CN108445344A - Method and system for predicting electrode short circuit based on current - Google Patents
Method and system for predicting electrode short circuit based on current Download PDFInfo
- Publication number
- CN108445344A CN108445344A CN201810214300.8A CN201810214300A CN108445344A CN 108445344 A CN108445344 A CN 108445344A CN 201810214300 A CN201810214300 A CN 201810214300A CN 108445344 A CN108445344 A CN 108445344A
- Authority
- CN
- China
- Prior art keywords
- value
- cathode
- current value
- short
- determination
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 35
- 238000005070 sampling Methods 0.000 claims description 4
- 238000012163 sequencing technique Methods 0.000 claims description 3
- 235000013399 edible fruits Nutrition 0.000 claims description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims 1
- 239000011362 coarse particle Substances 0.000 abstract description 2
- 238000010586 diagram Methods 0.000 description 4
- 210000004027 cell Anatomy 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 210000001787 dendrite Anatomy 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000003331 infrared imaging Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical group 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
- G01R31/00—Arrangements for testing electric properties; Arrangements for locating electric faults; Arrangements for electrical testing characterised by what is being tested not provided for elsewhere
- G01R31/50—Testing of electric apparatus, lines, cables or components for short-circuits, continuity, leakage current or incorrect line connections
- G01R31/52—Testing for short-circuits, leakage current or ground faults
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
- G01R31/00—Arrangements for testing electric properties; Arrangements for locating electric faults; Arrangements for electrical testing characterised by what is being tested not provided for elsewhere
- G01R31/50—Testing of electric apparatus, lines, cables or components for short-circuits, continuity, leakage current or incorrect line connections
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/06—Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese
- C25C1/10—Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese of chromium or manganese
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/12—Electrolytic production, recovery or refining of metals by electrolysis of solutions of copper
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/16—Electrolytic production, recovery or refining of metals by electrolysis of solutions of zinc, cadmium or mercury
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/18—Electrolytic production, recovery or refining of metals by electrolysis of solutions of lead
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/06—Operating or servicing
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D21/00—Processes for servicing or operating cells for electrolytic coating
- C25D21/12—Process control or regulation
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D17/00—Constructional parts, or assemblies thereof, of cells for electrolytic coating
- C25D17/005—Contacting devices
Abstract
The invention discloses a method and a system for predicting electrode short circuit based on current. The method comprises the following steps: obtaining the current value of a cathode in an anode-cathode pair; acquiring a plurality of current values within a set time period; determining an increase value of the plurality of current values over time; judging whether the added value is within a set current range, if so, fitting the plurality of current values according to a time sequence by using a linear fitting method to obtain a linear model; obtaining the slope and the decision coefficient of the linear model; and judging whether the slope is in a set slope range, if so, judging whether the decision coefficient is smaller than the set decision coefficient value, if not, determining that the electrodes of the anode-cathode pair have the hidden danger of short circuit, and otherwise, determining that the electrodes do not have the hidden danger of short circuit. By adopting the method or the system, the existence of coarse particles on the surface of the cathode can be effectively judged, hidden dangers are found before short circuit occurs, the electrolytic current efficiency and the product quality are obviously improved, and the product cost is reduced.
Description
Technical field
The present invention relates to aqueous solution electrolysis field, a kind of method more particularly to prediction electric pole short circuit based on electric current and
System.
