CN108441758B - A kind of high-speed EMUs axle steel and preparation method thereof suitable for extremely frigid zones - Google Patents

A kind of high-speed EMUs axle steel and preparation method thereof suitable for extremely frigid zones Download PDF

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CN108441758B
CN108441758B CN201810145721.XA CN201810145721A CN108441758B CN 108441758 B CN108441758 B CN 108441758B CN 201810145721 A CN201810145721 A CN 201810145721A CN 108441758 B CN108441758 B CN 108441758B
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temperature
axle steel
steel
axle
preparation
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CN108441758A (en
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吴毅
尹鸿祥
张恒
张弘
张关震
赵方伟
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China Academy of Railway Sciences Corp Ltd CARS
Metals and Chemistry Research Institute of CARS
Beijing CARS Advanced Material Technology Co Ltd
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China Academy of Railway Sciences Corp Ltd CARS
Metals and Chemistry Research Institute of CARS
Beijing CARS Advanced Material Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/005Modifying the physical properties by deformation combined with, or followed by, heat treatment of ferrous alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/005Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/42Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/46Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/008Martensite

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

The present invention provides a kind of axle steel and preparation method thereof for extremely frigid zones high-speed EMUs, the axle steel by weight percentage, C 0.22~0.28%, Si 0.15~0.40%, Mn 0.4~0.65, S≤0.005%, P≤0.010%, Cr 1.4~2.2%, Cu≤0.20%, Mo 0.10~0.15%, V 0.16~0.25%, RE 0.005~0.03%, Ni 1.5~2.0%, Al 0.010~0.045%, surplus are Fe and inevitable impurity.The present invention is added and is integrated refinement technology by reasonable ingredient, obtains at low cost, cryogenic property, anti-fatigue performance and the excellent axle steel of harden ability.

