CN108442570B - Solid-liquid phase change composite material - Google Patents

Solid-liquid phase change composite material Download PDF

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Publication number
CN108442570B
CN108442570B CN201810549851.XA CN201810549851A CN108442570B CN 108442570 B CN108442570 B CN 108442570B CN 201810549851 A CN201810549851 A CN 201810549851A CN 108442570 B CN108442570 B CN 108442570B
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infrared
phase change
change layer
layer
reflection
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CN108442570A (en
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柯秀芳
何淋
马晓震
柯勇
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Guangdong University of Technology
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Guangdong University of Technology
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    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B2/00Walls, e.g. partitions, for buildings; Wall construction with regard to insulation; Connections specially adapted to walls
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/02Materials undergoing a change of physical state when used
    • C09K5/06Materials undergoing a change of physical state when used the change of state being from liquid to solid or vice versa
    • C09K5/063Materials absorbing or liberating heat during crystallisation; Heat storage materials
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62Insulation or other protection; Elements or use of specified material therefor
    • E04B1/74Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
    • E04B1/76Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
    • E04B1/78Heat insulating elements
    • E04B1/80Heat insulating elements slab-shaped

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  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Electromagnetism (AREA)
  • Structural Engineering (AREA)
  • Civil Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Thermal Sciences (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Acoustics & Sound (AREA)
  • Laminated Bodies (AREA)

Abstract

The solid-liquid phase change composite material provided by the invention has better thermal inertia, is more suitable for building enclosure structures, and requires lower energy consumption. In practical application, the infrared reflection intensity in the infrared gradient reflection phase-change layer changes in a gradient manner, a glass layer which is compounded with one side of the infrared gradient reflection phase-change layer with high infrared reflection intensity is arranged at the outermost side of a building and firstly receives insolation, and a part of the infrared gradient reflection phase-change layer with high infrared reflection intensity can reflect most infrared rays and gradually reduce the temperature from the outer side to the inner side, so that the infrared gradient reflection phase-change layer can reflect infrared rays to the greatest extent while consuming infrared reflection materials, further the thermal inertia of solid-liquid phase-change materials is improved, and the infrared gradient reflection phase-change layer is more suitable for building envelope structures.

