CN108439743A - Biogas residue deep dehydration and the method for desiccation after a kind of anaerobic digestion - Google Patents

Biogas residue deep dehydration and the method for desiccation after a kind of anaerobic digestion Download PDF

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Publication number
CN108439743A
CN108439743A CN201810491670.6A CN201810491670A CN108439743A CN 108439743 A CN108439743 A CN 108439743A CN 201810491670 A CN201810491670 A CN 201810491670A CN 108439743 A CN108439743 A CN 108439743A
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biogas residue
deep dehydration
desiccation
dehydration
solar energy
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曹波
刘�东
杨晶歆
郭雪青
陈晨
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ZHENJIANG WATER Co
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ZHENJIANG WATER Co
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/006Electrochemical treatment, e.g. electro-oxidation or electro-osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/14Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Treatment Of Sludge (AREA)

Abstract

The invention belongs to field of environment protection, biogas residue deep dehydration and the method for desiccation after a kind of anaerobic digestion are provided, is included the following steps:a)Pretreatment:The solid content for entering the biogas residue of pyrohydrolysis system is adjusted using excess sludge, solid content is adjusted to 8% or more, and into high-temperature-hot-water solution device, hydrolysis temperature is 150 ~ 170 DEG C, hydrolysis time is 30 40min, and the biogas residue after hydrolysis enters deep dehydration after heat exchange is cooling;b)Deep dehydration:Flocculant PAM is added, moisture content is dropped to 60% or less by 92% using electrolysis drying process;c)Solar energy desiccation:Biogas residue after deep dehydration is entered into solar energy desiccation factory moisture content after solar energy desiccation by screw conveyor and is down to 40% hereinafter, the above percentage is mass percent.The present invention improves the efficiency of biogas residue dehydration, and pretreatment can kill all pathogenic bacteria, be conducive to its recycling, and operating cost is low.

Description

一种厌氧消化后沼渣深度脱水以及干化的方法A method for deep dehydration and drying of biogas residue after anaerobic digestion

技术领域technical field

本发明属于环保领域,涉及一种厌氧消化后沼渣深度脱水以及干化的方法。The invention belongs to the field of environmental protection and relates to a method for deep dehydration and drying of biogas residue after anaerobic digestion.

背景技术Background technique

随着污水处理总量的逐年增加,污泥的处理量也逐年增加,污泥的处理处置成为亟待解决的重要问题。污泥厌氧消化技术成为污泥无害化、减量化、资源化的有效途径之一,而厌氧消化后沼渣均用于园林绿化等用途,沼渣深度脱水成为沼渣资源化利用的基础。As the total amount of sewage treatment increases year by year, the amount of sludge treatment also increases year by year, and the treatment and disposal of sludge has become an important problem to be solved urgently. Sludge anaerobic digestion technology has become one of the effective ways to make sludge harmless, reduce, and recycle sludge. After anaerobic digestion, biogas residues are used for landscaping and other purposes. Deep dehydration of biogas residues becomes a resource utilization of biogas residues. The basics.

目前,沼渣深度脱水的方法主要包括三种:太阳能干化占地面积较大、依赖气候条件、干化时间长,干化的效率较低;化学调理后板框压滤需要加入石灰、铁盐等无机絮凝剂改变污泥的特性,该方法会对后续的资源化产生一定的影响;高压脉冲电解脱水能耗较高,脱水成本高;板框脱水自动化程度不高,脱水规模有限。At present, there are mainly three methods for deep dehydration of biogas residues: solar drying takes up a large area, depends on climatic conditions, takes a long time to dry, and has low drying efficiency; after chemical conditioning, plate and frame filter presses need to add lime, iron, etc. Inorganic flocculants such as salt change the characteristics of sludge, and this method will have a certain impact on subsequent resource utilization; high-voltage pulse electrolytic dehydration consumes a lot of energy and dewaters high costs; the degree of automation of plate and frame dehydration is not high, and the scale of dehydration is limited.

发明内容Contents of the invention

1、所要解决的技术问题:1. Technical problems to be solved:

现有的沼渣深度脱水的方法,太能干化占地面大,依赖气候条件,高压脉冲电解脱水能耗较高,脱水成本高。In the existing method of deep dehydration of biogas residues, Taineng drying takes up a large area and depends on climatic conditions. High-voltage pulse electrolytic dehydration consumes a lot of energy and dehydration costs are high.

