CN108441792A - A kind of aluminium alloy and its heat treatment method - Google Patents

A kind of aluminium alloy and its heat treatment method Download PDF

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Publication number
CN108441792A
CN108441792A CN201810341266.0A CN201810341266A CN108441792A CN 108441792 A CN108441792 A CN 108441792A CN 201810341266 A CN201810341266 A CN 201810341266A CN 108441792 A CN108441792 A CN 108441792A
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aluminium alloy
heat treatment
temperature
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treatment method
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CN108441792B (en
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李凯
谢昭民
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Yiyang Instrument Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C49/00Alloys containing metallic or non-metallic fibres or filaments
    • C22C49/02Alloys containing metallic or non-metallic fibres or filaments characterised by the matrix material
    • C22C49/04Light metals
    • C22C49/06Aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C49/00Alloys containing metallic or non-metallic fibres or filaments
    • C22C49/14Alloys containing metallic or non-metallic fibres or filaments characterised by the fibres or filaments
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/002Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working by rapid cooling or quenching; cooling agents used therefor
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon

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  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

The invention discloses a kind of heat treatment methods of aluminium alloy, and according to mass percent meter, the aluminium alloy includes following components:Metallic fiber 8~10%, Mg5.5~7.2%, Zn 1.0~2.5%, Cu 0.8~1.8%, Sc 0.08~0.18%, Zr 0.08~0.18%, Y 0.12~0.22%, Si 0.02~0.07%, 0.01~0.03% Za Zhi≤0.15% of Mn 0.02~0.07%, Er 0.01~0.03%, Ce, surplus Al;Heat treatment step includes:S1, high-temperature heat treatment is carried out to aluminium alloy at 500~600 DEG C, is quenched using PAG quenching liquids after high-temperature heat treatment, obtains the aluminium alloy after high-temperature process;The content of PAG Type of Collective object is 15~60wt% in PAG quenching liquids, and the temperature of PAG quenching liquids is 40~80 DEG C, and the stir speed (S.S.) of PAG quenching liquids is 100~200r/s;S2, cold deformation processing is carried out to the aluminium alloy after high-temperature process, obtains the aluminium alloy after cold deformation;S3,1~2h is tempered at 300~400 DEG C to the aluminium alloy after cold deformation;S4, it is made annealing treatment later, the temperature of annealing is 100~160 DEG C, the time is 6~8h, improves the intensity of aluminium alloy, and the invention also includes aluminium alloys prepared by above-mentioned heat treatment method.

