CN108441680A - Resistance to oxidation is without zinc flower pattern high-carbon steel galvanizing by dipping kirsite containing V - Google Patents
Resistance to oxidation is without zinc flower pattern high-carbon steel galvanizing by dipping kirsite containing V Download PDFInfo
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- CN108441680A CN108441680A CN201810423076.3A CN201810423076A CN108441680A CN 108441680 A CN108441680 A CN 108441680A CN 201810423076 A CN201810423076 A CN 201810423076A CN 108441680 A CN108441680 A CN 108441680A
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- Prior art keywords
- dipping
- galvanizing
- zinc
- alloy
- oxidation
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C18/00—Alloys based on zinc
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
- C23C2/06—Zinc or cadmium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/34—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
- C23C2/36—Elongated material
- C23C2/38—Wires; Tubes
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Coating With Molten Metal (AREA)
Abstract
The invention discloses resistances to oxidation without zinc flower pattern high-carbon steel galvanizing by dipping kirsite containing V and its processing technology.According to weight percent, the ingredient of the alloy is：Li：0.4‑1.2wt.%,W:0.8‑1.0wt.%,V:0.5‑0.8wt.%,Ge：2.0 3.0wt.%, Sc:0.4‑0.8wt.%,Th：0.2 0.5wt.%, surplus are zinc.The development of the alloy can solve the phenomenon that plating piece surface zinc flower generates in industrial galvanizing by dipping production.The characteristics of also having production cost low, being convenient for large-scale production.
Description
Technical field
The present invention relates to technical field of alloy, specifically, being related to a kind of kirsite.
Background technology
Most widely used steel material in industry, in the environment such as air, seawater, soil and construction material in use,
Different degrees of corrosion can occur.According to statistics, it is total that the steel material that the whole world is lost by corrosion every year can about account for it
The 1/3 of yield.In order to ensure the normal use of steel product, extend its service life, the anti-corrosion protection technology of steel is always
It has received universal attention.
The fusing point of zinc is very low, only 419.7 DEG C, and can immersion plating within the temperature range of 450-480 DEG C.It typically results in
Grey coating be made of two layerings：Outer layer is zinc layers, and internal layer is one zinc intermetallic compounds layer of iron.Intermetallic compound
Generation can make that metallurgical binding, adhesion-tight are presented between coating and matrix.Due to zinc have good ductility, alloy-layer with
Base steel adhesion-tight, therefore hot dip part can carry out the various moldings such as cold punching, rolling, wire drawing, bending without damaging coating.Pure zinc layer
It is that most one layer of zinc coat rich in plasticity, property are essentially close to pure zinc in galvanizing, there is ductility, scratched so it is imbued with
Property.
Galvanizing by dipping is to delay one of most effective means of steel material environmental corrosion, it is surface is cleaned, activation
Steel product afterwards is dipped in the zinc liquid of melting, by the reaction and diffusion between iron zinc, is adhered in steel product coating surface
The good zn alloy coating of property.Compared with other metal protection methods, physical barriers and electrification of the hot-dip galvanizing technique in coating
It learns in the protection feature that is combined of protection, in the bond strength of coating and matrix, the compactness of coating, durability, maintenance-free
In adaptability with economy and its to article shape and size, there is unrivaled advantage.Hot dip galvanized product master at present
There are steel plate, steel band, steel wire, steel pipe etc., wherein hot-dip galvanized steel sheet proportion maximum.For a long time, hot-dip galvanizing technique
Because of its cheap plating cost, excellent protection feature and beautiful appearance and the favor for receiving people, be widely used in automobile,
The fields such as building, household electrical appliances, chemical industry, machinery, oil, metallurgy, light industry, traffic, electric power, aviation and ocean engineering.