Description

A kind of high-speed EMUs axle steel and preparation method thereof suitable for extremely frigid zones
Technical field
The invention belongs to field of alloy steel, and in particular to a kind of high-speed EMUs axle steel suitable for extremely frigid zones and its Preparation method.
Background technique
Important running part of the axle as high-speed EMUs is subject to the key part of dynamic loading, and stress is complicated, And it may be paid high attention to all the time by certain impact, security reliability, wherein the clothes of axle at low ambient temperatures Labour integrity problem is even more that can not be ignored.The axle of motor train unit material of China's extensive utilization be mainly from Europe EA4T or 30NiCrMoV12 axle steel, their corresponding standard EN13261 and UNI6787 do not make requirement to cryogenic property.2012 On December 1, has opened first high-speed railway and has breathed out-big Line for Passenger Transportation in China's extremely frigid zones, and the route minimum temperature is reachable- 40℃.With the implementation of going global and the Belt and Road national development strategy, the height of China's independent research in the near future Fast motor train unit train can also export to (- 60 DEG C) of extremely frigid zones country and use, thus about the low temperature for solving axle be on active service can It is more urgent by property problem.
Summary of the invention
The axle steel and preparation method thereof that the object of the present invention is to provide a kind of for extremely frigid zones high-speed EMUs, this hair It is bright to add and integrate refinement technology by Rational Composition, improve low-temperature flexibility, fatigue behaviour and the harden ability of the axle steel.
It is as follows for realizing above-mentioned purpose technical solution of the present invention:
The present invention provides a kind of high-speed EMUs axle steel, by weight percentage, it includes C 0.22~0.28%, Si 0.15~0.40%, Mn 0.4~0.65, S≤0.005%, P≤0.010%, Cr 1.4~2.2%, Cu≤0.20%, Mo 0.10~0.15%, V 0.16~0.25%, RE 0.005~0.03%, Ni 1.5~2.0%, Al 0.010~ 0.045%, surplus is Fe and inevitable impurity.
Preferably, by weight percentage, it includes: C 0.24~0.28%, Si 0.30~0.40%, Mn 0.40~ 0.60, S≤0.005%, P≤0.010%, Cr 1.45~1.60%, Cu≤0.10%, Mo 0.12~0.15%, V 0.22 ~0.25%, RE 0.01~0.03%, Ni 1.7~1.9%, Al 0.010~0.035%, surplus is for Fe and inevitably Impurity.
Preferably, in the inevitable impurity, H≤1.5ppm, O≤10ppm.
The tissue signature of axle steel of the present invention is tiny lamellar martensite, and tissue grain size is greater than 9.0 grades.
It is slightly≤0.5, A is carefully≤0.5 that the field trash of the axle steel, which is rated A,;B is slightly that≤0.5, B is carefully≤0.5;C ≤ 0.5, C of thick system is carefully≤0.5;D is slightly that≤0.5, D is carefully≤1.0;(B+C+D) thick system≤1.0, (B+C+D) are carefully≤1.5.
Tensile strength >=950MPa of the axle steel, yield strength >=850MPa, elongation percentage >=18%, the contraction percentage of area >=50%;Its smooth RfL>=495MPa, notch RfE>=370MPa, RfL/RfE≤1.50。
The axle steel is at -40 DEG C, side knock KV2>=70J, impact of collision KV2≥80J;Preferably, described At -60 DEG C of axle steel, impact of collision KV2≥50J。
The preparation method of axle steel of the present invention, includes the following steps:
(1) melting in furnace is added in steel scrap and preprocessed molten iron, it is rear to carry out ladle furnace refining and vacuum drying oven degassing;
(2) continuous casting steel machine obtains slab;
(3) slab that step (2) obtains is rolled into steel billet;
(4) steel billet that step (3) obtains is forged;
(5) it is heat-treated.
Preferably, in the step (1), melting in electric arc furnaces, electric furnace steel tapping temperature is added in steel scrap and preprocessed molten iron It is 1630-1650 DEG C, rear to carry out ladle furnace refining and vacuum drying oven degassing;In the step (2), tapping temperature is 1560-1570 DEG C, Pouring temperature is 1540-1555 DEG C, and continuous casting steel machine obtains the slab that diameter is 690mm;In the step (3), step (2) are obtained To slab be heated to 1250-1280 DEG C, keep the temperature 1.5-2h, it is rear to roll;Preferably, the initial temperature of the rolling is 1150 DEG C, the final temperature of the rolling is 900 DEG C, is then cooled down, and preferably air is cooling;In the step (4), step (3) are obtained The heating steel billet arrived is preferably heated to 1150 DEG C to 1120-1190 DEG C, after forged,;Preferably, initial forging temperature 1000- 1120 DEG C, final forging temperature is 800 DEG C, it is highly preferred that initial forging temperature is 1120 DEG C, final forging temperature is 800 DEG C.