Description

A kind of aluminium alloy and its heat treatment method
Technical field
The present invention relates to technical field of aluminium alloy preparation, more particularly to a kind of aluminium alloy and its heat treatment method.
Background technology
Aluminium alloy is most widely used one kind non-ferrous metal structural material in industry, in Aeronautics and Astronautics, automobile, machinery It has been widely applied in manufacture, ship and chemical industry.The performance for how improving aluminium alloy, especially for carrying for intensity of aluminum alloy It is high, it has also become the problem of industry research staff pays close attention to always.
Metallic fiber is infant industry material developed in recent years, is a key areas of modern science.Metal By the compound assembling of metal wire material, a set of special process such as multiple bundle drawing method, annealing, solution treatment is made fiber, per share to have Thousands of, Shuo Wangen.Metallic fiber surface area is very big, so that it is had in internal structure, magnetism, thermal resistance and fusing point etc. extraordinary Performance.Metallic fiber string diameter is up to 1-2 microns, and elongation percentage is more than 1%, and fibre strength can reach 1200-1800Mpa, very To the tensile strength for being more than material itself.The composite material constituted using metallic fiber as base material is in electronics, chemical industry, machinery, army The industries such as thing, weaving, food, medicine are widely deployed utilization, have opened up wide application prospect.
Above-mentioned metallic fiber is added in aluminium alloy and improves intensity of aluminum alloy, but find can also be by this researcher One step improves the intensity of the aluminium alloy containing metallic fiber.
Invention content
The technical issues of in order to solve how to improve the intensity of the aluminium alloy containing metallic fiber, the present invention propose a kind of aluminium Alloy and its heat treatment method.
The technical problem of the present invention is resolved by technical solution below:
The present invention proposes a kind of heat treatment method of aluminium alloy, according to mass percent meter, the aluminium alloy include with Lower component:Metallic fiber 8~10%, Mg5.5~7.2%, Zn 1.0~2.5%, Cu 0.8~1.8%, Sc 0.08~ 0.18%, Zr 0.08~0.18%, Y 0.12~0.22%, Si 0.02~0.07%, Mn 0.02~0.07%, Er 0.01 ~0.03%, Ce 0.01~0.03%, Za Zhi≤0.15%, surplus Al;
The heat treatment step includes:
S1, high-temperature heat treatment is carried out to the aluminium alloy at 500~600 DEG C, PAG quenching liquids is used after high-temperature heat treatment Quenching, obtains the aluminium alloy after high-temperature process;The content of PAG Type of Collective objects is 15~60wt% in the PAG quenching liquids, described The temperature of PAG quenching liquids is 40~80 DEG C, and the stir speed (S.S.) of the PAG quenching liquids is 100~200r/s;
S2, cold deformation processing is carried out to the aluminium alloy after high-temperature process, obtains the aluminium alloy after cold deformation;
S3,1~2h is tempered at 300~400 DEG C to the aluminium alloy after cold deformation;
S4, it is made annealing treatment later, the temperature of the annealing is 100~160 DEG C, the time is 6~8h.
Preferably, in step sl, the time of the high-temperature heat treatment is 3~4h.
Preferably, the cold deformation processing includes cold drawing or cold rolling.
Preferably, the cold deformation of the aluminium alloy of the cold deformation processing is 5~15%.
Further, in step sl, the content of PAG Type of Collective objects is 25~45wt% in the PAG quenching liquids, described The temperature of PAG quenching liquids is 50~70 DEG C, and the stir speed (S.S.) of the PAG quenching liquids of quenching is 130~160r/s.
Preferably, the temperature of the annealing is 120~150 DEG C, the time is 7~7.5h.
Preferably, the aluminium alloy is Al-alloy products made of extrusion casint.
Preferably, according to mass percent meter, the aluminium alloy includes following components:Metallic fiber 8%, Mg6.2%, Zn1.0%, Cu 1%, Sc 0.12%, Zr 0.13%, Y 0.16%, Si 0.04%, Mn 0.07%, Er 0.02%, Ce 0.02%, Za Zhi≤0.15%, surplus Al.
Further, the metallic fiber includes stainless steel fibre and/or carbon steel fiber.
The invention also provides a kind of aluminium alloys prepared by the heat treatment method using aluminium alloy described in any one of the above embodiments.
The beneficial effect of the present invention compared with the prior art includes:The aluminium alloy includes multiple element and metallic fiber structure At multiple element is unevenly distributed in alloy matrix aluminum, and after high-temperature heat treatment, each element is divided in alloy matrix aluminum It dissipates, improves distributing homogeneity, quenched using PAG quenching liquids, PAG polymer can tightly be adsorbed on aluminum alloy surface at high temperature Thermal insulation layer is formed, it is gradually molten with the cooling PAG thin polymer films of aluminium alloy to reduce aluminum alloy surface cooling rate Solution, becomes homogeneous aqueous solution, to obtain uniform quenching cooling effect, reduces the quenched residual stress of aluminum alloy plate materials, prevents The cracking of aluminium alloy is stopped, aluminium alloy is subjected to cold deformation processing later, the residual stress on aluminium alloy is divided equally, at it Quick forming core in temper afterwards, annealing can prevent the core fast growth to be formed, the second phase made uniformly to be precipitated, and improve aluminium conjunction The intensity of gold, gained aluminium alloy after being handled using the present invention, room temperature tensile intensity is improved significantly, highest can be improved to 735MPa is improved well by the intensity of scheme products obtained therefrom designed by the present invention.