Background technology
In the aqueous solution electrolysis refining and the industrial processes of electrolytic deposition of the metals such as copper, lead, zinc, nickel, manganese, generally
Single electrolytic cell includes the cathode of tens of pieces of anodes and corresponding number, and anode plate and cathode plate intersection is arranged side by side.Electrolytic cell
Anode, cathode are all plates, because referred to herein as anode plate, cathode plate, single side area are 1m2More than, single-piece electrode plate can pass through
The electric current of 500A or more.Due to narrow space between yin, yang pole plate on electrolytic cell, tens millimeters of electrode distance, on electrode surface
The deformation of part may cause electric current to be unevenly distributed at the electrode surface, and local current densities is caused to increase；In electrolytic process
The ratio or ingredient of additive are lacked of proper care, and electrode plate surface is caused to form dendrite；The anode used is refined, some ingredients are more than to want
It asks, corresponding cathode surface is caused to form knot grain.These the occurrence of, can cause cathode surface to be locally generated knot grain simultaneously gradually fast
The long great achievement oversize grain of speed, when particle is contacted with anode surface, formation short circuit, not only reduces electric current between a cathode and an anode
Efficiency, while cathode quality is also reduced, or even cause the serious conditions such as the scaling loss of cathode plate and conductive rod, deformation.
Currently, for the short circuit between K-A, generally take infrared imaging detection, drag table detection, watering detection etc.
Method.These methods are all after having formed short circuit between a cathode and an anode, in the case where cathode conducting end is significantly generated heat
It can just detect short-circuit generation, then carry out short-circuit cleaning and had resulted in the loss of electric current so when detecting short circuit
With the reduction of cathode quality.
Invention content
The method and system for predicting electric pole short circuit based on electric current that the object of the present invention is to provide a kind of, to solve existing skill
When detecting the short circuit between K-A in art, had resulted in electric current loss and cathode quality reduction the problem of, lead to
It crosses and electric pole short circuit is predicted, determine that the hidden danger of short circuit improves the quality of cathode to avoid the loss of electric current in advance.
To achieve the above object, the present invention provides following schemes：
A method of the prediction electric pole short circuit based on electric current, the method includes：
Obtain the current value of the anode-cathode centering cathode of current collecting device acquisition；
In set period of time, multiple current values of the anode-cathode centering cathode are obtained；
Determine the value added that the multiple current value changes over time；
Judge that value added that the multiple current value changes over time whether within the scope of setting electric current, obtains the first judgement
As a result；
When first judging result indicates value added that the multiple current value changes over time not in setting electric current model
When enclosing interior, determine that short-circuit hidden danger is not present in the electrode of the anode-cathode pair；
When first judging result indicates value added that the multiple current value changes over time in setting electric current range
When interior, the multiple current value is fitted in chronological order using linear fit method, obtains linear model；
Obtain the slope and the coefficient of determination of the linear model；
Judge that the slope whether in setting slope range, obtains the second judging result；
When second judging result indicates that the slope when setting in slope range, does not determine the anode-cathode
To electrode short-circuit hidden danger is not present；
When second judging result indicates whether the slope when setting in slope range, judges the coefficient of determination
Less than setting coefficient of determination value, third judging result is obtained；
When the third judging result indicates that the coefficient of determination is less than setting coefficient of determination value, the anode-is determined
Short-circuit hidden danger is not present in the electrode of cathode pair；
When the third judging result indicates the coefficient of determination not less than setting coefficient of determination value, the sun is determined
There is short-circuit hidden danger in the electrode of pole-cathode pair.
Optionally, the sampling period of the current collecting device is less than 5 minutes, and the set period of time is 100 minutes.
Optionally, the value added that the multiple current value of the determination changes over time, specifically includes：
The multiple current value is sorted by acquisition time, the electric current value sequence after being sorted；
Obtain the difference between the last one current value and first current value in the electric current value sequence；
The difference is determined as the value added that the multiple current value changes over time.
Optionally, the setting electric current ranging from 10~60A.
Optionally, the slope range that sets is 0.10~0.60A/min, and the coefficient of determination value that sets is 0.7.
Optionally, there is short-circuit hidden danger in the electrode of the determination anode-cathode pair, further include later：
The warning message that electrode has short-circuit hidden danger is generated, to remind staff to handle.
