CN108441351A - A kind of weaving degreaser - Google Patents
A kind of weaving degreaser Download PDFInfo
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- CN108441351A CN108441351A CN201810363612.5A CN201810363612A CN108441351A CN 108441351 A CN108441351 A CN 108441351A CN 201810363612 A CN201810363612 A CN 201810363612A CN 108441351 A CN108441351 A CN 108441351A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
- C11D1/945—Mixtures with anionic, cationic or non-ionic compounds containing a combination of non-ionic compounds differently alcoxylised or with different alkylated chains
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
- C11D3/0015—Softening compositions liquid
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2034—Monohydric alcohols aromatic
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/221—Mono, di- or trisaccharides or derivatives thereof
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/06—Ether- or thioether carboxylic acids
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
Abstract
The invention discloses a kind of weaving degreasers, belong to chemical field.The present invention is according to the mass fraction, take the sodium chloride solution, 8 ~ 10 parts of sorbester p17s, 4 ~ 6 parts of isosorbide dimethyl ethers, 3 ~ 6 parts of aliphatic ester α sulfonate, 100 ~ 150 parts of water mixing that 50 ~ 70 portions of degreaser activating agents, 40 ~ 60 parts of soft antibacterial additives, 12 ~ 15 parts of isoamyl acetates, 20 ~ 40 parts of n-butanols, 40 ~ 50 parts of mass fractions are 0.5%, it is warming up to 70 ~ 80 DEG C and is stirred 3 ~ 5h to get weaving degreaser.The present invention solves that current Fabric degreaser oil removing is slow, oil removing is not thorough, effect is single, and the good degreaser of effect has the problem of injury to human body and environment.
Description
Technical field
The invention belongs to chemical fields, and in particular to a kind of weaving degreaser.
Background technology
With the increasingly raising of living standard, modern increasingly focuses on health, is removed when selecting personal clothing
Consider outside its color and style, further accounts for the safety of clothing, the feature of environmental protection and functionality.For example whether clothing has sterilization
Deodorization functions, if anion can be discharged and play the effect of keeping fit and healthy, if having function of infrared emitting etc..In addition,
In daily life, work, it often will appear the case where being stained with oil stain, and some dry-cleaning class organic agents are not suitable in family
Middle use.Also occur some effective degreasers currently on the market, but the universal oil removing of degreaser currently on the market is slow, oil removing
Be not thorough, effect it is single, and deoiling effect it is good damage health, have a pollution to environment, and because acid or alkalinity are strong, and right
Fabric, skin etc. are corrosive.Therefore, it is significantly and very big to the degreaser presence of human body close friend to produce a kind of effect of deoiling
The market demand.
Invention content
The technical problems to be solved by the invention:For current Fabric degreaser oil removing is slow, oil removing is not thorough, effect list
One, and the good degreaser of effect has the problem of injury to human body and environment, provides a kind of weaving degreaser.
In order to solve the above technical problems, the present invention is using technical solution as described below:
A kind of weaving degreaser, according to the mass fraction include following component, 12 ~ 15 parts of isoamyl acetates, 20 ~ 40 parts of n-butanols,
40 ~ 50 parts of mass fractions are 0.5% sodium chloride solution, 8 ~ 10 parts of Arlacel-80s, 4 ~ 6 parts of isosorbide dimethyl ethers, 3 ~ 6 parts of fat
Acid esters α-sulfonate, 100 ~ 150 parts of water, which is characterized in that further include 50 ~ 70 portions of degreaser activating agents, 40 ~ 60 parts of soft antibacterials
Additive;
The preparation method of the degreaser activating agent, includes the following steps:
(1)Take isomerous tridecanol polyoxyethylene ether 1300 in mass ratio 2:1, which is added isomerous tridecanol polyoxyethylene ether 1303, mixes,
It is stirred in 85 ~ 90 DEG C of oil baths, obtains stirring mixture, take stirring mixture in mass ratio 20 ~ 25:21 ~ 26 are added along fourth
Enedioic acid acid anhydride is stirred in 70 ~ 80 DEG C, obtains mixture;
(2)Take mixture in mass ratio 2:1 be added butanediol mixing, be stirred in 50 ~ 60 DEG C, add mixture quality 1 ~
3% sulfuric acid is warming up to 140 ~ 150 DEG C and is stirred to react, obtains reactant, takes reactant in mass ratio 10:1 is added sodium hydrogensulfite
Solution is stirred in 80 ~ 90 DEG C, is cooled to room temperature, and adjusts pH to 6 ~ 7, obtains cooling thing, take cooling thing in mass ratio 5:2:1
