CN108441332A - A kind of cleaning agent containing nonionic surfactant - Google Patents

A kind of cleaning agent containing nonionic surfactant Download PDF

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Publication number
CN108441332A
CN108441332A CN201810271204.7A CN201810271204A CN108441332A CN 108441332 A CN108441332 A CN 108441332A CN 201810271204 A CN201810271204 A CN 201810271204A CN 108441332 A CN108441332 A CN 108441332A
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CN
China
Prior art keywords
parts
nonionic surfactant
ether
cleaning agent
fatty alcohol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810271204.7A
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Chinese (zh)
Inventor
王加国
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JIANGSU HAI'AN PETROCHEMICAL PLANT
Original Assignee
JIANGSU HAI'AN PETROCHEMICAL PLANT
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JIANGSU HAI'AN PETROCHEMICAL PLANT filed Critical JIANGSU HAI'AN PETROCHEMICAL PLANT
Priority to CN201810271204.7A priority Critical patent/CN108441332A/en
Publication of CN108441332A publication Critical patent/CN108441332A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008Polymeric surface-active agents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/06Phosphates, including polyphosphates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2068Ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/30Amines; Substituted amines ; Quaternized amines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/33Amino carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707Polyethers, e.g. polyalkyleneoxides

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The present invention discloses a kind of cleaning agent containing nonionic surfactant, which is characterized in that includes according to the mass fraction:5 20 parts of nonionic surfactant, 18 parts of ethanol amine, 5 20 parts of butyl glycol ether, 18 parts of fatty alcohol polyoxyethylene ether, 5 12 parts of Fatty alcohol polyoxyethylene polyoxypropylene ether, 10 18 parts of aliphatic alcohol polyethenoxy methyl ether, 0.1 0.2 parts of ethylenediamine tetra-acetic acid, 0.05 0.12 parts of calgon, 0.08 0.12 parts of sodium tripolyphosphate, 45 50 parts of deionized water.The cleaning agent clean dirt ability is strong, and the cost of component raw material is low, pollution-free.