Preferably, in the step (5), the heat treatment the following steps are included: a normalizing is heated to 860-900 DEG C, 3-5h is kept the temperature, rear air is cooling;After be again heated to 860-900 DEG C, keep the temperature 4.0-5.0h, water quenching cooling;After be again heated to 850- 870 DEG C, keep the temperature 3.0-4.0h, water quenching cooling;It is tempered again and is heated to 630-650 DEG C, keep the temperature 6.0-6.5 hours, be cooled to room temperature;
Preferably, in the step (5), the heat treatment step is as follows: a normalizing is heated to 870 DEG C, keeps the temperature 4h, after Air is cooling;After be again heated to 880 DEG C, keep the temperature 4h, water quenching cooling;After be again heated to 860 DEG C, keep the temperature 3h, water quenching cooling;It returns again Fire is heated to 640 DEG C, keeps the temperature 6.0 hours, air is cooled to room temperature.
Axle steel of the present invention plays solidification refinement, Deformation recrystallization refinement and heat treatment by RE and the compound addition of V element Comprehensive refinement technology is refined, tissue grain size and inclusion morphology size is effectively had adjusted, obtains the tiny fine sheet of crystal grain Martensitic structure obtains good low temperature obdurability.The present invention passes through the conjunction of Ni and Cr element under the premise of save the cost Reason is adjusted, and obtains the high-speed EMUs axle steel that a kind of cryogenic property is excellent, fatigue behaviour is good and harden ability is excellent.
106244933 A of Chinese invention patent CN discloses a kind of high speed axle Steel material and its heat treatment method, this hair Cr content in bright patent axle steel is suitable with the Cr content in EA4T axle steel, have harden ability deficiency and corrosion fatigue difference ask Topic.And the design of the steel grade does not consider cryogenic property, technique be primary quenching, ingredient and technique and axle steel of the present invention in the presence of compared with Big difference, grain size, field trash grading and room-temperature mechanical property are not as good as axle steel of the present invention.
104264065 A of Chinese invention patent CN discloses a kind of axles steel of bullet train containing vanadium, the invention patent vehicle Cr content in axis steel is suitable with the Cr content in EA4T axle steel, also there is the problem of harden ability deficiency and corrosion fatigue difference.It should The ingredient and preparation process and axle steel of the present invention of steel grade have relatively big difference, and the design of its ingredient and preparation process does not consider height Cold area (- 60 DEG C) cryogenic property, grain size, room temperature tensile properties and fatigue behaviour are not as good as axle steel of the present invention.
105821309 A of Chinese invention patent CN discloses a kind of steel heat treatment process of axle of motor train unit containing vanadium, the vehicle There are larger differences on ingredient for axis steel and axle steel of the present invention, though technique takes quenching add-back fire process twice, with this Invention axle steel is compared, and does not carry out normalized treatment before first time quenching, the design of the steel grade does not consider -60 DEG C of impacts yet Can, tensile property and fatigue behaviour are also not as good as axle steel of the present invention.
Specific embodiment
The present invention is further described in detail With reference to embodiment, and the embodiment provided is only for explaining The bright present invention, the range being not intended to be limiting of the invention.
Test method in following embodiments is unless otherwise specified conventional method, original as used in the following examples Material, material etc. are commercially available products unless otherwise specified.