Description

Solid-liquid phase change composite material
Technical Field
The invention relates to the technical field of building materials, in particular to a solid-liquid phase-change composite material.
Background
Phase change material (PCM-Phase Change Material) refers to a substance that changes state of a substance with a change in temperature and can provide latent heat. The process of transforming physical properties is known as the phase change process, where the phase change material will absorb or release a significant amount of latent heat. The phase change material may be classified as a hydrated salt phase change material such as CaCl 2 ·6H 2 O and waxy phase change materials such as paraffin have wide application in building energy conservation, one important aspect is an enclosure structure for buildings in a passive mode, such as walls, windows, floors, roofs, concrete, brick members and the like, and the O and waxy phase change materials have the effects of enhancing the heat capacity of the building enclosure, improving the heat inertia of the building, reducing the energy consumption of refrigerating or heating the building, being beneficial to improving the heat comfort of the indoor environment of the building and realizing the zero energy consumption of the building.
At present, the thermal inertia of the phase change material applied to the building industry is not satisfactory, the liquid phase change material absorbs more solar radiation, overheat is easy to form, the consumed energy is high, and therefore, the development of the phase change material with better thermal inertia and lower solar radiation absorption is very interesting.
Disclosure of Invention
In view of the above, the technical problem to be solved by the present invention is to provide a solid-liquid phase-change composite material, which has better thermal inertia and lower energy consumption.
The invention provides a solid-liquid phase-change composite material, which comprises the following components:
a first glass layer;
an infrared gradient reflection phase change layer compounded on the first glass layer;
and the second glass layer is compounded on the infrared gradient reflection phase change layer.
Preferably, the infrared gradient reflection phase change layer includes:
a first infrared reflective phase change layer composited on the first glass layer;
a second infrared reflective phase change layer composited on the first infrared reflective phase change layer;
a third infrared reflective phase change layer composited on the second infrared reflective phase change layer;
a fourth infrared reflective phase change layer composited on the third infrared reflective phase change layer;
a fifth infrared reflective phase change layer compounded on the fourth infrared reflective phase change layer, the second glass layer being compounded on the fifth infrared reflective phase change layer;
the infrared reflection intensities of the first infrared reflection phase-change layer, the second infrared reflection phase-change layer, the third infrared reflection phase-change layer, the fourth infrared reflection phase-change layer and the fifth infrared reflection phase-change layer are gradually decreased in a gradient mode.
Preferably, the method comprises the steps of,
the thickness of the first infrared reflection phase-change layer is 2-3 mm;
the thickness of the second infrared reflection phase-change layer is 1-2 mm;
the thickness of the third infrared reflection phase-change layer is 1-2 mm;
the thickness of the fourth infrared reflection phase-change layer is 1-2 mm;
the thickness of the fifth infrared reflection phase-change layer is 1-2 mm.
Preferably, the thickness of the first glass layer is 3-5 mm.
Preferably, the thickness of the infrared gradient reflection phase-change layer is 6-11 mm.
Preferably, the thickness of the second glass layer is 3-5 mm.
The invention provides a solid-liquid phase-change composite material, which comprises the following components:
a first glass layer;
an infrared gradient reflection phase change layer compounded on the first glass layer;
and the second glass layer is compounded on the infrared gradient reflection phase change layer.
The solid-liquid phase change composite material provided by the invention has better thermal inertia, is more suitable for building enclosure structures, and has lower energy consumption. In practical application, the infrared reflection intensity in the infrared gradient reflection phase-change layer changes in a gradient manner, a glass layer or a resin layer which is compounded with one side of the infrared gradient reflection phase-change layer with high infrared reflection intensity is arranged at the outermost side of a building, insolation is firstly received, most of infrared rays can be reflected out from the part of the infrared gradient reflection phase-change layer with high infrared reflection intensity, and the temperature is gradually reduced from the outer side to the inner side, so that the infrared gradient reflection phase-change layer can reflect infrared rays to the greatest extent while consuming infrared reflection materials, further the thermal inertia of solid-liquid phase-change materials is improved, and the infrared gradient reflection phase-change layer is more suitable for building envelope structures.
Drawings
FIG. 1 is a schematic diagram of a solid-liquid phase-change composite material according to embodiment 1 of the present invention;
fig. 2 is a schematic structural diagram of a solid-liquid phase-change composite material according to embodiment 2 of the present invention.
Detailed Description
For a further understanding of the present invention, preferred embodiments of the invention are described below in conjunction with the examples, but it should be understood that these descriptions are merely intended to illustrate further features and advantages of the invention, and are not limiting of the claims of the invention.
The invention provides a solid-liquid phase-change composite material, which comprises the following components:
a first glass layer;
an infrared gradient reflection phase change layer compounded on the first glass layer;
and the second glass layer is compounded on the infrared gradient reflection phase change layer. Referring to fig. 1, fig. 1 is a schematic structural diagram of a solid-liquid phase-change composite material provided in embodiment 1 of the present invention.
The thickness of the first glass layer is preferably 3 to 5mm. In certain embodiments of the invention, the first glass layer has a thickness of 3mm.
The thickness of the infrared gradient reflection phase-change layer is preferably 6-11 mm. In certain embodiments of the present invention, the infrared gradient reflective phase change layer has a thickness of 6mm.
The infrared gradient reflective phase change layer preferably comprises:
a first infrared reflective phase change layer composited on the first glass layer;
a second infrared reflective phase change layer composited on the first infrared reflective phase change layer;
a third infrared reflective phase change layer composited on the second infrared reflective phase change layer;
a fourth infrared reflective phase change layer composited on the third infrared reflective phase change layer;
a fifth infrared reflective phase change layer compounded on the fourth infrared reflective phase change layer, the second glass layer being compounded on the fifth infrared reflective phase change layer;