The quality of galvanizing is related with many factors, includes the chemical composition of steel part, the alloying component of zinc bath, zinc-plated temperature
Degree, operating procedure etc..There is the crystallization decorative pattern of coated metal, this crystallization decorative pattern in solidification in the hot-dip coated surface of steel plate
It is particularly evident to galvanized sheet, the appearance of beautiful zinc crystallization is showed, thus as the important feature of heat zinc coating plate appearance, usually
This crystallization decorative pattern is referred to as zinc flower.This zinc-plated plate surface liquid Zn forms beautiful zinc flower after crystallisation by cooling, and as plating
The distinctive mark of zine plate is widely used in building trade.But when hot-dip galvanizing sheet steel progress application, surface is convex caused by zinc is spent
Recessed injustice is still high-visible after painting, to affect the surface quality of product, limits normal zinc flower hot-galvanized steel plate
Application.
High-carbon steel (High Carbon Steel) often claims tool steel, phosphorus content that can be quenched from 0.60% to 1.70%
And tempering.High-carbon steel has high intensity and hardness, high elastic limit and fatigue after appropriate heat treatment or Cold-draw Hardening
The limit, cutting ability is fine, but welding performance and cold plastic deformation energy force difference.Due to phosphorus content height, when water quenching, which easy tos produce, to be split
Line.Generally used after quenching through average tempering or normalizing or under surface hardening state.Mainly for the manufacture of spring and wear-resisting
Part.High-carbon steel is the steel grade being most widely used at present, and the main object of galvanizing by dipping.According to automobile and other industries compared with
High request, people propose the imagination eliminated high-carbon steel zinc flower and make zinc flower refinement very early, but up to the present there is no one
Kind efficient and succinct production method or processing technology.
This patent provides a kind of novel surface and spends high-carbon steel galvanizing by dipping kirsite without zinc.By controlling lithium content simultaneously
Trace element is added simultaneously, to greatly improve forming core of the zinc liquid of high-carbon steel surface in solidification and grow up.Control zinc flower with
And the formation and roughening of harmful phase, and the mechanical property of existing dip galvanized is maintained simultaneously.It is contemplated that such alloy industry
Change can obtain great economic and social benefit.In the near future, as more engineer application fields are expanded, such is novel
Alloy will be used widely in more galvanizings by dipping.
Invention content
The purpose of the present invention is to overcome the deficiency in the prior art, and providing one kind can make under 360-450 degree atmospheric conditions
Resistance to oxidation is without zinc flower pattern high-carbon steel galvanizing by dipping kirsite containing V.The development of the alloy can solve industrial hot-dip
The phenomenon that plating piece surface zinc flower generates in zinc production.The characteristics of also having production cost low, being convenient for large-scale production.
To achieve the goals above, the present invention adopts the following technical scheme that：
A kind of resistance to oxidation is without zinc flower pattern high-carbon steel galvanizing by dipping kirsite containing V.By weight percentage, the group of alloy becomes：
Li： 0.4-1.2wt.%,W:0.8-1.0wt.%,V:0.5-0.8wt.%,Ge：2.0-3.0wt.%, Sc:0.4-0.8wt.%,
Th：0.2-0.5wt.%, surplus are zinc.The weight that the kirsite loses in fusion process because of the reasons such as volatilization and formation clinker
Amount is in 1.0-2.0wt.% or so.
Preparation method of the above-mentioned resistance to oxidation without zinc flower pattern high-carbon steel galvanizing by dipping kirsite containing V, includes the following steps：It will
As above the raw material matched is added in the electric induction furnace of atmosphere protection, and uses silicon carbide crucible；Sensing heating is to 500-600 degree
Alloy solution is formed, and is sufficiently stirred 10 minutes or so using electromagnetic agitation effect；Alloy liquid is quiet in the heat preservation of 500-600 degree
It sets to be cast to after ten minutes in the same level equipment of heat top and carries out semi-continuous casting into required billet, it is 5- that ingot casting, which moves down speed,
10m/min.The ingot casting can be handled for the galvanizing by dipping of subsequent handling to be protected to steel wire as galvanizing by dipping raw material
Operation, the wherein operating temperature of galvanizing by dipping are 360-450 degree, and the hot dipping time is 30-40 seconds.
