CN108441344A - A kind of new-energy automobile vehicle window wash agent - Google Patents
A kind of new-energy automobile vehicle window wash agent Download PDFInfo
- Publication number
- CN108441344A CN108441344A CN201810352947.7A CN201810352947A CN108441344A CN 108441344 A CN108441344 A CN 108441344A CN 201810352947 A CN201810352947 A CN 201810352947A CN 108441344 A CN108441344 A CN 108441344A
- Authority
- CN
- China
- Prior art keywords
- parts
- energy automobile
- new
- agent
- vehicle window
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 66
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 40
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 37
- 239000012459 cleaning agent Substances 0.000 claims abstract description 21
- 235000019795 sodium metasilicate Nutrition 0.000 claims abstract description 20
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 19
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims abstract description 19
- 229940048086 sodium pyrophosphate Drugs 0.000 claims abstract description 19
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 19
- 235000019818 tetrasodium diphosphate Nutrition 0.000 claims abstract description 19
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims abstract description 19
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 8
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- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 26
- -1 fatty alcohol phosphate Chemical class 0.000 claims description 19
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- GHLITDDQOMIBFS-UHFFFAOYSA-H cerium(3+);tricarbonate Chemical compound [Ce+3].[Ce+3].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O GHLITDDQOMIBFS-UHFFFAOYSA-H 0.000 claims description 5
- UBXAKNTVXQMEAG-UHFFFAOYSA-L strontium sulfate Inorganic materials [Sr+2].[O-]S([O-])(=O)=O UBXAKNTVXQMEAG-UHFFFAOYSA-L 0.000 claims description 5
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 5
- 229910019142 PO4 Inorganic materials 0.000 claims description 4
- WCCJDBZJUYKDBF-UHFFFAOYSA-N copper silicon Chemical compound [Si].[Cu] WCCJDBZJUYKDBF-UHFFFAOYSA-N 0.000 claims description 4
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- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 4
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- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 4
- 239000003921 oil Substances 0.000 claims description 4
- 239000010452 phosphate Substances 0.000 claims description 4
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 4
- YMCIVAPEOZDEGH-UHFFFAOYSA-N 5-chloro-2,3-dihydro-1h-indole Chemical compound ClC1=CC=C2NCCC2=C1 YMCIVAPEOZDEGH-UHFFFAOYSA-N 0.000 claims description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 150000005215 alkyl ethers Chemical class 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
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- 239000007788 liquid Substances 0.000 abstract description 8
- 238000003860 storage Methods 0.000 abstract description 3
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- 230000000052 comparative effect Effects 0.000 description 8
- 238000002474 experimental method Methods 0.000 description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 6
- 239000012530 fluid Substances 0.000 description 6
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- 229920000742 Cotton Polymers 0.000 description 5
- 239000005357 flat glass Substances 0.000 description 5
- 235000019353 potassium silicate Nutrition 0.000 description 5
- 235000019441 ethanol Nutrition 0.000 description 4
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- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical class CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 244000137852 Petrea volubilis Species 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
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- 229910000831 Steel Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- 239000007938 effervescent tablet Substances 0.000 description 2
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- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- BQPXGQXOBKDNDA-UHFFFAOYSA-N 4-methyl-5-(3-phenylpropyl)-2H-triazole Chemical compound CC1=C(CCCC2=CC=CC=C2)N=NN1 BQPXGQXOBKDNDA-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 241001062009 Indigofera Species 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 230000002528 anti-freeze Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- XIWFQDBQMCDYJT-UHFFFAOYSA-M benzyl-dimethyl-tridecylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 XIWFQDBQMCDYJT-UHFFFAOYSA-M 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 229940043237 diethanolamine Drugs 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
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- 238000007598 dipping method Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
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- 231100000719 pollutant Toxicity 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 238000007788 roughening Methods 0.000 description 1
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- 239000013049 sediment Substances 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
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- 239000011684 sodium molybdate Substances 0.000 description 1
- 235000015393 sodium molybdate Nutrition 0.000 description 1
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 description 1
- 239000012086 standard solution Substances 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 229940032912 zephiran Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
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- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
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-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0073—Anticorrosion compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/1233—Carbonates, e.g. calcite or dolomite
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
- C11D3/3738—Alkoxylated silicones
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/78—Neutral esters of acids of phosphorus
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/18—Glass; Plastics
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of new-energy automobile vehicle window wash agent.It is grouped as by the group of following parts by weight：20 50 parts of neopelex, 48 parts of sodium metasilicate, 3 10 parts of ethylene glycol, 35 parts of sodium pyrophosphate, 13 parts of natrium malicum, 35 parts of antifoaming agent, 35 parts of emulsifier, 35 parts of bleeding agent, 300 1000 parts of water.The automotive window cleaning agent of the present invention, cleaning performance is good, and detergent solution is in stable condition, and long-term storage is homogeneous liquid, cleaning solution is small to the corrosivity of plastics and metal product, and thermal stability and low-temperature stability are good, and water-resistance is good without precipitation.