the infrared reflection intensities of the first infrared reflection phase-change layer, the second infrared reflection phase-change layer, the third infrared reflection phase-change layer, the fourth infrared reflection phase-change layer and the fifth infrared reflection phase-change layer are gradually decreased in a gradient mode.
Referring to fig. 2, fig. 2 is a schematic structural diagram of a solid-liquid phase-change composite material provided in embodiment 2 of the present invention.
The thickness of the first infrared reflection phase change layer is preferably 2-3 mm. In certain embodiments of the present invention, the first infrared reflective phase change layer has a thickness of 2mm.
The first infrared reflective phase change layer is preferably a hybrid layer comprising a solid-liquid phase change material and an infrared reflective material. In the present invention, the solid-liquid phase change material preferably includes one or more of a hydrated salt phase change material and a waxy phase change material. In certain embodiments of the present invention, the solid-liquid phase-change material is CaCl 2 ·6H 2 O, paraffin, stearic acid or lauric acid. The infrared reflecting material is preferably In (Sn) 2 O 3 (ITO) or TiO 2 . The content of the infrared reflection material in the first infrared reflection phase change layer is preferably 1 to 20wt%. In certain embodiments of the present invention, the infrared reflective material is present in the first infrared reflective phase change layer in an amount of 20 weight%.
The thickness of the second infrared reflection phase change layer is preferably 1-2 mm. In certain embodiments of the present invention, the second infrared reflective phase change layer has a thickness of 1mm.
The materials and components of the second ir reflecting phase-change layer are preferably the same as those of the first ir reflecting phase-change layer, and will not be described herein. The content of the infrared reflection material in the second infrared reflection phase change layer is preferably 1 to 20wt%. In certain embodiments of the present invention, the second infrared reflective phase change layer has a content of 16 weight percent of the infrared reflective material.
The thickness of the third infrared reflection phase change layer is preferably 1-2 mm. In certain embodiments of the present invention, the thickness of the third infrared reflective phase change layer is 1mm.
The materials and components of the third ir reflecting phase change layer are preferably the same as those of the first ir reflecting phase change layer, and will not be described herein. The content of the infrared reflection material in the third infrared reflection phase change layer is preferably 1 to 20wt%. In certain embodiments of the present invention, the infrared-reflective material is present in the third infrared-reflective phase change layer in an amount of 12 weight%.
The thickness of the fourth infrared reflection phase-change layer is preferably 1-2 mm. In certain embodiments of the present invention, the fourth infrared reflective phase change layer has a thickness of 1mm.
The materials and components of the fourth ir reflecting phase-change layer are preferably the same as those of the first ir reflecting phase-change layer, and will not be described herein. In the fourth infrared reflection phase change layer, the content of the infrared reflection material is preferably 1 to 20wt%. In certain embodiments of the present invention, the infrared-reflective material is present in the fourth infrared-reflective phase change layer in an amount of 8 weight%.
The thickness of the fifth infrared reflection phase-change layer is preferably 1-2 mm. In certain embodiments of the present invention, the thickness of the fifth infrared reflective phase change layer is 1mm.
The materials and components of the fifth ir reflecting phase-change layer are preferably the same as those of the first ir reflecting phase-change layer, and will not be described herein. In the fifth infrared reflection phase change layer, the content of the infrared reflection material is preferably 1 to 20wt%. In certain embodiments of the present invention, the infrared reflective material is present in the fifth infrared reflective phase change layer in an amount of 4 weight%.
The thickness of the second glass layer is preferably 3 to 5mm. In certain embodiments of the invention, the second glass layer has a thickness of 3mm.
In the invention, the solid-liquid phase-change composite material is preferably prepared according to the following method:
a) Coating a first infrared reflection phase change material on the first glass layer, and forming a first infrared reflection phase change layer after curing;
b) Coating the second infrared reflection phase change material on the first infrared reflection phase change layer, and forming a second infrared reflection phase change layer after curing;
c) Coating the third infrared reflection phase change material on the second infrared reflection phase change layer, and forming a third infrared reflection phase change layer after curing;
d) Coating the fourth infrared reflection phase change material on the third infrared reflection phase change layer, and forming a fourth infrared reflection phase change layer after curing;
e) And coating the fifth infrared reflection phase change material on the fourth infrared reflection phase change layer, coating a second glass layer on the fifth infrared reflection phase change material, and curing to form a fifth infrared reflection phase change layer, thereby obtaining the solid-liquid phase-change composite material.
The materials and components of the first infrared reflection phase-change layer, the second infrared reflection phase-change layer, the third infrared reflection phase-change layer, the fourth infrared reflection phase-change layer and the fifth infrared reflection phase-change layer are the same, and are not described in detail herein.
The method for preparing the first infrared reflection phase change material is not particularly limited, and the method for preparing the infrared reflection phase change material well known to those skilled in the art can be adopted. The present invention preferably prepares the first infrared reflective phase change material according to the following method:
mixing the solid-liquid phase change material, the infrared reflection material and the dispersing agent, and grinding to obtain the first infrared reflection phase change material.
The infrared reflecting material is preferably an infrared reflecting material with a particle size of 20-50 nm. In certain embodiments of the present application, the infrared reflective material is an infrared reflective material having a particle size of 20 nm.
The dispersant is preferably dispersant PE. The content of the infrared reflecting material in the obtained first infrared reflecting phase change layer is preferably 1 to 20wt%. In certain embodiments of the present invention, the infrared reflective material is present in the first infrared reflective phase change layer in an amount of 20 weight%.
The method of polishing is not particularly limited, and polishing methods known to those skilled in the art may be employed. The particle size after grinding is not particularly limited, and may be any particle size known to those skilled in the art.
