CN108441036A - PVC waterproof coatings with anti-aging effect - Google Patents

PVC waterproof coatings with anti-aging effect Download PDF

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Publication number
CN108441036A
CN108441036A CN201810111637.6A CN201810111637A CN108441036A CN 108441036 A CN108441036 A CN 108441036A CN 201810111637 A CN201810111637 A CN 201810111637A CN 108441036 A CN108441036 A CN 108441036A
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CN
China
Prior art keywords
parts
waterproof coatings
pvc waterproof
pvc
aging effect
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201810111637.6A
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Chinese (zh)
Inventor
詹绍炬
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Zhi Chuang Space Enterprise Management Co., Ltd.
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Anhui Meng Guo Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Anhui Meng Guo Technology Co Ltd filed Critical Anhui Meng Guo Technology Co Ltd
Priority to CN201810111637.6A priority Critical patent/CN108441036A/en
Publication of CN108441036A publication Critical patent/CN108441036A/en
Withdrawn legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C09D127/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/38—Boron-containing compounds
    • C08K2003/387—Borates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses the PVC waterproof coatings with anti-aging effect, the raw material composition of the PVC waterproof coatings is by weight ratio：Polyvinyl chloride resin, 80~100 parts, cycloaliphatic epoxy resin, 20~35 parts, di-n-octyl phthalate, 10~25 parts, calcium carbonate, 15~30 parts, haloflex, 10~20 parts, zinc borate, 8~15 parts, magnesium stearate, 5~15 parts, phosphorous vinegar, 15~25 parts.The present invention need to only coat 0.1~0.3mm thickness by optimizing component formula, the PVC waterproof coatings provided, when use, with good water resistance, anti-ultraviolet aging performance, and not occurring coating shedding situation after 120 DEG C of heat ageing 240h, adhesive force is good, and service life is long.

