CN108442116A - The preparation method of high stable polyester fabric antistatic agent - Google Patents
The preparation method of high stable polyester fabric antistatic agent Download PDFInfo
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- CN108442116A CN108442116A CN201810230097.3A CN201810230097A CN108442116A CN 108442116 A CN108442116 A CN 108442116A CN 201810230097 A CN201810230097 A CN 201810230097A CN 108442116 A CN108442116 A CN 108442116A
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- antistatic agent
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
- D06M13/148—Polyalcohols, e.g. glycerol or glucose
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/2243—Mono-, di-, or triglycerides
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses the preparation method of high stable polyester fabric antistatic agent, method includes：Propylene glycol and ethyl alcohol are added into reaction kettle, heat temperature raising, and open reflux；Butanol phosphate, stearic acid, polyurethane and dimethyl terephthalate (DMT) are added into reaction kettle, turn on agitator, and heated up simultaneously；Reaction kettle is cooled to room temperature, nitrogen is passed through, in an inert atmosphere, diethanol amine and surfactant is added, stirring obtains antistatic agent.A kind of high stable polyester fabric antistatic agent of the present invention, antistatic agent has very high stability, is applied when on polyester fabric, and polyester fabric has very high antistatic property, it is not easy to charge, it can prevent fabric from adsorbing dust, and in the specific occasion of antistatic, can be applied well, and stability is very high, comprehensive performance is superior, and preparation method is simple, of low cost.
Description
Technical field
The present invention relates to antistatic agent field more particularly to the preparation methods of high stable polyester fabric antistatic agent.
Background technology
Electrostatic is shifted by the influence of various external force by the electronics of atoms outermost, is respectively formed negative ions and is caused
's.
The intensity of polyester fiber is nearly 1 times higher than cotton, 3 times higher than wool, therefore dacron is durable.And it can also be
70~170 DEG C of uses, are that heat resistance and thermal stability are best in synthetic fibers.For the elasticity of terylene close to wool, crease resistance is super
Other fibers are crossed, fabric does not wrinkle, and conformality is good.
But terylene is made as fabric, terylene is very easy to generate electrostatic, especially in autumn and winter.One denier fabric
Electrification, very more will be attracted on clothes so that clothes is very dirty due to electrostatic interaction very much.And electrostatic may
Cause the harm such as fire, and explosion.Although also having antistatic agent on the market now, effect is not satisfactory, antistatic
Performance is poor.
Invention content
In view of this, the present invention provides the preparation methods of high stable polyester fabric antistatic agent.
The preparation method of high stable polyester fabric antistatic agent, method include：
Propylene glycol and ethyl alcohol are added into reaction kettle, are heated to 60-70 DEG C, and opens reflux；
Butanol phosphate, stearic acid, polyurethane and dimethyl terephthalate (DMT) are added into reaction kettle, stirring is opened
Device, mixing speed 120-180r/min, and heat up simultaneously, it is warming up to 140-160 DEG C, reacts 20-40min；
Reaction kettle is cooled to room temperature, nitrogen is passed through, in an inert atmosphere, diethanol amine and surfactant is added,
5-10min is stirred, antistatic agent is obtained.
Preferably, the method is：
Propylene glycol and ethyl alcohol are added into reaction kettle, are heated to 63-67 DEG C, and opens reflux；
Butanol phosphate, stearic acid, polyurethane and dimethyl terephthalate (DMT) are added into reaction kettle, stirring is opened
Device, mixing speed 130-170r/min, and heat up simultaneously, it is warming up to 145-155 DEG C, reacts 26-34min；
Reaction kettle is cooled to room temperature, nitrogen is passed through, in an inert atmosphere, diethanol amine and surfactant is added,
6-9min is stirred, antistatic agent is obtained.
Preferably, the method is：
Propylene glycol and ethyl alcohol are added into reaction kettle, are heated to 65 DEG C, and opens reflux；
Butanol phosphate, stearic acid, polyurethane and dimethyl terephthalate (DMT) are added into reaction kettle, stirring is opened
Device, mixing speed 150r/min, and heat up simultaneously, 148 DEG C are warming up to, 31min is reacted；
Reaction kettle is cooled to room temperature, nitrogen is passed through, in an inert atmosphere, diethanol amine and surfactant is added,
8min is stirred, antistatic agent is obtained.
Preferably, the method further includes：Accurately weigh butanol phosphate, stearic acid, propylene glycol, ethyl alcohol, terephthaldehyde
Dimethyl phthalate, diethanol amine, polyurethane and surfactant.
Preferably, the surfactant is fatty alcohol polyoxyethylene ether ammonium sulfate.
A kind of high stable polyester fabric antistatic agent of the present invention, antistatic agent has very high stability, by it
It applies when on polyester fabric, polyester fabric has very high antistatic property, it is not easy to charge, can prevent fabric from adsorbing
Dust, and in the specific occasion of antistatic, can be applied well, and stability is very high, comprehensive performance is superior, and
Preparation method is simple, of low cost.