Cocoamidopropyl betaine, AEO carboxylic acid sodium mixing are to get degreaser activating agent;
The preparation method of the soft antibacterial additive, includes the following steps:
A. methylol silicone oil, methyl dimethoxysilane in mass ratio 20 is taken:30:1 is added tetramethylammonium hydroxide, is warming up to 90
~ 100 DEG C are stirred, and vacuum distillation obtains vacuum distillation object, take vacuum distillation object in mass ratio 2:1:10, which are added propylene oxide, is total to
Polyethers, absolute ethyl alcohol, are passed through nitrogen protection, are stirred in 65 ~ 75 DEG C, rotary evaporation, obtain rotary evaporation object;
B. rotary evaporation object in mass ratio 3 is taken:2:15 are added ethyl chloroacetate, absolute ethyl alcohol, nitrogen protection are passed through, in 70 ~ 75
DEG C be stirred, mixture A must be stirred, according to the mass fraction, take 20 ~ 30 parts of stirring mixture A, 2 ~ 5 portions of origanum oils, 3 ~ 6 parts
Scutelloside mixes to get soft antibacterial additive.
Compared with other methods, advantageous effects are the present invention:
(1)The present invention is by 1,303 two kinds of isomerous tridecanol polyoxyethylene ether 1300, isomerous tridecanol polyoxyethylene ether nonionic tables
Face activating agent carries out compounding and raw material, addition maleic anhydride, butanediol is used as to polymerize to form amphiphilic surfactant,
Introduce shorter coupling link, forcibly so that the arrangement of hydrophilic head base it is even closer, can reduce hydrophilic head base aggregation,
The introducing of electrostatic repulsion in adsorption process and aquation resistance, coupling link not only reduces distance between hydrophilic head base, Er Qiela
The close distance of two alkane interchains, is conducive to synergistic effect and occurs when surfactant is in self-organizing, have in oil removing
Stronger surface-active, in low temperature, there are two sulfonic group and two non-ionic segments for surfactant, have stronger hydrophilic
Property, and the surface tension very little of methyl, therefore the presence of methyl can further enhance surfactant reduction in heterogeneous structure
The ability of surface tension, when temperature gradually rises, sulfonic presence makes surfactant have water-soluble increase, is adsorbed on
The trend that the quantity on surface reduces, this trend can be such that surface tension increases, but simultaneously because contain tool nonionic table in structure
The presence of the polyoxyethylene structure of face activating agent feature, and the reduction of surfactant solubility is forced, make surfactant molecule
With better hydrophobic performance, it is possible to be easier to be adsorbed by surface, the ability for reducing surface tension is stronger, reaches preferable
Oil removing again easy-to-use water cleaning performance, while with AEO carboxylic acid sodium compound, due to containing ethoxy in its molecule
Base has excellent resistance to hard water, stronger lime soap dispersing power and excellent compatibility, adds cocamidopropyl propyl amide
Glycine betaine is a kind of amphoteric surfactant of function admirable, in structure the presence of carboxyl, quaternary ammonium group and Long carbon chain make it
Superior function with washing, thickening, foam stabilizing, three belong to environment-friendly type surfactant, hypotoxicity, biological degradability compared with
It is good, human body and environment will not be polluted;
(2)Hydroxy silicon oil and methyl dimethoxysilane are carried out polymerisation by the present invention, form intermediate product, then with epoxy third
Alkane copolyether carries out ring-opening reaction, uses ethyl chloroacetate quaternized on this basis, has synthesized soft antibacterial additive, polyethers ammonia
Base modified organic silicon softening agent mainly introduces polyether-based and ammonia alkyl in its polysiloxanes, has both amino and polyether-based
Double grading, the amino contained can effectively promote the flexibility and washability of fabric, and the polyether-based in system can be effective
The hydrophily of fabric is promoted, but since the heat-resistant stable of polyether group is poor, with the raising of temperature, the stabilization of lotion
Impatient acute decline, that is, using silica chain as main chain, introduces amino group and Hydrophilicrto polyether group in the side chain by quaternized,
Later by system amino carry out it is quaternized, effectively improve the cationic of system, this to its heat-resistant stable and with
It suffers from terms of the fastness that fabric fibre combines and is significantly promoted, while can also be improved to fabric yellowing resistance,
It can assign soft fabric smooth feel after cleaning of deoiling, restore Fabric Physical index.