Description of the drawings
Fig. 1 is the technical process for casting figure of aluminium alloy in the specific embodiment of the invention.
Specific implementation mode
Below against attached drawing 1 and in conjunction with preferred embodiment, the invention will be further described.
Embodiment 1
Aluminium alloy in the present embodiment is Al-alloy products made of extrusion casint.
The present embodiment proposes a kind of heat treatment method of aluminium alloy, according to mass percent meter, the aluminium alloy include with Lower component:Carbon steel fiber 8%, Mg6.2%, Zn1.0%, Cu 1%, Sc 0.12%, Zr 0.13%, Y 0.16%, Si 0.04%, Mn 0.07%, Er 0.02%, Ce 0.02%, Za Zhi≤0.15%, surplus Al;
The heat treatment step includes:
S1, high-temperature heat treatment 3h is carried out to the aluminium alloy at 500 DEG C, is quenched using PAG quenching liquids after high-temperature heat treatment Fire obtains the aluminium alloy after high-temperature process;The content of PAG Type of Collective objects is 15wt% in the PAG quenching liquids, and the PAG quenches The temperature of fiery liquid is 75 DEG C, and the stir speed (S.S.) of the PAG quenching liquids is 130r/s;
S2, cold drawing processing is carried out to the aluminium alloy after high-temperature process, obtains the aluminium alloy after cold drawing;Wherein, aluminium alloy Cold deformation is 8%.
S3,2h is tempered at 300 DEG C to the aluminium alloy after cold drawing;
S4, it is made annealing treatment later, the temperature of the annealing is 120 DEG C, time 6h.
The present embodiment further includes aluminium alloy prepared by above-mentioned heat treatment method.
Embodiment 2
Aluminium alloy in the present embodiment is Al-alloy products made of extrusion casint.
The present embodiment proposes a kind of heat treatment method of aluminium alloy, according to mass percent meter, the aluminium alloy include with Lower component:Carbon steel fiber 8%, Mg6.2%, Zn1.0%, Cu 1%, Sc 0.12%, Zr 0.13%, Y 0.16%, Si 0.04%, Mn 0.07%, Er 0.02%, Ce 0.02%, Za Zhi≤0.15%, surplus Al;
The heat treatment step includes:
S1, high-temperature heat treatment 3.5h is carried out to the aluminium alloy at 600 DEG C, PAG quenching liquids is used after high-temperature heat treatment Quenching, obtains the aluminium alloy after high-temperature process;The content of PAG Type of Collective objects is 25wt%, the PAG in the PAG quenching liquids The temperature of quenching liquid is 60 DEG C, and the stir speed (S.S.) of the PAG quenching liquids is 130r/s;
S2, cold drawing processing is carried out to the aluminium alloy after high-temperature process, obtains the aluminium alloy after cold drawing;Wherein, aluminium alloy Cold deformation is 10%.
S3,2h is tempered at 400 DEG C to the aluminium alloy after cold drawing;
S4, it is made annealing treatment later, the temperature of the annealing is 150 DEG C, time 7h.
The present embodiment further includes aluminium alloy prepared by above-mentioned heat treatment method.
Embodiment 3
Aluminium alloy in the present embodiment is Al-alloy products made of extrusion casint.
The present embodiment proposes a kind of heat treatment method of aluminium alloy, according to mass percent meter, the aluminium alloy include with Lower component:Stainless steel fibre 9%, Mg7.2%, Zn1.5%, Cu 1.5%, Sc 0.15%, Zr 0.18%, Y 0.18%, Si 0.06%, Mn 0.06%, Er 0.01%, Ce 0.01%, Za Zhi≤0.15%, surplus Al;
The heat treatment step includes:
S1, high-temperature heat treatment 4h is carried out to the aluminium alloy at 550 DEG C, is quenched using PAG quenching liquids after high-temperature heat treatment Fire obtains the aluminium alloy after high-temperature process;The content of PAG Type of Collective objects is 45wt% in the PAG quenching liquids, and the PAG quenches The temperature of fiery liquid is 70 DEG C, and the stir speed (S.S.) of the PAG quenching liquids is 130r/s;
S2, cold drawing processing is carried out to the aluminium alloy after high-temperature process, obtains the aluminium alloy after cold drawing;Wherein, aluminium alloy Cold deformation is 15%.
S3,1.5h is tempered at 350 DEG C to the aluminium alloy after cold drawing;
S4, it is made annealing treatment later, the temperature of the annealing is 160 DEG C, time 8h.
The present embodiment further includes aluminium alloy prepared by above-mentioned heat treatment method.
Embodiment 4
Aluminium alloy in the present embodiment is Al-alloy products made of extrusion casint.
The present embodiment proposes a kind of heat treatment method of aluminium alloy, according to mass percent meter, the aluminium alloy include with Lower component:Stainless steel fibre 9%, Mg7.2%, Zn1.5%, Cu 1.5%, Sc 0.15%, Zr 0.18%, Y 0.18%, Si 0.06%, Mn 0.06%, Er 0.01%, Ce 0.01%, Za Zhi≤0.15%, surplus Al;