Description

A kind of cleaning agent containing nonionic surfactant
Technical field
The present invention relates to the technical field of cleaning agent, more particularly to a kind of cleaning agent containing nonionic surfactant.
Background technology
Liquid crystal display (LCD) can remain after filled liquid crystal in cell surface, PIN foot and slit under vacuum Liquid crystal if not removing the appearance that will seriously affect product, the display performance even service life, or causes fault.LCD scavengers The process that skill substantially experienced organic matter solvent to semi-aqueous cleaning forms three kinds of cleaning ways:The first is to use ozone-depleting Property the cleaning of substance (ODS) solvent, such as freon (CFC-113), 1,1,1- trichloroethanes, carbon tetrachloride etc., because having chemically The characteristics such as matter is stable, nonflammable, surface tension is low, attacking material surface, evaporation rate be not fast are used widely, and are volatilized simultaneously Point entering air and not only breaking up atmospheric ozone layer can also generate nitrate, sulfate or even Secondary Organic gas by photochemical reaction Colloidal sol (important composition of PM2.5), has been cited as limited production and regulated substance;Second of non-DOS solvents cleaning, can subtract to a certain degree Of low pollution but component used still belong to inflammable explosive article, and cleaning equipment need to make requirement of explosion proof.Both modes all belong to solvent cleaning, dash forward The environmental problem gone out more makes its application be very limited.
Invention content
The object of the present invention is to provide a kind of cleaning agents containing nonionic surfactant, solve the above-mentioned prior art and ask One or more in topic.
A kind of cleaning agent containing nonionic surfactant provided by the invention includes according to the mass fraction:5-20 parts Nonionic surfactant;1-8 parts of ethanol amine;5-20 parts of butyl glycol ether;1-8 parts of fatty alcohol polyoxyethylene ether; 5-12 parts of Fatty alcohol polyoxyethylene polyoxypropylene ether;10-18 parts of aliphatic alcohol polyethenoxy methyl ether;0.1-0.2 parts of second Ethylenediamine tetraacetic acid (EDTA);0.05-0.12 parts of calgon;0.08-0.12 parts of sodium tripolyphosphate;45-50 parts of deionized water.
A kind of cleaning agent containing nonionic surfactant includes according to the mass fraction:10 parts of non-ionic surface is lived Property agent;5 parts of ethanol amine;15 parts of butyl glycol ether;5 parts of fatty alcohol polyoxyethylene ether;10 parts of aliphatic alcohol polyethenoxy Polyethenoxy ether;15 parts of aliphatic alcohol polyethenoxy methyl ether;0.15 part of ethylenediamine tetra-acetic acid;0.1 part of calgon; 0.1 part of sodium tripolyphosphate;47.85 the deionized water of part.
In some embodiments, nonionic surfactant is polyethylene glycol 200, polyethylene glycol 400, polyethylene glycol 800, any one in Span 80, polysorbas20 and triton x-100.
Beneficial effect:
1) speed for washing dirt is fast, and molten dirt, which thoroughly, by experiment measures cleaning agent itself, to be had very strong reaction to dirt, divide Scavenging activity is dissipated or dissolved, dirt can be thoroughly removed very much;
2) drug used in the cleaning agent is cheap and easily-available, and based on production domesticization, cleaning is at low cost, does not cause excessive money Source consumes;
3) cleaning process will not remain insoluble matter in liquid crystal display surface, not generate new spot, not form new be harmful to In the coating of subsequent handling.
Specific implementation mode
The present invention is described in more detail below by embodiment.
Case study on implementation 1:
A kind of cleaning agent a containing nonionic surfactant includes according to the mass fraction:5 parts of polyethylene glycol 200s, 1 part Ethanol amine, 5 parts of butyl glycol ether, 1 part of fatty alcohol polyoxyethylene ether, 5 parts of Fatty alcohol polyoxyethylene polyoxypropylene ether, 10 parts of aliphatic alcohol polyethenoxy methyl ether, 0.1 part of ethylenediamine tetra-acetic acid, 0.05 part of calgon, the three of 0.08 part Polyphosphate sodium, 45 parts of deionized water.
Case study on implementation 2:
A kind of cleaning agent b containing nonionic surfactant includes according to the mass fraction:10 parts of polysorbas20s, 5 parts of second Hydramine, 15 parts of butyl glycol ether, 5 parts of fatty alcohol polyoxyethylene ether, 10 parts of Fatty alcohol polyoxyethylene polyoxypropylene ether, 15 The aliphatic alcohol polyethenoxy methyl ether, 0.15 part of ethylenediamine tetra-acetic acid, 0.1 part of calgon, 0.1 part of trimerization phosphorus of part Sour sodium, 47.85 parts of deionized water.
Case study on implementation 3:
A kind of cleaning agent c containing nonionic surfactant includes according to the mass fraction:20 parts of triton x-100s, 8 The ethanol amine, 20 parts of butyl glycol ether, 8 parts of fatty alcohol polyoxyethylene ether, 12 parts of aliphatic alcohol polyethenoxy polyoxy third of part Alkene ether, 18 parts of aliphatic alcohol polyethenoxy methyl ether, 0.2 part of ethylenediamine tetra-acetic acid, 0.12 part of calgon, 0.12 part Sodium tripolyphosphate, 50 parts of deionized water.
A kind of cleaning agent containing nonionic surfactant of case study on implementation is subjected to cleaning ability test, test method is such as Under:It by glass slide after simply cleaning, then is dried up after being rinsed with absolute ethyl alcohol, acetone, water, weighs, remember after drying to constant weight Record quality is M1;It is applied in test piece and spreads mechanical greasy dirt, be put into after being dried to constant weight in drier and weigh, record mass M 2;It will Test piece is put into cleaning agent, using intermittent stirring, stands 20~30min of washing.It takes out, is rinsed with water repeatedly, is put into drier It weighs after middle drying to constant weight, quality M3.Parallel determination 3 times, takes its average value.Cleaning ability evaluation is public with clean dirt rate Formula is calculated as M2-M3/M2-M1.
Test result is as follows shown in table:
Experimental subjects Clean dirt rate
Cleaning agent a 98.00%
Cleaning agent b 97.89%
Cleaning agent c 98.56%
From above-mentioned cleaning ability test in, it can be found that case study on implementation obtain it is a kind of containing the clear of nonionic surfactant Lotion clean dirt effect is good, and the cost of component raw material is low, pollution-free.
Presented above is only the preferred embodiment of the present invention, it is noted that those skilled in the art, not Under the premise of being detached from the invention design, various modifications and improvements can be made, these also should be regarded as the protection model of invention Within enclosing.

