000635 electron micrograph Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/44—Mechanical structures for providing tensile strength and external protection for fibres, e.g. optical transmission cables
- G02B6/4401—Optical cables
- G02B6/4429—Means specially adapted for strengthening or protecting the cables
- G02B6/443—Protective covering
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/20—Carboxylic acid amides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0862—Nickel
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
- Insulated Conductors (AREA)
Abstract
The present invention relates to a kind of superelevation weatherability optical cables, and the superelevation weatherability optical cable is from the inside to the outside successively by optical fiber, insulating layer, waterproof layer, flame-retardant layer, anti-erosion layer, oversheath composition;Wherein, oversheath is made of thermoplastic polyurethane elastomer, nichrome and polyamide, and the mass ratio of thermoplastic polyurethane elastomer, nichrome and polyamide is 10 in the oversheath:2~3:5~6.The present invention makes the weatherability, anti-flammability, water proofing property of optical cable be not fully exerted by the structure of reasonable Arrangement optical cable from the inside to the outside, generally improve the application effect of optical cable, and it is used by oversheath and anti-erosion layer collocation, the weather resistance that optical cable can be played to greatest extent allows optical cable to be used in harsh even rugged environment.
Description
Technical field
The present invention relates to a kind of optical cables, and in particular to a kind of superelevation weatherability optical cable.
Background technology
With the great development of 21 century information-intensive society, we are increasing the live information flow-rate in each field, show
The development trend of huge explosion, this makes the high speed of communication, large capacity become possibility, is established for construction of information expressway
Good basis.Currently, the application of fiber optic communication oneself throughout the fields such as submarine communication, long distance line, cable television, LAN.
Optical cable often decides optical fiber as material most commonly seen in the information communications field, weatherability or erosion resisting
The stability of the information transmission system.But as industrial development is expanded to harsh environments such as deep-sea, plateaus, existing optical cable is often not
Industrial needs can be met.For example, optical cable is under the conditions of harsh tropical ocean environment, throughout the year damp and hot, high temperature and vibrations even
It is filled in the adverse circumstances of salt fog, mist of oil, the structure and performance of the materials such as sheath can be easy old by serious influence
Change fracture, cause optical fiber exposed, to destroy the stability of information transmission, causes huge economic losses;Solar radiation, temperature and
Humidity influences maximum to the aging of optical cable, they can make the rubber material of outer surface be hardened, become fragile because following the string.Thus may be used
See, weatherability has become one of important performance indexes of optical cable.For the weatherability of broad sense, seek to have resistance to ultraviolet
Line, heat-resisting, cold-resistant, water-fast etch, resistance to husky erosion and wind erosion property, while also to have both the performances such as resistance to ozone.
Therefore, it is anxious in infocommunications industry the weatherability of optical cable how to be improved by improving the corrosion resistance of optical cable
The technical issues of need to solving.
Invention content
Corrosion resistance and weatherability in order to solve optical cable in the prior art technical problem to be improved, the present invention propose
Following technical solution:
A kind of superelevation weatherability optical cable, from the inside to the outside successively by optical fiber, insulating layer, waterproof layer, flame-retardant layer, anti-erosion layer,
Oversheath forms;
Wherein, oversheath is made of thermoplastic polyurethane elastomer, nichrome and polyamide;
Wherein, the mass ratio of thermoplastic polyurethane elastomer, nichrome and polyamide is 10 in the oversheath:2
~3:5~6.
Preferably, the acrylate resin layer that optical fiber is coated by bare fibre and its outer surface is constituted.
Preferably, insulating layer is polyethylene;
Preferably, waterproof layer is polyvinyl chloride;
Preferably, flame-retardant layer is 105 DEG C of irradiation cross-linking flame-retardant polythene materials.
Preferably, the anti-erosion layer is made of ethylene propylene diene rubber and the compound with formula (1) structural formula, wherein
The mass ratio 10 of ethylene propylene diene rubber and the compound with formula (1) structural formula in the anti-erosion layer:4~7, wherein formula (1)
For:
In formula (1), m=2~7.