The method for preparing the second infrared reflection phase change material is not particularly limited, and the method for preparing the infrared reflection phase change material well known to those skilled in the art can be adopted. The present invention preferably prepares the second infrared reflective phase change material according to the following method:
mixing the solid-liquid phase change material, the infrared reflection material and the dispersing agent, and grinding to obtain the second infrared reflection phase change material.
The infrared reflecting material is preferably an infrared reflecting material with a particle size of 20-50 nm. In certain embodiments of the present application, the infrared reflective material is an infrared reflective material having a particle size of 20 nm. The dispersant is preferably dispersant PE. The content of the infrared reflecting material in the obtained second infrared reflecting phase change layer is preferably 1 to 20wt%. In certain embodiments of the present invention, the second infrared reflective phase change layer has a content of 16 weight percent of the infrared reflective material.
The method of polishing is not particularly limited, and polishing methods known to those skilled in the art may be employed. The particle size after grinding is not particularly limited, and may be any particle size known to those skilled in the art.
The method for preparing the third infrared reflection phase change material is not particularly limited, and the method for preparing the infrared reflection phase change material well known to those skilled in the art can be adopted. The present invention preferably prepares the third infrared reflective phase change material according to the following method:
mixing the solid-liquid phase change material, the infrared reflection material and the dispersing agent, and grinding to obtain the third infrared reflection phase change material.
The infrared reflecting material is preferably an infrared reflecting material with a particle size of 20-50 nm. In certain embodiments of the present application, the infrared reflective material is an infrared reflective material having a particle size of 20 nm. The dispersant is preferably dispersant PE. The content of the infrared reflecting material in the obtained third infrared reflecting phase change layer is preferably 1 to 20wt%. In certain embodiments of the present invention, the infrared-reflective material is present in the third infrared-reflective phase change layer in an amount of 12 weight%.
The method of polishing is not particularly limited, and polishing methods known to those skilled in the art may be employed. The particle size after grinding is not particularly limited, and may be any particle size known to those skilled in the art.
The method for preparing the fourth infrared reflection phase change material is not particularly limited, and the method for preparing the infrared reflection phase change material well known to those skilled in the art can be adopted. The present invention preferably prepares the fourth infrared reflective phase change material according to the following method:
mixing the solid-liquid phase change material, the infrared reflection material and the dispersing agent, and grinding to obtain the fourth infrared reflection phase change material.
The infrared reflecting material is preferably an infrared reflecting material with a particle size of 20-50 nm. In certain embodiments of the present application, the infrared reflective material is an infrared reflective material having a particle size of 20 nm. The dispersant is preferably dispersant PE. The content of the infrared reflecting material in the obtained fourth infrared reflecting phase change layer is preferably 1 to 20wt%. In certain embodiments of the present invention, the infrared-reflective material is present in the fourth infrared-reflective phase change layer in an amount of 8 weight%.
The method of polishing is not particularly limited, and polishing methods known to those skilled in the art may be employed. The particle size after grinding is not particularly limited, and may be any particle size known to those skilled in the art.
The method for preparing the fifth infrared reflection phase change material is not particularly limited, and the method for preparing the infrared reflection phase change material well known to those skilled in the art can be adopted. The present invention preferably prepares the fifth infrared reflective phase change material according to the following method:
mixing the solid-liquid phase change material, the infrared reflection material and the dispersing agent, and grinding to obtain the fifth infrared reflection phase change material.
The infrared reflecting material is preferably an infrared reflecting material with a particle size of 20-50 nm. In certain embodiments of the present application, the infrared reflective material is an infrared reflective material having a particle size of 20 nm. The dispersant is preferably dispersant PE. The content of the infrared reflecting material in the obtained fifth infrared reflecting phase change layer is preferably 1 to 20wt%. In certain embodiments of the present invention, the infrared reflective material is present in the fifth infrared reflective phase change layer in an amount of 4 weight%.
The method of polishing is not particularly limited, and polishing methods known to those skilled in the art may be employed. The particle size after grinding is not particularly limited, and may be any particle size known to those skilled in the art.
The solid-liquid phase change composite material prepared by the invention is heated until the infrared phase change material is melted to be in a liquid phase for experiments. Experimental results show that the temperature of the liquid phase of the solid-liquid phase change composite material prepared by the method is 5-7% lower than that of the composite material without the infrared gradient reflection phase change layer.
The solid-liquid phase change composite material provided by the invention has better thermal inertia, is more suitable for building enclosure structures, and has lower energy consumption. In practical application, the infrared reflection intensity in the infrared gradient reflection phase-change layer changes in a gradient manner, a glass layer or a resin layer which is compounded with one side of the infrared gradient reflection phase-change layer with high infrared reflection intensity is arranged at the outermost side of a building, insolation is firstly received, most of infrared rays can be reflected out from the part of the infrared gradient reflection phase-change layer with high infrared reflection intensity, and the temperature is gradually reduced from the outer side to the inner side, so that the infrared gradient reflection phase-change layer can reflect infrared rays to the greatest extent while consuming infrared reflection materials, further the thermal inertia of solid-liquid phase-change materials is improved, and the infrared gradient reflection phase-change layer is more suitable for building envelope structures.
The above description of the embodiments is only for aiding in the understanding of the method of the present invention and its core ideas. It should be noted that it will be apparent to those skilled in the art that various modifications and adaptations of the invention can be made without departing from the principles of the invention and these modifications and adaptations are intended to be within the scope of the invention as defined in the following claims.