Claims (3)

1. a kind of cleaning agent containing nonionic surfactant, which is characterized in that include according to the mass fraction:
5-20 parts of nonionic surfactant;
1-8 parts of ethanol amine;
5-20 parts of butyl glycol ether;
1-8 parts of fatty alcohol polyoxyethylene ether;
5-12 parts of Fatty alcohol polyoxyethylene polyoxypropylene ether;
10-18 parts of aliphatic alcohol polyethenoxy methyl ether;
0.1-0.2 parts of ethylenediamine tetra-acetic acid;
0.05-0.12 parts of calgon;
0.08-0.12 parts of sodium tripolyphosphate;
45-50 parts of deionized water.
2. a kind of cleaning agent containing nonionic surfactant according to claim 1, which is characterized in that press mass parts Number is counted:
10 parts of nonionic surfactant;
5 parts of ethanol amine;
15 parts of butyl glycol ether;
5 parts of fatty alcohol polyoxyethylene ether;
10 parts of Fatty alcohol polyoxyethylene polyoxypropylene ether;
15 parts of aliphatic alcohol polyethenoxy methyl ether;
0.15 part of ethylenediamine tetra-acetic acid;
0.1 part of calgon;
0.1 part of sodium tripolyphosphate;
47.85 the deionized water of part.
3. a kind of cleaning agent containing nonionic surfactant according to claim 1 or 2, which is characterized in that described Nonionic surfactant is that polyethylene glycol 200, polyethylene glycol 400, polyethylene glycol-800, Span 80, polysorbas20 and Qula lead to X- Any one in 100.
CN201810271204.7A 2018-03-29 2018-03-29 A kind of cleaning agent containing nonionic surfactant Pending CN108441332A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810271204.7A CN108441332A (en) 2018-03-29 2018-03-29 A kind of cleaning agent containing nonionic surfactant

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810271204.7A CN108441332A (en) 2018-03-29 2018-03-29 A kind of cleaning agent containing nonionic surfactant

Publications (1)

Publication Number Publication Date
CN108441332A true CN108441332A (en) 2018-08-24

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CN201810271204.7A Pending CN108441332A (en) 2018-03-29 2018-03-29 A kind of cleaning agent containing nonionic surfactant

Country Status (1)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109645000A (en) * 2018-12-24 2019-04-19 南京科翼新材料有限公司 A kind of agricultural high-efficiency bleeding agent composition and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104774697A (en) * 2015-04-28 2015-07-15 苏州永创达电子有限公司 Liquid crystal cleaning agent
CN105418639A (en) * 2015-11-13 2016-03-23 南京理工大学 Method for synthesis of TEX under catalysis of nonionic surfactant
CN107488527A (en) * 2017-08-29 2017-12-19 河北宇天昊远纳米材料有限公司 A kind of liquid crystal panel glass cleaner

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104774697A (en) * 2015-04-28 2015-07-15 苏州永创达电子有限公司 Liquid crystal cleaning agent
CN105418639A (en) * 2015-11-13 2016-03-23 南京理工大学 Method for synthesis of TEX under catalysis of nonionic surfactant
CN107488527A (en) * 2017-08-29 2017-12-19 河北宇天昊远纳米材料有限公司 A kind of liquid crystal panel glass cleaner

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109645000A (en) * 2018-12-24 2019-04-19 南京科翼新材料有限公司 A kind of agricultural high-efficiency bleeding agent composition and preparation method thereof

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Application publication date: 20180824