Technical scheme of the present invention has as follows by beneficial effect:
(1) weatherability, anti-flammability, water proofing property of optical cable is made to obtain fully by the structure of reasonable Arrangement optical cable from the inside to the outside
It plays, generally improves the application effect of optical cable.
(2) by rationally designing the component and each group distribution ratio of oversheath, optical cable can be significantly improved after seawater immersion
Tensile strength so that the weatherability of optical cable is significantly improved, and finds that polyamide has and has very much by many experiments
The sealing of hole of effect acts on, and the weatherability to improving optical cable plays the role of sizable.
(3) present invention can especially into compound (1) by rationally designing the component and its proportioning of anti-erosion layer
To significantly reduce optical cable weight gain after seawater immersion, corrosion progress is set to be effectively suppressed, so that optical cable is weather-proof
Property is significantly improved.
(4) oversheath and anti-erosion layer collocation use in optical cable of the invention, can play the weather-proof of optical cable to greatest extent
Performance allows optical cable to be used in harsh even rugged environment, has expanded the range of optical cable application environment.
Description of the drawings
Fig. 1 is electron micrograph of the optical cable of the present invention after seawater immersion test.
Specific implementation mode
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiments and comparative example,
The present invention will be described in further detail.
Embodiment 1
A kind of superelevation weatherability optical cable, from the inside to the outside successively by optical fiber, insulating layer, waterproof layer, flame-retardant layer, anti-erosion layer,
Oversheath forms;
Wherein, oversheath is made of thermoplastic polyurethane elastomer, nichrome and polyamide;Thermoplasticity in oversheath
The mass ratio of polyurethane elastomer, nichrome and polyamide is 10:2:5.
Wherein, the acrylate resin layer that optical fiber is coated by bare fibre and its outer surface is constituted, and insulating layer is polyethylene, waterproof
Layer is polyvinyl chloride, and flame-retardant layer is 105 DEG C of irradiation cross-linking flame-retardant polythene materials.
Wherein, anti-erosion layer is made of ethylene propylene diene rubber and the compound with formula (1) structural formula, three in anti-erosion layer
The mass ratio 10 of first EP rubbers and the compound with formula (1) structural formula:4, wherein formula (1) is:
In formula (1), m=2~7.
Embodiment 2
A kind of superelevation weatherability optical cable, from the inside to the outside successively by optical fiber, insulating layer, waterproof layer, flame-retardant layer, anti-erosion layer,
Oversheath forms;
Wherein, oversheath is made of thermoplastic polyurethane elastomer, nichrome and polyamide;Thermoplasticity in oversheath
The mass ratio of polyurethane elastomer, nichrome and polyamide is 10:2:6.
Wherein, the acrylate resin layer that optical fiber is coated by bare fibre and its outer surface is constituted, and insulating layer is polyethylene, waterproof
Layer is polyvinyl chloride, and flame-retardant layer is 105 DEG C of irradiation cross-linking flame-retardant polythene materials.
Wherein, anti-erosion layer is made of ethylene propylene diene rubber and the compound with formula (1) structural formula, three in anti-erosion layer
The mass ratio 10 of first EP rubbers and the compound with formula (1) structural formula:5, wherein formula (1) is:
In formula (1), m=2~7.
Embodiment 3
A kind of superelevation weatherability optical cable, from the inside to the outside successively by optical fiber, insulating layer, waterproof layer, flame-retardant layer, anti-erosion layer,
Oversheath forms;
Wherein, oversheath is made of thermoplastic polyurethane elastomer, nichrome and polyamide;Thermoplasticity in oversheath
The mass ratio of polyurethane elastomer, nichrome and polyamide is 10:3:5.
Wherein, the acrylate resin layer that optical fiber is coated by bare fibre and its outer surface is constituted, and insulating layer is polyethylene, waterproof
Layer is polyvinyl chloride, and flame-retardant layer is 105 DEG C of irradiation cross-linking flame-retardant polythene materials.