A kind of system of the prediction electric pole short circuit based on electric current, the system comprises：
Current value acquisition module, the current value of the anode-cathode centering cathode for obtaining current collecting device acquisition；
In set period of time, multiple current values of the anode-cathode centering cathode are obtained；
Value added determining module, the value added changed over time for determining the multiple current value；
First judgment module, for judging value added that the multiple current value changes over time whether in setting electric current model
In enclosing, the first judging result is obtained；
Short-circuit hidden danger determining module is not present in electrode, for when first judging result indicate the multiple current value with
When the value added of time change is not within the scope of setting electric current, determine that short-circuit hidden danger is not present in the electrode of the anode-cathode pair；
Linear fit module, for indicating the increase that the multiple current value changes over time when first judging result
When value is within the scope of setting electric current, the multiple current value is fitted in chronological order using linear fit method, is obtained
Linear model；
Slope and coefficient of determination acquisition module, slope and the coefficient of determination for obtaining the linear model；
Third judgment module, for judging that the slope whether in setting slope range, obtains the second judging result；
Short-circuit hidden danger determining module is not present in the electrode, is additionally operable to indicate the slope not when second judging result
When setting in slope range, determine that short-circuit hidden danger is not present in the electrode of the anode-cathode pair；
Third judgment module, for when second judging result indicates that the slope is in setting slope range, sentencing
Whether the coefficient of determination that breaks is less than setting coefficient of determination value, obtains third judging result；
Short-circuit hidden danger determining module is not present in the electrode, is additionally operable to indicate the decision system when the third judging result
When number is less than setting coefficient of determination value, determine that short-circuit hidden danger is not present in the electrode of the anode-cathode pair；
There is short-circuit hidden danger determining module in electrode, indicate that the coefficient of determination is not less than for working as the third judging result
When setting coefficient of determination value, determine that the electrode of the anode-cathode pair has short-circuit hidden danger.
Optionally, the value added determining module, specifically includes：
Sequencing unit, for the multiple current value to be sorted by acquisition time, the electric current value sequence after being sorted；
Difference acquiring unit, for obtaining in the electric current value sequence between the last one current value and first current value
Difference；
Value added determination unit, for the difference to be determined as the value added that the multiple current value changes over time.
Optionally, the system also includes：
Warning message generation module generates after there is short-circuit hidden danger in the electrode for determining the anode-cathode pair
There is the warning message of short-circuit hidden danger in electrode, to remind staff to handle.
According to specific embodiment provided by the invention, the invention discloses following technique effects：
This linearly increasing characteristic that the present invention is shown using cathode surface ion close to before anode surface, proposes to pass through
It is continuous to measure cathode current, the changing pattern of cathode current is analyzed during the time of 100min or so, to cathode
Short circuit is predicted.Once it was found that this feature, so that it may to judge to exist short-circuit hidden danger, occur first 1 hour in short circuit or more
Time, provide warning information, prompt to carry out short-circuit hidden danger processing, occur so as to avoid subsequent short circuit, eliminate electric current
Other are destroyed caused by loss and short circuit, have very important application value.For improve Faradaic current efficiency and product quality,
It reduces product cost and new technology and methods is provided.
Description of the drawings
It in order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, below will be to institute in embodiment
Attached drawing to be used is needed to be briefly described, it should be apparent that, the accompanying drawings in the following description is only some implementations of the present invention
Example, for those of ordinary skill in the art, without having to pay creative labor, can also be according to these attached drawings
Obtain other attached drawings.
Fig. 1 is the flow diagram of the method for the prediction electric pole short circuit the present invention is based on electric current；
Fig. 2 is the structural schematic diagram of the system of the prediction electric pole short circuit the present invention is based on electric current.
Specific implementation mode
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete
Site preparation describes, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on
Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other
Embodiment shall fall within the protection scope of the present invention.
In order to make the foregoing objectives, features and advantages of the present invention clearer and more comprehensible, below in conjunction with the accompanying drawings and specific real
Applying mode, the present invention is described in further detail.