Description
Technical field
The invention belongs to new-energy automobile beautifying technique fields, and in particular to a kind of new-energy automobile vehicle window wash agent.
Background technology
Automobile glass cleaning agent is commonly called as bath of glass, is used for the operational maintenance of shield glass, the vapour sold in the market
Vehicle glass cleaner mainly has three kinds of liquid glass water, rain brush essence and solid glass water effervescent tablet, and wherein liquid glass water can be straight
It connects addition to use, rain brush essence is the concentrate of liquid glass water, and when use need to be diluted with water, and solid glass water effervescent tablet is then
By not solvent-laden automobile glass cleaning agent after rain brush essence further concentration, compression, when use, need to add water fully to dissolve.
Liquid glass water is most widely used usage type currently on the market, because its is easy to use, and can be added
Antifreeze is directly replaced without preparing or diluting.But current market sales of liquid glass water, cleaning
It is inefficient, and cleaning agent has been used long to will produce flocculent deposit, influence using effect.
Patent 201110387919.7 discloses a kind of long effective environmental protection type automobile window glass cleaning solution.By mass percentage
Meter, following components is agitated to react：Ethyl alcohol, ethylene glycol monobutyl ether, alkyl phenol polyoxyethylene ether, dodecylbenzyl chlorination
Ammonium, ethylene glycol, glycerine, polyoxyethylene alkyl phenyl ether, sodium benzoate, methyl phenylpropyl triazole, sodium molybdate, ethylenediamine tetrem
Acid disodium, sodium chloride, sun-proof indigo plant, triethanolamine, antifoaming agent, industrial pure water.Patent 201210488869.6 discloses a kind of vehicle
With bath of glass, consist of the following components in percentage by weight：5-10% propylene glycol monomethyl ethers, 20-40% isopropanols, 4-12% 12
Zephiran, 1-7% anhydrous sodium metasilicates, surplus are deionized water.The vehicle glass water can be removed effectively
Water solubility on glass and water-insoluble dirt, delay wiper aging.But cleaning agent cleaning is inefficient, is easy
Generate flocculent deposit.
Invention content
The purpose of the present invention is to provide a kind of new-energy automobile vehicle window wash agent.
A kind of new-energy automobile vehicle window wash agent, is grouped as by the group of following parts by weight：Neopelex 20-
50 parts, 4-8 parts of sodium metasilicate, 3-10 parts of ethylene glycol, 3-5 parts of sodium pyrophosphate, 1-3 parts of natrium malicum, 3-5 parts of antifoaming agent, emulsifier
3-5 parts, 3-5 parts of bleeding agent, 300-1000 parts of water.
The antifoaming agent is glycerine, polyether modified siloxane, the one or more in dimethicone.
The emulsifier is triglycerin aliphatic ester, fatty alcohol phosphate polyoxyethylene ether, polyoxyethylene alkyl ether, copper silicon
One or more in oil.
The bleeding agent is polyethylene glycol, empgen BB, one kind in diisooctyl maleate sulfonate
Or more than one.
The cleaning agent further includes 1-3 parts of cerous carbonates.
The cleaning agent further includes 1-3 parts of celestines.
The preparation method of above-mentioned new-energy automobile vehicle window wash agent, which is characterized in that carry out in accordance with the following steps：
(1) according to parts by weight, 300-1000 parts of water is weighed, reaction kettle is added, neopelex is then added
20-50 parts, 4-8 parts of sodium metasilicate, 3-10 parts of ethylene glycol, 3-5 parts of sodium pyrophosphate, 1-3 parts of natrium malicum is warming up to 40-50 DEG C, stirs
Mix 10-30min；
(2) it is cooled to room temperature, 3-5 parts of antifoaming agent, 3-5 parts of emulsifier is added, 3-5 parts of bleeding agent stirs 10-30min, system
At.