Description

PVC waterproof coatings with anti-aging effect
Technical field
The present invention relates to a kind of PVC waterproof materials, and in particular to a kind of PVC waterproof coatings with anti-aging effect.
Background technology
Polyvinyl chloride (PVC) is most important in man-made polymer and uses most common one kind, and being primarily due to it has Prodigious variability can coordinate different purposes and needs during manufacturing PVC products, various plasticizers and addition is added Agent changes its physics and chemical property.After the maximum of PVC is characterized as addition liquid plasticizer, glass transition temperature will be opened Begin to decline, because semi-rigid can be prepared to the soft material with extensive spring rate in plasticization, this is soft PVC tool The reason of practicability.Existing PVC water-proof air-inflateds fabric is widely used in inflatable life jacket, biochemical defence suit, oxygen bag, inflation The fields such as pad, airbed, air dome, air bag, aircushion vehicle and Waterproof Breathable top grade dress material, and it is generally by base fabric and patch The PVC film in base fabric side is closed to form.In particular for air dome in use, needing that there is good antioxidation, but One layer of PVC film is only arranged in existing air dome fabric, and antioxidant effect is poor.
Invention content
The technical problem to be solved by the present invention is to：One layer of PVC film is only arranged in existing air dome fabric, anti-oxidant Effect is poor, and the present invention provides the PVC waterproof coatings with anti-aging effect to solve the above problems.
The present invention is achieved through the following technical solutions：
PVC waterproof coatings with anti-aging effect, the raw material of the PVC waterproof coatings forms is by weight ratio：
Polyvinyl chloride resin, 80~100 parts,
Cycloaliphatic epoxy resin, 20~35 parts,
Di-n-octyl phthalate, 10~25 parts,
Calcium carbonate, 15~30 parts,
Haloflex, 10~20 parts,
Zinc borate, 8~15 parts,
Magnesium stearate, 5~15 parts,
Phosphorous vinegar, 15~25 parts.
Preferably, the raw material composition of the PVC waterproof coatings is by weight ratio：
Polyvinyl chloride resin, 85~95 parts,
Cycloaliphatic epoxy resin, 25~32 parts,
Di-n-octyl phthalate, 12~20 parts,
Calcium carbonate, 18~25 parts,
Haloflex, 12~18 parts,
Zinc borate, 10~13 parts,
Magnesium stearate, 6~12 parts,
Phosphorous vinegar, 18~22 parts.
Preferably, the raw material composition of the PVC waterproof coatings is by weight ratio：
Polyvinyl chloride resin, 90 parts,
Cycloaliphatic epoxy resin, 28 parts,
Di-n-octyl phthalate, 18 parts,
Calcium carbonate, 20 parts,
Haloflex, 16 parts,
Zinc borate, 12 parts,
Magnesium stearate, 10 parts,
Phosphorous vinegar, 20 parts.
Preferably, the raw material composition of the PVC waterproof coatings further includes diisooctyl phthalate, the O-phthalic The mass values of sour di-n-octyl and diisooctyl phthalate are 1~3.5.
Preferably, the mass values of the di-n-octyl phthalate and diisooctyl phthalate are 2.
The present invention has the advantage that and advantageous effect：
The present invention need to only coat 0.1~0.3mm thickness by optimizing component formula, the PVC waterproof coatings provided, when use Degree has good water resistance, anti-ultraviolet aging performance, and does not occur coating shedding situation after 120 DEG C of heat ageing 240h, Adhesive force is good, and service life is long.
Specific implementation mode
To make the objectives, technical solutions, and advantages of the present invention clearer, with reference to embodiment, the present invention is made Further to be described in detail, exemplary embodiment of the invention and its explanation are only used for explaining the present invention, are not intended as to this The restriction of invention.
Embodiment 1
The present invention provides a kind of PVC waterproof coatings with anti-aging effect, and the raw material composition of the PVC waterproof coatings is pressed Weight is：
80~100 parts of polyvinyl chloride resin, 20~35 parts of cycloaliphatic epoxy resin, 10~25 parts of di-n-octyl phthalate, carbon 15~30 parts of sour calcium, 10~20 parts of haloflex, 8~15 parts of zinc borate, 5~15 parts of magnesium stearate, phosphorous vinegar 15~25 Part.The mass values of di-n-octyl phthalate and diisooctyl phthalate are 1~3.5.
Embodiment 2
The present invention provides a kind of PVC waterproof coatings with anti-aging effect, and the raw material composition of the PVC waterproof coatings is pressed Weight is：
80~100 parts of polyvinyl chloride resin, 20~35 parts of cycloaliphatic epoxy resin, 10~25 parts of di-n-octyl phthalate, carbon 15~30 parts of sour calcium, 10~20 parts of haloflex, 8~15 parts of zinc borate, 5~15 parts of magnesium stearate, phosphorous vinegar 15~25 Part.The mass values of di-n-octyl phthalate and diisooctyl phthalate are 1~3.5.
Embodiment 3
The present invention provides a kind of PVC waterproof coatings with anti-aging effect, and the raw material composition of the PVC waterproof coatings is pressed Weight is：
85~95 parts of polyvinyl chloride resin, 25~32 parts of cycloaliphatic epoxy resin, 12~20 parts of di-n-octyl phthalate, carbon 18~25 parts of sour calcium, 12~18 parts of haloflex, 10~13 parts of zinc borate, 6~12 parts of magnesium stearate, phosphorous vinegar 18~ 22 parts.The mass values of di-n-octyl phthalate and diisooctyl phthalate are 1~3.5.
Embodiment 4
The present invention provides a kind of PVC waterproof coatings with anti-aging effect, and the raw material composition of the PVC waterproof coatings is pressed Weight is：
85~95 parts of polyvinyl chloride resin, 25~32 parts of cycloaliphatic epoxy resin, 12~20 parts of di-n-octyl phthalate, carbon 18~25 parts of sour calcium, 12~18 parts of haloflex, 10~13 parts of zinc borate, 6~12 parts of magnesium stearate, phosphorous vinegar 18~ 22 parts.The mass values of di-n-octyl phthalate and diisooctyl phthalate are 1~3.5.
Embodiment 5
The present invention provides a kind of PVC waterproof coatings with anti-aging effect, and the raw material composition of the PVC waterproof coatings is pressed Weight is：
90 parts of polyvinyl chloride resin, 28 parts of cycloaliphatic epoxy resin, 18 parts of di-n-octyl phthalate, 20 parts of calcium carbonate, chlorination 16 parts of polyethylene, 12 parts of zinc borate, 10 parts of magnesium stearate, phosphorous acid, 20 parts.Di-n-octyl phthalate and phthalic acid The mass values of di-isooctyl are 2.
Above-described specific implementation mode has carried out further the purpose of the present invention, technical solution and advantageous effect It is described in detail, it should be understood that the foregoing is merely the specific implementation mode of the present invention, is not intended to limit the present invention Protection domain, all within the spirits and principles of the present invention, any modification, equivalent substitution, improvement and etc. done should all include Within protection scope of the present invention.