Fig. 1 is the flow diagram of the method for the prediction electric pole short circuit the present invention is based on electric current.As shown in Figure 1, the side
Method includes：
Step 101：Obtain the current value of the anode-cathode centering cathode of current collecting device acquisition.In set period of time
It is interior, obtain multiple current values of the anode-cathode centering cathode.Current collecting device is by the way of continuous acquisition into line number
According to acquisition, the sampling period is less than 5 minutes, i.e., at least sampling in every 5 minutes is primary.Set period of time is 100 minutes, and time period is
By many experiments and analysis, the period obtained.In this set period of time, entire prediction result is more accurate.
Step 102：Determine the value added that the multiple current value changes over time.Determine the multiple current value at any time
The detailed process of the value added of variation is：
The multiple current value is sorted by acquisition time, the electric current value sequence after being sorted；
Obtain the difference between the last one current value and first current value in the electric current value sequence；By the difference
It is determined as the value added that the multiple current value changes over time, value added is positive value at this time.
Step 103：Judge value added that multiple current values change over time whether within the scope of setting electric current；If not,
Execute step 104；If so, executing step 105.The setting electric current ranging from positive value, usually can be set as 10~60A.
Step 104：Determine that short-circuit hidden danger is not present in the electrode of the anode-cathode pair.
Step 105：Multiple current values are fitted in chronological order using linear fit method, obtain linear model.
Step 106：Obtain the slope and the coefficient of determination of the linear model.
Step 107：Judge the slope whether in setting slope range.If not, executing step 108；If so, holding
Row step 109.It is normally set up 0.10~0.60A/min of slope range.
Step 108：Determine that short-circuit hidden danger is not present in the electrode of the anode-cathode pair.
Step 109：Judge whether the coefficient of determination is less than setting coefficient of determination value, if so, executing step 110；If not,
Execute step 111.The present invention's sets coefficient of determination value as 0.7.
Step 110：Determine that short-circuit hidden danger is not present in the electrode of the anode-cathode pair.
Step 111：Determine that the electrode of the anode-cathode pair has short-circuit hidden danger.When the third judging result indicates
When being, indicate that cathode surface, i.e., will be with positive contact with coarse particle, there are short-circuit hidden danger.
After the electrode for determining the anode-cathode pair has short-circuit hidden danger, electrode can be generated and there is short-circuit hidden danger
Warning message avoids the generation of short circuit to remind staff to handle.
Before the present invention is implemented, by on-the-spot test and research, it is found that cathode current is most sensitive to short-circuit generating process
Information.In normal electrolytic process, cathode current shows very stable pattern.But electric current quickly increases after short circuit occurs
Big arrive average current 3 times, and occurring in preceding 3~4h times in short circuit, when the oversize grain of cathode surface generation is leaned on growing up
Nearly anode, apart from anode surface 1-3mm when, the significant change of cathode current can be caused, the linear of 0.10~0.6A/min is presented
Increase pattern.When particle contact to anode surface, cathode current is increased rapidly and is vibrated, until forming stable circuit with anode
Connection, electric current reach maximum short circuit value.
Fig. 2 is the structural schematic diagram of the system of the prediction electric pole short circuit the present invention is based on electric current.As shown in Fig. 2, the system
System includes：
Current value acquisition module 201, the electric current of the anode-cathode centering cathode for obtaining current collecting device acquisition
Value；In set period of time, multiple current values of the anode-cathode centering cathode are obtained；
Value added determining module 202, the value added changed over time for determining the multiple current value；
First judgment module 203, for judging whether the value added that the multiple current value changes over time is electric in setting
It flows in range, obtains the first judging result；
Short-circuit hidden danger determining module 204 is not present in electrode, for indicating the multiple electric current when first judging result
When the value added that value changes over time is not within the scope of setting electric current, determine that short circuit is not present in the electrode of the anode-cathode pair
Hidden danger；
Linear fit module 205, for indicating what the multiple current value changed over time when first judging result
When value added is within the scope of setting electric current, the multiple current value is fitted in chronological order using linear fit method,
Obtain linear model；
Slope and coefficient of determination acquisition module 206, slope and the coefficient of determination for obtaining the linear model；
Third judgment module 207, for judging that the slope whether in setting slope range, obtains the second judgement knot
Fruit；
Short-circuit hidden danger determining module 204 is not present in the electrode, is additionally operable to indicate described oblique when second judging result
Rate determines that short-circuit hidden danger is not present in the electrode of the anode-cathode pair not when setting in slope range；
Third judgment module 208 is used for when second judging result indicates that the slope is in setting slope range,
Judge whether the coefficient of determination is less than setting coefficient of determination value, obtains third judging result；
Short-circuit hidden danger determining module 204 is not present in the electrode, is additionally operable to when third judging result expression is described certainly
When determining coefficient less than setting coefficient of determination value, determine that short-circuit hidden danger is not present in the electrode of the anode-cathode pair；
There is short-circuit hidden danger determining module 209 in electrode, for indicating the coefficient of determination not when the third judging result
When less than setting coefficient of determination value, determine that the electrode of the anode-cathode pair has short-circuit hidden danger.