It is additionally added 1-3 parts of cerous carbonate in the step (1).
It is additionally added 1-3 parts of celestine in the step (1).
Beneficial effects of the present invention：The automotive window cleaning agent of the present invention, cleaning performance is good, and detergent solution state is steady
Fixed, long-term storage is homogeneous liquid, cleaning solution is small to the corrosivity of plastics and metal product, thermal stability and low temperature without precipitation
It has good stability, water-resistance is good.
Specific implementation mode
With reference to specific embodiment, the present invention will be further described.
Embodiment 1
A kind of new-energy automobile vehicle window wash agent, is grouped as by the group of following parts by weight：Neopelex 35
Part, 6 parts of sodium metasilicate, 6 parts of ethylene glycol, 4 parts of sodium pyrophosphate, 2 parts of natrium malicum, 4 parts of glycerine, 4 parts of triglycerin aliphatic ester gather
4 parts of ethylene glycol, 600 parts of water.
The preparation method of above-mentioned new-energy automobile vehicle window wash agent, which is characterized in that carry out in accordance with the following steps：
(1) according to parts by weight, 600 parts of water is weighed, reaction kettle is added, 35 parts of neopelex is then added,
6 parts of sodium metasilicate, 6 parts of ethylene glycol, 4 parts of sodium pyrophosphate, 2 parts of natrium malicum are warming up to 45 DEG C, stir 20min；
(2) it is cooled to room temperature, 4 parts of glycerine, 4 parts of triglycerin aliphatic ester is added, 4 parts of polyethylene glycol stirs 20min,
It is made.
Embodiment 2
A kind of new-energy automobile vehicle window wash agent, is grouped as by the group of following parts by weight：Neopelex 20
Part, 4 parts of sodium metasilicate, 3 parts of ethylene glycol, 3 parts of sodium pyrophosphate, 1 part of natrium malicum, 3 parts of polyether modified siloxane, fatty alcohol phosphate
3 parts of polyoxyethylene ether, 3 parts of empgen BB, 300 parts of water.
The preparation method of above-mentioned new-energy automobile vehicle window wash agent, which is characterized in that carry out in accordance with the following steps：
(1) according to parts by weight, 300 parts of water is weighed, reaction kettle is added, 20 parts of neopelex is then added,
4 parts of sodium metasilicate, 3 parts of ethylene glycol, 3 parts of sodium pyrophosphate, 1 part of natrium malicum are warming up to 40 DEG C, stir 10min；
(2) it is cooled to room temperature, 3 parts of polyether modified siloxane, 3 parts of fatty alcohol phosphate polyoxyethylene ether, dodecane is added
3 parts of base glycine betaine stirs 20min, is made.
Embodiment 3
A kind of new-energy automobile vehicle window wash agent, is grouped as by the group of following parts by weight：Neopelex 50
Part, 8 parts of sodium metasilicate, 10 parts of ethylene glycol, 5 parts of sodium pyrophosphate, 3 parts of natrium malicum, 5 parts of dimethicone, 5 parts of copper silicon oil, along fourth
5 parts of enedioic acid di-isooctyl sulfonate, 1000 parts of water.
The preparation method of above-mentioned new-energy automobile vehicle window wash agent, which is characterized in that carry out in accordance with the following steps：
(1) according to parts by weight, 1000 parts of water is weighed, reaction kettle is added, 50 parts of neopelex is then added,
8 parts of sodium metasilicate, 10 parts of ethylene glycol, 5 parts of sodium pyrophosphate, 3 parts of natrium malicum are warming up to 50 DEG C, stir 30min；
(2) it is cooled to room temperature, 5 parts of dimethicone, 5 parts of copper silicon oil, diisooctyl maleate sulfonate 5 is added
Part, 20min is stirred, is made.