The heat treatment step includes:
S1, high-temperature heat treatment 3h is carried out to the aluminium alloy at 600 DEG C, is quenched using PAG quenching liquids after high-temperature heat treatment Fire obtains the aluminium alloy after high-temperature process;The content of PAG Type of Collective objects is 60wt% in the PAG quenching liquids, and the PAG quenches The temperature of fiery liquid is 50 DEG C, and the stir speed (S.S.) of the PAG quenching liquids is 160r/s;
S2, cold drawing processing is carried out to the aluminium alloy after high-temperature process, obtains the aluminium alloy after cold drawing;Wherein, aluminium alloy Cold deformation is 10%.
S3,2h is tempered at 350 DEG C to the aluminium alloy after cold drawing;
S4, it is made annealing treatment later, the temperature of the annealing is 150 DEG C, time 7.5h.
The present embodiment further includes aluminium alloy prepared by above-mentioned heat treatment method.
Embodiment 5
Aluminium alloy in the present embodiment is Al-alloy products made of extrusion casint.
The present embodiment proposes a kind of heat treatment method of aluminium alloy, according to mass percent meter, the aluminium alloy include with Lower component:Stainless steel fibre 10%, Mg6.8%, Zn2.5%, Cu 1.8%, Sc 0.08%, Zr 0.18%, Y 0.12%, Si 0.04%, Mn 0.07%, Er 0.03%, Ce 0.01%, Za Zhi≤0.15%, surplus Al;
The heat treatment step includes:
S1, high-temperature heat treatment 4h is carried out to the aluminium alloy at 600 DEG C, is quenched using PAG quenching liquids after high-temperature heat treatment Fire obtains the aluminium alloy after high-temperature process;The content of PAG Type of Collective objects is 15wt% in the PAG quenching liquids, and the PAG quenches The temperature of fiery liquid is 60 DEG C, and the stir speed (S.S.) of the PAG quenching liquids is 200r/s;
S2, cold-rolling treatment is carried out to the aluminium alloy after high-temperature process, obtains the aluminium alloy after cold rolling;Wherein, aluminium alloy Cold deformation is 5%.
S3,2h is tempered at 350 DEG C to the aluminium alloy after cold rolling;
S4, it is made annealing treatment later, the temperature of the annealing is 140 DEG C, time 7h.
The present embodiment further includes aluminium alloy prepared by above-mentioned heat treatment method.
Embodiment 6
Aluminium alloy in the present embodiment is Al-alloy products made of extrusion casint.
The present embodiment proposes a kind of heat treatment method of aluminium alloy, according to mass percent meter, the aluminium alloy include with Lower component:Stainless steel fibre 10%, Mg6.8%, Zn2.5%, Cu 1.8%, Sc 0.08%, Zr 0.18%, Y 0.12%, Si 0.04%, Mn 0.07%, Er 0.03%, Ce 0.01%, Za Zhi≤0.15%, surplus Al;
The heat treatment step includes:
S1, high-temperature heat treatment 4h is carried out to the aluminium alloy at 500 DEG C, is quenched using PAG quenching liquids after high-temperature heat treatment Fire obtains the aluminium alloy after high-temperature process;The content of PAG Type of Collective objects is 30wt% in the PAG quenching liquids, and the PAG quenches The temperature of fiery liquid is 80 DEG C, and the stir speed (S.S.) of the PAG quenching liquids is 150r/s;
S2, cold-rolling treatment is carried out to the aluminium alloy after high-temperature process, obtains the aluminium alloy after cold rolling;Wherein, aluminium alloy Cold deformation is 9%.
S3,1.5h is tempered at 400 DEG C to the aluminium alloy after cold rolling;
S4, it is made annealing treatment later, the temperature of the annealing is 150 DEG C, time 7h.
The present embodiment further includes aluminium alloy prepared by above-mentioned heat treatment method.
As the deformation of the present embodiment, the aluminium alloy in above-described embodiment can also be by gravitational casting or low pressure casting Made of Al-alloy products.
The intensity of aluminium alloy after above-described embodiment 1-6 heat treatments and the aluminium alloy before heat treatment is compared, specifically It is to be tested according to GB/t228-2010, obtains the Tensile strength data of the aluminium alloy, be shown in Table 1.
The comparison of the tensile strength of the 1 front and back aluminium alloy of embodiment 1-6 heat treatments of table
Embodiment Tensile strength (MPa) before heat treatment Tensile strength (MPa) after heat treatment
Embodiment 1 619 694
Embodiment 2 618 687
Embodiment 3 596 679
Embodiment 4 588 716
Embodiment 5 628 728
Embodiment 6 635 735
From table 1 it follows that the tensile strength of the aluminium alloy after technical solution heat nursing using the present invention obtains It significantly improves, highest can be improved to 735MPa.
The above content is a further detailed description of the present invention in conjunction with specific preferred embodiments, and it cannot be said that The specific implementation of the present invention is confined to these explanations.For those skilled in the art to which the present invention belongs, it is not taking off Under the premise of from present inventive concept, several equivalent substitute or obvious modifications can also be made, and performance or use is identical, all answered When being considered as belonging to protection scope of the present invention.