Wherein, the value added determining module 202, specifically includes：
Sequencing unit, for the multiple current value to be sorted by acquisition time, the electric current value sequence after being sorted；
Difference acquiring unit, for obtaining in the electric current value sequence between the last one current value and first current value
Difference；
Value added determination unit, for the difference to be determined as the value added that the multiple current value changes over time.
The system also includes：Warning message generation module, for there are short in the electrode for determining the anode-cathode pair
After the hidden danger of road, the warning message that electrode has short-circuit hidden danger is generated, to remind staff to handle.
Each embodiment is described by the way of progressive in this specification, the highlights of each of the examples are with other
The difference of embodiment, just to refer each other for identical similar portion between each embodiment.
Principle and implementation of the present invention are described for specific case used herein, and above example is said
The bright method and its core concept for being merely used to help understand the present invention；Meanwhile for those of ordinary skill in the art, foundation
The thought of the present invention, there will be changes in the specific implementation manner and application range.In conclusion the content of the present specification is not
It is interpreted as limitation of the present invention.
Claims (9)
1. a kind of method of the prediction electric pole short circuit based on electric current, which is characterized in that the method includes：
Obtain the current value of the anode-cathode centering cathode of current collecting device acquisition；
In set period of time, multiple current values of the anode-cathode centering cathode are obtained；
Determine the value added that the multiple current value changes over time；
Judge that value added that the multiple current value changes over time whether within the scope of setting electric current, obtains the first judgement knot
Fruit；
When first judging result indicates value added that the multiple current value changes over time not within the scope of setting electric current
When, determine that short-circuit hidden danger is not present in the electrode of the anode-cathode pair；
When first judging result indicates value added that the multiple current value changes over time within the scope of setting electric current,
The multiple current value is fitted in chronological order using linear fit method, obtains linear model；
Obtain the slope and the coefficient of determination of the linear model；
Judge that the slope whether in setting slope range, obtains the second judging result；
When second judging result indicates that the slope when setting in slope range, does not determine the anode-cathode pair
Short-circuit hidden danger is not present in electrode；
When second judging result indicates that the slope when setting in slope range, judges whether the coefficient of determination is less than
Coefficient of determination value is set, third judging result is obtained；
When the third judging result indicates that the coefficient of determination is less than setting coefficient of determination value, the anode-cathode is determined
To electrode short-circuit hidden danger is not present；
When the third judging result indicates the coefficient of determination not less than setting coefficient of determination value, described anode-the moon is determined
Extremely to electrode there is short-circuit hidden danger.
2. the method for prediction electric pole short circuit according to claim 1, which is characterized in that the sampling of the current collecting device
Period is less than 5 minutes, and the set period of time is 100 minutes.
3. the method for prediction electric pole short circuit according to claim 1, which is characterized in that the multiple current value of determination
The value added changed over time, specifically includes：
The multiple current value is sorted by acquisition time, the electric current value sequence after being sorted；
Obtain the difference between the last one current value and first current value in the electric current value sequence；
The difference is determined as the value added that the multiple current value changes over time.