Specific implementation mode
Cocoamidopropyl betaine:It is purchased from Shanghai Chu Xing Chemical Co., Ltd.s.
Isomerous tridecanol polyoxyethylene ether 1300, isomerous tridecanol polyoxyethylene ether 1303, fatty alcohol polyoxyethylene ether carboxylic
Sour sodium:It is purchased from Hai'an petrochemical plant.
Degreaser activating agent:
(1)Take isomerous tridecanol polyoxyethylene ether 1300 in mass ratio 2:1, which is added isomerous tridecanol polyoxyethylene ether 1303, mixes,
It is stirred 20 ~ 30min in 85 ~ 90 DEG C of oil baths, obtains stirring mixture, takes stirring mixture in mass ratio 20 ~ 25:21~26
Maleic anhydride is added, is stirred 2 ~ 3h in 70 ~ 80 DEG C, obtains mixture;
(2)Take mixture in mass ratio 2:1 is added butanediol mixing, is stirred 30 ~ 40min in 50 ~ 60 DEG C, adds mixing
The sulfuric acid that the mass fraction of amount of substance 1 ~ 3% is 80%, is warming up to 140 ~ 150 DEG C and is stirred to react 4 ~ 6h, obtain reactant, take reactant
In mass ratio 10:1 is added the solution of sodium bisulfite that mass fraction is 35%, is stirred 1 ~ 2h in 80 ~ 90 DEG C, is cooled to room
Temperature adjusts pH to 6 ~ 7, obtains cooling thing, take cooling thing in mass ratio 5:2:1 Cocoamidopropyl betaine, fatty alcohol polyoxy second
Alkene ether carboxylic acid sodium mixes to get degreaser activating agent.
Soft antibacterial additive:
A. methylol silicone oil, methyl dimethoxysilane in mass ratio 20 is taken:30:1 is added tetramethylammonium hydroxide, is warming up to 90
~ 100 DEG C are stirred 6 ~ 7h, and vacuum distillation obtains vacuum distillation object, take vacuum distillation object in mass ratio 2:1:10 are added epoxy third
Alkane copolyether, absolute ethyl alcohol, are passed through nitrogen protection, and 3 ~ 4h is stirred in 65 ~ 75 DEG C, and rotary evaporation obtains rotary evaporation object;
B. rotary evaporation object in mass ratio 3 is taken:2:15 are added ethyl chloroacetate, absolute ethyl alcohol, nitrogen protection are passed through, in 70 ~ 75
DEG C be stirred 3 ~ 5h, mixture A must be stirred, according to the mass fraction, take 20 ~ 30 parts of stirring mixture A, 2 ~ 5 portions of origanum oils, 3 ~
6 parts of scutellosides, 1 ~ 3 part of honeysuckle mixing are to get soft antibacterial additive.
A kind of weaving degreaser takes 50 ~ 70 portions of degreaser activating agents, 40 ~ 60 parts of soft antibacterial additions according to the mass fraction
Agent, 12 ~ 15 parts of isoamyl acetates, 20 ~ 40 parts of n-butanols, the sodium chloride solution that 40 ~ 50 parts of mass fractions are 0.5%, 8 ~ 10 parts of departments
Disk -80,4 ~ 6 parts of isosorbide dimethyl ethers, 3 ~ 6 parts of aliphatic ester α-sulfonate, 100 ~ 150 parts of water mixing, are warming up to 70 ~ 80 DEG C
3 ~ 5h is stirred to get weaving degreaser.
Cocoamidopropyl betaine:It is purchased from Shanghai Chu Xing Chemical Co., Ltd.s.
Isomerous tridecanol polyoxyethylene ether 1300, isomerous tridecanol polyoxyethylene ether 1303, fatty alcohol polyoxyethylene ether carboxylic
Sour sodium:It is purchased from Hai'an petrochemical plant.