Claims (10)

1. a kind of heat treatment method of aluminium alloy, which is characterized in that according to mass percent meter, the aluminium alloy includes with the following group Point:Metallic fiber 8~10%, Mg5.5~7.2%, Zn 1.0~2.5%, Cu 0.8~1.8%, Sc 0.08~0.18%, Zr 0.08~0.18%, Y 0.12~0.22%, Si 0.02~0.07%, Mn 0.02~0.07%, Er 0.01~ 0.03%, Ce 0.01~0.03%, Za Zhi≤0.15%, surplus Al;
The heat treatment step includes:
S1, high-temperature heat treatment is carried out to the aluminium alloy at 500~600 DEG C, is quenched using PAG quenching liquids after high-temperature heat treatment Fire obtains the aluminium alloy after high-temperature process;The content of PAG Type of Collective objects is 15~60wt% in the PAG quenching liquids, described The temperature of PAG quenching liquids is 40~80 DEG C, and the stir speed (S.S.) of the PAG quenching liquids is 100~200r/s;
S2, cold deformation processing is carried out to the aluminium alloy after high-temperature process, obtains the aluminium alloy after cold deformation;
S3,1~2h is tempered at 300~400 DEG C to the aluminium alloy after cold deformation;
S4, it is made annealing treatment later, the temperature of the annealing is 100~160 DEG C, the time is 6~8h.
2. the heat treatment method of aluminium alloy as described in claim 1, which is characterized in that in step sl, at the high warm The time of reason is 3~4h.
3. the heat treatment method of aluminium alloy as described in claim 1, which is characterized in that cold deformation processing include cold drawing or Cold rolling.
4. the heat treatment method of aluminium alloy as described in claim 1, which is characterized in that the aluminium alloy of the cold deformation processing Cold deformation is 5~15%.
5. the heat treatment method of aluminium alloy as described in claim 1, which is characterized in that in step sl, the PAG quenching liquids The content of middle PAG Type of Collective object is 25~45wt%, and the temperature of the PAG quenching liquids is 50~70 DEG C, the PAG quenching liquids of quenching Stir speed (S.S.) be 130~160r/s.
6. the heat treatment method of aluminium alloy as described in claim 1, which is characterized in that in step s 4, the annealing Temperature be 120~150 DEG C, the time is 7~7.5h.
7. the heat treatment method of aluminium alloy as described in claim 1, which is characterized in that the aluminium alloy forms for extrusion casint Al-alloy products.
8. the heat treatment method of aluminium alloy as described in claim 1, which is characterized in that according to mass percent meter, the aluminium Alloy includes following components:Metallic fiber 8%, Mg6.2%, Zn1.0%, Cu 1%, Sc 0.12%, Zr 0.13%, Y 0.16%, Si 0.04%, Mn 0.07%, Er 0.02%, Ce 0.02%, Za Zhi≤0.15%, surplus Al.
9. the heat treatment method of aluminium alloy as described in claim 1, which is characterized in that the metallic fiber includes stainless steel fibre Dimension and/or carbon steel fiber.
10. aluminium alloy prepared by a kind of heat treatment method using claim 1-9 any one of them aluminium alloys.
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Cited By (2)

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Publication number Priority date Publication date Assignee Title
CN112147737A (en) * 2020-09-24 2020-12-29 南京邮电大学 Method for manufacturing high-temperature-resistant fiber Bragg grating
CN115652231A (en) * 2022-11-18 2023-01-31 南通市华阳铝制品有限公司 Heat treatment method for high-strength aluminum alloy section

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Publication number Priority date Publication date Assignee Title
CN112147737A (en) * 2020-09-24 2020-12-29 南京邮电大学 Method for manufacturing high-temperature-resistant fiber Bragg grating
CN115652231A (en) * 2022-11-18 2023-01-31 南通市华阳铝制品有限公司 Heat treatment method for high-strength aluminum alloy section
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Denomination of invention: An aluminum alloy and its heat treatment method

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