4. the method for prediction electric pole short circuit according to claim 1, which is characterized in that the setting electric current ranging from 10~
60A。
5. the method for prediction electric pole short circuit according to claim 1, which is characterized in that the slope range that sets is 0.10
~0.60A/min, the coefficient of determination value that sets is 0.7.
6. the method for prediction electric pole short circuit according to claim 1, which is characterized in that the determination anode-cathode
To electrode there is short-circuit hidden danger, further include later：
The warning message that electrode has short-circuit hidden danger is generated, to remind staff to handle.
7. a kind of system of the prediction electric pole short circuit based on electric current, which is characterized in that the system comprises：
Current value acquisition module, the current value of the anode-cathode centering cathode for obtaining current collecting device acquisition；It is setting
In period, multiple current values of the anode-cathode centering cathode are obtained；
Value added determining module, the value added changed over time for determining the multiple current value；
First judgment module, for judging value added that the multiple current value changes over time whether in setting electric current range
It is interior, obtain the first judging result；
Short-circuit hidden danger determining module is not present in electrode, for indicating the multiple current value at any time when first judging result
When the value added of variation is not within the scope of setting electric current, determine that short-circuit hidden danger is not present in the electrode of the anode-cathode pair；
Linear fit module, for indicating that the value added that the multiple current value changes over time exists when first judging result
When within the scope of setting electric current, the multiple current value is fitted in chronological order using linear fit method, is obtained linear
Model；
Slope and coefficient of determination acquisition module, slope and the coefficient of determination for obtaining the linear model；
Third judgment module, for judging that the slope whether in setting slope range, obtains the second judging result；
Short-circuit hidden danger determining module is not present in the electrode, is additionally operable to indicate that the slope is not being set when second judging result
When determining in slope range, determine that short-circuit hidden danger is not present in the electrode of the anode-cathode pair；
Third judgment module, for when second judging result indicates that the slope is in setting slope range, judging institute
It states whether the coefficient of determination is less than setting coefficient of determination value, obtains third judging result；
Short-circuit hidden danger determining module is not present in the electrode, is additionally operable to indicate that the coefficient of determination is small when the third judging result
When setting coefficient of determination value, determine that short-circuit hidden danger is not present in the electrode of the anode-cathode pair；
There is short-circuit hidden danger determining module in electrode, for indicating the coefficient of determination not less than setting when the third judging result
When coefficient of determination value, determine that the electrode of the anode-cathode pair has short-circuit hidden danger.
8. the system of prediction electric pole short circuit according to claim 7, which is characterized in that the value added determining module, tool
Body includes：
Sequencing unit, for the multiple current value to be sorted by acquisition time, the electric current value sequence after being sorted；
Difference acquiring unit, for obtaining the difference in the electric current value sequence between the last one current value and first current value
Value；
Value added determination unit, for the difference to be determined as the value added that the multiple current value changes over time.
9. the system of prediction electric pole short circuit according to claim 7, which is characterized in that the system also includes：
Warning message generation module generates electrode after there is short-circuit hidden danger in the electrode for determining the anode-cathode pair
There are the warning messages of short-circuit hidden danger, to remind staff to handle.