Embodiment 4
A kind of new-energy automobile vehicle window wash agent, is grouped as by the group of following parts by weight：Neopelex 35
Part, 6 parts of sodium metasilicate, 6 parts of ethylene glycol, 4 parts of sodium pyrophosphate, 2 parts of natrium malicum, 2 parts of cerous carbonate, 4 parts of glycerine, triglycerin fat
4 parts of acid esters, 4 parts of polyethylene glycol, 600 parts of water.
The preparation method of above-mentioned new-energy automobile vehicle window wash agent, which is characterized in that carry out in accordance with the following steps：
(1) according to parts by weight, 600 parts of water is weighed, reaction kettle is added, 35 parts of neopelex is then added,
6 parts of sodium metasilicate, 6 parts of ethylene glycol, 4 parts of sodium pyrophosphate, 2 parts of natrium malicum, 2 parts of cerous carbonate are warming up to 45 DEG C, stir 20min；
(2) it is cooled to room temperature, 4 parts of glycerine, 4 parts of triglycerin aliphatic ester is added, 4 parts of polyethylene glycol stirs 20min,
It is made.
Embodiment 5
A kind of new-energy automobile vehicle window wash agent, is grouped as by the group of following parts by weight：Neopelex 35
Part, 6 parts of sodium metasilicate, 6 parts of ethylene glycol, 4 parts of sodium pyrophosphate, 2 parts of natrium malicum, 4 parts of glycerine, 2 parts of celestine, triglycerin fat
4 parts of acid esters, 4 parts of polyethylene glycol, 600 parts of water.
The preparation method of above-mentioned new-energy automobile vehicle window wash agent, which is characterized in that carry out in accordance with the following steps：
(1) according to parts by weight, 600 parts of water is weighed, reaction kettle is added, 35 parts of neopelex is then added,
6 parts of sodium metasilicate, 6 parts of ethylene glycol, 4 parts of sodium pyrophosphate, 2 parts of natrium malicum, 2 parts of celestine are warming up to 45 DEG C, stir 20min；
(2) it is cooled to room temperature, 4 parts of glycerine, 4 parts of triglycerin aliphatic ester is added, 4 parts of polyethylene glycol stirs 20min,
It is made.
Embodiment 6
A kind of new-energy automobile vehicle window wash agent, is grouped as by the group of following parts by weight：Neopelex 35
Part, 6 parts of sodium metasilicate, 6 parts of ethylene glycol, 4 parts of sodium pyrophosphate, 2 parts of natrium malicum, 4 parts of glycerine, 4 parts of triglycerin aliphatic ester gather
4 parts of ethylene glycol, 10 parts of word clothing extracting solution, 600 parts of water.
The extracting method of the word clothing extracting solution is：Fresh word clothing is taken, is smashed to pieces, the 30% of 3-6 times of parts by weight is added
Ethanol water refluxing extraction, merging filtrate, activated carbon decolorizing, the volume for concentrating filtrate are the 1/3 of merging filtrate volume, system
At.
The preparation method of above-mentioned new-energy automobile vehicle window wash agent, which is characterized in that carry out in accordance with the following steps：
(1) according to parts by weight, 600 parts of water is weighed, reaction kettle is added, 35 parts of neopelex is then added,
6 parts of sodium metasilicate, 6 parts of ethylene glycol, 4 parts of sodium pyrophosphate, 2 parts of natrium malicum are warming up to 45 DEG C, stir 20min；
(2) it is cooled to room temperature, 4 parts of glycerine, 4 parts of triglycerin aliphatic ester, 4 parts of polyethylene glycol, the extraction of word clothing is added
10 parts of liquid stirs 20min, is made.
Comparative example 1
A kind of new-energy automobile vehicle window wash agent, is grouped as by the group of following parts by weight：Neopelex 35
Part, 6 parts of sodium metasilicate, 6 parts of ethylene glycol, 4 parts of sodium pyrophosphate, 4 parts of glycerine, 4 parts of triglycerin aliphatic ester, 4 parts of polyethylene glycol, water
600 parts.
The preparation method of above-mentioned new-energy automobile vehicle window wash agent, which is characterized in that carry out in accordance with the following steps：
(1) according to parts by weight, 600 parts of water is weighed, reaction kettle is added, 35 parts of neopelex is then added,
6 parts of sodium metasilicate, 6 parts of ethylene glycol, 4 parts of sodium pyrophosphate are warming up to 45 DEG C, stir 20min；(2) it is cooled to room temperature, glycerine is added
4 parts, 4 parts of triglycerin aliphatic ester, 4 parts of polyethylene glycol stirs 20min, is made.