Claims (5)

1. the PVC waterproof coatings with anti-aging effect, which is characterized in that the raw material composition of the PVC waterproof coatings is by weight Part matches：
Polyvinyl chloride resin, 80~100 parts,
Cycloaliphatic epoxy resin, 20~35 parts,
Di-n-octyl phthalate, 10~25 parts,
Calcium carbonate, 15~30 parts,
Haloflex, 10~20 parts,
Zinc borate, 8~15 parts,
Magnesium stearate, 5~15 parts,
Phosphorous vinegar, 15~25 parts.
2. the PVC waterproof coatings according to claim 1 with anti-aging effect, which is characterized in that the PVC waterproofs apply The raw material of layer forms：
Polyvinyl chloride resin, 85~95 parts,
Cycloaliphatic epoxy resin, 25~32 parts,
Di-n-octyl phthalate, 12~20 parts,
Calcium carbonate, 18~25 parts,
Haloflex, 12~18 parts,
Zinc borate, 10~13 parts,
Magnesium stearate, 6~12 parts,
Phosphorous vinegar, 18~22 parts.
3. the PVC waterproof coatings according to claim 2 with anti-aging effect, which is characterized in that the PVC waterproofs apply The raw material of layer forms：
Polyvinyl chloride resin, 90 parts,
Cycloaliphatic epoxy resin, 28 parts,
Di-n-octyl phthalate, 18 parts,
Calcium carbonate, 20 parts,
Haloflex, 16 parts,
Zinc borate, 12 parts,
Magnesium stearate, 10 parts,
Phosphorous vinegar, 20 parts.
4. the PVC waterproof coatings according to claim 1 with anti-aging effect, which is characterized in that the PVC waterproofs apply The raw material composition of layer further includes diisooctyl phthalate, and the di-n-octyl phthalate and phthalic acid two are different pungent The mass values of ester are 1~3.5.
5. the PVC waterproof coatings according to claim 4 with anti-aging effect, which is characterized in that the O-phthalic The mass values of sour di-n-octyl and diisooctyl phthalate are 2.
CN201810111637.6A 2018-02-05 2018-02-05 PVC waterproof coatings with anti-aging effect Withdrawn CN108441036A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
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CN108441036A true CN108441036A (en) 2018-08-24

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113308939A (en) * 2021-03-26 2021-08-27 枣阳市惠氏包装有限公司 Method for improving moisture-proof, water-proof and sun-proof performance of environment-friendly packaging box

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101113272A (en) * 2006-07-28 2008-01-30 中宏（天津）实业有限公司 Process for manufacturing single-component roofing waterproof paint
CN102127867A (en) * 2011-04-01 2011-07-20 安徽柏拉图涂层织物有限公司 PVC (Polyvinyl Chloride) coating waterproof cloth
CN103756455A (en) * 2014-01-14 2014-04-30 北京海斯迪克新材料有限公司 High-temperature resistant strippable protection coating and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101113272A (en) * 2006-07-28 2008-01-30 中宏（天津）实业有限公司 Process for manufacturing single-component roofing waterproof paint
CN102127867A (en) * 2011-04-01 2011-07-20 安徽柏拉图涂层织物有限公司 PVC (Polyvinyl Chloride) coating waterproof cloth
CN103756455A (en) * 2014-01-14 2014-04-30 北京海斯迪克新材料有限公司 High-temperature resistant strippable protection coating and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
杨丽: "《常用塑料配方集》", 30 April 1990, 化学工业出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113308939A (en) * 2021-03-26 2021-08-27 枣阳市惠氏包装有限公司 Method for improving moisture-proof, water-proof and sun-proof performance of environment-friendly packaging box

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Effective date of registration: 20181211

Address after: 230000 Academician Building, Xiyou Road, Hefei High-tech Zone, Anhui Province, 17 Floors

Applicant after: Anhui Zhi Chuang Space Enterprise Management Co., Ltd.

Address before: 230000 Academician Building, Hefei High-tech District, Anhui Province

Applicant before: Anhui Meng Guo Technology Co., Ltd.

TA01 Transfer of patent application right
WW01 Invention patent application withdrawn after publication

Application publication date: 20180824

WW01 Invention patent application withdrawn after publication