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810214300.8A CN108445344B (en) | 2018-03-15 | 2018-03-15 | Method and system for predicting electrode short circuit based on current |
| AU2018353937A AU2018353937B2 (en) | 2018-03-15 | 2018-06-27 | Method and system for predicting electrode short circuit based on current |
| US16/461,233 US20200284851A1 (en) | 2018-03-15 | 2018-06-27 | Method and system for predicting electrode short circuit based on current |
| PCT/CN2018/093015 WO2019174152A1 (en) | 2018-03-15 | 2018-06-27 | Current-based electrode short circuit prediction method and system |
| CL2019001848A CL2019001848A1 (en) | 2018-03-15 | 2019-07-04 | Procedure and system for predicting an electrode short circuit based on current. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810214300.8A CN108445344B (en) | 2018-03-15 | 2018-03-15 | Method and system for predicting electrode short circuit based on current |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108445344A true CN108445344A (en) | 2018-08-24 |
| CN108445344B CN108445344B (en) | 2019-02-22 |
Family
ID=63194507
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810214300.8A Active CN108445344B (en) | 2018-03-15 | 2018-03-15 | Method and system for predicting electrode short circuit based on current |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20200284851A1 (en) |
| CN (1) | CN108445344B (en) |
| AU (1) | AU2018353937B2 (en) |
| CL (1) | CL2019001848A1 (en) |
| WO (1) | WO2019174152A1 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109055999A (en) * | 2018-09-04 | 2018-12-21 | 北方工业大学 | Method and system for rapidly judging short circuit of electrode based on temperature |
| CN109457276A (en) * | 2019-01-22 | 2019-03-12 | 北方工业大学 | Electrode short circuit detection method and system |
| CN109541370A (en) * | 2018-11-16 | 2019-03-29 | 北方工业大学 | Method and system for detecting cathode short circuit according to voltage drop |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117737815A (en) * | 2024-02-21 | 2024-03-22 | 山东裕能电力器材有限公司 | Intelligent operation quality early warning system suitable for electroplating bath impurity removal device |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1516753A (en) * | 2001-06-25 | 2004-07-28 | ���п�ķ�����Ϲɷݹ�˾ | Method for improvement of current efficiency in electrolysis |
| CN1841056A (en) * | 2005-03-30 | 2006-10-04 | 日本特殊陶业株式会社 | Gas detection apparatus, gas-sensor control circuit used for gas detection apparatus, and inspection method for gas detection apparatus |
| CN201083802Y (en) * | 2007-10-12 | 2008-07-09 | 新源动力股份有限公司 | Proton exchange film fuel battery film electrode short circuit detection device |
| US20120304771A1 (en) * | 2011-06-06 | 2012-12-06 | Hitachi, Ltd. | Inspection Apparatus and Inspection Method for Lithium Ion Secondary Battery, and Secondary Battery Module |
| CN106312216A (en) * | 2016-10-21 | 2017-01-11 | 清华大学 | Method for short-circuit detection of workpiece in electrolytic machining process |
| CN205941831U (en) * | 2016-06-23 | 2017-02-08 | 深圳市维都利电子有限公司 | Lithium cell electrode short circuit test device |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101131410B (en) * | 2007-10-12 | 2010-07-28 | 新源动力股份有限公司 | Film electrode short detecting device for fuel batter with proton exchange film and detecting method thereof |
| CN101957398B (en) * | 2010-09-16 | 2012-11-28 | 河北省电力研究院 | Method for detecting and calculating primary time constant of power grid based on electromechanical and electromagnetic transient hybrid simulation technology |
| IL239852A (en) * | 2015-07-08 | 2016-12-29 | Algolion Ltd | Lithium-ion battery safety monitoring |
-
2018
- 2018-03-15 CN CN201810214300.8A patent/CN108445344B/en active Active
- 2018-06-27 US US16/461,233 patent/US20200284851A1/en not_active Abandoned
- 2018-06-27 WO PCT/CN2018/093015 patent/WO2019174152A1/en active Application Filing
- 2018-06-27 AU AU2018353937A patent/AU2018353937B2/en not_active Ceased
-
2019
- 2019-07-04 CL CL2019001848A patent/CL2019001848A1/en unknown
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1516753A (en) * | 2001-06-25 | 2004-07-28 | ���п�ķ�����Ϲɷݹ�˾ | Method for improvement of current efficiency in electrolysis |