The axle steel of the present invention of embodiment 1-3 is shown in Table 1 at being grouped as.
The present invention of table 1 be suitable for the high-speed EMUs axle steel of extremely frigid zones at being grouped as (wt%)
The preparation method of the high-speed EMUs axle steel of embodiment 1-3:
(1) raw scrap material and preprocessed molten iron are added melting in electric arc furnaces, 1630~1650 DEG C of electric furnace steel tapping temperature, after Carry out ladle furnace refining and vacuum degassing furnace degassing;
(2) continuous casting steel machine, tapping temperature are 1560~1570 DEG C, and pouring temperature is 1540~1555 DEG C, on conticaster Pour into the slab of diameter 690mm;
(3) slab that step (2) obtains is heated to 1250~1280 DEG C, is rolled after keeping the temperature 1.5~2h, rolling Initial temperature is 1150 DEG C, and the final temperature of rolling is 900 DEG C, and air is cooled to room temperature, and obtains steel billet;
(4) for the heating steel billet for obtaining step (3) to 1150 DEG C, initial forging temperature is 1120 DEG C, and final forging temperature is 800 DEG C;
(5) normalizings are heated to 870 DEG C, keep the temperature 4h, and rear air is cooling;After be heated to 880 DEG C, soaking time 4h, Water quenching cooling;After be heated to 860 DEG C, soaking time 3h, water quenching cooling;It is tempered again and is heated to 640 DEG C, keep the temperature 6.0 hours, it is empty Air cooling is to room temperature.
According to the national standard GB/T 10561-2005 " measurement of the nonmetallic inclusionsin steel content-micro- inspection of standard judge picture Test method " with GB/T6394-2017 " metal mean grain size measuring method " respectively to using the above method preparation embodiment 1-3 High-speed EMUs axle steel field trash and tissue grain size grade, field trash and tissue grain size be all satisfied iron About EA4T axle steel in road parent company standard technological document TJ/CL 276A-2016 " the provisional technical conditions of axle of motor train unit " With the requirement of 30NiCrMoV12 axle steel, test number is shown in Table 2 and table 3.
The steel clamp sundries rating result of the axle steel of 2 embodiment 1-3 of table compares
The grain size rating result of the axle steel of 3 embodiment 1-3 of table compares
The axle steel of embodiment 1-3 is surveyed by " 229-2007 metal materials of GB/T-Charpy pendulum impact test method " Determine impact property, measure draftability by " 2010 metal material stretching test first part of GB/T228.1-: room temperature test method " GB/T 4337 " Metal Material Fatigue tests rotoflector method " measurement small sample fatigue behaviour can, be pressed, the results are shown in Table 4 and table 5。
Railway parent company standard technological document " the provisional technical conditions of TJ/CL 276A-2016 axle of motor train unit ", Europe Standard EN 13261 " railway applications-wheel to and bogie-axle-product requirement " and UNI6787 are " for railway wheel pair, tool Have high-fatigue strength and property of toughness, quenched special alloy steel forging axis " not to EA4T axle steel and 30NiCrMoV12 The cryogenic property of axle steel is required, and is shown in Table 4 and table 5.
Mechanical property, impact property and the fatigue behaviour of 1-3 axle steel of the embodiment of the present invention are all satisfied standard and are better than EA4T axle steel and 30NiCrMoV12 axle steel.Compared with 30NiCrMoV12 axle steel, axle steel of the present invention is reducing cost Under the premise of, excellent low temperature impact properties are obtained, the requirement of extremely frigid zones high-speed EMUs axle can be satisfied with.
The tensile property and impact property of table 4 embodiment 1-3 axle steel and EA4T axle steel and 30NiCrMoV12 axle steel Comparison
The fatigue behaviour of 5 embodiment 1-3 axle steel of table and EA4T axle steel and 30NiCrMoV12 axle steel compares
In short, specific description of embodiments of the present invention above is not intended to limit the present invention, those skilled in the art can be with It is variously modified or deforms according to the present invention, as long as it does not depart from the spirit of the invention, should belong to right appended by the present invention and wants The range asked.

