CN108439798A - 一种抗菌陶瓷及其制备方法 - Google Patents

一种抗菌陶瓷及其制备方法 Download PDF

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CN108439798A
CN108439798A CN201810269071.XA CN201810269071A CN108439798A CN 108439798 A CN108439798 A CN 108439798A CN 201810269071 A CN201810269071 A CN 201810269071A CN 108439798 A CN108439798 A CN 108439798A
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王维娜
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Abstract

本发明公开了一种抗菌陶瓷，由以下按照重量份的原料组成：大理石8‑15份、硅石32‑39份、钛白粉4‑7份、长石12‑23份、氧化铝6‑9份、碳酸钡3‑7份、碳酸钠2‑5份、熟滑石1‑3份、三氧化二银1‑5份、纳米锌6‑12份、超细氧化钛粉体24‑42份、氧化镁8‑26份、超细电气石粉体2‑9份、氧化钾6‑13份和微米沸石23‑38份。本发明还公布了该陶瓷的制备方法。本发明制备的抗菌陶瓷在用餐后无需清洁剂清洗，只需少量自来水就可以彻底清除油污，使用1000次后不会滋生水垢，扔可以保持表面的洁净；该陶瓷由于加入银元素并且可以发射远红外线，可以高效抑制和灭杀细菌，抑制霉菌的产生。

Description

一种抗菌陶瓷及其制备方法
本申请为申请号2016103136977、申请日2016年05月12日、发明名称“一种抗菌陶瓷及其制备方法”的分案申请。
技术领域
本发明涉及一种陶瓷，具体是一种抗菌陶瓷。
背景技术
随着工业的发展和人类活动的日益频繁，城市和乡镇的污染越来越严重，由此滋生的细菌越来越多，各种各样的疾病也越来越多。陶瓷制品具有类似于金属的强度、丰富的装饰效果、良好的耐磨性、化学稳定性和耐腐蚀性，陶瓷制品广泛进入日常生活，深受人们的喜爱。但是近年来，消费者对于日用陶瓷、卫生陶瓷和建筑陶瓷的性能要求不断提高，不但要求产品美观、实用和耐磨，还要求具有环保和健康的功能。但是传统陶瓷产品的表面为凹凸不平的，容易导致细菌和污染物的粘附；传统陶瓷以白色为主，釉面只采用硅酸锆起白色作用，并无其他功能，而且传统陶瓷釉面在放大镜下是凹凸不平的，使得污垢和细菌易于躲藏，进而繁殖。
发明内容
本发明的目的在于提供一种抗菌陶瓷，以解决上述背景技术中提出的问题。
为实现上述目的，本发明提供如下技术方案：
一种抗菌陶瓷，由以下按照重量份的原料组成：大理石8-15份、硅石32-39份、钛白粉4-7份、长石12-23份、氧化铝6-9份、碳酸钡3-7份、碳酸钠2-5份、熟滑石1-3份、三氧化二银1-5份、纳米锌6-12份、超细氧化钛粉体24-42份、氧化镁8-26份、超细电气石粉体2-9份、氧化钾6-13份和微米沸石23-38份，所述抗菌陶瓷的制备方法，具体步骤如下：
步骤一，将大理石、硅石、钛白粉、长石、氧化铝、碳酸钡、碳酸钠、熟滑石和三氧化二银在球磨机中球磨5-10小时混合均匀，采用振动筛过滤，经过1-2天的时间沉淀使得杂质沉在底层，过滤后，得到陶瓷釉料；
步骤二，将纳米锌、超细氧化钛粉体、氧化镁和氧化钾在混合均匀加水在50-75摄氏度的烘干房放置1-2天，在烧结窑900-1060摄氏度下煅烧10-15小时，取出后再混合超细电气石粉体和微米沸石加水混合均匀后在窑温960-1150摄氏度下煅烧12-18小时，取出成品；
步骤三，将陶瓷釉料涂覆在成品上，在温度为1100-1200摄氏度的温度下烧结1-2天，得到最终产品。
作为本发明进一步的方案：由以下按照重量份的原料组成：大理石11-15份、硅石35-39份、钛白粉5-7份、长石16-23份、氧化铝7-9份、碳酸钡4-7份、碳酸钠3-5份、熟滑石2-3份、三氧化二银2-5份、纳米锌8-12份、超细氧化钛粉体29-42份、氧化镁14-26份、超细电气石粉体5-9份、氧化钾9-13份和微米沸石28-38份。
作为本发明进一步的方案：由以下按照重量份的原料组成：大理石13份、硅石36份、钛白粉6份、长石19份、氧化铝8份、碳酸钡6份、碳酸钠4份、熟滑石3份、三氧化二银4份、纳米锌10份、超细氧化钛粉体36份、氧化镁21份、超细电气石粉体7份、氧化钾12份和微米沸石34份。
与现有技术相比，本发明的有益效果是：本发明制备的抗菌陶瓷在用餐后无需清洁剂清洗，只需少量自来水就可以彻底清除油污，使用1000次后不会滋生水垢，扔可以保持表面的洁净；该陶瓷由于加入银元素并且可以发射远红外线，可以高效抑制和灭杀细菌，抑制霉菌的产生。
具体实施方式
下面结合具体实施方式对本专利的技术方案作进一步详细地说明。
实施例1
一种抗菌陶瓷，由以下按照重量份的原料组成：大理石8份、硅石32份、钛白粉4份、长石12份、氧化铝6份、碳酸钡3份、碳酸钠2份、熟滑石1份、三氧化二银1份、纳米锌6份、超细氧化钛粉体24份、氧化镁8份、超细电气石粉体2份、氧化钾6份和微米沸石23份。
所述抗菌陶瓷的制备方法，具体步骤如下：
步骤一，将大理石、硅石、钛白粉、长石、氧化铝、碳酸钡、碳酸钠、熟滑石和三氧化二银在球磨机中球磨5小时混合均匀，采用振动筛过滤，经过1天的时间沉淀使得杂质沉在底层，过滤后，得到陶瓷釉料；
步骤二，将纳米锌、超细氧化钛粉体、氧化镁和氧化钾在混合均匀加水在50摄氏度的烘干房放置1天，在烧结窑900摄氏度下煅烧10小时，取出后再混合超细电气石粉体和微米沸石加水混合均匀后在窑温960摄氏度下煅烧12小时，取出成品；
步骤三，将陶瓷釉料涂覆在成品上，在温度为1100摄氏度的温度下烧结1天，得到最终产品。
实施例2
一种抗菌陶瓷，由以下按照重量份的原料组成：大理石11份、硅石35份、钛白粉5份、长石16份、氧化铝7份、碳酸钡4份、碳酸钠3份、熟滑石2份、三氧化二银2份、纳米锌8份、超细氧化钛粉体29份、氧化镁14份、超细电气石粉体5份、氧化钾9份和微米沸石28份。
所述抗菌陶瓷的制备方法，具体步骤如下：
步骤一，将大理石、硅石、钛白粉、长石、氧化铝、碳酸钡、碳酸钠、熟滑石和三氧化二银在球磨机中球磨7小时混合均匀，采用振动筛过滤，经过1天的时间沉淀使得杂质沉在底层，过滤后，得到陶瓷釉料；
步骤二，将纳米锌、超细氧化钛粉体、氧化镁和氧化钾在混合均匀加水在62摄氏度的烘干房放置1天，在烧结窑960摄氏度下煅烧12小时，取出后再混合超细电气石粉体和微米沸石加水混合均匀后在窑温1030摄氏度下煅烧15小时，取出成品；
步骤三，将陶瓷釉料涂覆在成品上，在温度为1130摄氏度的温度下烧结1天，得到最终产品。
实施例3
一种抗菌陶瓷，由以下按照重量份的原料组成：大理石13份、硅石36份、钛白粉6份、长石19份、氧化铝8份、碳酸钡6份、碳酸钠4份、熟滑石3份、三氧化二银4份、纳米锌10份、超细氧化钛粉体36份、氧化镁21份、超细电气石粉体7份、氧化钾12份和微米沸石34份。
所述抗菌陶瓷的制备方法，具体步骤如下：
步骤一，将大理石、硅石、钛白粉、长石、氧化铝、碳酸钡、碳酸钠、熟滑石和三氧化二银在球磨机中球磨9小时混合均匀，采用振动筛过滤，经过2天的时间沉淀使得杂质沉在底层，过滤后，得到陶瓷釉料；
步骤二，将纳米锌、超细氧化钛粉体、氧化镁和氧化钾在混合均匀加水在69摄氏度的烘干房放置2天，在烧结窑1020摄氏度下煅烧14小时，取出后再混合超细电气石粉体和微米沸石加水混合均匀后在窑温1130摄氏度下煅烧17小时，取出成品；
步骤三，将陶瓷釉料涂覆在成品上，在温度为1180摄氏度的温度下烧结2天，得到最终产品。
实施例4
一种抗菌陶瓷，由以下按照重量份的原料组成：大理石15份、硅石39份、钛白粉7份、长石23份、氧化铝9份、碳酸钡7份、碳酸钠5份、熟滑石3份、三氧化二银5份、纳米锌12份、超细氧化钛粉体42份、氧化镁26份、超细电气石粉体9份、氧化钾13份和微米沸石38份。
所述抗菌陶瓷的制备方法，具体步骤如下：
步骤一，将大理石、硅石、钛白粉、长石、氧化铝、碳酸钡、碳酸钠、熟滑石和三氧化二银在球磨机中球磨10小时混合均匀，采用振动筛过滤，经过2天的时间沉淀使得杂质沉在底层，过滤后，得到陶瓷釉料；
步骤二，将纳米锌、超细氧化钛粉体、氧化镁和氧化钾在混合均匀加水在75摄氏度的烘干房放置2天，在烧结窑1060摄氏度下煅烧15小时，取出后再混合超细电气石粉体和微米沸石加水混合均匀后在窑温1150摄氏度下煅烧18小时，取出成品；
步骤三，将陶瓷釉料涂覆在成品上，在温度为1200摄氏度的温度下烧结2天，得到最终产品。
实施例1-4利用纳米锌和激活的银离子起到广谱抗菌，利用超细氧化钛粉体、超细电气石粉体和微米沸石来产生远红外线和负离子、矿物质材料溶出人体所需的微量元素，经检测，在 24 小时内，对大肠杆菌的抗菌率大于 95％，在 24 小时内，对金黄色葡萄球
菌的抗菌率大于 95％。
上面对本专利的较佳实施方式作了详细说明，但是本专利并不限于上述实施方式，在本领域的普通技术人员所具备的知识范围内，还可以在不脱离本专利宗旨的前提下做出各种变化。

Claims (3)

1.一种抗菌陶瓷的制备方法，其特征在于，所述的抗菌陶瓷，由以下按照重量份的原料组成：大理石8-15份、硅石32-39份、钛白粉4-7份、长石12-23份、氧化铝6-9份、碳酸钡3-7份、碳酸钠2-5份、熟滑石1-3份、三氧化二银1-5份、纳米锌6-12份、超细氧化钛粉体24-42份、氧化镁8-26份、超细电气石粉体2-9份、氧化钾6-13份和微米沸石23-38份，所述抗菌陶瓷的制备方法，具体步骤如下：
步骤一，将大理石、硅石、钛白粉、长石、氧化铝、碳酸钡、碳酸钠、熟滑石和三氧化二银在球磨机中球磨5-10小时混合均匀，采用振动筛过滤，经过1-2天的时间沉淀使得杂质沉在底层，过滤后，得到陶瓷釉料；
步骤二，将纳米锌、超细氧化钛粉体、氧化镁和氧化钾在混合均匀加水在50-75摄氏度的烘干房放置1-2天，在烧结窑900-1060摄氏度下煅烧10-15小时，取出后再混合超细电气石粉体和微米沸石加水混合均匀后在窑温960-1150摄氏度下煅烧12-18小时，取出成品；
步骤三，将陶瓷釉料涂覆在成品上，在温度为1100-1200摄氏度的温度下烧结1-2天，得到最终产品。
2.根据权利要求1所述的抗菌陶瓷的制备方法，其特征在于，所述的抗菌陶瓷，由以下按照重量份的原料组成：大理石11-15份、硅石35-39份、钛白粉5-7份、长石16-23份、氧化铝7-9份、碳酸钡4-7份、碳酸钠3-5份、熟滑石2-3份、三氧化二银2-5份、纳米锌8-12份、超细氧化钛粉体29-42份、氧化镁14-26份、超细电气石粉体5-9份、氧化钾9-13份和微米沸石28-38份。
3.根据权利要求1所述的抗菌陶瓷的制备方法，其特征在于，所述的抗菌陶瓷，由以下按照重量份的原料组成：大理石13份、硅石36份、钛白粉6份、长石19份、氧化铝8份、碳酸钡6份、碳酸钠4份、熟滑石3份、三氧化二银4份、纳米锌10份、超细氧化钛粉体36份、氧化镁21份、超细电气石粉体7份、氧化钾12份和微米沸石34份。
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