Degreaser activating agent:
(1)Take isomerous tridecanol polyoxyethylene ether 1300 in mass ratio 2:1, which is added isomerous tridecanol polyoxyethylene ether 1303, mixes,
It is stirred 20min in 85 DEG C of oil baths, obtains stirring mixture, takes stirring mixture in mass ratio 20:21 are added maleic two
Acid anhydrides is stirred 2h in 70 DEG C, obtains mixture;
(2)Take mixture in mass ratio 2:1 is added butanediol mixing, is stirred 30min in 50 DEG C, adds mixture quality
The sulfuric acid that 1% mass fraction is 80%, is warming up to 140 DEG C and is stirred to react 4h, obtain reactant, take reactant in mass ratio 10:1 adds
Enter the solution of sodium bisulfite that mass fraction is 35%, be stirred 1h in 80 DEG C, be cooled to room temperature, adjusts pH to 6, obtain cooling
Object takes cooling thing in mass ratio 5:2:1 Cocoamidopropyl betaine, AEO carboxylic acid sodium mix to get going
Finish activating agent.
Soft antibacterial additive:
A. methylol silicone oil, methyl dimethoxysilane in mass ratio 20 is taken:30:1 is added tetramethylammonium hydroxide, is warming up to 90
DEG C it is stirred 6h, is evaporated under reduced pressure, obtains vacuum distillation object, takes vacuum distillation object in mass ratio 2:1:10 are added propylene oxide copolymer
Ether, absolute ethyl alcohol, are passed through nitrogen protection, and 3h is stirred in 65 DEG C, and rotary evaporation obtains rotary evaporation object;
B. rotary evaporation object in mass ratio 3 is taken:2:15 are added ethyl chloroacetate, absolute ethyl alcohol, are passed through nitrogen protection, are stirred in 70 DEG C
Mix mixing 3h, must stir mixture A, according to the mass fraction, take 20 parts stir mixture A, 2 portions of origanum oils, 3 parts of scutellosides, 1 part
Honeysuckle mixes to get soft antibacterial additive.
A kind of weaving degreaser takes 50 portions of degreaser activating agents, 40 parts of soft antibacterial additives, 12 according to the mass fraction
The sodium chloride solution, 8 parts of Arlacel-80s, 4 parts of isobides that part isoamyl acetate, 20 parts of n-butanols, 40 parts of mass fractions are 0.5%
Dimethyl ether, 3 parts of aliphatic ester α-sulfonate, 100 parts of water mixing are warming up to 70 DEG C and are stirred 3h to get weaving degreaser.
Cocoamidopropyl betaine:It is purchased from Shanghai Chu Xing Chemical Co., Ltd.s.
Isomerous tridecanol polyoxyethylene ether 1300, isomerous tridecanol polyoxyethylene ether 1303, fatty alcohol polyoxyethylene ether carboxylic
Sour sodium:It is purchased from Hai'an petrochemical plant.
Degreaser activating agent:
(1)Take isomerous tridecanol polyoxyethylene ether 1300 in mass ratio 2:1, which is added isomerous tridecanol polyoxyethylene ether 1303, mixes,
It is stirred 30min in 90 DEG C of oil baths, obtains stirring mixture, takes stirring mixture in mass ratio 25:26 are added maleic two
Acid anhydrides is stirred 3h in 80 DEG C, obtains mixture;
(2)Take mixture in mass ratio 2:1 is added butanediol mixing, is stirred 40min in 60 DEG C, adds mixture quality
The sulfuric acid that 3% mass fraction is 80%, is warming up to 150 DEG C and is stirred to react 6h, obtain reactant, take reactant in mass ratio 10:1 adds
Enter the solution of sodium bisulfite that mass fraction is 35%, be stirred 2h in 90 DEG C, be cooled to room temperature, adjusts pH to 7, obtain cooling
Object takes cooling thing in mass ratio 5:2:1 Cocoamidopropyl betaine, AEO carboxylic acid sodium mix to get going
Finish activating agent.