Claims (13)

1. a kind of high-speed EMUs axle steel, by weight percentage, it includes: C 0.24~0.28%, Si 0.30~ 0.40%, Mn 0.40~0.60, S≤0.005%, P≤0.010%, Cr 1.45~1.60%, Cu≤0.10%, Mo 0.12 ~0.15%, V 0.22~0.25%, RE 0.01~0.03%, Ni 1.7~1.9%, Al 0.010~0.035%, surplus For Fe and inevitable impurity.
2. axle steel according to claim 1, which is characterized in that in the inevitable impurity, H≤1.5ppm, O ≤10ppm。
3. axle steel according to claim 1 or 2, which is characterized in that its tissue signature is tiny lamellar martensite, tissue Grain size is greater than 9.0 grades.
4. axle steel according to claim 1 or 2, which is characterized in that it is slightly that≤0.5, A is carefully that its field trash, which is rated A, ≤0.5;B is slightly that≤0.5, B is carefully≤0.5;C is slightly that≤0.5, C is carefully≤0.5;D is slightly that≤0.5, D is carefully≤1.0;(B+C+ D) thick system≤1.0, (B+C+D) are carefully≤1.5.
5. axle steel according to claim 1 or 2, which is characterized in that tensile strength >=950MPa of the axle steel is bent Take intensity >=850MPa, elongation percentage >=18%, the contraction percentage of area >=50%;Its smooth RfL>=495MPa, notch RfE≥ 370MPa, RfL/RfE≤1.50。
6. axle steel according to claim 1 or 2, which is characterized in that the axle steel is at -40 DEG C, side knock KV2>=70J, impact of collision KV2≥80J;At -60 DEG C of the axle steel, impact of collision KV2≥50J。
7. the preparation method of axle steel according to claim 1 to 6, includes the following steps:
(1) melting in furnace is added in steel scrap and preprocessed molten iron, it is rear to carry out ladle furnace refining and vacuum drying oven degassing;
(2) continuous casting steel machine obtains slab;
(3) slab that step (2) obtains is rolled into steel billet;
(4) steel billet that step (3) obtains is forged;
(5) it is heat-treated.
8. the preparation method of axle steel according to claim 7, which is characterized in that in the step (1), by steel scrap and in advance It handles molten iron and melting in electric arc furnaces is added, 1630-1650 DEG C of electric furnace steel tapping temperature, rear progress ladle furnace refining and vacuum drying oven are de- Gas;
In the step (2), tapping temperature is 1560-1570 DEG C, and pouring temperature is 1540-1555 DEG C, and continuous casting steel machine obtains directly Diameter is the slab of 690mm;
In the step (3), the slab that step (2) obtains is heated to 1250-1280 DEG C, keeps the temperature 1.5-2h, it is rear to roll;It is described The initial temperature of rolling is 1150 DEG C, and the final temperature of the rolling is 900 DEG C, is then cooled down;
In the step (4), the heating steel billet that step (3) is obtained to 1120-1190 DEG C, after forged;Initial forging temperature is 1000-1120 DEG C, final forging temperature is 800 DEG C.
9. the preparation method of axle steel according to claim 8, which is characterized in that described to be cooled in the step (3) Air is cooling.
10. the preparation method of axle steel according to claim 8, which is characterized in that in the step (4), by step (3) Obtained heating steel billet to 1150 DEG C, after forged.
11. the preparation method of axle steel according to claim 8, which is characterized in that in the step (4), initial forging temperature It is 1120 DEG C, final forging temperature is 800 DEG C.
12. the preparation method of axle steel according to any one of claims 7 to 11, which is characterized in that the step (5) In, the following steps are included: a normalizing is heated to 860-900 DEG C, heat preservation 3-5h, rear air is cooling for the heat treatment;Add again afterwards Heat keeps the temperature 4.0-5.0h, water quenching cooling to 860-900 DEG C;After be again heated to 850-870 DEG C, keep the temperature 3.0-4.0h, water quenching But;It is tempered again and is heated to 630-650 DEG C, keep the temperature 6.0-6.5 hours, be cooled to room temperature.
13. the preparation method of axle steel according to claim 12, which is characterized in that in the step (5), at the heat Steps are as follows for reason: a normalizing is heated to 870 DEG C, keeps the temperature 4h, and rear air is cooling;After be again heated to 880 DEG C, keep the temperature 4h, water quenching It is cooling;After be again heated to 860 DEG C, keep the temperature 3h, water quenching cooling;It is tempered again and is heated to 640 DEG C, keep the temperature 6.0 hours, air is cooled to Room temperature.
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CN108359917B (en) * 2018-04-04 2019-09-10 长春工业大学 A kind of bullet train hole-bored axle from end to end steel and preparation method thereof
CN109182910A (en) * 2018-10-20 2019-01-11 江苏铸鸿锻造有限公司 A kind of carbon manganese steel forging circle of low-temperature impact-resistant and preparation method thereof
CN109763063B (en) * 2018-12-19 2020-08-21 钢铁研究总院 Alloy structural steel suitable for high-strength transmission shaft
CN112008031B (en) * 2020-08-25 2023-06-16 无锡继平新材料科技有限公司 Forging and heat treatment process of valve body for shale gas exploitation
CN115074502B (en) * 2022-07-21 2022-11-15 太原科技大学 Large-scale shaft forging and heat treatment process thereof

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