Specific implementation mode
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described,
Obviously, described embodiments are some of the embodiments of the present invention, instead of all the embodiments.Based on the implementation in the present invention
Example, every other embodiment obtained by those of ordinary skill in the art without making creative efforts belong to
The scope of protection of the invention.
It should be appreciated that ought use in this specification and in the appended claims, term " comprising " and "comprising" instruction
Described feature, entirety, step, operation, the presence of element and/or component, but one or more of the other feature, whole is not precluded
Body, step, operation, element, component and/or its presence or addition gathered.
It will be further appreciated that the term "and/or" used in description of the invention and the appended claims is
Refer to any combinations and all possible combinations of one or more of associated item listed, and includes these combinations.
Embodiment 1
High stable polyester fabric antistatic agent, antistatic agent are by quality component：
Preparation method is：
Accurately weigh butanol phosphate, stearic acid, propylene glycol, ethyl alcohol, dimethyl terephthalate (DMT), diethanol amine, poly- ammonia
Ester and sodium sulfate of polyethenoxy ether of fatty alcohol；
Propylene glycol and ethyl alcohol are added into reaction kettle, are heated to 60 DEG C, and opens reflux；
Butanol phosphate, stearic acid, polyurethane and dimethyl terephthalate (DMT) are added into reaction kettle, stirring is opened
Device, mixing speed 180r/min, and heat up simultaneously, 160 DEG C are warming up to, 20min is reacted；
Reaction kettle is cooled to room temperature, nitrogen is passed through, in an inert atmosphere, diethanol amine and fatty alcohol polyoxy second is added
Alkene ether sodium sulfate stirs 5min, obtains antistatic agent.
A kind of anti-electrostatic polyester fabric, wherein dye dosage antistatic agent content are 0.04.
Embodiment 2
High stable polyester fabric antistatic agent, antistatic agent are by quality component：
Preparation method is：
Accurately weigh butanol phosphate, stearic acid, propylene glycol, ethyl alcohol, dimethyl terephthalate (DMT), diethanol amine, poly- ammonia
Ester and fatty alcohol polyoxyethylene ether ammonium sulfate；
Propylene glycol and ethyl alcohol are added into reaction kettle, are heated to 63 DEG C, and opens reflux；
Butanol phosphate, stearic acid, polyurethane and dimethyl terephthalate (DMT) are added into reaction kettle, stirring is opened
Device, mixing speed 170r/min, and heat up simultaneously, 145 DEG C are warming up to, 34min is reacted；
Reaction kettle is cooled to room temperature, nitrogen is passed through, in an inert atmosphere, diethanol amine and fatty alcohol polyoxy second is added
Alkene ether ammonium sulfate stirs 6min, obtains antistatic agent.
A kind of anti-electrostatic polyester fabric, wherein dye dosage antistatic agent content are 0.035.
Embodiment 3
High stable polyester fabric antistatic agent, antistatic agent are by quality component：
Preparation method is：
Accurately weigh butanol phosphate, stearic acid, propylene glycol, ethyl alcohol, dimethyl terephthalate (DMT), diethanol amine, poly- ammonia
Ester and sldium lauryl sulfate；
Propylene glycol and ethyl alcohol are added into reaction kettle, are heated to 70 DEG C, and opens reflux；
Butanol phosphate, stearic acid, polyurethane and dimethyl terephthalate (DMT) are added into reaction kettle, stirring is opened
Device, mixing speed 120r/min, and heat up simultaneously, 140 DEG C are warming up to, 40min is reacted；
Reaction kettle is cooled to room temperature, nitrogen is passed through, in an inert atmosphere, diethanol amine and laruyl alcohol sulfuric acid is added
Sodium stirs 10min, obtains antistatic agent.
A kind of anti-electrostatic polyester fabric, wherein dye dosage antistatic agent content are 0.02.
Embodiment 4
High stable polyester fabric antistatic agent, antistatic agent are by quality component：
Preparation method is：
Accurately weigh butanol phosphate, stearic acid, propylene glycol, ethyl alcohol, dimethyl terephthalate (DMT), diethanol amine, poly- ammonia
Ester and fatty alcohol polyoxyethylene ether ammonium sulfate；
Propylene glycol and ethyl alcohol are added into reaction kettle, are heated to 67 DEG C, and opens reflux；
Butanol phosphate, stearic acid, polyurethane and dimethyl terephthalate (DMT) are added into reaction kettle, stirring is opened
Device, mixing speed 130r/min, and heat up simultaneously, 155 DEG C are warming up to, 26min is reacted；
Reaction kettle is cooled to room temperature, nitrogen is passed through, in an inert atmosphere, diethanol amine and fatty alcohol polyoxy second is added
Alkene ether ammonium sulfate stirs 6-9min, obtains antistatic agent.
A kind of anti-electrostatic polyester fabric, wherein dye dosage antistatic agent content are 0.025.