Experimental example 1：Cleaning solution appearance quality detection
Because the storage time of automobile glass cleaning agent is longer, therefore product must be stablized, uniformly, the cleaning solution examination of preparation
Sample, will be after cleaning fluid samples placement a period of time under the conditions of set point of temperature, and whether range estimation cleaning fluid samples are homogeneous liquid.
Has plug graduated cylinder using 100mL, after the cleaning agent of embodiment 1-6 and comparative example 1 are fully shaken up, apparatus plug graduated cylinder takes
Fluid samples 100mL is cleaned, plug is loaded onto.Graduated cylinder is placed for 24 hours under the conditions of 25 DEG C, visually inspects embodiment 1-6 and comparative example 1
Cleaning agent style without layering and deposited phenomenon；Graduated cylinder is placed for 24 hours under the conditions of 38 DEG C, visual inspection embodiment 1-6's
Cleaning agent style is without layering and deposited phenomenon；The cleaning agent style of comparative example 1 has lamination, and has a little glue heavy
It forms sediment.
Experimental example 2：Cleaning solution cleaning strength measures
According to GB/T 23436-2009, a certain amount of standard solid object is smeared on glass, is used respectively under prescribed conditions
Sample and titer are cleaned, and the quality of cleaning performance is compared.
The preparation steps of standard cleaning liquid are as follows：
(1) measure respectively to scale 130mL ethyl alcohol, 20mL isopropanols, 0.15mL alkyl phenol polyoxyethylene ether,
The water of 2.5mL diethanol amine and 347.35mL are added in the beaker of 750mL, and being sufficiently stirred with glass bar makes it be uniformly mixed.
(2) the standard cleaning liquid 50mL being uniformly mixed in beaker is measured, by 1:1 volume ratio is added 50mL distilled water and carries out
Dilution is uniformly mixed spare.
Test experiments step：
(1) pretreatment of glass surface
Prepare 10g grain sizes and is not more than 20 μm of aluminium oxide, the diatomite of the above-mentioned specifications of 10g.I type samples, by 10g diatomite
It is uniformly mixed with 2g water and is used as polishing agent, sheet glass is immersed scouring, removes the dirt and grease of glass surface, then again
With clear water rinse glass surface, as once-through operation cannot fully erased glass surface dirt, repeat aforesaid operations, until glass
After the moisture film uniformity on glass surface, naturally dry glass.II type samples use 10g aluminium oxide and 2g water to be uniformly mixed as throwing
Photo etching, then according to above-mentioned steps repetitive operation.
(2) pollution is handled
After standard solid object is stirred evenly, it is applied to glass sheet surface, keep smearing dynamics consistent and smears number phase
Together, 10min is spontaneously dried.
(3) cleaning strength is tested
1. dipping the appropriate titer in beaker with absorbent cotton, absorbent cotton is made to soak completely, it is past to clamp absorbent cotton with tweezers
Stop after multiple cleaning glass window piece 10 times, control wiping frequency is about 1 time/3s, and dynamics uniformity is kept in wiping process.
2. after sheet glass natural drying after from sheet glass 30cm glass sheet surface pollutant residual condition,
That is the bright and clean degree of standard cleaning liquid cleaning sheet glass.
3. replacing standard cleaning liquid with the cleaning agent sample of embodiment 1-6 and comparative example 1, repeats step 2., it is bright to observe its
Net degree is simultaneously compared with titer cleaning performance.
Experimental result is as shown in table 1：
1 each experimental group cleaning force of table is compared with standard solution
As can be seen from Table 1, embodiment 1-3 and the cleaning force of embodiment 5 are suitable with titer, embodiment 4 and embodiment 6
Cleaning agent be higher than titer, the cleaning force of comparative example 1 is not so good as titer, is substandard product.
Experimental example 3：Cleaning solution metal protection measures
According to the regulation of GB/T 23436-2009, test to test piece appearance and mass change.
1. preparation
(1) prepare metal testing plate
1. removing scratch, cut, hole along the direction polishing aluminium flake parallel with long side and copper sheet with 320A and 400A sand paper
Point etc., same sand paper can only polish a kind of metal, and steel disc need not polish.