Soft antibacterial additive:
A. methylol silicone oil, methyl dimethoxysilane in mass ratio 20 is taken:30:1 is added tetramethylammonium hydroxide, is warming up to
100 DEG C are stirred 7h, and vacuum distillation obtains vacuum distillation object, take vacuum distillation object in mass ratio 2:1:10 are added propylene oxide
Copolyether, absolute ethyl alcohol, are passed through nitrogen protection, and 4h is stirred in 75 DEG C, and rotary evaporation obtains rotary evaporation object;
B. rotary evaporation object in mass ratio 3 is taken:2:15 are added ethyl chloroacetate, absolute ethyl alcohol, are passed through nitrogen protection, are stirred in 75 DEG C
Mix mixing 5h, must stir mixture A, according to the mass fraction, take 30 parts stir mixture A, 5 portions of origanum oils, 6 parts of scutellosides, 3 parts
Honeysuckle mixes to get soft antibacterial additive.
A kind of weaving degreaser takes 70 portions of degreaser activating agents, 60 parts of soft antibacterial additives, 15 according to the mass fraction
The sodium chloride solution, 10 parts of Arlacel-80s, 6 portions of different sorbs that part isoamyl acetate, 40 parts of n-butanols, 50 parts of mass fractions are 0.5%
Diethylene glycol dimethyl ether, 6 parts of aliphatic ester α-sulfonate, 150 parts of water mixing are warming up to 80 DEG C and are stirred 5h to get weaving degreaser.
Cocoamidopropyl betaine:It is purchased from Shanghai Chu Xing Chemical Co., Ltd.s.
Isomerous tridecanol polyoxyethylene ether 1300, isomerous tridecanol polyoxyethylene ether 1303, fatty alcohol polyoxyethylene ether carboxylic
Sour sodium:It is purchased from Hai'an petrochemical plant.
Degreaser activating agent:
(1)Take isomerous tridecanol polyoxyethylene ether 1300 in mass ratio 2:1, which is added isomerous tridecanol polyoxyethylene ether 1303, mixes,
It is stirred 25min in 87 DEG C of oil baths, obtains stirring mixture, takes stirring mixture in mass ratio 23:24 are added maleic two
Acid anhydrides is stirred 2h in 75 DEG C, obtains mixture;
(2)Take mixture in mass ratio 2:1 is added butanediol mixing, is stirred 35min in 55 DEG C, adds mixture quality
The sulfuric acid that 2% mass fraction is 80%, is warming up to 145 DEG C and is stirred to react 5h, obtain reactant, take reactant in mass ratio 10:1 adds
Enter the solution of sodium bisulfite that mass fraction is 35%, be stirred 1h in 85 DEG C, be cooled to room temperature, adjusts pH to 6, obtain cooling
Object takes cooling thing in mass ratio 5:2:1 Cocoamidopropyl betaine, AEO carboxylic acid sodium mix to get going
Finish activating agent.
Soft antibacterial additive:
A. methylol silicone oil, methyl dimethoxysilane in mass ratio 20 is taken:30:1 is added tetramethylammonium hydroxide, is warming up to 95
DEG C it is stirred 6h, is evaporated under reduced pressure, obtains vacuum distillation object, takes vacuum distillation object in mass ratio 2:1:10 are added propylene oxide copolymer
Ether, absolute ethyl alcohol, are passed through nitrogen protection, and 3h is stirred in 70 DEG C, and rotary evaporation obtains rotary evaporation object;
B. rotary evaporation object in mass ratio 3 is taken:2:15 are added ethyl chloroacetate, absolute ethyl alcohol, are passed through nitrogen protection, are stirred in 73 DEG C
Mix mixing 4h, must stir mixture A, according to the mass fraction, take 25 parts stir mixture A, 3 portions of origanum oils, 4 parts of scutellosides, 2 parts
Honeysuckle mixes to get soft antibacterial additive.
A kind of weaving degreaser takes 60 portions of degreaser activating agents, 50 parts of soft antibacterial additives, 13 according to the mass fraction
The sodium chloride solution, 9 parts of Arlacel-80s, 5 parts of isobides that part isoamyl acetate, 30 parts of n-butanols, 45 parts of mass fractions are 0.5%
Dimethyl ether, 4 parts of aliphatic ester α-sulfonate, 125 parts of water mixing are warming up to 75 DEG C and are stirred 4h to get weaving degreaser.
Comparative example 1:It is essentially identical with the preparation method of embodiment 2, it has only the difference is that lacking degreaser activating agent.