2、技术方案:2. Technical solution:

本发明针对现有沼渣脱水方法的不足,提供一种厌氧消化后沼渣深度脱水以及干化的方法,包括以下步骤:a)预处理:利用剩余污泥对进入热水解系统的沼渣的含固率进行调节,含固率调至8%以上,进入高温热水解装置,水解温度为150~170℃,水解时间为30-40min,水解后的沼渣经过换热冷却后进入深度脱水;b)深度脱水:加入絮凝剂PAM,采用电解干化工艺将含水率由92%降到60%以下;c)太阳能干化:将深度脱水后的沼渣通过螺旋输送机进入太阳能干化厂经过太阳能干化后含水率降至40%以下,以上百分比为质量百分比。Aiming at the deficiencies of the existing biogas residue dehydration methods, the present invention provides a method for deep dehydration and drying of biogas residue after anaerobic digestion, including the following steps: a) Pretreatment: use the remaining sludge to dehydrate the biogas residue entering the thermal hydrolysis system The solid content of the slag is adjusted, the solid content is adjusted to more than 8%, and it enters the high-temperature thermal hydrolysis device. The hydrolysis temperature is 150-170°C, and the hydrolysis time is 30-40min. Deep dehydration; b) Deep dehydration: add flocculant PAM, and use electrolytic drying process to reduce the water content from 92% to below 60%; c) Solar drying: The biogas residue after deep dehydration enters the solar drying process through a screw conveyor. The moisture content of the chemical plant is reduced to below 40% after solar drying, and the above percentages are mass percentages.

进一步的,在深度脱水中加入的PAM为污泥干重的6/10000-7/10000。Further, the PAM added in the deep dehydration is 6/10000-7/10000 of the dry weight of the sludge.

3、有益效果:3. Beneficial effects:

本发明提供的一种厌氧消化后沼渣深度脱水以及干化的方法通过高温热水解预处理,破坏沼渣的絮体及细胞结构,沼渣中被胞外聚合物吸附的水分和胞内结合水释放出来,更多的结合水转化为自由水,降低了后续沼渣脱水的难度;电解干化工艺整个环节全自动控制,连续运行,工作效率高,运行成本低;电解过程中会产生80℃左右的温度,沼渣进入太阳能干化厂后会带有一定的温度,沼渣的水分极易挥发,无需外加辅助热源进行伴热,显著提升了太阳能干化的效率。The method for deep dehydration and drying of biogas residues after anaerobic digestion provided by the present invention uses high-temperature thermal hydrolysis pretreatment to destroy the floc and cell structure of biogas residues, and the water and cells in biogas residues absorbed by extracellular polymers The internal bound water is released, and more bound water is converted into free water, which reduces the difficulty of subsequent biogas residue dehydration; the whole process of electrolytic drying process is fully automatic control, continuous operation, high work efficiency, low operating cost; electrolysis process will A temperature of about 80°C is generated, and the biogas residue will have a certain temperature after entering the solar drying plant. The moisture in the biogas residue is very volatile, and there is no need for an external auxiliary heat source for heat tracing, which significantly improves the efficiency of solar drying.

具体实施方式Detailed ways

下面通过实施例来对本发明进行详细说明。The present invention will be described in detail below by way of examples.

本发明提供一种厌氧消化后沼渣深度脱水以及干化的方法,包括以下步骤:a)预处理:利用剩余污泥对进入热水解系统的沼渣的含固率进行调节,含固率调至8%以上,进入高温热水解装置,水解温度为150~170℃,水解时间为30-40min,水解后的沼渣经过换热冷却后进入深度脱水;采用高温热水解工艺进行预处理,通过高温热水解预处理,破坏沼渣的絮体及细胞结构,沼渣中被胞外聚合物吸附的水分和胞内结合水释放出来,更多的结合水转化为自由水,降低了后续沼渣脱水的难度。The invention provides a method for deep dehydration and drying of biogas residues after anaerobic digestion, including the following steps: a) Pretreatment: using excess sludge to adjust the solid content rate of biogas residues entering the thermal hydrolysis system, and the solid content Adjust the rate to above 8%, enter the high-temperature thermal hydrolysis device, the hydrolysis temperature is 150-170 ℃, and the hydrolysis time is 30-40min. Pretreatment, through high-temperature thermal hydrolysis pretreatment, destroys the floc and cell structure of the biogas residue, releases the water absorbed by the extracellular polymer and the bound water in the cell, and converts more bound water into free water. The difficulty of subsequent biogas residue dehydration is reduced.

b)深度脱水:加入絮凝剂PAM,采用电解干化将含水率由92%降到60%以下; c)太阳能干化:将深度脱水后的沼渣通过螺旋输送机进入太阳能干化厂经过太阳能干化后含水率降至40%以下,以上百分比为质量百分比。在深度脱水的电解干化中会产生80℃左右的温度,沼渣进入太阳能干化厂后会带有一定的温度,沼渣的水分极易挥发,无需外加辅助热源进行伴热,显著提升了太阳能干化的效率。b) Deep dehydration: add flocculant PAM, and use electrolytic drying to reduce the moisture content from 92% to below 60%; c) Solar drying: the biogas residue after deep dehydration enters the solar drying plant through a screw conveyor and passes through the solar energy. After drying, the moisture content drops below 40%, and the above percentages are mass percentages. In the electrolytic drying of deep dehydration, a temperature of about 80°C will be generated. After entering the solar drying plant, the biogas residue will have a certain temperature. The efficiency of solar drying.

实施例1Example 1

一种厌氧消化后沼渣深度脱水以及干化的方法,包括以下步骤:a)预处理:利用剩余污泥对进入热水解系统的沼渣的含固率进行调节,含固率调至8%以上,进入高温热水解装置,水解温度为150℃,水解时间为30min,水解后的沼渣经过换热冷却后进入深度脱水;b)深度脱水:加入絮凝剂PAM,采用电解干化工艺将含水率降到58%;c)太阳能干化:将深度脱水后的沼渣通过螺旋输送机进入太阳能干化厂经过太阳能干化后含水率降至38%,以上百分比为质量百分比。A method for deep dehydration and drying of biogas residues after anaerobic digestion, comprising the following steps: a) Pretreatment: using excess sludge to adjust the solid content of biogas residues entering the thermal hydrolysis system, the solid content is adjusted to More than 8%, enter the high-temperature thermal hydrolysis device, the hydrolysis temperature is 150°C, and the hydrolysis time is 30 minutes. The hydrolyzed biogas residue enters deep dehydration after heat exchange and cooling; b) Deep dehydration: add flocculant PAM, and use electrolytic drying The process reduces the moisture content to 58%; c) Solar drying: the deeply dehydrated biogas residue enters the solar drying plant through a screw conveyor and the moisture content drops to 38% after solar drying, the above percentages are mass percentages.

在深度脱水中加入的PAM为污泥干重的7/10000。The PAM added in the deep dehydration is 7/10000 of the dry weight of the sludge.

实施例2Example 2

一种厌氧消化后沼渣深度脱水以及干化的方法,包括以下步骤:a)预处理:利用剩余污泥对进入热水解系统的沼渣的含固率进行调节,含固率调至8%以上,进入高温热水解装置,水解温度为170℃,水解时间为40min,水解后的沼渣经过换热冷却后进入深度脱水;b)深度脱水:加入絮凝剂PAM,采用电解干化工艺将含水率降到56%;c)太阳能干化:将深度脱水后的沼渣通过螺旋输送机进入太阳能干化厂经过太阳能干化后含水率降至36%,以上百分比为质量百分比。A method for deep dehydration and drying of biogas residues after anaerobic digestion, comprising the following steps: a) Pretreatment: using excess sludge to adjust the solid content of biogas residues entering the thermal hydrolysis system, the solid content is adjusted to More than 8%, enter the high-temperature thermal hydrolysis device, the hydrolysis temperature is 170°C, and the hydrolysis time is 40min. The hydrolyzed biogas residue enters deep dehydration after heat exchange and cooling; b) deep dehydration: add flocculant PAM, and use electrolytic drying The process reduces the moisture content to 56%; c) Solar drying: the deeply dehydrated biogas residue enters the solar drying plant through a screw conveyor and the moisture content drops to 36% after solar drying, the above percentages are mass percentages.

在深度脱水中加入的PAM为污泥干重的6/10000。The PAM added in the deep dehydration is 6/10000 of the dry weight of the sludge.

虽然本发明已以较佳实施例公开如上,但它们并不是用来限定本发明的,任何熟习此技艺者,在不脱离本发明之精神和范围内,自当可作各种变化或润饰,因此本发明的保护范围应当以本申请的权利要求保护范围所界定的为准。Although the present invention has been disclosed as above with preferred embodiments, they are not intended to limit the present invention. Any skilled person can make various changes or modifications without departing from the spirit and scope of the present invention. Therefore, the protection scope of the present invention should be defined by the protection scope of the claims of the present application.

Claims (2)

1. biogas residue deep dehydration and the method for desiccation, include the following steps after anaerobic digestion:a)Pretreatment:Utilize excess sludge The solid content of biogas residue to entering pyrohydrolysis system is adjusted, and solid content is adjusted to 8% or more, into high-temperature-hot-water solution device, water It is 150 ~ 170 DEG C, hydrolysis time 30-40min to solve temperature, and the biogas residue after hydrolysis enters deep dehydration after heat exchange is cooling; b)Deep dehydration:Flocculant PAM is added, moisture content is dropped to 60% or less by 92% using electrolysis drying process;c)The sun is competent Change:Biogas residue after deep dehydration is entered solar energy desiccation factory moisture content after solar energy desiccation by screw conveyor to be down to 40% hereinafter, the above percentage is mass percent.
2. the method as described in claim 1, the PAM being added in deep dehydration is the 6/10000-7/10000 of mud dry weight.
CN201810491670.6A 2018-05-22 2018-05-22 Biogas residue deep dehydration and the method for desiccation after a kind of anaerobic digestion Withdrawn CN108439743A (en)

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CN113683279A (en) * 2021-09-09 2021-11-23 北京尚水清源水处理技术有限公司 Dehydration method of thermal hydrolysis anaerobic digestion sludge

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Application publication date: 20180824