Compared with prior art, the present invention has the advantages that：
（1）Patent of the present invention provides a kind of solution of materialogy for the generation of current high-carbon steel galvanizing by dipping zinc flower.
The kirsite has extremely excellent resistance to volatilization and oxidation resistent susceptibility, can reach in 400-800 degree temperature ranges in air
5 hours are stood under environment without significantly aoxidizing.The melt treatments process such as the liquid alloy is being stirred, is being blown
In, after its skin covering of the surface is destroyed because being vigorously stirred, energy rapid regeneration successfully hinders the oxidation and volatilization of alloy.
（2）Hot-galvanized steel structural member standard provides that the galvanized layer thickness of galvanized part need to ensure at 30-60 microns, to ensure
The corrosion resistance of plating piece and good adhesiveness.In addition, the operating temperature of general galvanizing by dipping is 450-580 degree, galvanizing by dipping
Time is 30-60 seconds.Zinc-plated using this patent uses alloy, under the low temperature environment of 360-450 degree, so that it may at 30-40 seconds
Inherence high-carbon steel surface hot-dip on thickness be 50-80 microns of coating.Since operating temperature is low, the hot dipping time is short, energy saving
It is with obvious effects.Convenient for operation, year consuming fund is also less, for the prefered method in galvanizing by dipping production.
（3）Galvanized sheet is divided by appearance pattern to be had zinc flower and spends two kinds without zinc.General zinc layers get over Gao Yuegui, identical zinc
Layer has Hua Gui without flower ratio.Consider from the market demand, production is high without zinc flower prod economic well-being of workers and staff.The alloy protected using this patent,
It can go out the hot dip galvanized product of no zinc flower in high-carbon steel surface production on conventional hot dip zinc production line.In desert
Under environment, the oxidation rate of the material is 1.5 × 10-4Mm/.Thus under desert climate, which can use 30 safely
Year or more without apparent oxidative phenomena occur.In comparison, the zinc coat of common hot-dip galvanizing alloy is in desert Environment
General working life is 20 years or so down.
Specific implementation mode
Embodiment 1
One kind is in 360-450 degree using resistance to oxidation without zinc flower pattern high-carbon steel galvanizing by dipping kirsite containing V.By weight percentage
Meter, the chemical composition of alloy are：Li： 0.4wt.%,W:0.8wt.%,V:0.5wt.%,Ge：2.0wt.%, Sc:0.4wt.%,
Th：0.2wt.%, surplus are zinc.The preparation method of alloy：As above the raw material matched is added to the electric induction furnace of atmosphere protection
It is interior, and use silicon carbide crucible；Sensing heating forms alloy solution to 500-600 degree, and is fully stirred using electromagnetic agitation effect
It mixes 10 minutes or so；Alloy liquid is stood to be cast to after ten minutes in the same level equipment of heat top in the heat preservation of 500-600 degree and is carried out
At required billet, it is 5-10m/min that ingot casting, which moves down speed, for semi-continuous casting.The ingot casting can regard galvanizing by dipping raw material and use
It is handled in the galvanizing by dipping of subsequent handling to carry out protection operation to steel wire, the wherein operating temperature of galvanizing by dipping is 360-450
Degree, hot dipping time are 30-40 seconds.
The kirsite has extremely excellent resistance to volatilization and oxidation resistent susceptibility, can reach in 400-800 degree temperature ranges
It is interior that 5 hours are stood under atmospheric environment without significantly aoxidizing.The liquid alloy is being stirred, is being blown etc. at melts
During reason, after its skin covering of the surface is destroyed because being vigorously stirred, energy rapid regeneration successfully hinders the oxidation and volatilization of alloy.It adopts
Zinc-plated with this patent uses alloy, under the low temperature environment of 360-450 degree, so that it may with interior on high-carbon steel surface in 30-40 seconds
The coating that thickness is 50-80 microns in hot-dip.Since operating temperature is low, the hot dipping time is short, and energy-saving effect is apparent.Convenient for worker
Operation, year consuming fund is also less, for the prefered method in galvanizing by dipping production.The alloy protected using this patent, Ke Yi
The hot dip galvanized product of no zinc flower can be gone out on conventional hot dip zinc production line in high-carbon steel surface production.In desert Environment
Under, the oxidation rate of the material is 1.5 × 10-4Mm/.Thus under desert climate, the material can use safely 30 years with
On without apparent oxidative phenomena occur.In comparison, the zinc coat of common hot-dip galvanizing alloy is one under desert Environment
As working life be 20 years or so.