2. steel disc and the aluminium flake polished and copper sheet are cleaned up with 95% ethyl alcohol, dried with silk, is put into 23 DEG C ± 5
DEG C vacuum desiccator in keep 1h or more.
(2) prepare sample
Cleaning fluid samples are continued plus water is configured to test the required minimum sample using concentration.
2. experimental procedure
1. being injected in three screw socket conical flasks respectively, 300mL is minimum to use concentration samples.
2. weighing each metal testing plate quality (being careful not to stay in fingerprint in test piece), it is denoted as m1, it is accurate to 0.1mg.
3. three kinds of metal testing plates are suspended on cord in conical flask respectively, bottom of bottle is not touched, bottle cap is covered.
4. three ready screw socket conical flasks are put into 50 DEG C ± 2 DEG C of thermostatic vacuum drier, 48h is kept.
5. taking out metal testing plate, corrosion product is brushed away with banister brush, then cleaned with 95% ethyl alcohol, silk is dried, observation examination
Whether piece surface has phenomena such as pitting corrosion or surface roughening, is then placed in 23 DEG C ± 5 DEG C of vacuum desiccator and keeps at least 1h.
6. weighing each metal testing plate quality, it is denoted as m2, it is accurate to 0.1mg, vernier caliper measurement specimen size is used in combination, is measured
Value calculates the mass change of each metal testing plate per surface area, takes the arithmetic mean of instantaneous value of measurement result twice accurately to 0.02mm
As measurement result.
3. calculation formula
The mass change of metal testing plate is calculated by following formula：
M=(m2-m1)/s
In formula, the mass change of M- metal testing plates, mg/cm2；
m1Metal testing plate quality, mg before experiment；
m2Metal testing plate quality after experiment, mg；
The surface area of s- metal testing plates, cm2。
Experimental result is as shown in table 2；
The mass change of 2 metal testing plate of table
Note：* P is represented<0.05；* represents P<0.01.
As can be seen from Table 2, embodiment 1-6 prepare cleaning agent cleaning metal testing plate mass change respectively ±
0.20mg/cm2、±0.15mg/cm2, meet the requirements of the standard, comparative example 1 does not meet standard requirement, the cleaning of 6 cleaning agent of embodiment
Metal testing plate mass change significantly less than embodiment 1, cleaning performance is significantly better than embodiment 1.
Experimental example 4：The measurement that cleaning solution influences plastics
According to the regulation of GB/T 23436-2009, shadow of the cleaning fluid samples to plastics test piece appearance and mass change is examined
It rings.
1. experimental procedure
1. by plastics test piece, Rapid Cleaning is clean in water, is blotted or is dried with cotton gauze, is put into 23 DEG C ± 5 DEG C of vacuum
It is kept in drier more than for 24 hours, is denoted as m1, weigh and be accurate to 0.1mg, measure the surface area of each plastics test piece.
2. being separately added into 200mL cleaning fluid samples in screw socket conical flask, the two panels plastics test piece of material of the same race is put into
Into same conical flask, so that plastics test piece is totally submerged in the sample, cover bottle cap, it is dry to be put into 50 DEG C ± 2 DEG C of constant-temperature vacuum
In dry device, 120h is kept.
3. taking out plastics test piece, get express developed totally, blotted with cotton gauze in water, whether there is or not open for observation plastics strip
Phenomena such as splitting, be bubbled, deforming.
4. being weighed after plastics test piece spontaneously dries 3h, it is denoted as m2, weigh and be accurate to 0.1mg.
5. calculating the mass change of each plastics test piece, take the arithmetic mean of instantaneous value of measurement result as measurement result.
2. calculation formula
The mass change of plastics test piece is calculated by following formula：
M=(m2-m1)/s
In formula, the mass change of M- plastics test pieces, mg/cm2；
m1Plastics test piece quality, mg before experiment；
m2Plastics test piece quality, mg after experiment；
The surface area of s- plastics test pieces, cm2。
Experimental result is as shown in table 3；
The mass change of 3 plastics test piece of table
Note：* P is represented<0.05；* represents P<0.01.