Claims (5)

1. A solid-liquid phase composite comprising:
a first glass layer;
an infrared gradient reflection phase change layer compounded on the first glass layer;
a second glass layer composited on the infrared gradient reflection phase change layer;
the infrared gradient reflection phase change layer includes:
a first infrared reflective phase change layer composited on the first glass layer;
a second infrared reflective phase change layer composited on the first infrared reflective phase change layer;
a third infrared reflective phase change layer composited on the second infrared reflective phase change layer;
a fourth infrared reflective phase change layer composited on the third infrared reflective phase change layer;
a fifth infrared reflective phase change layer compounded on the fourth infrared reflective phase change layer, the second glass layer being compounded on the fifth infrared reflective phase change layer;
the first infrared reflection phase change layer, the second infrared reflection phase change layer, the third infrared reflection phase change layer, the fourth infrared reflection phase change layer and the fifth infrared reflection phase change layer are all mixed layers formed by solid-liquid phase change materials and infrared reflection materials, and the infrared reflection intensity sequentially decreases in a gradient manner;
the solid-liquid phase change material is CaCl 2 ·6H 2 O, paraffin, stearic acid or lauric acid; the infrared reflecting material is ITO or TiO 2
2. The solid-liquid phase-change composite material according to claim 1, wherein,
the thickness of the first infrared reflection phase change layer is 2-3 mm;
the thickness of the second infrared reflection phase change layer is 1-2 mm;
the thickness of the third infrared reflection phase change layer is 1-2 mm;
the thickness of the fourth infrared reflection phase change layer is 1-2 mm;
the thickness of the fifth infrared reflection phase-change layer is 1-2 mm.
3. The solid-liquid phase-change composite material according to claim 1, wherein the thickness of the first glass layer is 3-5 mm.
4. The solid-liquid phase-change composite material according to claim 1, wherein the thickness of the infrared gradient reflection phase-change layer is 6-11 mm.
5. The solid-liquid phase-change composite material according to claim 1, wherein the thickness of the second glass layer is 3-5 mm.
CN201810549851.XA 2018-05-31 2018-05-31 Solid-liquid phase change composite material Active CN108442570B (en)