Embodiment 2
One kind is in 360-450 degree using resistance to oxidation without zinc flower pattern high-carbon steel galvanizing by dipping kirsite containing V.By weight percentage
Meter, the chemical composition of alloy are：Li： 0.8wt.%,W:0.8wt.%,V:0.6wt.%,Ge：2.4wt.%, Sc:0.6wt.%,
Th：0.3wt.%, surplus are zinc.The preparation method of alloy：As above the raw material matched is added to the electric induction furnace of atmosphere protection
It is interior, and use silicon carbide crucible；Sensing heating forms alloy solution to 500-600 degree, and is fully stirred using electromagnetic agitation effect
It mixes 10 minutes or so；Alloy liquid is stood to be cast to after ten minutes in the same level equipment of heat top in the heat preservation of 500-600 degree and is carried out
At required billet, it is 5-10m/min that ingot casting, which moves down speed, for semi-continuous casting.The ingot casting can regard galvanizing by dipping raw material and use
It is handled in the galvanizing by dipping of subsequent handling to carry out protection operation to steel wire, the wherein operating temperature of galvanizing by dipping is 360-450
Degree, hot dipping time are 30-40 seconds.
The kirsite has extremely excellent resistance to volatilization and oxidation resistent susceptibility, can reach in 400-800 degree temperature ranges
It is interior that 5 hours are stood under atmospheric environment without significantly aoxidizing.The liquid alloy is being stirred, is being blown etc. at melts
During reason, after its skin covering of the surface is destroyed because being vigorously stirred, energy rapid regeneration successfully hinders the oxidation and volatilization of alloy.It adopts
Zinc-plated with this patent uses alloy, under the low temperature environment of 360-450 degree, so that it may with interior on high-carbon steel surface in 30-40 seconds
The coating that thickness is 50-80 microns in hot-dip.Since operating temperature is low, the hot dipping time is short, and energy-saving effect is apparent.Convenient for worker
Operation, year consuming fund is also less, for the prefered method in galvanizing by dipping production.The alloy protected using this patent, Ke Yi
The hot dip galvanized product of no zinc flower can be gone out on conventional hot dip zinc production line in high-carbon steel surface production.In desert Environment
Under, the oxidation rate of the material is 1.5 × 10-4Mm/.Thus under desert climate, the material can use safely 30 years with
On without apparent oxidative phenomena occur.In comparison, the zinc coat of common hot-dip galvanizing alloy is one under desert Environment
As working life be 20 years or so.
Embodiment 3
One kind is in 360-450 degree using resistance to oxidation without zinc flower pattern high-carbon steel galvanizing by dipping kirsite containing V.By weight percentage
Meter, the chemical composition of alloy are：Li： 1.0wt.%,W:0.8wt.%,V:0.8wt.%,Ge：2.4wt.%, Sc:0.6wt.%,
Th：0.4wt.%, surplus are zinc.The preparation method of alloy：As above the raw material matched is added to the electric induction furnace of atmosphere protection
It is interior, and use silicon carbide crucible；Sensing heating forms alloy solution to 500-600 degree, and is fully stirred using electromagnetic agitation effect
It mixes 10 minutes or so；Alloy liquid is stood to be cast to after ten minutes in the same level equipment of heat top in the heat preservation of 500-600 degree and is carried out
At required billet, it is 5-10m/min that ingot casting, which moves down speed, for semi-continuous casting.The ingot casting can regard galvanizing by dipping raw material and use
It is handled in the galvanizing by dipping of subsequent handling to carry out protection operation to steel wire, the wherein operating temperature of galvanizing by dipping is 360-450
Degree, hot dipping time are 30-40 seconds.