Embodiment 5
High stable polyester fabric antistatic agent, antistatic agent are by quality component：
Preparation method is：
Accurately weigh butanol phosphate, stearic acid, propylene glycol, ethyl alcohol, dimethyl terephthalate (DMT), diethanol amine, poly- ammonia
Ester and sldium lauryl sulfate；
Propylene glycol and ethyl alcohol are added into reaction kettle, are heated to 65 DEG C, and opens reflux；
Butanol phosphate, stearic acid, polyurethane and dimethyl terephthalate (DMT) are added into reaction kettle, stirring is opened
Device, mixing speed 150r/min, and heat up simultaneously, 148 DEG C are warming up to, 31min is reacted；
Reaction kettle is cooled to room temperature, nitrogen is passed through, in an inert atmosphere, diethanol amine and laruyl alcohol sulfuric acid is added
Sodium stirs 8min, obtains antistatic agent.
A kind of anti-electrostatic polyester fabric, wherein dye dosage antistatic agent content are 0.03.
Antistatic agent prepared by the preparation method of embodiment 1 to 5 is applied to polyester fabric, measures its antistatic property, ties
Fruit is as follows：
By counting table above, it can be seen that surface specific resistance average out to 8.5 × 109Ω cm or less, surface charge density are flat
It is 4uc/cm2Below, electrostatic half-life average out to 1s is hereinafter, have very strong resistance to voltage.It can prevent fabric from adsorbing
Dust, and in the specific occasion of antistatic, can be applied well.
The steps in the embodiment of the present invention can be sequentially adjusted, merged and deleted according to actual needs.
It is described in detail herein, applies specific case and the principle of the present invention and embodiment are explained
It states, above example is merely used to help understand the method and its core concept of the present invention；Meanwhile for the general skill of this field
Art personnel, according to the thought of the present invention, there will be changes in the specific implementation manner and application range, in conclusion this
Description should not be construed as limiting the invention.
Claims (5)
1. the preparation method of high stable polyester fabric antistatic agent, which is characterized in that method includes：
Propylene glycol and ethyl alcohol are added into reaction kettle, are heated to 60-70 DEG C, and opens reflux；
Butanol phosphate, stearic acid, polyurethane and dimethyl terephthalate (DMT) are added into reaction kettle, turn on agitator,
Mixing speed is 120-180r/min, and is heated up simultaneously, is warming up to 140-160 DEG C, reacts 20-40min；
Reaction kettle is cooled to room temperature, nitrogen is passed through, in an inert atmosphere, diethanol amine and surfactant, stirring is added
5-10min obtains antistatic agent.
2. preparation method as described in claim 1, which is characterized in that the method is：
Propylene glycol and ethyl alcohol are added into reaction kettle, are heated to 63-67 DEG C, and opens reflux；
Butanol phosphate, stearic acid, polyurethane and dimethyl terephthalate (DMT) are added into reaction kettle, turn on agitator,
Mixing speed is 130-170r/min, and is heated up simultaneously, is warming up to 145-155 DEG C, reacts 26-34min；
Reaction kettle is cooled to room temperature, nitrogen is passed through, in an inert atmosphere, diethanol amine and surfactant, stirring is added
6-9min obtains antistatic agent.
3. preparation method as claimed in claim 2, which is characterized in that the method is：
Propylene glycol and ethyl alcohol are added into reaction kettle, are heated to 65 DEG C, and opens reflux；
Butanol phosphate, stearic acid, polyurethane and dimethyl terephthalate (DMT) are added into reaction kettle, turn on agitator,
Mixing speed is 150r/min, and is heated up simultaneously, is warming up to 148 DEG C, reacts 31min；
Reaction kettle is cooled to room temperature, nitrogen is passed through, in an inert atmosphere, diethanol amine and surfactant, stirring is added
8min obtains antistatic agent.
4. preparation method as described in any one of claims 1-3, which is characterized in that the method further includes：Accurately weigh butanol
Phosphate, stearic acid, propylene glycol, ethyl alcohol, dimethyl terephthalate (DMT), diethanol amine, polyurethane and surfactant.
5. preparation method as described in any one of claims 1-3, it is characterised in that：The surfactant is fatty alcohol polyoxy second
Alkene ether ammonium sulfate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810230097.3A CN108442116A (en) | 2018-03-20 | 2018-03-20 | The preparation method of high stable polyester fabric antistatic agent |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810230097.3A CN108442116A (en) | 2018-03-20 | 2018-03-20 | The preparation method of high stable polyester fabric antistatic agent |
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| CN108442116A true CN108442116A (en) | 2018-08-24 |
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| CN201810230097.3A Withdrawn CN108442116A (en) | 2018-03-20 | 2018-03-20 | The preparation method of high stable polyester fabric antistatic agent |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114395921A (en) * | 2021-12-21 | 2022-04-26 | 太仓市隆纺油剂有限公司 | Preparation method of antistatic polyester low-stretch yarn oil agent |
-
2018
- 2018-03-20 CN CN201810230097.3A patent/CN108442116A/en not_active Withdrawn
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114395921A (en) * | 2021-12-21 | 2022-04-26 | 太仓市隆纺油剂有限公司 | Preparation method of antistatic polyester low-stretch yarn oil agent |
| CN114395921B (en) * | 2021-12-21 | 2024-01-30 | 太仓市隆纺油剂有限公司 | Preparation method of antistatic polyester low stretch yarn oiling agent |
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Application publication date: 20180824 |