As can be seen from Table 3, embodiment 1-6 prepare cleaning agent cleaning plastics test piece mass change respectively ±
1.50mg/cm2、±0.20mg/cm2, meet the requirements of the standard, comparative example 1 does not meet standard requirement, the cleaning agent of embodiment 4-5
For the mass change of the plastics test piece of cleaning significantly less than embodiment 1, cleaning performance is significantly better than embodiment 1.
Claims (9)
1. a kind of new-energy automobile vehicle window wash agent, which is characterized in that be grouped as by the group of following parts by weight：Detergent alkylate
20-50 parts of sodium sulfonate, 4-8 parts of sodium metasilicate, 3-10 parts of ethylene glycol, 3-5 parts of sodium pyrophosphate, 1-3 parts of natrium malicum, antifoaming agent 3-5
Part, 3-5 parts of emulsifier, 3-5 parts of bleeding agent, 300-1000 parts of water.
2. new-energy automobile vehicle window wash agent according to claim 1, which is characterized in that the antifoaming agent is glycerine, is gathered
Ether modified siloxane, the one or more in dimethicone.
3. new-energy automobile vehicle window wash agent according to claim 1, which is characterized in that the emulsifier is triglycerin fat
Acid esters, fatty alcohol phosphate polyoxyethylene ether, polyoxyethylene alkyl ether, the one or more in copper silicon oil.
4. new-energy automobile vehicle window wash agent according to claim 1, which is characterized in that the bleeding agent is polyethylene glycol,
Empgen BB, the one or more in diisooctyl maleate sulfonate.
5. new-energy automobile vehicle window wash agent according to claim 4, which is characterized in that the cleaning agent further includes 1-3 parts
Cerous carbonate.
6. new-energy automobile vehicle window wash agent according to claim 4, which is characterized in that the cleaning agent further includes 1-3 parts
Celestine.
7. the preparation method of new-energy automobile vehicle window wash agent described in claim 1, which is characterized in that in accordance with the following steps into
Row：
(1) according to parts by weight, 300-1000 parts of water is weighed, reaction kettle is added, neopelex 20-50 is then added
Part, 4-8 parts of sodium metasilicate, 3-10 parts of ethylene glycol, 3-5 parts of sodium pyrophosphate, 1-3 parts of natrium malicum are warming up to 40-50 DEG C, stir 10-
30min；
(2) it is cooled to room temperature, 3-5 parts of antifoaming agent, 3-5 parts of emulsifier is added, 3-5 parts of bleeding agent stirs 10-30min, is made.
8. the preparation method of new-energy automobile vehicle window wash agent described in claim 1, which is characterized in that in the step (1) also
1-3 parts of cerous carbonate is added.
9. the preparation method of new-energy automobile vehicle window wash agent described in claim 1, which is characterized in that in the step (1) also
1-3 parts of celestine is added.
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| CN201810352947.7A CN108441344A (en) | 2018-04-19 | 2018-04-19 | A kind of new-energy automobile vehicle window wash agent |
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| CN201810352947.7A CN108441344A (en) | 2018-04-19 | 2018-04-19 | A kind of new-energy automobile vehicle window wash agent |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5906972A (en) * | 1994-10-14 | 1999-05-25 | Rhodia Inc. | Liquid detergent composition |
| CN103409110A (en) * | 2013-08-20 | 2013-11-27 | 南通市通州区益君劳务有限公司 | Cleaning and antifogging agent for glass |
| CN104277924A (en) * | 2013-07-12 | 2015-01-14 | 中国石油天然气股份有限公司 | Automobile windshield cleaning fluid |
| CN106978272A (en) * | 2017-05-03 | 2017-07-25 | 安徽万宝玻璃有限公司 | A kind of glass cleaner and preparation method thereof |
-
2018
- 2018-04-19 CN CN201810352947.7A patent/CN108441344A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5906972A (en) * | 1994-10-14 | 1999-05-25 | Rhodia Inc. | Liquid detergent composition |
| CN104277924A (en) * | 2013-07-12 | 2015-01-14 | 中国石油天然气股份有限公司 | Automobile windshield cleaning fluid |
| CN103409110A (en) * | 2013-08-20 | 2013-11-27 | 南通市通州区益君劳务有限公司 | Cleaning and antifogging agent for glass |
| CN106978272A (en) * | 2017-05-03 | 2017-07-25 | 安徽万宝玻璃有限公司 | A kind of glass cleaner and preparation method thereof |
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