| CN1841056A (en) * | 2005-03-30 | 2006-10-04 | 日本特殊陶业株式会社 | Gas detection apparatus, gas-sensor control circuit used for gas detection apparatus, and inspection method for gas detection apparatus |
| CN201083802Y (en) * | 2007-10-12 | 2008-07-09 | 新源动力股份有限公司 | Proton exchange film fuel battery film electrode short circuit detection device |
| US20120304771A1 (en) * | 2011-06-06 | 2012-12-06 | Hitachi, Ltd. | Inspection Apparatus and Inspection Method for Lithium Ion Secondary Battery, and Secondary Battery Module |
| CN205941831U (en) * | 2016-06-23 | 2017-02-08 | 深圳市维都利电子有限公司 | Lithium cell electrode short circuit test device |
| CN106312216A (en) * | 2016-10-21 | 2017-01-11 | 清华大学 | Method for short-circuit detection of workpiece in electrolytic machining process |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109055999A (en) * | 2018-09-04 | 2018-12-21 | 北方工业大学 | Method and system for rapidly judging short circuit of electrode based on temperature |
| CN109055999B (en) * | 2018-09-04 | 2019-09-24 | 北方工业大学 | Method and system for rapidly judging short circuit of electrode based on temperature |
| CN109541370A (en) * | 2018-11-16 | 2019-03-29 | 北方工业大学 | Method and system for detecting cathode short circuit according to voltage drop |
| CN109457276A (en) * | 2019-01-22 | 2019-03-12 | 北方工业大学 | Electrode short circuit detection method and system |
Also Published As
| Publication number | Publication date |
|---|---|
| AU2018353937B2 (en) | 2020-03-12 |
| AU2018353937A1 (en) | 2019-10-03 |
| US20200284851A1 (en) | 2020-09-10 |
| CL2019001848A1 (en) | 2019-10-18 |
| CN108445344B (en) | 2019-02-22 |
| WO2019174152A1 (en) | 2019-09-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108445344B (en) | Method and system for predicting electrode short circuit based on current | |
| CN106067560B (en) | The preparation method of internal short-circuit lithium-ion-power cell | |
| CN108411342B (en) | Method and system for predicting electrode short circuit based on pseudo resistance | |
| CN109055999B (en) | Method and system for rapidly judging short circuit of electrode based on temperature | |
| US10047449B2 (en) | Device and method for electrolytically coating an object | |
| JP2016515667A (en) | Electrolysis cell for electrowinning of metals | |
| CN108896856A (en) | Method and system for rapidly detecting cathode short circuit | |
| EA005178B1 (en) | Method for the improvement of current efficiency in electrolysis | |
| CN108254611B (en) | Electrode current measuring method and system | |
| CN109457276B (en) | Electrode short circuit detection method and system | |
| CN111203628B (en) | Welding detection method and welding equipment | |
| JP5114271B2 (en) | Around plating evaluation apparatus and evaluation method | |
| CN201962387U (en) | Anode effect predicting device for aluminum electrolytic cell | |
| McGinnity et al. | Development of a rapid measurement of current efficiency in the electrowinning of zinc | |
| CN109580757A (en) | A kind of method of concentration of metal ions in real time on-line monitoring anodic dissolution processes | |
| RU2626517C2 (en) | Systems and methods for prevention of thermal reactions in electrolysers | |
| CN112903794A (en) | Heavy metal analyzer and coating management method, device, equipment and medium thereof | |
| CN103898554B (en) | A kind of method and apparatus of quick elimination closing down magnesium electrolysis bath electric pole short circuit | |
| CN109799415B (en) | Method and system for judging cathode short circuit mode | |
| RU2009142104A (en) | METHOD FOR ELECTROLYTIC PRODUCTION OF METALS AT SIMULTANEOUS DEPOSITION OF IMPURITIES | |
| JPH0920989A (en) | Zinc electrolyzing method for controlling pb grade in electrolytic zing by using automatic pb analyzer | |
| CN109541370A (en) | Method and system for detecting cathode short circuit according to voltage drop | |
| CN116716622B (en) | Fluorine gas preparation method and system based on electrolysis conditions | |
| RU2004114855A (en) | METHOD FOR REGULATING THE ELECTROLYZER FOR PRODUCING ALUMINUM | |
| JP3371443B2 (en) | Short circuit detection method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |