CN108440935A - A kind of environment-friendly antibacterial plastics - Google Patents

A kind of environment-friendly antibacterial plastics Download PDF

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Publication number
CN108440935A
CN108440935A CN201810390449.1A CN201810390449A CN108440935A CN 108440935 A CN108440935 A CN 108440935A CN 201810390449 A CN201810390449 A CN 201810390449A CN 108440935 A CN108440935 A CN 108440935A
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CN
China
Prior art keywords
parts
environment
plastics
friendly antibacterial
antiseptic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810390449.1A
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Chinese (zh)
Inventor
王聘
宗妮
杨振翔
葛天航
薛勇
王建邦
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tianchang Xie Zheng Plastic Industry Co Ltd
Original Assignee
Tianchang Xie Zheng Plastic Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tianchang Xie Zheng Plastic Industry Co Ltd filed Critical Tianchang Xie Zheng Plastic Industry Co Ltd
Priority to CN201810390449.1A priority Critical patent/CN108440935A/en
Publication of CN108440935A publication Critical patent/CN108440935A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/262Alkali metal carbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention provides a kind of environment-friendly antibacterial plastics, is related to plastic manufacturing technology field.The plastics are by following parts by weight material composition:40 50 parts of makrolon, 15 20 parts of AS resins, 10 15 parts of cellulose, 8 12 parts of plants antimicrobial compound, 24 parts of calcium lactate, 13 parts of ethyl alcohol, 1.2 1.6 parts of dioctyl phthalate, 1.4 2.6 parts of antiseptic, 0.8 1.2 parts of age resister, 24 parts of fire retardant.The present invention uses plants antimicrobial compound and the dual antibacterial of antiseptic, can achieve the effect that environmental protection and high-efficiency antimicrobial, expands plastic applications range of the present invention.

Description

A kind of environment-friendly antibacterial plastics
Technical field
The present invention relates to plastic manufacturing technology fields, and in particular to a kind of environment-friendly antibacterial plastics.
Background technology
Plastics are a kind of synthetic materials, are one of the main materials that modern people use, with the development of the times at me Plastic industry of the state as one of light industry pillar industry, in recent years growth rate be always held at 10% or more, keeping While very fast development speed, economic benefit also has new raising.The above enterprise's output value total value of plastic article industry scale is light Third is occupied in 19 main industries of work, realizes sales ratio of industrial enterprises 97.8%, is higher than light industry average level.It is set from synthesis From the point of view of fat, plastics machinery and plastic products production, the powerful growth momentum of China Plastics Industry is all shown.
Nowadays plastics are because its price is suitable, the advantages that durable is facilitated to become very important a kind of material in daily life Material, and plastics material product has penetrated into each corner in life, including catering industry also greatly favors plastic products, But since traditional plastics itself contain noxious material, so food and drink at this stage and the used plastics of food packaging class are mostly spy Different plastics, but cost is higher mostly, and polluted as usage time increases easy growth bacterium.
Invention content
In order to achieve the above object, technical scheme of the present invention is achieved by the following technical programs:
A kind of environment-friendly antibacterial plastics, the plastics are made of the raw material of following parts by weight:40-50 parts of makrolon, AS trees 15-20 parts of fat, 10-15 parts of cellulose, 8-12 parts of plants antimicrobial compound, 2-4 parts of calcium lactate, 1-3 parts of ethyl alcohol, phthalic acid 1.2-1.6 parts of dioctyl ester, 1.4-2.6 parts of antiseptic, 0.8-1.2 parts of age resister, 2-4 parts of fire retardant.
Preferably, a kind of environment-friendly antibacterial plastics, the plastics are made of the raw material of following parts by weight:45 parts of makrolon, 18 parts of AS resins, 13 parts of cellulose, 10 parts of plants antimicrobial compound, 3 parts of calcium lactate, 2 parts of ethyl alcohol, dioctyl phthalate 1.4 parts, 2 parts of antiseptic, 1 part of age resister, 3 parts of fire retardant.
Wherein, the plants antimicrobial compound is the root of Dahurain angelica, peppermint, purslane powder equal proportion mixture, while the antibacterial Compound will first pass through alcohol leaching processing before use;The antiseptic is 6: 1 mixture of zinc oxide and lithium carbonate;It is described anti-aging Agent is dibutyl hydroxy toluene;The fire retardant is aluminium hydroxide.
The present invention provides a kind of environment-friendly antibacterial plastics, and advantage is compared with prior art:
(1) base stock that the present invention selects makrolon and AS resins are product plastics, more safety and environmental protection, and it is resistance to It is hot preferable.
(2) present invention uses plants antimicrobial compound and the dual anti-biotic material of antiseptic, can have while Environmental Safety Effect inhibits the growth of bacterium.
(3) present invention addition calcium lactate, dioctyl phthalate, dibutyl hydroxy toluene and aluminium hydroxide can be effective Increase the heat resistance of plastic product, and makes the heated unharmful substance volatilization of plastics of the present invention.
Specific implementation mode
In order to make the object, technical scheme and advantages of the embodiment of the invention clearer, with reference to the embodiment of the present invention pair Technical solution in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is a part of the invention Embodiment, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not making wound The every other embodiment obtained under the premise of the property made labour, shall fall within the protection scope of the present invention.
Embodiment 1
A kind of environment-friendly antibacterial plastics, the plastics are made of the raw material of following parts by weight:40 parts of makrolon, AS resins 15 Part, 10 parts of cellulose, 8 parts of plants antimicrobial compound, 2 parts of calcium lactate, 1 part of ethyl alcohol, 1.2 parts of dioctyl phthalate, antibacterial 1.4 parts of agent, 0.8 part of age resister, 2 parts of fire retardant.
The wherein described plants antimicrobial compound is that the root of Dahurain angelica, peppermint, purslane powder equal proportion mixture, while the antibacterial are multiple Alcohol leaching processing will be first passed through before use by closing object;The antiseptic is 6: 1 mixture of zinc oxide and lithium carbonate;The age resister For dibutyl hydroxy toluene;The fire retardant is aluminium hydroxide.
Embodiment 2
A kind of environment-friendly antibacterial plastics, the plastics are made of the raw material of following parts by weight:50 parts of makrolon, AS resins 20 Part, 15 parts of cellulose, 12 parts of plants antimicrobial compound, 4 parts of calcium lactate, 3 parts of ethyl alcohol, 1.6 parts of dioctyl phthalate, antibacterial 2.6 parts of agent, 1.2 parts of age resister, 4 parts of fire retardant.
The wherein described plants antimicrobial compound is that the root of Dahurain angelica, peppermint, purslane powder equal proportion mixture, while the antibacterial are multiple Alcohol leaching processing will be first passed through before use by closing object;The antiseptic is 6: 1 mixture of zinc oxide and lithium carbonate;The age resister For dibutyl hydroxy toluene;The fire retardant is aluminium hydroxide.
Embodiment 3
The antibiotic property of detection plastics of the present invention, selection abrasive lapping of the present invention prepare suitable Escherichia coli, golden yellow respectively at powder Color staphylococcus, streptococcus, Pseudomonas aeruginosa, Listeria, mould growth culture medium, and in configuration process be added this The plastic powders of invention, with culture medium substance weight: after 1 ratio mixing, it is thin plastic powders weight=2: to be inoculated with corresponding growth Bacterium is cultivated under optimum conditions, and the growing state of each bacterium, wherein this hair are observed in 1 month, 3 months, 5 months cycle time Bright plastics are made of following raw material:45 parts of makrolon, 18 parts of AS resins, 13 parts of cellulose, plants antimicrobial are compound 10 parts of object, 3 parts of calcium lactate, 2 parts of ethyl alcohol, 1.4 parts of dioctyl phthalate, 2 parts of antiseptic, 1 part of age resister, fire retardant 3 Part.And the plants antimicrobial compound is the root of Dahurain angelica, peppermint, purslane powder equal proportion mixture, while the antibiotic complex Alcohol leaching processing is first passed through before use;The antiseptic is 6: 1 mixture of zinc oxide and lithium carbonate;The age resister is two Butylated hydroxytoluene;The fire retardant is aluminium hydroxide.
Bacterial growth result such as following table:
Plastics of the present invention can effectively inhibit the growth of various bacteria as seen from the above table, and to large intestine bar common in life Bacterium, staphylococcus aureus and mould inhibition are especially prominent.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations;Although with reference to the foregoing embodiments Invention is explained in detail, it will be understood by those of ordinary skill in the art that:It still can be to aforementioned each implementation Technical solution recorded in example is modified or equivalent replacement of some of the technical features;And these modification or It replaces, the spirit and scope for various embodiments of the present invention technical solution that it does not separate the essence of the corresponding technical solution.

Claims (6)

1. a kind of environment-friendly antibacterial plastics, which is characterized in that the plastics are made of the raw material of following parts by weight:Makrolon 40- 50 parts, 15-20 parts of AS resins, 10-15 parts of cellulose, 8-12 parts of plants antimicrobial compound, 2-4 parts of calcium lactate, 1-3 parts of ethyl alcohol, 1.2-1.6 parts of dioctyl phthalate, 1.4-2.6 parts of antiseptic, 0.8-1.2 parts of age resister, 2-4 parts of fire retardant.
2. a kind of environment-friendly antibacterial plastics according to claim 1, which is characterized in that the plastics by following parts by weight original Material is made:45 parts of makrolon, 18 parts of AS resins, 13 parts of cellulose, 10 parts of plants antimicrobial compound, 3 parts of calcium lactate, ethyl alcohol 2 Part, 1.4 parts of dioctyl phthalate, 2 parts of antiseptic, 1 part of age resister, 3 parts of fire retardant.
3. a kind of environment-friendly antibacterial plastics according to claim 1-2, it is characterised in that:The plants antimicrobial compound is white The root of Dahurian angelica, peppermint, purslane powder equal proportion mixture, while the antibiotic complex will first pass through alcohol leaching processing before use.
4. a kind of environment-friendly antibacterial plastics according to claim 1-2, it is characterised in that:The antiseptic is zinc oxide and carbon 6: 1 mixture of sour lithium.
5. a kind of environment-friendly antibacterial plastics according to claim 1-2, which is characterized in that the age resister is dibutyl hydroxyl Base toluene.
6. a kind of environment-friendly antibacterial plastics according to claim 1-2, which is characterized in that the fire retardant is aluminium hydroxide.
CN201810390449.1A 2018-04-27 2018-04-27 A kind of environment-friendly antibacterial plastics Pending CN108440935A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810390449.1A CN108440935A (en) 2018-04-27 2018-04-27 A kind of environment-friendly antibacterial plastics

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CN201810390449.1A CN108440935A (en) 2018-04-27 2018-04-27 A kind of environment-friendly antibacterial plastics

Publications (1)

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CN108440935A true CN108440935A (en) 2018-08-24

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113881264A (en) * 2021-11-03 2022-01-04 上海马利画材股份有限公司 Pigment composition and preparation method and application thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103937195A (en) * 2014-05-12 2014-07-23 宁波高新区卓尔化工科技有限公司 Toughening engineering plastic and preparation method thereof
CN106118009A (en) * 2016-07-12 2016-11-16 新昌县绿泰塑胶有限公司 A kind of Antibacterial flame retardant plastic

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103937195A (en) * 2014-05-12 2014-07-23 宁波高新区卓尔化工科技有限公司 Toughening engineering plastic and preparation method thereof
CN106118009A (en) * 2016-07-12 2016-11-16 新昌县绿泰塑胶有限公司 A kind of Antibacterial flame retardant plastic

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
商成杰: "《功能纺织品》", 31 July 2006, 中国纺织出版社 *
段予忠等: "《塑料母料生产及引用技术》", 31 August 1999, 中国轻工业出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113881264A (en) * 2021-11-03 2022-01-04 上海马利画材股份有限公司 Pigment composition and preparation method and application thereof

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Application publication date: 20180824

RJ01 Rejection of invention patent application after publication