Comparative example 2:It is essentially identical with the preparation method of embodiment 2, it has only the difference is that lacking soft antibacterial additive.
Comparative example 3:The weaving degreaser of Shanghai City company production.
The clothes for speckling with kitchen oil stain is soaked in respectively in degreaser and the degreaser of comparative example obtained by examples detailed above, leaching
Degreasing situation is observed after steeping 2h.Follow-up observation one week records clothing corrosion condition.Test result is shown in Table 1.
Test event | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 | Comparative example 3 |
Oily waste degradation situation | Greasy dirt removes substantially | Greasy dirt removes substantially | Greasy dirt removes substantially | Greasy dirt removes mostly | Greasy dirt removes substantially | Greasy dirt removes mostly |
Clothing appearance | It is unchanged | It is unchanged | It is unchanged | It is unchanged | It is unchanged | Slight decoloration, decorative pattern deformation |
Clothing extent of corrosion after a week | Do not corrode | Do not corrode | Do not corrode | Do not corrode | Do not corrode | Garment portion has been corroded |
Security test:The degreaser of above-described embodiment is subjected to gavage to mouse by the dosage of 0.1mg/10g, is filled daily
Stomach is primary, and mouse activity is normal after 20 days, and feed is normal, and two is just normal, and therefore, degreaser of the invention is non-toxic or low-toxic system
Agent.
In summary, degreaser of the invention goes oil stain effect good, and to clothing without destructiveness, is worth using.
Claims (1)
1. a kind of weaving degreaser includes following component, 12 ~ 15 parts of isoamyl acetates, 20 ~ 40 parts of positive fourths according to the mass fraction
Alcohol, the sodium chloride solution that 40 ~ 50 parts of mass fractions are 0.5%, 8 ~ 10 parts of Arlacel-80s, 4 ~ 6 parts of isosorbide dimethyl ethers, 3 ~ 6 parts
Aliphatic ester α-sulfonate, 100 ~ 150 parts of water, which is characterized in that further include 50 ~ 70 portions of degreaser activating agents, 40 ~ 60 parts of softnesses
Antibacterial additives;
The preparation method of the degreaser activating agent, includes the following steps:
(1)Take isomerous tridecanol polyoxyethylene ether 1300 in mass ratio 2:1, which is added isomerous tridecanol polyoxyethylene ether 1303, mixes,
It is stirred in 85 ~ 90 DEG C of oil baths, obtains stirring mixture, take stirring mixture in mass ratio 20 ~ 25:21 ~ 26 are added along fourth
Enedioic acid acid anhydride is stirred in 70 ~ 80 DEG C, obtains mixture;
(2)Take mixture in mass ratio 2:1 be added butanediol mixing, be stirred in 50 ~ 60 DEG C, add mixture quality 1 ~
3% sulfuric acid is warming up to 140 ~ 150 DEG C and is stirred to react, obtains reactant, takes reactant in mass ratio 10:1 is added sodium hydrogensulfite
Solution is stirred in 80 ~ 90 DEG C, is cooled to room temperature, and adjusts pH to 6 ~ 7, obtains cooling thing, take cooling thing in mass ratio 5:2:1
Cocoamidopropyl betaine, AEO carboxylic acid sodium mixing are to get degreaser activating agent;
The preparation method of the soft antibacterial additive, includes the following steps:
A. methylol silicone oil, methyl dimethoxysilane in mass ratio 20 is taken:30:1 is added tetramethylammonium hydroxide, is warming up to 90
~ 100 DEG C are stirred, and vacuum distillation obtains vacuum distillation object, take vacuum distillation object in mass ratio 2:1:10, which are added propylene oxide, is total to
Polyethers, absolute ethyl alcohol, are passed through nitrogen protection, are stirred in 65 ~ 75 DEG C, rotary evaporation, obtain rotary evaporation object;
B. rotary evaporation object in mass ratio 3 is taken:2:15 are added ethyl chloroacetate, absolute ethyl alcohol, nitrogen protection are passed through, in 70 ~ 75
DEG C be stirred, mixture A must be stirred, according to the mass fraction, take 20 ~ 30 parts of stirring mixture A, 2 ~ 5 portions of origanum oils, 3 ~ 6 parts
Scutelloside mixes to get soft antibacterial additive.
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