The kirsite has extremely excellent resistance to volatilization and oxidation resistent susceptibility, can reach in 400-800 degree temperature ranges
It is interior that 5 hours are stood under atmospheric environment without significantly aoxidizing.The liquid alloy is being stirred, is being blown etc. at melts
During reason, after its skin covering of the surface is destroyed because being vigorously stirred, energy rapid regeneration successfully hinders the oxidation and volatilization of alloy.It adopts
Zinc-plated with this patent uses alloy, under the low temperature environment of 360-450 degree, so that it may with interior on high-carbon steel surface in 30-40 seconds
The coating that thickness is 50-80 microns in hot-dip.Since operating temperature is low, the hot dipping time is short, and energy-saving effect is apparent.Convenient for worker
Operation, year consuming fund is also less, for the prefered method in galvanizing by dipping production.The alloy protected using this patent, Ke Yi
The hot dip galvanized product of no zinc flower can be gone out on conventional hot dip zinc production line in high-carbon steel surface production.In desert Environment
Under, the oxidation rate of the material is 1.5 × 10-4Mm/.Thus under desert climate, the material can use safely 30 years with
On without apparent oxidative phenomena occur.In comparison, the zinc coat of common hot-dip galvanizing alloy is one under desert Environment
As working life be 20 years or so.
Claims (3)
1. a kind of resistance to oxidation is without zinc flower pattern high-carbon steel galvanizing by dipping kirsite containing V；According to weight percent, the ingredient of the alloy
For：Li： 0.4-1.2wt.%,W:0.8-1.0wt.%,V:0.5-0.8wt.%,Ge：2.0-3.0wt.%, Sc:0.4-0.8wt.%,
Th：0.2-0.5wt.%, surplus are zinc.
2. resistance to oxidation is without zinc flower pattern high-carbon steel galvanizing by dipping kirsite containing V according to claim 1, it is characterised in that including
Following steps：As above the raw material matched is added in the electric induction furnace of atmosphere protection, and uses silicon carbide crucible；Sensing heating
Alloy solution is formed to 500-600 degree, and is sufficiently stirred 10 minutes or so using electromagnetic agitation effect；By alloy liquid in 500-
600 degree of heat preservations, which stand to be cast to after ten minutes in the same level equipment of heat top, carries out semi-continuous casting into required billet, ingot casting
It is 5-10m/min to move down speed.
3. resistance to oxidation is without zinc flower pattern high-carbon steel galvanizing by dipping kirsite containing V according to claim 1, it is characterised in that include
Following procedure of processing：The ingot casting can be handled to carry out steel wire as galvanizing by dipping raw material for the galvanizing by dipping of subsequent handling
Protection operation, the wherein operating temperature of galvanizing by dipping are 360-450 degree, and the hot dipping time is 30-40 seconds.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810423076.3A CN108441680A (en) | 2018-05-05 | 2018-05-05 | Resistance to oxidation is without zinc flower pattern high-carbon steel galvanizing by dipping kirsite containing V |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810423076.3A CN108441680A (en) | 2018-05-05 | 2018-05-05 | Resistance to oxidation is without zinc flower pattern high-carbon steel galvanizing by dipping kirsite containing V |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108441680A true CN108441680A (en) | 2018-08-24 |
Family
ID=63202193
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810423076.3A Withdrawn CN108441680A (en) | 2018-05-05 | 2018-05-05 | Resistance to oxidation is without zinc flower pattern high-carbon steel galvanizing by dipping kirsite containing V |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108441680A (en) |
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2018
- 2018-05-05 CN CN201810423076.3A patent/CN108441680A/en not_active Withdrawn
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Application publication date: 20180824 |