Wherein, anti-erosion layer is made of ethylene propylene diene rubber and the compound with formula (1) structural formula, three in anti-erosion layer
The mass ratio 10 of first EP rubbers and the compound with formula (1) structural formula:6, wherein formula (1) is:
In formula (1), m=2~7.
Embodiment 4
A kind of superelevation weatherability optical cable, from the inside to the outside successively by optical fiber, insulating layer, waterproof layer, flame-retardant layer, anti-erosion layer,
Oversheath forms;
Wherein, oversheath is made of thermoplastic polyurethane elastomer, nichrome and polyamide;It is hot in the oversheath
The mass ratio of plastic polyurethane elastomer, nichrome and polyamide is 10:3:6.
Wherein, the acrylate resin layer that optical fiber is coated by bare fibre and its outer surface is constituted, and insulating layer is polyethylene, waterproof
Layer is polyvinyl chloride, and flame-retardant layer is 105 DEG C of irradiation cross-linking flame-retardant polythene materials.
Wherein, anti-erosion layer is made of ethylene propylene diene rubber and the compound with formula (1) structural formula, three in anti-erosion layer
The mass ratio 10 of first EP rubbers and the compound with formula (1) structural formula:7, wherein formula (1) is:
In formula (1), m=2~7.
Comparative example 1
It is 10 by the mass ratio of thermoplastic polyurethane elastomer, nichrome and polyamide in 1 oversheath of embodiment:2:
5 mass ratioes for being adjusted to polyurethane elastomer, nichrome and polyamide are 10:2:0, i.e., do not add polyamide, Qi Tacan
Number is same as Example 1.
Comparative example 2
It is 10 by the mass ratio of thermoplastic polyurethane elastomer, nichrome and polyamide in 1 oversheath of embodiment:2:
5 mass ratioes for being adjusted to polyurethane elastomer, nichrome and polyamide are 10:1:7, i.e., do not add polyamide, Qi Tacan
Number is same as Example 1.
Comparative example 3
It is 10 by the mass ratio of thermoplastic polyurethane elastomer, nichrome and polyamide in 1 oversheath of embodiment:2:
5 mass ratioes for being adjusted to polyurethane elastomer, nichrome and polyamide are 10:4:4 (i.e. 5:2:2), other parameters and reality
It is identical to apply example 1.
Comparative example 4
It is 10 by the mass ratio of thermoplastic polyurethane elastomer, nichrome and polyamide in 1 oversheath of embodiment:2:
5 mass ratioes for being adjusted to polyurethane elastomer, nichrome and polyamide are 10:1:4, other parameters are same as Example 1.
Comparative example 5
It is 10 by the mass ratio of thermoplastic polyurethane elastomer, nichrome and polyamide in 1 oversheath of embodiment:2:
5 mass ratioes for being adjusted to polyurethane elastomer, nichrome and polyamide are 10:4:7, other parameters are same as Example 1.
Comparative example 6
By the mass ratio 10 of ethylene propylene diene rubber in 1 anti-erosion layer of embodiment and the compound with formula (1) structural formula:4
It is adjusted to 10:0, other parameters are same as Example 1.
Comparative example 7
By the mass ratio 10 of ethylene propylene diene rubber in anti-erosion layer in embodiment 1 and the compound with formula (1) structural formula:
4 are adjusted to 10:3, other parameters are same as Example 1.
Comparative example 8
By the mass ratio 10 of ethylene propylene diene rubber in anti-erosion layer in embodiment 1 and the compound with formula (1) structural formula:
4 are adjusted to 10:8 (i.e. 5:4), other parameters are same as Example 1.
Following table describes the component of oversheath and anti-erosion layer in embodiment 1-4 and comparative example 1-8 and constitutes in detail.