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CN110130791A (en) * 2019-05-29 2019-08-16 广东工业大学 A kind of high reflecting glass window

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CN102757185A (en) * 2012-07-26 2012-10-31 福耀玻璃工业集团股份有限公司 Low-radiation heat-treatable coated glass and interlayer glass product thereof
CN204020142U (en) * 2014-08-14 2014-12-17 宁波浙铁大风化工有限公司 A kind of intelligent glass of automatic temperature-control
CN204138748U (en) * 2014-04-03 2015-02-04 周少波 Inversion of phases vanadium dioxide film structure
CN105041136A (en) * 2015-07-28 2015-11-11 东南大学 Glass window with double sandwich layers and phase-change materials
CN105372847A (en) * 2015-11-13 2016-03-02 北汽福田汽车股份有限公司 Light-adjusting thin film, glasses having same and optical window
CN105366955A (en) * 2015-11-13 2016-03-02 北汽福田汽车股份有限公司 Temperature regulating glass and automotive
CN106082711A (en) * 2016-06-02 2016-11-09 中国科学院广州能源研究所 A kind of energy-conservation laminated glass of intelligent dimming and preparation method thereof
CN208733852U (en) * 2018-05-31 2019-04-12 广东工业大学 A kind of solid-liquid phase change composite material

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0036657A2 (en) * 1980-03-25 1981-09-30 Ardco, Inc. Infrared reflective, visible light transparent windows
CN102757185A (en) * 2012-07-26 2012-10-31 福耀玻璃工业集团股份有限公司 Low-radiation heat-treatable coated glass and interlayer glass product thereof
CN204138748U (en) * 2014-04-03 2015-02-04 周少波 Inversion of phases vanadium dioxide film structure
CN204020142U (en) * 2014-08-14 2014-12-17 宁波浙铁大风化工有限公司 A kind of intelligent glass of automatic temperature-control
CN105041136A (en) * 2015-07-28 2015-11-11 东南大学 Glass window with double sandwich layers and phase-change materials
CN105372847A (en) * 2015-11-13 2016-03-02 北汽福田汽车股份有限公司 Light-adjusting thin film, glasses having same and optical window
CN105366955A (en) * 2015-11-13 2016-03-02 北汽福田汽车股份有限公司 Temperature regulating glass and automotive
CN106082711A (en) * 2016-06-02 2016-11-09 中国科学院广州能源研究所 A kind of energy-conservation laminated glass of intelligent dimming and preparation method thereof
CN208733852U (en) * 2018-05-31 2019-04-12 广东工业大学 A kind of solid-liquid phase change composite material

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