In order to verify the weather-proof effect of embodiment 1-4 and comparative example 1-8, by the optical cable sample of embodiment 1-4 and comparative example 1-8
Product carry out weatherability detection, as a result as follows:
The above results show that (1) present invention by the component and each group distribution ratio of rational design oversheath, can be carried significantly
High optical cable tensile strength after seawater immersion, further illustrates that the weatherability of optical cable is significantly improved;(2) present invention passes through conjunction
The component and its proportioning of reason design anti-erosion layer can significantly reduce optical cable and be impregnated in seawater especially into compound (1)
Weight gain afterwards further illustrates that corrosion progress is inhibited, and the weatherability of optical cable is significantly improved;(3) present invention's is outer
Sheath and anti-erosion layer collocation use, and can play the weather resistance of optical cable to greatest extent, optical cable is allow to be used for harshness very
Into rugged environment, the range of optical cable application environment has been expanded.
Claims (5)
1. a kind of superelevation weatherability optical cable, which is characterized in that the superelevation weatherability optical cable is from the inside to the outside successively by optical fiber, insulation
Layer, waterproof layer, flame-retardant layer, anti-erosion layer, oversheath composition;Wherein, the oversheath is by thermoplastic polyurethane elastomer, nickel chromium triangle
Alloy and polyamide composition, thermoplastic polyurethane elastomer in the oversheath, nichrome and polyamide mass ratio
It is 10:2~3:5~6;The acrylate resin layer that the optical fiber is coated by bare fibre and its outer surface is constituted.
2. superelevation weatherability optical cable according to claim 1, which is characterized in that the insulating layer is polyethylene.
3. superelevation weatherability optical cable according to claim 1, which is characterized in that the waterproof layer is polyvinyl chloride.
4. superelevation weatherability optical cable according to claim 1, which is characterized in that the flame-retardant layer is 105 DEG C of cross-linking radiations
Fire-retardant polyethylene material.
5. superelevation weatherability optical cable according to claim 1, which is characterized in that the anti-erosion layer is by ethylene propylene diene rubber
It is formed with the compound with formula (1) structural formula, ethylene propylene diene rubber and the change with formula (1) structural formula in the anti-erosion layer
Close the mass ratio 10 of object:4~7, wherein formula (1) is:
In formula (1), m=2~7.
Priority Applications (2)
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CN202010401768.5A CN111522109B (en) | 2018-03-25 | 2018-03-25 | Optical cable with ultrahigh weather resistance |
CN201810248801.8A CN108445592B (en) | 2018-03-25 | 2018-03-25 | Optical cable with ultrahigh weather resistance |
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CN201810248801.8A CN108445592B (en) | 2018-03-25 | 2018-03-25 | Optical cable with ultrahigh weather resistance |
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CN202010401768.5A Division CN111522109B (en) | 2018-03-25 | 2018-03-25 | Optical cable with ultrahigh weather resistance |
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CN202010401768.5A Active CN111522109B (en) | 2018-03-25 | 2018-03-25 | Optical cable with ultrahigh weather resistance |
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CN107057186A (en) * | 2017-03-23 | 2017-08-18 | 国网山东省电力公司莒县供电公司 | A kind of corrosion resistant ADSS optical cables and preparation method thereof |
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CN202204975U (en) * | 2011-09-19 | 2012-04-25 | 吴江市欣达通信科技股份有限公司 | Single-core circular armored cable |
CN104834068A (en) * | 2015-05-26 | 2015-08-12 | 长飞光纤光缆股份有限公司 | Superfine-diameter high-performance jumper wire optical cable |
WO2018002041A1 (en) * | 2016-06-27 | 2018-01-04 | Heraeus Sensor Technology Gmbh | Cable for contacting a sensor, temperature measuring device, method for connecting a cable to a temperature measuring device and use of an alloy for producing a cable |
CN206002726U (en) * | 2016-08-22 | 2017-03-08 | 长光通信科技江苏有限公司 | A kind of armored soft optical cable |
CN205984359U (en) * | 2016-08-23 | 2017-02-22 | 安徽电信器材贸易工业有限责任公司 | Soft withstand voltage anti vibration communications optical cable |
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Also Published As
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CN108445592B (en) | 2020-06-12 |
CN111522109B (en) | 2021-11-23 |
CN111522109A (en) | 2020-08-11 |
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